|
Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless to pale yellow clear liquid (est) |
| Assay: | 96.00 to 100.00 %
|
| Food Chemicals Codex Listed: | Yes |
| Specific Gravity: | 1.03000 to 1.03500 @ 25.00 °C.
|
| Pounds per Gallon - (est).: | 8.571 to 8.612
|
| Refractive Index: | 1.45700 to 1.46300 @ 20.00 °C.
|
| Boiling Point: | 196.00 to 197.00 °C. @ 760.00 mm Hg
|
| Boiling Point: | 100.00 °C. @ 30.00 mm Hg
|
| Acid Value: | 1.00 max. KOH/g
|
| Vapor Pressure: | 0.324000 mmHg @ 25.00 °C. (est) |
| Vapor Density: | 5.1 ( Air = 1 ) |
| Flash Point: | 174.00 °F. TCC ( 78.89 °C. )
|
| logP (o/w): | 1.352 (est) |
| Shelf Life: | 24.00 month(s) or longer if stored properly. |
| Storage: | store in cool, dry place in tightly sealed containers, protected from heat and light. |
| Soluble in: |
| | alcohol | | | water, 4534 mg/L @ 25 °C (est) |
| Insoluble in: |
| | water |
| Similar Items: note |
| isoamyl 3-methyl thiopropionate |
| methyl-3-methyl thiopropionate |
Organoleptic Properties:
| |
| Odor Type: sulfurous |
| |
| | sulfurous metallic pineapple fruity ripe pulpy tomato |
Odor Description: at 0.10 % in propylene glycol. | sulfury metallic pineapple fruity ripe pulpy tomato |
| |
| | sulfurous metallic pineapple fruity ripe pulpy tomato |
Odor Description:
| Sulfureous, metallic, pineapple, fruity ripe, pulpy and tomato Mosciano, Gerard P&F 19, No. 1, 27, (1994) |
| |
| |
| Flavor Type: sulfurous |
| |
| | sulfurous onion garlic pineapple rummy vegetable |
Taste Description: at 30.00 ppm. | Sulfureous, onion garlic, pineapple, rumy, vegetative Mosciano, Gerard P&F 19, No. 1, 27, (1994) |
| |
| Odor and/or flavor descriptions from others (if found). |
| |
| R C Treatt & Co Ltd |
| Ethyl-3-methylthio Propionate Halal, Kosher |
| Odor Description: | fruity, cooked pineapple |
| Taste Description: | fruity Used in bakery and soft confection at 2ppm, and desserts and beverages at 1ppm. |
| |
| Indukern F&F |
| ETHYL 3-METHYLTHIOPROPIONATE |
| Odor Description: | SULFUROUS, METALIC, FRUITY, PINEAPPLE |
| |
| |
Cosmetic Information:
Suppliers:
| Advanced Biotech |
| ETHYL (3-METHYLTHIO) PROPIONATE
|
| Ambles Nature et Chimie |
| ETHYL 3-METHYLTHIO PROPIONATE
|
| Anhui Haibei |
| Ethyl 3-methylthio Propionate
Odor: Sulfury metallic pineapple fruity ripe pulpy tomato |
| Axxence Aromatic |
| ETHYL 3-(METHYLTHIO)-PROPIONATE Natural
Kosher |
| Sustainability |
| Beijing Lys Chemicals |
| Ethyl 3-(methylthio)propionate
|
| Berjé |
| Ethyl-3-Methyl Thio Propionate
|
| Media |
| BOC Sciences |
| For experimental / research use only. |
| Ethyl 3-methylthiopropionate
|
| Charkit Chemical |
| ETHYL 3-METHYLTHIOPROPIONATE FEMA 3343
|
| Charkit Chemical |
| ETHYL 3-METHYLTHIOPROPIONATE NATURAL FEMA 3343
|
| Citrus and Allied Essences |
| Ethyl 3-Methyl Thiopropionate FCC
|
| Market Report |
| DeLong Chemicals America |
| Ethyl 3-methylthiopropionate, Kosher
|
| Endeavour Specialty Chemicals |
| Ethyl 3-(methylthio)propionate 98% F&F
|
| Speciality Chemical Product Groups |
| Ernesto Ventós |
| ETHYL 3-METHYLTHIOPROPIONATE
Odor: FRUITY,VEGETABLE,SWEET,ALLIACEOUS |
| Excellentia International |
| Ethyl-3-Methyl Thio Propionate Natural
|
| FCI SAS |
| ETHYL-3-METHYLTHIO PROPIONATE
Odor: Pineapple and tomato |
| Frutarom |
| ETHYL 3-METHYLTHIOPROPIONATE
KOSHER Flavor: Sulfurous, Metallic, Pineapple, Fruity, Ripe, Tomato |
| CBD Offering |
| IFF |
| ETHYL 3-METHYLTHIOPROPIONATE
KOSHER Flavor: Sulfurous, Metallic, Pineapple, Fruity, Ripe, Tomato |
| Indukern F&F |
| ETHYL 3-METHYLTHIOPROPIONATE
