Articles:
2-methyl-2-butenal
Notes:
Isol. from chives (Allium schoenoprasum). Also present in onion, tomato, cheeses, Scotch, spearmint oil, tangerine peel oil, cooked chicken and other foods. Flavour ingredient
trans-2-Methyl-2-butenal is an organic compound with the formula CH3CH=C(CH3)CHO. This colorless liquid is a building block in organic synthesis. It is an ?,?-unsaturated aldehyde related to the better known crotonaldehyde.
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BOC Sciences Best of Chemicals Supplier Quality supplier of research chemicals and biochemicals including inhibitors, building blocks, GMP Products, impurities and metabolites, APIs for Veterinary, Natural Compounds, ADCs, Stem Cell Molecule and chiral compounds. BOC Sciences provides a wide range of services to support the pharmaceutical industry through all stages of drug discovery including Custom Synthesis of those chemicals that are not in stock, Isotope Labeling Service, Chiral Synthesis and Resolution, Bioconjugation, PEGylation services, analytical services. BOC Sciences is a brand of BOCSCI Inc. We leverage our wide spectrum of business in the fields of development, manufacturing, marketing, and distribution to help you make best-informed decisions tailored to your evolving needs for premium chemicals. Our complete suite of CRO services spans the entire molecule development pipeline including contract research for target identification, building blocks, compound synthesis, biochemical and cellular analysis, preclinical animal tests, and clinical studies. Email: Marketing US Email: Marketing Email: Sales US Email: Sales Voice: 1-631-485-4226 Fax: 1-631-614-7828 US Voice: 1-631-485-4226 US Fax: 1-631-614-7828 Europe 44-203-286-1088 Facebook Twitter Linkedin Blog Get the App! Product(s): 1115-11-3 Tiglic aldehyde
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CJ Latta & Associates, LLC Extensive Line Aromatic Chemicals and Organic Acids. CJ Latta & Associates is a distributor of specialty aromatics and organic acids used in the formulation of flavors and fragrance manufactured worldwide. We pride ourselves on our reputation for, fair pricing, quality and reliability. We’ve built our business on successfully sourcing and developing many challenging specialty chemicals and fine ingredients for our clients. Email: Info US Email: Chip Latta Email: Sales US Email: Chip Latta Voice: (630) 240-8079 Product(s): TIGLIC ALDEHYDE
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Penta International Corporation Chemistry innovation At Penta, our products and services help businesses do business better. For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes. US Email: Technical Services US Email: Sales US Voice: (973) 740-2300 US Fax: (973) 740-1839 Product(s): 13-30300 2-METHYL-2-BUTENAL
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Sigma-Aldrich Complete Supply Chain The perfect blend of products and services that bring your creativity to life. Sigma-Aldrich is a leading Life Science and High Technology company dedicated to providing high-quality, safe and certified flavor ingredients with transparent and easily accessible documentation to customers around the globe. Sigma-Aldrich also provides a suite of analytical tools that allow food analysts to simplify sample preparation, cleanup and analysis steps, while increasing sensitivity to trace ingredients and harmful substances to meet regulations and quality standards. Email: Information US Email: Sales US Voice: 800-244-1173 US Fax: 800-368-4661 Facebook Twitter Instagram Linkedin Flavors and Fragrances Analysis FandF Newsletter Subscription Flavors and Fragrances Learning Center Certified Food Grade Products Product(s): W340707 trans-2-Methyl-2-butenal, sum of isomers, ≥99%, FG SDS
