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Category: flavoring agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Organoleptic Properties:
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| Odor Type: alliaceous |
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| | sharp alliaceous onion sulfurous garlic horseradish minty coffee |
Odor Description: at 0.10 % in propylene glycol. | sharp alliaceous onion sulfurous garlic horseradish mint coffee |
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| | sharp sulfurous onion garlic horseradish minty coffee |
Odor Description:
| Sharp, sulfuraceous, onion, garlic, horseradish, mint and coffee Mosciano, Gerard P&F 14, No. 6, 47, (1989) |
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| Flavor Type: alliaceous |
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| | leek horseradish cabbage green tomato coffee |
Taste Description: at 15.00 ppm. | Leek, horseradish, cabbage, green, tomato and coffee Mosciano, Gerard P&F 14, No. 6, 47, (1989) |
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| Odor and/or flavor descriptions from others (if found). |
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Cosmetic Information:
Suppliers:
Safety Information:
| Preferred SDS: View |
| European information : |
| Most important hazard(s): | | T - Toxic. |
R 22 - Harmful if swallowed. R 23 - Toxic by inhalation. S 02 - Keep out of the reach of children. S 23 - Do not breath vapour. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 - Wear suitable clothing, gloves and eye/face protection. S 45 - In case of accident or if you feel unwell seek medical advice immediately.
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| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
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| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
oral-rat LD50 493 mg/kg LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
BEHAVIORAL: COMA American Industrial Hygiene Association Journal. Vol. 19, Pg. 171, 1958.
intraperitoneal-rat LD50 373 mg/kg BEHAVIORAL: COMA
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION American Industrial Hygiene Association Journal. Vol. 19, Pg. 171, 1958.
intraperitoneal-mouse LD50 100 mg/kg National Technical Information Service. Vol. AD277-689
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| Dermal Toxicity: |
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Not determined
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| Inhalation Toxicity: |
inhalation-mouse LC50 178 ppm/4H BEHAVIORAL: ATAXIA
BEHAVIORAL: MUSCLE WEAKNESS
LUNGS, THORAX, OR RESPIRATION: CYANOSIS American Industrial Hygiene Association Journal. Vol. 19, Pg. 171, 1958.
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Safety in Use Information:
| Category: | flavoring agents |
| Recommendation for benzyl mercaptan usage levels up to: | | | not for fragrance use.
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| Maximised Survey-derived Daily Intakes (MSDI-EU): | 1.20 (μg/capita/day) |
| Structure Class: | II |
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 3 |
| Click here to view publication 3 |
| | average usual ppm | average maximum ppm |
| baked goods: | 0.50000 | 0.75000 |
| beverages(nonalcoholic): | 0.15000 | 0.25000 |
| beverages(alcoholic): | - | - |
| breakfast cereal: | - | - |
| cheese: | - | - |
| chewing gum: | - | - |
| condiments / relishes: | - | - |
| confectionery froastings: | - | - |
| egg products: | - | - |
| fats / oils: | - | - |
| fish products: | - | - |
| frozen dairy: | 0.15000 | 0.50000 |
| fruit ices: | 0.15000 | 0.50000 |
| gelatins / puddings: | - | - |
| granulated sugar: | - | - |
| gravies: | - | - |
| hard candy: | 0.50000 | 0.75000 |
| imitation dairy: | - | - |
| instant coffee / tea: | - | - |
| jams / jellies: | - | - |
| meat products: | - | - |
| milk products: | - | - |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | - | - |
| snack foods: | - | - |
| soft candy: | - | - |
| soups: | - | - |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
Safety References:
| European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
| European Food Safety Authority (EFSA) reference(s): |
Flavouring Group Evaluation 8 (FGE.08)[1]: Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical group 20 View page or View pdf |