Odor: SULFUROUS, METALIC, FRUITY, PINEAPPLE |
| Jiangyin Healthway |
| Ethyl 3-methylthio propionate
|
| New functional food ingredients |
| Jinan Enlighten Chemical Technology(Wutong Aroma ) |
| Ethyl 3-methylthio propionate, Kosherk
|
| K.L. Koh Enterprise |
| ETHYL 3-METHYLTHIOPROPIONATE
|
| Kingchem Laboratories |
| ETHYL 3-METHYLTHIOPROPIONATE
Odor: Pineapple |
| Lluch Essence |
| ETHYL 3-METHYL THIOPROPIONATE NATURAL
|
| Lluch Essence |
| ETHYL 3-METHYL THIOPROPIONATE
Odor: GARLIC LIKE, SULPHUROUS |
| M&U International |
| ETHYL-3-METHYLTHIO PROPIONATE, Kosher
|
| Moellhausen |
| ETHYL 3-METHYLTHIOPROPIONATE
|
| Natural Advantage |
| Ethyl Methylthiopropionate Nat, 1% in Triacetin Nat USOC
Flavor: blueberry, caramellic, cheesy, fruity, grape, red, metallic, sulphurous |
| Riverside Aromatics LTD.is the exclusive distributor for Europe in UK for any non-US based inquiries |
| Natural Advantage |
| Ethyl Methylthiopropionate Nat, 1% in Triacetin
Flavor: blueberry, caramellic, cheesy, fruity, grape, red, metallic, sulphurous |
| Natural Advantage |
| Ethyl Methylthiopropionate Nat, Neat
Flavor: blueberry, caramellic, cheesy, fruity, grape, red, metallic, sulphurous |
| Penta International |
| ETHYL-3-METHYLTHIOPROPIONATE NATURAL
|
| Penta International |
| ETHYL-3-METHYLTHIOPROPIONATE
|
| R C Treatt & Co Ltd |
| Ethyl-3-methylthio Propionate
Halal, Kosher Odor: fruity, cooked pineapple Flavor: fruity Used in bakery and soft confection at 2ppm, and desserts and beverages at 1ppm. |
| Reincke & Fichtner |
| Ethyl-3-methylthiopropionate
|
| Riverside Aromatics |
| ETHYL 3-METHYLTHIOPROPIONATE NATURAL
|
| Robinson Brothers |
| Ethyl 3-(methylthio)propionate F&F
|
| https://www.robinsonbrothers.uk/chemistry-competences |
| Santa Cruz Biotechnology |
| For experimental / research use only. |
| Ethyl 3-(methylthio)propionate
|
| Sigma-Aldrich |
| Ethyl 3-(methylthio)propionate, ≥99%, FCC, FG
Odor: citrus; pineapple |
| Certified Food Grade Products |
| Sunaux International |
| Ethyl-3-methylthio Propionate
|
| Synerzine |
| ETHYL 3-(METHYLTHIO)PROPIONATE
|
| Synerzine |
| Ethyl Methyl Mercaptopropionate (natural)
|
| Synerzine |
| Ethyl Methyl Mercaptopropionate (synthetic)
|
| Taytonn ASCC |
| Ethyl 3-Methylthiopropionate
Odor: Fruity, Tropical |
| TCI AMERICA |
| For experimental / research use only. |
| Ethyl 3-(Methylthio)propionate >98.0%(GC)
|
| Tengzhou Jitian Aroma Chemiclal |
| Ethyl-3-methylthio propionate
|
| Tengzhou Xiang Yuan Aroma Chemicals |
| Ethyl Methyl Thio-3-Propionate
|
| Tianjin Danjun International |
| Ethyl 3-(methylthio)propionate
|
| United International |
| Ethyl 3-methylthiopropionate
|
| WholeChem |
| Ethyl 3-methylthio propionate
|
Safety Information:
| Preferred SDS: View |
| European information : |
| Most important hazard(s): | | Xi - Irritant |
R 36/37/38 - Irritating to eyes, respiratory system, and skin. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
|
| |
| Hazards identification |
| |
| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
| |
| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
gavage-rat LD50 [sex: M,F] > 5000 mg/kg (Panasevich et al., 1980)
|
| Dermal Toxicity: |
|
Not determined
|
| Inhalation Toxicity: |
|
Not determined
|
Safety in Use Information:
| Category: | flavor and fragrance agents |
| RIFM Fragrance Material Safety Assessment: Search |
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
| Recommendation for ethyl methyl mercaptopropionate usage levels up to: | | | 0.0500 % in the fragrance concentrate.
