Perflavory
Typical G.C. analysis
cananga odorata oil china
#%LeftshiftComponents
 24.14  benzyl acetate
 1.90  benzyl alcohol
 20.45  benzyl benzoate
 0.16beta- cadinene
 0.24delta- cadinene
 2.69gamma- cadinene
 0.51beta- caryophyllene
 0.97(E)- cinnamyl acetate
 0.27para- cresol
 2.05para- cresyl methyl ether
 0.22gamma- elemene
 1.54(E)-iso eugenol
 0.67alpha- farnesene
 0.21(Z,E)- farnesol
 6.08  geranyl acetate
 0.27alpha- humulene
 29.20  linalool
 0.144- methoxybenzyl acetate
 0.29  methyl 3-methoxybenzene
 2.70  methyl benzoate
 0.632- phenethyl acetate

L-F. Zhu, Y-H. Li, B-L. Li, B-Y. Lu and W-L. Zhang, Aromatic plants and essential constituents (supplement 1). South China Institute of Botany, Chinese Academy of Sciences, Hai Feng Publ. Co. distributed by Peace Book Co., Ltd., Hong Kong (1995).

P&F 24, No. 4, 31, (1999)

cassia leaf oil
#%LeftshiftComponents
 0.54  benzaldehyde
 1.82  benzyl benzoate
 1.58  camphene
 2.60  camphor
 2.90delta-3- carene
 6.24beta- caryophyllene
 46.52(E)- cinnamaldehyde
 2.64(E)- cinnamyl acetate
 1.40alpha- copaene
 4.18para- cymene
 3.63  eugenol
 0.30  eugenyl acetate
 0.85alpha- humulene
 2.98  linalool
 0.79ortho- methoxycinnamaldehyde
 0.07  myrcene
 9.16beta-phellandrene + limonene
 3.47alpha- pinene
 1.02beta- pinene
 0.07alpha- terpineol

L.-F. Zhu, Y.-H. Li, B.-L. Li, B.-Y. Lu and N.-H. Xia, Aromatic Plants and Essential Constituents. South China Institute of Botany, Chinese Academy of Sciences, Hai Feng Publish. Co. distributed by Peace Book Co. Ltd., Hong Kong (1993).

P&F 19, No. 4, 33, (1994)

cinnamomum angustifolium rafin. oil madagascar
#%LeftshiftComponents
273.00  bicyclogermacrene
290.30delta- cadinene
40.10  camphene
180.10  camphor
71.80delta-3- carene
390.10  carvacrol
206.20beta- caryophyllene
331.00  caryophyllene oxide
129.701,8- cineole
340.20(E)- cinnamaldehyde
280.90(Z)- cinnamaldehyde
380.40(E)- cinnamyl acetate
320.30para- cymen-8-ol
1617.60para- cymene
30.30alpha- fenchene
300.30  geranyl acetate
261.80  germacrene D
360.40  guaiol
220.20alpha- humulene
111.80  limonene
193.30  linalool
310.20para- mentha-1(7),5-dien-2-ol
92.60  myrcene
350.40(E)- nerolidol
151.10(E)-beta- ocimene
130.20(Z)-beta- ocimene
823.40alpha- phellandrene
14.80alpha- pinene
51.20beta- pinene
61.00  sabinene
230.20  salicylaldehyde
371.40  spathulenol
210.70  terpinen-4-ol
100.30alpha- terpinene
140.50gamma- terpinene
252.10alpha- terpineol
170.30  terpinolene
21.90alpha- thujene
240.40  viridiflorene
J. of Ess. Oil Res. 12, No. 5, 537, (2000)
cinnamomum cassia bark oil china
#%LeftshiftComponents
10.54  benzaldehyde
201.82  benzyl benzoate
31.58  camphene
102.60  camphor
62.90delta-3- carene
166.24beta- caryophyllene
1246.52(E)- cinnamaldehyde
152.64(E)- cinnamyl acetate
141.40alpha- copaene
74.18para- cymene
133.63  eugenol
180.30  eugenyl acetate
170.85alpha- humulene
92.98  linalool
190.79ortho- methoxycinnamaldehyde
40.07  myrcene
89.16beta-phellandrene + limonene
23.47alpha- pinene
51.02beta- pinene
110.07alpha- terpineol

N. Bouzid, K. Toulgouate, G. Villarem and A. Gaset, Analyse quantitative des fractions d’huile essentielle pouvant co-exister lors d’hydrodistillation & plants aromatiques. Rivista Ital. EPPOS, (April), 15-25 (1997).