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Tianjin Danjun International Trade Co., LTD. Quality Products We know the Chinese chemical market well. Tianjin danjun international trade co., LTD. is an organic chemicals trading company approved by the relevant state authorities to register. We have about 300 kinds of products (natural aroma chemicals, synthetic aroma chemicals and pharmaceutical intermediates). Most of the products are used in flavor and fragrance industry. We know the Chinese chemical market well and we have close relationship with many of the main manufacturers, and to provide our customers with quality goods together with comprehensive service. Email: Info Email: Sales Voice: +86-15822601686 Products List: View Product(s): L-035 Tiglic aldehyde
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| CAS Number: | 1115-11-3 |  3D/inchi
|
| Beilstein Number: | 1698207 | |
| MDL: | MFCD00006977 | |
| CoE Number: | 2281 | |
| XlogP3-AA: | 0.90 (est) | |
| Molecular Weight: | 84.11796000 | |
| Formula: | C5 H8 O | |
| NMR Predictor: | Predict (works with chrome or firefox) | |
| Also(can) Contains: | (E)-tiglaldehyde | |
| (Z)-tiglaldehyde | ||
Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
| Google Scholar: | Search |
| Google Books: | Search |
| Google Scholar: with word "volatile" | Search |
| Google Scholar: with word "flavor" | Search |
| Google Scholar: with word "odor" | Search |
| Perfumer and Flavorist: | Search |
| Google Patents: | Search |
| US Patents: | Search |
| EU Patents: | Search |
| Pubchem Patents: | Search |
| PubMed: | Search |
| NCBI: | Search |
| FEMA Number: | 3407 2-methyl-2-butenal |
| FDA: | No longer provide for the use of these seven synthetic flavoring substances |
| FDA Mainterm (SATF): | 497-03-0 ; 2-METHYL-2-BUTENAL |
Physical Properties:
| Appearance: | colorless clear liquid (est) |
| Assay: | 97.00 to 100.00 % |
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.87100 @ 25.00 °C. |
| Refractive Index: | 1.44800 @ 20.00 °C. |
| Boiling Point: | 116.00 to 118.00 °C. @ 752.00 mm Hg |
| Boiling Point: | 63.00 to 65.00 °C. @ 119.00 mm Hg |
| Vapor Pressure: | 17.107000 mmHg @ 25.00 °C. (est) |
| Flash Point: | 65.00 °F. TCC ( 18.33 °C. ) |
| logP (o/w): | 1.190 (est) |
| Soluble in: | |
| alcohol | |
| water, 1.342e+004 mg/L @ 25 °C (est) | |
| Insoluble in: | |
| water | |
| Similar Items: note | |
| (E)-tiglaldehyde | |
| (Z)-tiglaldehyde | |
Organoleptic Properties:
| Odor Type: green | |
| Odor Strength: | high , recommend smelling in a 1.00 % solution or less |
| Substantivity: | 16 hour(s) at 100.00 % |
| pungent green ethereal nutty anisic fruity | |
| Odor Description: at 1.00 % in dipropylene glycol. | pungent green ethereal nutty anisic fruity |
| pungent green ethereal sharp nutty anisic | |
| Odor Description: | Diffusive, pungent, green, ethareal, sharp penetrating, nutty and anisic Mosciano, Gerard P&F 14, No. 6, 47, (1989) |
| Flavor Type: fruity | |
| fresh fruity green pulpy almond nutty | |
| Taste Description: at 50.00 ppm. | Fresh, fruity, green, pulpy and almond nutty Mosciano, Gerard P&F 14, No. 6, 47, (1989) |
| Odor and/or flavor descriptions from others (if found). | |
| Sigma-Aldrich | |
| trans-2-Methyl-2-butenal, sum of isomers, ≥99%, FG | |
| Odor Description: | green; fruity |
| Taste Description: | fresh fruity green pulp almond nut |
Cosmetic Information:
| None found |
Suppliers:
| BOC Sciences |
| For experimental / research use only. |
| Tiglic aldehyde |
| CJ Latta & Associates |
| TIGLIC ALDEHYDE |
| Penta International |
| 2-METHYL-2-BUTENAL |
| Sigma-Aldrich |
| trans-2-Methyl-2-butenal, sum of isomers, ≥99%, FG
Odor: green; fruity |
| Certified Food Grade Products |
| Tianjin Danjun International |
| Tiglic aldehyde |
Safety Information:
| Preferred SDS: View | |
| European information : | |
| Most important hazard(s): | |
| Xi - Irritant | |
|
R 11 - Highly flammable. R 36/37/38 - Irritating to eyes, respiratory system, and skin. S 02 - Keep out of the reach of children. S 16 - Keep away from sources of ignition - No Smoking. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 - Wear suitable gloves and eye/face protection. | |
| Hazards identification | |
| Classification of the substance or mixture | |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |
| None found. | |
| GHS Label elements, including precautionary statements | |