Flavouring Group Evaluation 74 (FGE.74)[1]: Consideration of Simple Aliphatic Sulphides and Thiols evaluated by JECFA (61st meeting) Structurally related to Aliphatic and Alicyclic Mono-, Di-, Tri-, and Polysulphides with or without Additional Oxygenated Functional Groups from Chemical Group 20 evaluated by EFSA in FGE.08 (2008) View page or View pdf |
Flavouring Group Evaluation 8, Revision 1 (FGE.08Rev1): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Flavouring Group Evaluation 91 (FGE.91): Consideration of simple aliphatic and aromatic sulphides and thiols evaluated by JECFA (53rd and 68th meetings) structurally related to aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups evaluated by EFSA in FGE.08Rev1 (2009) View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 8, Revision 3 (FGE.08Rev3): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 08, Revision 4 (FGE.08Rev4): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Safety and efficacy of eight compounds belonging to different chemical groups when used as flavourings for cats and dogs View page or View pdf |
| EPI System: | View |
| Chemical Carcinogenesis Research Information System: | Search |
| AIDS Citations: | Search |
| Cancer Citations: | Search |
| Toxicology Citations: | Search |
| EPA Substance Registry Services (TSCA): | 100-53-8 |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| Laboratory Chemical Safety Summary : | 7509 |
| National Institute of Allergy and Infectious Diseases: | Data |
| WGK Germany: | 3 |
| | phenylmethanethiol |
| Chemidplus: | 0000100538 |
| RTECS: | XT8650000 for cas# 100-53-8 |
References:
Other Information:
Potential Blenders and core components note
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| For Odor |
| alliaceous |
| | dimethyl trisulfide | FL/FR |
| | dipropyl disulfide | FL/FR |
| | ferula assa-foetida gum oil | FL/FR |
| | garlic oil china | FL/FR |
| | methyl furfuryl disulfide | FL/FR |
| | propyl mercaptan | FL/FR |
| S-( | methyl thio) butyrate | FL/FR |
| citrus |
| | grapefruit mercaptan | FL/FR |
| coffee |
| | coffee difuran | FL/FR |
| creamy |
| 2,3- | butane diol | FR |
| ethereal |
| 2- | methyl-1-butanol | FL/FR |
| floral |
| | petitgrain lemon oil | FL/FR |
| fruity |
| | furfuryl acetate | FL/FR |
| green |
| 2-iso | butyl thiazole | FL/FR |
| | geranium thiazole | FL/FR |
| | green dioxolane | FR |
| 1- | hepten-3-ol | FL/FR |
| (Z)-4- | hexen-1-ol | FL/FR |
| (E)-4- | hexen-1-ol | |
| (Z)-3- | hexen-1-yl tiglate | FL/FR |
| 3- | hexenal | FL/FR |
| 1- | penten-3-ol | FL/FR |
| (E)-2- | pentenal | FL/FR |
| malty |
| S- | methyl methioninium chloride | |
| meaty |
| | meaty dithiane | FL/FR |
| soapy |
| | benzyl laurate | FL/FR |
| spicy |
| | ethyl vinyl ketone | FL/FR |
| | cassis pentanone | FL/FR |
| | dimethyl disulfide | FL/FR |
| | dimethyl sulfide | FL/FR |
| | ethyl methyl mercaptopropionate | FL/FR |
| | ferula assa-foetida absolute | FL/FR |
| | methyl 3-(methyl thio) propionate | FL/FR |
| 2- | methyl 5-(methyl thio) furan | FL/FR |
| | methyl mercaptan | FL/FR |
| 3-( | methyl thio) hexanol | FL/FR |
| 2-( | methyl thio) phenol | FL/FR |
| | onion oil | FL/FR |
| 2- | phenethyl isothiocyanate | FL/FR |
| S- | tropical 2-thiobutyrate | FL/FR |
| 4- | tropical oxathiane | FL/FR |
| vegetable |
| | methional | FL/FR |
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| For Flavor |
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| No flavor group found for these |
| | allyl methyl disulfide | FL |
| | allyl methyl trisulfide | FL |
| | allyl propyl disulfide | FL |
| | allyl propyl sulfide | FL |
| | allyl propyl trisulfide | FL |
| iso | amyl mercaptan | FL |
| | diethyl trisulfide | FL |
| | diisopropyl sulfide | FL |
| | diisopropyl trisulfide | FL |
| | dimethyl tetrasulfide | FL |
| (Z+E)-2,5- | dimethyl-3-tetrahydrofuran thiol | FL |
| (Z+E)-2,5- | dimethyl-3-thioacetoxytetrahydrofuran | FL |
| | dipropyl sulfide | FL |
| | ethyl isothiocyanate | FL |
| | ethyl methyl trisulfide | FL |
| | ethyl propyl disulfide | FL |
| | ethyl propyl trisulfide | FL |
| | heptyl mercaptan | FL |
| 4- | mercapto-3-methyl-2-butanol | FL |
| | mercaptoacetaldehyde | FL |
| | methyl butyl sulfide | FL |
| 4-( | methyl thio) butanol | FL |
| 2-( | methyl thio) methyl-2-butenal | FL |
| 4- | methyl thiobutyl isothiocyanate | FL |
| 6- | methyl thiohexyl isothiocyanate | FL |
| 5- | methyl thiopentyl isothiocyanate | FL |
| 2- | methyl-5-methoxythiazole | FL |
| 4- | pentenyl isothiocyanate | FL |
| 2- | phenethyl isothiocyanate | FL/FR |