P&F 23, No. 1, 39, (1998)

cinnamomum zeylanicum bark oil india
In 1989, Variyar and Bandyopadhayay used retention time data of authentic compounds on a packed GC column to determine the composition of bark and twig oils of Cinnamomum zeylanicum of Kerala (India) origin. The compounds characterized in these oils can be seen in Table VIII. Only the bark oil will be shown here:
#%LeftshiftComponents
50.90beta- caryophyllene
30.261,8- cineole
882.11(E)- cinnamaldehyde
100.95(E)- cinnamyl acetate
97.69(E)- cinnamyl alcohol
110.41  coumarin
120.76  eugenol
70.28alpha- humulene
20.18  limonene
42.48  linalool
10.18alpha- pinene
60.80  terpinen-4-ol

P. S. Variyar and Bandyopadhayay, On some chemical aspects of Cinnamomum zeylanicum. PAFAI, (Oct/Dec), 35-38 (1989).

P&F 23, No. 1, 39, (1998)

cinnamomum zeylanicum bark oil sri lauka
Using GC (retention indices) Bouzid et al. (1997) analyzed an oil of cinnamon bark. The compounds identified were as follows:
#%LeftshiftComponents
11trace-0.05  benzaldehyde
250.40-1.00  benzyl benzoate
20.04-0.05  camphene
40.01-0.02delta-3- carene
19trace-0.12  caryophyllene
131.00-2.00beta- caryophyllene
2072.00-82.15(E)- cinnamaldehyde
170.12-0.98(Z)- cinnamaldehyde
213.24-3.65(E)- cinnamyl acetate
230.50-0.60(E)- cinnamyl alcohol
100.04-0.05alpha- copaene
90.25-0.35para- cymene
221.07-13.30  eugenol
140.20-0.62alpha- humulene
70.09-0.10  limonene
120.70-1.06  linalool
50.06para-menthene
180.09-0.15ortho- methoxybenzaldehyde
240.30-0.80ortho- methoxycinnamaldehyde
60.07-0.08  myrcene
80.40-0.64beta- phellandrene
160.10-0.70  phenyl propionaldehyde
10.04-0.07alpha- pinene
30.02-0.03beta- pinene
150.35-0.62alpha-terpineol + borneol
cinnamomum zeylanicum fruit oil india
In 1997, Jayaprakasha et al. analyzed two oils of the fruit of C. zeylanicum by GC and GC/MS. Although the oils were produced from fruit harvested in two different locations in India, Karnataka and Kerala, the oil compositions were similar as can be seen from the following analytical results:
#%LeftshiftComponents
322.7-2.8  benzyl benzoate
80.3-0.4  borneol
212.3-3.0delta- cadinene
201.2-1.6gamma- cadinene
311.0-1.5alpha- cadinol
302.7-3.4T- cadinol
159.2-13.7beta- caryophyllene
240.9-1.1  caryophyllene oxide
100.6-4.3(E)- cinnamaldehyde
70.2-0.3(Z)- cinnamaldehyde
1642.4-54.2(E)- cinnamyl acetate
112.0-2.2(E)- cinnamyl alcohol
141.8-3.1alpha- copaene
290.5-0.8  cubenol
270.4-0.510-epi-gamma- eudesmol
120.2-0.3  eugenol
191.7-2.0  germacrene B
180.7-0.8  germacrene D
260.3  germacrene D-4-ol
250.5-0.6  globulol
220.4beta- guaiene
172.8-3.1alpha- humulene
340.0-0.3  methyl oleate
330.0-0.3  methyl palmitate
280.3alpha- muurolol
30.0-0.2  myrcene
230.2-0.4  nerolidol
60.2-0.5(E)-beta- ocimene
40.1-0.7alpha- phellandrene
50.4-1.6beta- phellandrene
132.9-4.33- phenyl propyl acetate
10.1-1.6alpha- pinene
20.1-0.6beta- pinene
90.3alpha- terpineol

