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Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless clear liquid (est) |
| Assay: | 98.00 to 100.00 %
|
| Food Chemicals Codex Listed: | Yes |
| Specific Gravity: | 1.04310 to 1.04600 @ 25.00 °C.
|
| Pounds per Gallon - (est).: | 8.680 to 8.704
|
| Refractive Index: | 1.50200 to 1.50600 @ 20.00 °C.
|
| Melting Point: | -35.00 to -34.00 °C. @ 760.00 mm Hg
|
| Boiling Point: | 212.00 to 214.00 °C. @ 760.00 mm Hg
|
| Boiling Point: | 95.00 to 96.00 °C. @ 15.00 mm Hg
|
| Acid Value: | 1.00 max. KOH/g
|
| Vapor Pressure: | 0.267000 mmHg @ 25.00 °C. |
| Vapor Density: | 5.17 ( Air = 1 ) |
| Flash Point: | 190.00 °F. TCC ( 87.78 °C. )
|
| logP (o/w): | 2.640 |
| Soluble in: |
| | alcohol | | | fixed oils | | | propylene glycol | | | water, 720 mg/L @ 25 °C (exp) |
| Insoluble in: |
| | glycerin |
| Stability: |
| | non-discoloring in most media |
Organoleptic Properties:
| |
| Odor Type: minty |
| |
| Odor Strength: | medium |
| |
| Substantivity: | 12 hour(s) at 100.00 % |
| |
| | fruity dry musty sweet wintergreen |
Odor Description: at 100.00 %. | fruity dry musty sweet wintergreen Luebke, William tgsc, (1994) |
| |
| | sweet wintergreen fruity medicinal cherry grape |
Odor Description:
| Sweet, wintergreen, fruity, medicinal, cherry, grape Mosciano, Gerard P&F 16, No. 5, 71, (1991) |
| |
| |
| Flavor Type: medicinal |
| |
| | sweet medicinal green minty fruity wintergreen |
Taste Description: at 30.00 ppm. | Sweet, medicinal, green, minty, fruity, birch beer and wintergreen like Mosciano, Gerard P&F 16, No. 5, 71, (1991) |
| |
| Odor and/or flavor descriptions from others (if found). |
| |
| Symrise |
| Ethyl benzoate |
| Odor Description: | mild, sweeter than methyl ester |
| Taste Description: | wintergreen, tar-like, green, minty, honey, phenolic Useful in: brown nuts, vanilla, savory spices, fruity citrus, fruity red, fruity yellow, fruity tropical, sweet others, alcoholics. |
| |
| Moellhausen |
| ETHYL BENZOATE |
| Odor Description: | aromatic, balsamic, phenolic, wintergreen |
| Taste Description: | honey, mint, medicinal, fruity |
| |
| |
Cosmetic Information:
Suppliers:
| Advanced Biotech |
| ETHYL BENZOATE NATURAL
99% min. Odor: Fruity |
| Alfrebro |
| ETHYL BENZOATE NATURAL
Odor: Heavy, Floral, Fruity |
| Allan Chemical |
| Ethyl Benzoate
|
| Ambles Nature et Chimie |
| BENZOATE ETHYLE NAT
|
| Augustus Oils |
| Ethyl Benzoate
|
| Services |
| Aurochemicals |
| ETHYL BENZOATE, Natural
|
| Axxence Aromatic |
| ETHYL BENZOATE Natural
Kosher |
| Sustainability |
| Bell Flavors & Fragrances |
| Ethyl Benzoate
|
| Berjé |
| Ethyl Benzoate
|
| Media |
| BOC Sciences |
| For experimental / research use only. |
| Ethyl Benzoate > 95%
|
| Charkit Chemical |
| ETHYL BENZOATE FEMA 2422
|
| Diffusions Aromatiques |
| ETHYL BENZOATE NATUREL
|
| Elan Inc. |
| ETHYL BENZOATE
FCC, Kosher |
| EMD Millipore |
| For experimental / research use only. |
| Ethyl Benzoate
|
| Ernesto Ventós |
| ETHYL BENZOATE
Odor: FRUITY, MEDICINAL, CHERRY, GRAPE Flavor: SWEET,MEDICINAL,GREEN,FRUITY,MINTY |
| Excellentia International |
| Ethyl Benzoate Natural
|
| ExtraSynthese |
| For experimental / research use only. |
| Benzoic acid ethylester (GC) ≥99%
|
| Fleurchem |
| ethyl benzoate natural
|
| fnfsurplus.com |
| Ethyl Benzoate, Ester
|
| Frutarom |
| ETHYL BENZOATE