| | propenyl propyl disulfide | FL |
| iso | propyl disulfide | FL |
| | tetrahydrothiophene | FL |
| | thiophene | FL |
| 2,3,5- | trithiahexane | FL |
| S- | tropical 2-thiobutyrate | FL/FR |
| alliaceous |
| | allyl disulfide | FL |
| | allyl mercaptan | FL |
| | allyl thiopropionate | FL |
| 1,3- | butane dithiol | FL |
| | cyclopentyl mercaptan | FL |
| | dicyclohexyl disulfide | FL |
| | diethyl disulfide | FL |
| | dimethyl trisulfide | FL/FR |
| | dipropyl disulfide | FL/FR |
| | dipropyl trisulfide | FL |
| | ferula assa-foetida gum oil | FL/FR |
| | garlic oil china | FL/FR |
| 3- | mercapto-2-methyl pentanol | FL |
| 3- | mercapto-2-pentanone | FL |
| | methyl 3-mercaptobutanoate | FL |
| 2- | methyl thioacetaldehyde | FL |
| | propyl mercaptan | FL/FR |
| 3- | tetrahydrothiophenone | FL |
| | truffle sulfide | FL |
| burnt |
| | methyl phenyl disulfide | FL |
| cabbage |
| | methyl 2-thiofuroate | FL |
| citrus |
| | grapefruit mercaptan | FL/FR |
| | petitgrain lemon oil | FL/FR |
| coffee |
| | coffee difuran | FL/FR |
| | methyl furfuryl disulfide | FL/FR |
| corn chip |
| 2- | acetyl-2-thiazoline | FL |
| eggy |
| iso | propyl mercaptan | FL |
| estery |
| | furfuryl acetate | FL/FR |
| ethereal |
| | benzyl laurate | FL/FR |
| 2- | methyl-1-butanol | FL/FR |
| fatty |
| | dimethyl sulfoxide | FL |
| fermented |
| | methyl thio isovalerate | FL |
| fruity |
| | methionyl butyrate | FL |
| 4- | tropical oxathiane | FL/FR |
| garlic |
| | allyl methyl sulfide | FL |
| | garlic oleoresin | FL |
| green |
| 2-iso | butyl thiazole | FL/FR |
| | cassis pentanone | FL/FR |
| 2- | furyl acetone | FL |
| | geranium thiazole | FL/FR |
| 1- | hepten-3-ol | FL/FR |
| (Z)-4- | hexen-1-ol | FL/FR |
| (E)-4- | hexen-1-ol | |
| (Z)-3- | hexen-1-yl tiglate | FL/FR |
| 3- | hexenal | FL/FR |
| 1- | penten-3-ol | FL/FR |
| (E)-2- | pentenal | FL/FR |
| meaty |
| | meaty dithiane | FL/FR |
| 3- | mercapto-2-butanone | FL |
| (R,S)-2- | mercapto-3-butanol | FL |
| 2-( | methyl thio) phenol | FL/FR |
| bis(2- | methyl-3-furyl) disulfide | FL |
| | phenyl mercaptan | FL |
| | pyrazinyl ethane thiol | FL |
| ortho- | thiocresol | FL |
| metallic |
| 2,5- | dihydroxy-1,4-dithiane | FL |
| 3-( | methyl thio) hexanol | FL/FR |
| musty |
| 2- | methyl 5-(methyl thio) furan | FL/FR |
| S-( | methyl thio) butyrate | FL/FR |
| onion |
| | methionol | FL |
| | methyl propyl disulfide | FL |
| | methyl propyl trisulfide | FL |
| | propyl thioacetate | FL |
| roasted |
| | ethyl 3-(furfuryl thio) propionate | FL |
| | hexyl mercaptan | FL |
| seafood |
| 1,4- | dithiane | FL |
| spicy |
| | benzyl isothiocyanate | FL |
| | ethyl vinyl ketone | FL/FR |
| sulfurous |
| | allyl sulfide | FL |
| | butyl mercaptan | FL |
| | diallyl polysulfides | FL |
| | diallyl tetrasulfide | FL |
| | diallyl trisulfide | FL |
| | dimethyl disulfide | FL/FR |
| | dimethyl sulfide | FL/FR |
| | ethyl methyl mercaptopropionate | FL/FR |
| | ethyl methyl sulfide | FL |
| S- | ethyl thioacetate | FL |
| | ferula assa-foetida absolute | FL/FR |
| | furfuryl methyl sulfide | FL |
| | furfuryl thiopropionate | FL |
| 3- | mercapto-2-methyl pentanal | FL |
| | methyl 2-(methyl thio) butyrate | FL |
| | methyl 2-methyl-3-furyl disulfide | FL |
| | methyl 4-(methyl thio) butyrate | FL |
| | methyl benzyl disulfide | FL |
| | methyl mercaptan | FL/FR |
| S- | methyl methioninium chloride | |
| 1-( | methyl thio)-2-butanone | FL |
| | methyl thiomethyl butyrate | FL |
| | onion oil | FL/FR |
| | onion oleoresin | FL |
| | potato butanone | FL |
| tomato |
| | methional | FL/FR |
| vegetable |
| | methyl 3-(methyl thio) propionate | FL/FR |
| | radish isothiocyanate | FL |
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Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | benzene methane thiol | | | benzenemethanethiol | | | benzhydrosulfide | | | benzyl hydrosulfide | | | benzyl mercaptan natural | | | benzyl thiol | | | benzylhydrosulphide | | | benzylmercaptan | | | benzylthiol | | alpha- | cresyl mercaptan | | a- | mercaptoluene | | | mercaptomethylbenzene | | | mercaptotoluene | | alpha- | mercaptotoluene | | | phenyl methane thiol | | | phenyl methyl mercaptan | | | phenylmethanethiol | | | thiobenzyl alcohol | | a- | toluene thiol | | alpha- | toluene thiol | | | toluene-a-thiol | | a- | toluenethiol | | a- | tolyl mercaptan | | alpha- | tolyl mercaptan |
Articles:
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