G. K. Jayaprakasha, L. Jaganmohan Rao and K. K. Sakariah, Chemical composition of the folatile oil from the fruits of Cinnamomum zeylanicum Blume. Flav. Fragr. J., 12, 331-333 (1997)

P&F 23, No. 1, 39, (1998)

cinnamomum zeylanicum leaf oil
The seasonal variation in the composition of cinnamon leaf oil produced from leaves harvested at different times of the year was studied by Kaul et al. (1996). They found that oil produced from leaves harvested either in the summer or in the winter possessed comparable chemical compositions, whereas an oil produced from leaves harvested in the rainy season had a reduced level of eugenol and an increased level of eugenyl acetate (Table VIII). Note: this page will only include the summer harvest.
#%LeftshiftComponents
220.43  benzyl benzoate
200.06delta- cadinene
30.12  camphene
170.48beta- caryophyllene
210.26  caryophyllene oxide
130.17(E)- cinnamaldehyde
160.19(E)- cinnamyl acetate
90.07  citronellal
60.36para- cymene
150.34beta- elemene
1493.94  eugenol
191.07  eugenyl acetate
180.12alpha- humulene
70.31 limonene + 1,8-cineole
80.86  linalool
50.23alpha- phellandrene
20.33alpha- pinene
40.16beta- pinene
120.07  piperitone
100.09  terpinen-4-ol
110.10alpha- terpineol
10.03alpha- thujene

P. N. Kaul, A. K. Battacharya and B. R. Rajeswara Rae, Seasonal variation in the composition of the essential oil of cinnamon (Cinnamomum zeylanicum Blume) leaves. Indian Perfum., 40(2), 36-38 (1996).

P&F 22, No. 5, 71, (1997)

cinnamomum zeylanicum twig oil india
In 1989, Variyar and Bandyopadhayay used retention time data of authentic compounds on a packed GC column to determine the composition of bark and twig oils of Cinnamomum zeylanicum of Kerala (India) origin. The compounds characterized in these oils can be seen in Table VIII. Only the twig oil will be shown here:
#%LeftshiftComponents
50.73beta- caryophyllene
30.641,8- cineole
876.07(E)- cinnamaldehyde
100.43(E)- cinnamyl acetate
99.55(E)- cinnamyl alcohol
110.32  coumarin
124.03  eugenol
70.19alpha- humulene
20.14  limonene
43.05  linalool
10.21alpha- pinene
60.50  terpinen-4-ol

P. S. Variyar and Bandyopadhayay, On some chemical aspects of Cinnamomum zeylanicum. PAFAI, (Oct/Dec), 35-38 (1989).

P&F 23, No. 1, 39, (1998)

cinnamon bark oil ceylon
Using GC (retention indices) Bouzid et al. (1997) analyzed an oil of cinnamon bark. The compounds identified were as follows:
#%LeftshiftComponents
10.54  benzaldehyde
201.82  benzyl benzoate
31.58  camphene
102.60  camphor
62.90delta-3- carene
166.24beta- caryophyllene
1246.52(E)- cinnamaldehyde
152.64(E)- cinnamyl acetate
141.40alpha- copaene
74.18para- cymene
133.63  eugenol
180.30  eugenyl acetate
170.85alpha- humulene
92.98  linalool
190.79ortho- methoxycinnamaldehyde
40.07  myrcene
89.16beta-phellandrene + limonene
23.47alpha- pinene
51.02beta- pinene
110.07alpha- terpineol

N. Bouzid, K. Toulgouate, G. Villarem and A. Gaset, Analyse quantitative des fractions d'huile essentielle pouvant co-exister lors d'hydrodistillation de plants aromatiques. Rivista Ital. EPPOS, (April), 15-25 (1997).

P&F 23, No. 1, 39, (1998)