|
| |
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 24.00 (μg/capita/day) |
| Structure Class: | I |
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 6 |
| Click here to view publication 6 |
| | average usual ppm | average maximum ppm |
| baked goods: | - | 2.00000 |
| beverages(nonalcoholic): | - | 1.00000 |
| beverages(alcoholic): | - | - |
| breakfast cereal: | - | - |
| cheese: | - | - |
| chewing gum: | - | - |
| condiments / relishes: | - | - |
| confectionery froastings: | - | - |
| egg products: | - | - |
| fats / oils: | - | - |
| fish products: | - | - |
| frozen dairy: | - | 1.00000 |
| fruit ices: | - | 1.00000 |
| gelatins / puddings: | - | 1.00000 |
| granulated sugar: | - | - |
| gravies: | - | - |
| hard candy: | - | 2.00000 |
| imitation dairy: | - | - |
| instant coffee / tea: | - | - |
| jams / jellies: | - | 1.00000 |
| meat products: | - | - |
| milk products: | - | - |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | - | - |
| snack foods: | - | - |
| soft candy: | - | - |
| soups: | - | - |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
Safety References:
| European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
| European Food Safety Authority (EFSA) reference(s): |
Flavouring Group Evaluation 8 (FGE.08)[1]: Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical group 20 View page or View pdf |
Flavouring Group Evaluation 8, Revision 1 (FGE.08Rev1): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 8, Revision 3 (FGE.08Rev3): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 08, Revision 4 (FGE.08Rev4): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
| EPI System: | View |
| AIDS Citations: | Search |
| Cancer Citations: | Search |
| Toxicology Citations: | Search |
| EPA Substance Registry Services (TSCA): | 13327-56-5 |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| Laboratory Chemical Safety Summary : | 61592 |
| National Institute of Allergy and Infectious Diseases: | Data |
| WGK Germany: | 3 |
| | ethyl 3-methylsulfanylpropanoate |
| Chemidplus: | 0013327565 |
References:
Other Information:
Potential Blenders and core components note
| |
| For Odor |
| alliaceous |
| | dibutyl sulfide | FL/FR |
| 1,3- | dithiane | |
| | methyl furfuryl disulfide | FL/FR |
| berry |
| | raspberry ketone | FL/FR |
| | heptanoic acid | FL/FR |
| iso | valeric acid | FL/FR |
| chemical |
| | propyl propionate | FL/FR |
| ethereal |
| | propyl valerate | FL/FR |
| fatty |
| | allyl decanoate | FL/FR |
| | allyl octanoate | FL/FR |
| | methyl 2-hexenoate | FL/FR |
| fermented |
| | ethyl (E)-2-crotonate | FL/FR |
| floral |
| | geranyl valerate | FL/FR |
| | phenethyl isovalerate | FL/FR |
| fruity |
| | allyl 3,5,5-trimethyl hexanoate | FL/FR |
| | allyl cinnamate | FL/FR |
| | allyl cyclohexyl acetate | FL/FR |
| | allyl cyclohexyl butyrate | FL/FR |
| | allyl heptanoate | FL/FR |
| | allyl propionate | FL/FR |
| iso | amyl isovalerate | FL/FR |
| | amyl propionate | FL/FR |
| iso | amyl propionate | FL/FR |
| | amyl valerate | FL/FR |
| iso | amyl valerate | FL/FR |
| | ananas comosus extract | |
| | apricot fragrance | FR |
| | benzyl ethyl ether | FL/FR |
| iso | butyl (E)-2-butenoate | |
| iso | butyl butyrate | FL/FR |
| iso | butyl hexanoate | FL/FR |
| | butyl valerate | FL/FR |
| | dihydroactinidolide | FL/FR |