| Pictogram | |
| Hazard statement(s) | |
| None found. | |
| Precautionary statement(s) | |
| None found. | |
| Oral/Parenteral Toxicity: | |
| Not determined | |
| Dermal Toxicity: | |
| Not determined | |
| Inhalation Toxicity: | |
| Not determined | |
Safety in Use Information:
| Category: | flavor and fragrance agents | ||
| RIFM Fragrance Material Safety Assessment: Search | |||
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice | |||
| Recommendation for tiglaldehyde usage levels up to: | |||
| 0.5000 % in the fragrance concentrate. | |||
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). | |||
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library | |||
| publication number: 7 | |||
| Click here to view publication 7 | |||
| average usual ppm | average maximum ppm | ||
| baked goods: | - | 5.00000 | |
| beverages(nonalcoholic): | - | 5.00000 | |
| beverages(alcoholic): | - | - | |
| breakfast cereal: | - | - | |
| cheese: | - | - | |
| chewing gum: | - | 5.00000 | |
| condiments / relishes: | - | - | |
| confectionery froastings: | - | - | |
| egg products: | - | - | |
| fats / oils: | - | - | |
| fish products: | - | - | |
| frozen dairy: | - | 5.00000 | |
| fruit ices: | - | 5.00000 | |
| gelatins / puddings: | - | 5.00000 | |
| granulated sugar: | - | - | |
| gravies: | - | 2.50000 | |
| hard candy: | - | 5.00000 | |
| imitation dairy: | - | - | |
| instant coffee / tea: | - | - | |
| jams / jellies: | - | - | |
| meat products: | - | 2.50000 | |
| milk products: | - | - | |
| nut products: | - | - | |
| other grains: | - | - | |
| poultry: | - | - | |
| processed fruits: | - | - | |
| processed vegetables: | - | - | |
| reconstituted vegetables: | - | - | |
| seasonings / flavors: | - | - | |
| snack foods: | - | - | |
| soft candy: | - | - | |
| soups: | - | 2.50000 | |
| sugar substitutes: | - | - | |
| sweet sauces: | - | - | |
Safety References:
| European Food Safety Authority (EFSA) reference(s): | |
| Flavouring Group Evaluation 201: 2-Alkylated aliphatic acyclic alpha,beta-unsaturated aldehydes and precursors with or without additional double bonds from chemical subgroup 1.1.2 of FGE.19[1] View page or View pdf | |
| EPI System: | View |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| Laboratory Chemical Safety Summary : | 10336 |
| National Institute of Allergy and Infectious Diseases: | Data |
| WISER: | UN 1989 |
| WGK Germany: | 3 |
| 2-methylbut-2-enal | |
| Chemidplus: | 0001115113 |
References:
| 2-methylbut-2-enal | |
| NIST Chemistry WebBook: | Search Inchi |
| Pubchem (cid): | 10336 |
| Pubchem (sid): | 134979446 |
| Flavornet: | 1115-11-3 |
| Pherobase: | View |
Other Information:
| (IUPAC): | Atomic Weights of the Elements 2011 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| FDA Substances Added to Food (formerly EAFUS): | View |
| HMDB (The Human Metabolome Database): | HMDB31512 |
| FooDB: | FDB008133 |
| VCF-Online: | VCF Volatile Compounds in Food |
| ChemSpider: | View |
| Wikipedia: | View |
Potential Blenders and core components note
Potential Uses:
| almond | FR | |
| cheese | FL | |
| cherry | FR | |
| chicken | FL | |
| coffee | FR | |
| fruit tropical fruit | FL | |
| grape | FR | |
| green | FR | |
| tomato | FL | |
| vanilla | FR |
Occurrence (nature, food, other): note
| chive plant Search Trop Picture | |
| coffee Search PMC Picture | |
| filbert roasted filbert Search Trop Picture | |
| garlic Search Trop Picture | |
| geranium oil Search Trop Picture | |
| mint Search Trop Picture | |
| onion Search Trop Picture | |
| safflower bud Search Trop Picture | |
| spearmint oil Search Trop Picture |
Synonyms:
| but-2-enal, 2-methyl- | |
| buten-2-al, methyl- | |
| 2- | butenal, 2-methyl- |
| crotonaldehyde, 2-methyl- | |
| 2,3- | dimethylacrolein |
| 2- | methyl but-2-en-1-al |
| 2- | methyl but-2-enal |
| 2- | methyl crotonaldehyde |
| 2- | methyl-2-buten-1-al |
| 2- | methyl-2-butenal |
| 2- | methylbut-2-enal |
| 2- | methylcrotonaldehyde |
| a- | methylcrotonaldehyde |
| tiglic acid aldehyde | |
| tiglic aldehyde |