michelia champaca concrete
#%LeftshiftComponents
520.05iso amyl benzoate
360.035-amyl-3,4-dimethyl isoxazole
370.023-amyl-4,5-dimethyl isoxazole
244trace(E)- anethole
1400.03  benzaldehyde
730.10(E+Z)- benzaldoxime
1590.20  benzoic acid
2160.01 benzyl (Z)-3-hexenoate
212trace  benzyl 2-methyl butyrate
250.60  benzyl acetate
382.00  benzyl alcohol
901.00  benzyl benzoate
211trace  benzyl butyrate
210.10  benzyl formate
2130.03  benzyl isovalerate
240trace  benzyl methyl ether
2170.20  benzyl phenyl acetate
2180.10 benzyl phenyl propionate
209trace  benzyl propionate
2150.02  benzyl tiglate
2140.04  benzyl valerate
1220.10  borneol
2030.03  bornyl acetate
1680.01  bovolide
210trace  butyl benzoate
1010.03beta- caryophyllene
640.20  caryophyllene oxide
40.031,8- cineole
750.30  cinnamic alcohol
1430.02  cinnamic aldehyde
2510.01  cinnamic aldehyde oxime
256trace  cinnamonitrile
710.10(E)- cinnamyl acetate
2310.05  cinnamyl benzoate
2280.01  cinnamyl formate
2290.01  cinnamyl isovalerate
2300.05  cinnamyl tiglate
1720.01  coumarin
1340.02  creosol
133tracepara- cresol
570.04  cubenol
530.02epi- cubenol
139tracebeta- cyclocitral
169trace  decan-5-olide
1180.05  decanol
170trace(Z)-7- decen-5-olide
1540.10  dehydro-beta-ionone
155trace dehydro-beta-ionone 5,6-epoxide
910.053-oxo- dihydro-alpha-ionol
450.01  dihydro-alpha-ionone
870.103-oxo- dihydro-alpha-ionone
820.20(E+Z)-dihydro-alpha-ionone oxime
600.40  dihydro-beta-ionol
930.203-oxo- dihydro-beta-ionol
1290.01 dihydro-beta-ionol 5,6-epoxide
460.30  dihydro-beta-ionone
1570.054-oxo-dihydro-beta-ionone
830.40(E+Z)-dihydro-beta-ionone oxime
500.02 dihydro-beta-ionyl formate
1710.03  dihydroactinidiolide
740.02  dihydrobovolide
610.037-oxo-dihydrotheaspirane a1
670.037-oxo-dihydrotheaspirane a2
620.027-oxo-dihydrotheaspirane b1
680.027-oxo-dihydrotheaspirane b2
1670.022,3-dimethyl-2-nonen-4-olide
120trace(E)-6,10- dimethyl-5,9-undecadien-2-ol
130trace5,8-epidioxy-6-megastigmen-9-ol
153trace2,3- epoxy-2,6,6-trimethyl cyclohexan-1,4-dione
1840.01  ethyl 2-hydroxy-3-methyl valerate
178trace  ethyl 2-methyl butyrate
179trace  ethyl 3-methyl butyrate
220.50  ethyl benzoate
1770.01  ethyl butyrate
181trace  ethyl caproate
196trace  ethyl caprylate
233trace  ethyl cinnamate
2380.03  ethyl nicotinate
183trace  ethyl tiglate
690.30  eugenol
770.10iso eugenol
430.80(E,E)-alpha- farnesene
1250.20(E,E)- farnesol
1380.01  geranial
1580.10  geranic acid
1240.02  geraniol
207trace  geranyl acetate
480.04(E)- geranyl acetone
206trace  geranyl formate
1270.30  geranyl linalool
1030.10  germacrene D
1490.012- heptadecanone
1070.01  heptanol
252trace  heptanonitrile
255trace  hexadecanonitrile
90.02  hexanol
106trace(E)-2- hexenal
100.01(Z)-3- hexen-1-ol
70.01(Z)-3- hexen-1-yl acetate
192trace(Z)-3- hexen-1-yl acetate
1910.05(Z)-3- hexen-1-yl benzoate
189trace(Z)-3- hexen-1-yl butyrate
188trace(Z)-3- hexen-1-yl formate
1900.02(Z)-3- hexen-1-yl tiglate
186trace  hexyl acetate
1870.05  hexyl benzoate
185trace  hexyl formate
102tracealpha- humulene
136tracepara- hydroxyanisole
784.00  indole
550.03(E)-beta- ionol
1560.054-oxo-beta- ionol
510.10alpha- ionol
128tracebeta- ionol 5,6-epoxide
470.03(E)-alpha- ionone
540.20(E)-beta- ionone
560.10beta-ionone 5,7-epoxide
860.50(E)-alpha-ionone oxime
890.90(E)-beta-ionone oxime
850.20(Z)-alpha-ionone oxime
880.30(Z)-beta-ionone oxime
208tracebeta-ionyl formate
490.05(Z)- jasmone
2490.02 jasmone oxime
3trace  limonene
160.80  linalool
120.20(Z)- linalool oxide furanoid
350.20(E)- linalool oxide pyranoid
312.50(Z)- linalool oxide pyranoid
1631.00  linoleic acid
1640.50  linolenic acid
193trace  methyl (E)-2-hexenoate