KOSHER Flavor: fruity dry musty sweet wintergreen |
| CBD Offering |
| Glentham Life Sciences |
| Ethyl benzoate
|
| Global Essence |
| Ethyl Benzoate Natural
|
| H. Interdonati, Inc. |
| Ethyl Benzoate Natural, Kosher
|
| Featured Products |
| IFF |
| ETHYL BENZOATE
KOSHER Flavor: fruity dry musty sweet wintergreen |
| Indenta Group |
| Ethyl Benzoate
|
| Indukern F&F |
| ETHYL BENZOATE
|
| K.L. Koh Enterprise |
| ETHYL BENZOATE
|
| Lluch Essence |
| ETHYL BENZOATE NATURAL
|
| Lluch Essence |
| ETHYL BENZOATE
|
| M&U International |
| ETHYL BENZOATE
|
| M&U International |
| NAT.ETHYL BENZOATE, Kosher
|
| Moellhausen |
| ETHYL BENZOATE
Odor: aromatic, balsamic, phenolic, wintergreen Flavor: honey, mint, medicinal, fruity |
| Pearlchem Corporation |
| Natural Ethyl Benzoate
|
| Penta International |
| ETHYL BENZOATE NATURAL
|
| Penta International |
| ETHYL BENZOATE
|
| PerfumersWorld |
| Ethyl Benzoate
Odor: fruity dry musty sweet wintergreen Warm floral-fruity somewhat heavy Use: Blends-well-with - +Ylang Labdanum Gums |
| R C Treatt & Co Ltd |
| Ethyl Benzoate
|
| Reincke & Fichtner |
| Ethyl Benzoate natural
|
| Reincke & Fichtner |
| Ethyl Benzoate
|
| Robertet |
| ETHYL BENZOATE
Pure & Nat (EU) |
| Seasons and Harvest / Crop calendar |
| Santa Cruz Biotechnology |
| For experimental / research use only. |
| Ethyl Benzoate
|
| Sigma-Aldrich |
| Ethyl benzoate, ≥99%, FCC, FG
Odor: anise; banana; berry; cherry; grape; floral; plum; vanilla; minty |
| Certified Food Grade Products |
| Sigma-Aldrich |
| Ethyl benzoate, natural, ≥99%, FCC, FG
Odor: anise; banana; berry; cherry; grape; floral; plum; vanilla; minty |
| SRS Aromatics |
| ETHYL BENZOATE
|
| Sunaux International |
| nat.Ethyl Benzoate
|
| Symrise |
| Ethyl benzoate
Odor: mild, sweeter than methyl ester Flavor: wintergreen, tar-like, green, minty, honey, phenolic Useful in: brown nuts, vanilla, savory spices, fruity citrus, fruity red, fruity yellow, fruity tropical, sweet others, alcoholics. |
| Taytonn ASCC |
| Ethyl Benzoate
Odor: Fruity, Floral, Dry, Musty, Warm |
| TCI AMERICA |
| For experimental / research use only. |
| Ethyl Benzoate >99.0%(GC)
|
| The John D. Walsh Company |
| Ethyl Benzoate
|
| The Lermond Company |
| ETHYL BENZOATE
|
| Ungerer & Company |
| Ethyl Benzoate Natural
|
| Ungerer & Company |
| Ethyl Benzoate
|
| United International |
| Ethyl benzoate Nat.
|
| United International |
| Ethyl Benzoate
|
| Vigon International |
| Ethyl Benzoate Natural
|
| Vigon International |
| Ethyl Benzoate
Odor: HEAVY, FLORAL, FRUITY |
| WEN International |
| ETHYL BENZOATE Natural
|
Safety Information:
| Preferred SDS: View |
| European information : |
| Most important hazard(s): | | Xi - Irritant |
R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing.
|
| |
| Hazards identification |
| |
| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
| |
| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Human Experience: |
| 8 % solution: no irritation or sensitization. |
| Oral/Parenteral Toxicity: |
oral-rat LD50 2100 mg/kg (Graham & Kuizenga, 1945)
oral-rat LD50 [sex: M,F] 6480 mg/kg (Smyth et al., 1954)
oral-rabbit LD50 2630 mg/kg BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
SKIN AND APPENDAGES (SKIN): HAIR: OTHER
BEHAVIORAL: MUSCLE WEAKNESS Journal of Pharmacology and Experimental Therapeutics. Vol. 84, Pg. 358, 1945.