| | ethyl 3-(2-furyl) propanoate | FL/FR |
| | ethyl 3-hexenoate | FL/FR |
| | ethyl 3-methyl valerate | FL/FR |
| | ethyl 5-hydroxyoctanoate | FL/FR |
| | ethyl butyrate | FL/FR |
| | ethyl cyclohexane propionate | FL/FR |
| | ethyl heptanoate | FL/FR |
| | ethyl hexanoate | FL/FR |
| | ethyl-2-cyclopentenyl acetate | FR |
| | fruity carboxylate | FR |
| | methyl hexanoate | FL/FR |
| | methyl isovalerate | FL/FR |
| | passiflora lauriflora fruit extract | CS |
| | pineapple hydroxyhexanoate | FL/FR |
| | prenyl acetate | FL/FR |
| iso | propyl butyrate | FL/FR |
| | propyl heptanoate | FL/FR |
| iso | propyl hexanoate | FL/FR |
| iso | propyl isobutyrate | FL/FR |
| | propyl isobutyrate | FL/FR |
| | prune specialty | FL/FR |
| green |
| | cognac heptanone | FL/FR |
| | galbanum oxyacetate | FR |
| (E)-2- | hexen-1-yl butyrate | FL/FR |
| 3- | hexenyl 2-methyl butyrate | FL/FR |
| | hexyl isobutyrate | FL/FR |
| | pineapple heptadienone 10% | FR |
| | spirogalbanone (Givaudan) | FR |
| herbal |
| | herbal undecanone | FR |
| nutty |
| 2- | methyl-3-ethoxypyrazine | FL/FR |
| spicy |
| | ethyl vinyl ketone | FL/FR |
| 1,3- | dithiolane | |
| | ethyl 2-mercaptopropionate | FL/FR |
| 2- | methyl 5-(methyl thio) furan | FL/FR |
| 3-( | methyl thio) hexanol | FL/FR |
| 4- | methyl-1,3-dithiane | |
| | passiflora acetate | FL/FR |
| tropical |
| | passiflora edulis fruit extract | FL/FR |
| | passiflora edulis fruit water | FL/FR |
| | pina colada fragrance | FR |
| | tropical 3-thiobutyrate | FL/FR |
| waxy |
| | ethyl octanoate | FL/FR |
| |
| For Flavor |
| |
| No flavor group found for these |
| | allyl 3,5,5-trimethyl hexanoate | FL/FR |
| | allyl cinnamate | FL/FR |
| | allyl cyclohexyl butyrate | FL/FR |
| | allyl cyclohexyl valerate | FL |
| | amyl propionate | FL/FR |
| | amyl valerate | FL/FR |
| | ananas comosus extract | |
| | benzyl ethyl ether | FL/FR |
| 9- | decen-2-one | FL |
| | ethyl 3-methyl valerate | FL/FR |
| | ethyl 5-hydroxyoctanoate | FL/FR |
| | ethyl cyclohexane propionate | FL/FR |
| | ethyl cyclohexyl carboxylate | FL |
| | geranyl valerate | FL/FR |
| | methyl 2-hexenoate | FL/FR |
| 2- | methyl-3-ethoxypyrazine | FL/FR |
| iso | propyl hexanoate | FL/FR |
| iso | propyl isobutyrate | FL/FR |
| | propyl valerate | FL/FR |
| | prune specialty | FL/FR |
| alliaceous |
| | allyl disulfide | FL |
| | allyl propionate | FL/FR |
| | allyl thiopropionate | FL |
| | chive flavor | FL |
| | cyclopentyl mercaptan | FL |
| | diethyl disulfide | FL |
| 3- | mercapto-2-pentanone | FL |
| 2- | methyl thioacetaldehyde | FL |
| 3- | tetrahydrothiophenone | FL |
| | truffle sulfide | FL |
| berry |
| | raspberry ketone | FL/FR |
| buttery |
| | butter onion garlic flavor | FL |
| cheesy |
| iso | valeric acid | FL/FR |
| citrus |
| | cognac heptanone | FL/FR |
| coffee |
| | methyl furfuryl disulfide | FL/FR |
| fatty |
| | allyl octanoate | FL/FR |
| fermented |
| | methyl thio isovalerate | FL |
| fruity |
| | allyl cyclohexyl acetate | FL/FR |
| | allyl decanoate | FL/FR |
| | allyl heptanoate | FL/FR |
| iso | amyl propionate | FL/FR |
| iso | amyl valerate | FL/FR |
| iso | butyl butyrate | FL/FR |
| iso | butyl hexanoate | FL/FR |
| | butyl valerate | FL/FR |
| | dihydroactinidolide | FL/FR |
| | ethyl 3-(2-furyl) propanoate | FL/FR |