260.02 methyl (E)-3-methyl-4-decenoate
800.14 methyl (E)-jasmonate
194trace  methyl (Z)-3-hexenoate
2010.01 methyl (Z)-3-methyl-4-decenoate
2000.02  methyl (Z)-4-decenoate
790.06  methyl (Z)-jasmonate
110.01  methyl 2-hydroxy-3-methyl butyrate
130.02 methyl 2-hydroxy-3-methyl valerate
1750.01  methyl 2-methyl butyrate
1760.01  methyl 3-methyl butyrate
2340.02  methyl 5-phenyl valerate
239trace4- methyl anisole
729.00  methyl anthranilate
175.00  methyl benzoate
1040.012- methyl butanol
105trace3- methyl butanol
140.02(E+Z)-2- methyl butyraldoxime
150.02(E+Z)-3- methyl butyraldoxime
174trace  methyl butyrate
1trace2- methyl butyronitrile
199trace  methyl caprinate
180trace  methyl caproate
1950.02  methyl caprylate
2320.05  methyl cinnamate
2420.10  methyl eugenol
2040.05  methyl geranate
173trace  methyl isobutyrate
2430.20  methyl isoeugenol
2500.02(Z)-methyl jasmonate oxime
2020.15  methyl laurate
942.01  methyl linoleate
960.50  methyl linolenate
2360.10  methyl N-acetyl anthranilate
650.02  methyl N-ethyl anthranilate
2370.10  methyl N-formyl anthranilate
630.05  methyl N-methyl anthranilate
280.15  methyl nicotinate
810.20  methyl palmitate
320.10  methyl phenyl acetate
340.15  methyl salicylate
920.20  methyl stearate
182trace  methyl tiglate
2350.01  methyl vanillate
5trace2- methyl-1-nitrobutane
146trace(E)-3- methyl-2-nonen-4-one
1190.02(E)-3- methyl-4-decen-1-ol
410.02(E)-3- methyl-4-decen-1-ol
580.043- methyl-5-(2,6,6-trimethyl cyclohex-1-en-1-yl) isoxazole
80.026- methyl-5-hepten-2-one
440.03(E+Z)-6- methyl-5-hepten-2-one oxime
99trace  myrcene
137trace  neral
1230.01  nerol
700.40(E)- nerolidol
205trace  neryl formate
590.101- nitro-2-phenethane
165trace  nonan-4-olide
1140.03  nonanol
1450.022- nonanone
2470.012- nonanone oxime
1170.02(Z,Z)-3,6- nonen-1-ol
115trace(Z)-3- nonen-1-ol
116trace(Z)-6- nonen-1-ol
1980.01(Z)-6- nonen-1-yl acetate
166trace2- nonen-4-olide
60.20(E)-beta- ocimene
1000.02(Z)-beta- ocimene
113trace(E,E)-2,4- octadien-1-ol
1120.01(Z,Z)-2,5-octadien-1-ol
1080.05  octanol
1440.013- octanone
246trace3- octanone oxime
253trace  octanonitrile
110trace(E)-2- octen-1-ol
109trace(Z)-2- octen-1-ol
1110.01(Z)-5- octen-1-ol
1970.05(Z)-5- octen-1-yl acetate
1610.20  palmitic acid
1480.012- pentadecanone
390.302- phenethyl acetate
4230.002- phenethyl alcohol
950.502- phenethyl benzoate
2200.012- phenethyl butyrate
2230.052- phenethyl caproate
2240.052- phenethyl caprylate
330.302- phenethyl formate
219trace2- phenethyl isobutyrate
2210.022- phenethyl isovalerate
241trace2- phenethyl methyl ether
2250.202- phenethyl phenyl acetate
2220.022- phenethyl tiglate
132trace  phenol
1410.02  phenyl acetaldehyde
761.00(E+Z)- phenyl acetaldoxime
230.01(E+Z)-phenyl acetaldoxime-O-methyl ether
1600.20  phenyl acetic acid
142trace  phenyl propionaldehyde
2270.053- phenyl propyl acetate
1310.023- phenyl propyl alcohol
2260.053- phenyl propyl formate
1260.30  phytol
97tracealpha- pinene
20.01beta- pinene
98trace  sabinene
245trace  safrole
1620.50  stearic acid
1210.03  terpinen-4-ol
270.10alpha- terpineol
254trace  tetradecanonitrile
840.054,4a,5,6-tetrahydro-4,4,7-trimethyl-2(3H)-naphthalenone
190.021,2,5,5-tetramethyl octahydroquinoline
660.031,3,7,7-tetramethyl-2-oxabicyclo(4.4.0)decan-9-one
290.202,5,5,8a- tetramethyl-6,7,8,8a-tetrahydro-1(5H)-1-benzopyran
180.02  theaspirane A
200.02  theaspirane B
1470.022- tridecanone
1520.012,6,6- trimethyl cyclohexan-1,4-dione
1500.206,10,14- trimethyl pentadecan-2-one
2480.056,10,14-trimethyl pentadecan-2-one oxime
1510.052,6,6- trimethyl-2-cyclohexen-1,4-dione
300.012,5,5-trimethyl-5,6,7,8-tetrahydroquinoline
240.012- undecanone
135tracepara- vinyl phenol