oral-rat LD50 2100 mg/kg SKIN AND APPENDAGES (SKIN): HAIR: OTHER
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
BEHAVIORAL: MUSCLE WEAKNESS Journal of Pharmacology and Experimental Therapeutics. Vol. 84, Pg. 358, 1945.
|
| Dermal Toxicity: |
skin-cat LDLo 10000 mg/kg BEHAVIORAL: MUSCLE WEAKNESS
GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS
BEHAVIORAL: TREMOR Journal of Pharmacology and Experimental Therapeutics. Vol. 84, Pg. 358, 1945.
|
| Inhalation Toxicity: |
|
Not determined
|
Safety in Use Information:
| Category: | flavor and fragrance agents |
| RIFM Fragrance Material Safety Assessment: Search |
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
| limits in the finished product for - "leave on the skin contact": | | | 0.5000 % Recommendation.
|
| limits in the finished product for - "wash off the skin contact": | | | 0.5000 % Recommendation.
|
| limits in the finished product for - "no skin contact": | | | 8.0000 % Recommendation.
|
| Recommendation for ethyl benzoate usage levels up to: | | | 8.0000 % in the fragrance concentrate.
|
| |
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 96.00 (μg/capita/day) |
| Maximised Survey-derived Daily Intakes (MSDI-USA): | 110.00 (μg/capita/day) |
| Structure Class: | I |
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 3 |
| Click here to view publication 3 |
| | average usual ppm | average maximum ppm |
| baked goods: | - | 10.00000 |
| beverages(nonalcoholic): | - | 2.80000 |
| beverages(alcoholic): | - | 0.50000 |
| breakfast cereal: | - | - |
| cheese: | - | - |
| chewing gum: | - | 59.00000 |
| condiments / relishes: | - | - |
| confectionery froastings: | - | - |
| egg products: | - | - |
| fats / oils: | - | - |
| fish products: | - | - |
| frozen dairy: | - | 2.80000 |
| fruit ices: | - | 2.80000 |
| gelatins / puddings: | - | 0.06000 |
| granulated sugar: | - | - |
| gravies: | - | - |
| hard candy: | - | 9.00000 |
| imitation dairy: | - | - |
| instant coffee / tea: | - | - |
| jams / jellies: | - | - |
| meat products: | - | - |
| milk products: | - | - |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | - | - |
| snack foods: | - | - |
| soft candy: | - | - |
| soups: | - | - |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
Safety References:
| Flavor & Extract Manufacturers Association (FEMA) reference(s): |
| The FEMA GRAS assessment of benzyl derivatives used as flavor ingredients. View pdf |
| European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
| European Food Safety Authority (EFSA) reference(s): |
Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) on a request from the Commission related to Flavouring Group Evaluation 20 (FGE.20): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical group 23 View page or View pdf |
Flavouring Group Evaluation 54 (FGE.54)[1] - Consideration of benzyl derivatives evaluated by JECFA (57th meeting) structurally related to benzyl alcohols, benzaldehydes, a related acetal, benzoic acids and related esters evaluated by EFSA in FGE.20 (2005) - Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food View page or View pdf |
Flavouring Group Evaluation 20, Revision 1 (FGE.20Rev1): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids and related esters from chemical group 23 View page or View pdf |
Flavouring Group Evaluation 54, Revision 1 (FGE.54Rev1): Consideration of benzyl derivatives evaluated by JECFA (57th meeting) structurally related to benzyl alcohols, benzaldehydes, a related acetal, benzoic acids and related esters evaluated by EFSA in FGE.20Rev1 (2009) View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 20, Revision 2 (FGE.20Rev2): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 20, Revision 3(FGE.20Rev3): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30 View page or View pdf |
| EPI System: | View |
| AIDS Citations: | Search |
| Cancer Citations: | Search |
| Toxicology Citations: | Search |
| EPA Substance Registry Services (TSCA): | 93-89-0 |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| Laboratory Chemical Safety Summary : | 7165 |
| National Institute of Allergy and Infectious Diseases: | Data |
| WGK Germany: | 1 |
| | ethyl benzoate |
| Chemidplus: | 0000093890 |
| RTECS: | DH0200000 for cas# 93-89-0 |
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | benzoic acid ethyl ester | | | benzoic acid ethylester | | | benzoic acid, ethyl ester | | | benzoic ether | | | benzoyl ethyl ether | | | ethyl benzene carboxylate | | | ethyl benzenecarboxylate | | nat. | ethyl benzoate | | | ethyl benzoate (natural) | | | ethyl benzoate FCC | | | ethyl benzoate natural | | | ethyl benzoate, natural | | | ethylbenzoate |
Articles:
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