| | ethyl 3-hexenoate | FL/FR |
| | ethyl butyrate | FL/FR |
| | ethyl heptanoate | FL/FR |
| | ethyl hexanoate | FL/FR |
| | furfuryl isovalerate | FL |
| | methionyl butyrate | FL |
| | methyl hexanoate | FL/FR |
| | methyl isovalerate | FL/FR |
| ( | methyl thio) methyl hexanoate | FL |
| | phenethyl isovalerate | FL/FR |
| | pineapple hydroxyhexanoate | FL/FR |
| | prenyl acetate | FL/FR |
| iso | propyl butyrate | FL/FR |
| | propyl isobutyrate | FL/FR |
| green |
| iso | amyl isovalerate | FL/FR |
| | dibutyl sulfide | FL/FR |
| (E)-2- | hexen-1-yl butyrate | FL/FR |
| 3- | hexenyl 2-methyl butyrate | FL/FR |
| | hexyl isobutyrate | FL/FR |
| meaty |
| (R,S)-2- | mercapto-3-butanol | FL |
| bis(2- | methyl-3-furyl) disulfide | FL |
| ortho- | thiocresol | FL |
| metallic |
| 3-( | methyl thio) hexanol | FL/FR |
| musty |
| | ethyl (E)-2-crotonate | FL/FR |
| 2- | methyl 5-(methyl thio) furan | FL/FR |
| onion |
| 1,3- | dithiane | |
| | ethyl 2-mercaptopropionate | FL/FR |
| | methionol | FL |
| | methyl propyl disulfide | FL |
| | methyl propyl trisulfide | FL |
| | onion flavor | FL |
| | propyl thioacetate | FL |
| seafood |
| 1,4- | dithiane | FL |
| spicy |
| | ethyl vinyl ketone | FL/FR |
| sulfurous |
| | allyl sulfide | FL |
| | butyl mercaptan | FL |
| 1,3- | dithiolane | |
| S- | ethyl thioacetate | FL |
| | furfuryl thiopropionate | FL |
| 3- | mercapto-2-methyl pentanal | FL |
| 3- | mercapto-2-methyl-1-butanol | FL |
| 4- | methyl-1,3-dithiane | |
| caramelized | onion oleoresin | FL |
| | tropical 3-thiobutyrate | FL/FR |
| tropical |
| | passiflora acetate | FL/FR |
| | passiflora edulis fruit extract | FL/FR |
| | passiflora edulis fruit water | FL/FR |
| | propyl propionate | FL/FR |
| waxy |
| iso | butyl (E)-2-butenoate | |
| | ethyl octanoate | FL/FR |
| | heptanoic acid | FL/FR |
| | propyl heptanoate | FL/FR |
| |
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | ethyl (3-methylthio) propionate | | | ethyl (3-methylthio) propionate natural | | | ethyl 3-(methyl thio) propanoate | | | ethyl 3-(methyl thio) propionate | | | ethyl 3-(methylmercapto)propionate | | | ethyl 3-(methylsulfanyl)propanoate | | | ethyl 3-(methylthio propionate | | | ethyl 3-(methylthio)-propionate | | | ethyl 3-(methylthio)propanoate | | | ethyl 3-(methylthio)propionate | | | ethyl 3-methyl mercaptopropionate | | | ethyl 3-methyl thiopropionate | | | ethyl 3-methyl thiopropionate FCC | | | ethyl 3-methylsulfanylpropanoate | | | ethyl 3-methylthio propionate | | | ethyl 3-methylthiopropionate | | | ethyl beta-methyl thiopropionate | | | ethyl methylthioproprionate natural | | | ethyl-3-(methyl thio) propionate | | | ethyl-3-(methylthio)-propionate natural | | | ethyl-3-methyl thio propionate | | | ethyl-3-methyl thiopropionate | | | ethyl-3-methylthio propionate | | | ethyl-3-methylthiopropionate | | | ethyl-3-metylthiopropionate, natural | | 3-( | methyl thio) propionic acid ethyl ester | | 3- | methyl thiopropionic acid ethyl ester | | 3-( | methylthio)propanoic acid ethyl ester | | (3- | methylthio)propionic acid ethyl ester | | 3-( | methylthio)propionic acid ethyl ester | | 3-( | methylthio)propionic acid ethylester | | | pineapple thiopropionate | | | propanoic acid, 3-(methylthio)-, ethyl ester | | | propionic acid, 3-methylthio-, ethyl ester |
Articles:
|