R. Kaiser, New volatile constituents of the flower concrete of Michelia champaca L. In: Proceedings of 11th International Congress of Essential Oils, Fragrances and Flavours. Edits., S. C. Bhattacharyya, N. Sen and K. L. Sethi, p. 1-13, Oxford & IBH Publishing Co., Pvt. Ltd, New Delhi (1989).

P&F 25, No. 4, 55, (2000)

ylang ylang flower oil
#%LeftshiftComponents
510.13alpha- amorphene
290.35(E)- anethole
50.94  benzaldehyde
2011.63  benzyl acetate
112.20  benzyl alcohol
636.19  benzyl benzoate
330.04  benzyl butyrate
651.37  benzyl salicylate
580.07alpha- bisabolol
470.713- buten-2-yl benzoate
360.08  butyl benzoate
530.16delta- cadinene
540.12gamma- cadinene
600.12 cadinol
610.12alpha- cadinol
421.69beta- caryophyllene
570.07  caryophyllene oxide
120.091,8- cineole
432.09(E)- cinnamyl acetate
300.26(E)- cinnamyl alcohol
380.13alpha- copaene
170.09para- cresol
100.34para- cresyl methyl ether
450.58beta- cubebene
260.131,4- dimethoxybenzene
250.173,4- dimethoxytoluene
211.46  ethyl benzoate
440.37(Z)-iso eugenol
522.34(E,E)-alpha- farnesene
620.84(E,E)- farnesol
640.61(E,E)- farnesyl acetate
371.96  geranyl acetate
495.55  germacrene D
30.28(E)-2- hexen-1-ol
90.16(Z)-3- hexen-1-yl acetate
550.19(Z)-3- hexen-1-yl benzoate
460.74alpha- humulene
130.07  limonene
1835.49  linalool
220.072- methoxy-4-methyl phenol
150.172- methoxyphenol
390.114-methoxyphenyl methyl acetate
310.05  methyl 2-methoxybenzoate
350.06  methyl 4-methoxybenzoate
320.08  methyl anthranilate
166.50  methyl benzoate
480.86  methyl eugenol
230.29  methyl salicylate
20.063- methyl-2-butenol
40.333- methyl-2-butenyl acetate
10.072- methyl-3-butenol
500.14gamma- muurolene
590.11alpha- muurolol
80.16  myrcene
270.27  nerol
560.13(E)- nerolidol
140.14(E)-beta- ocimene
280.202- phenyl-1-nitroethane
61.87alpha- pinene
70.66beta- pinene
340.084-(2- propenyl) phenol
240.14alpha- terpineol
415.51  tetradecane
400.16alpha- ylangene

E. E. Stashenko, W. Torres and J. R. Martinez Morales, A study of the compositional variation of the essential oil of ylang ylang (Cananga odorata Hook. fil. et Thomson, forma genuina) during flower development. J. High Resol. Chromatogr., 18, 101-104 (1995).

P&F 24, No. 4, 31, (1999)

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