Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Organoleptic Properties:
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Odor Type: green |
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Odor Strength: | medium , recommend smelling in a 10.00 % solution or less |
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Substantivity: | 4 hour(s) at 100.00 % |
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| natural apple juicy |
Odor Description: at 10.00 % in dipropylene glycol. | natural apple juice |
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Odor and/or flavor descriptions from others (if found). |
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Bedoukian Research |
cis-3-HEXENAL DIETHYL ACETAL ≥95.0% (cis), Kosher |
Odor Description: | A green apple, spicy odor with natural connotations Used mostly in fruity compositions. |
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Cosmetic Information:
Suppliers:
Safety Information:
European information : |
Most important hazard(s): | Xn - Harmful. |
R 22 - Harmful if swallowed. R 43 - May cause sensitisation by skin contact. S 02 - Keep out of the reach of children. S 20/21 - When using do not eat, drink or smoke. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 - Wear suitable gloves and eye/face protection.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
Not determined
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Dermal Toxicity: |
Not determined
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | flavor and fragrance agents |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
Recommendation for (Z)-3-hexenal diethyl acetal usage levels up to: | | 3.0000 % in the fragrance concentrate.
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Maximised Survey-derived Daily Intakes (MSDI-EU): | 0.097 (μg/capita/day) |
Modified Theoretical Added Maximum Daily Intake (mTAMDI): | 3900 (μg/person/day) |
Threshold of Concern: | 1800 (μg/person/day) |
Structure Class: | I |
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Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). |
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm. |
| average usage mg/kg | maximum usage mg/kg |
Dairy products, excluding products of category 02.0 (01.0): | 7.00000 | 35.00000 |
Fats and oils, and fat emulsions (type water-in-oil) (02.0): | 5.00000 | 25.00000 |
Edible ices, including sherbet and sorbet (03.0): | 10.00000 | 50.00000 |
Processed fruit (04.1): | 7.00000 | 35.00000 |
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): | - | - |
Confectionery (05.0): | 10.00000 | 50.00000 |
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): | 5.00000 | 25.00000 |
Bakery wares (07.0): | 10.00000 | 50.00000 |
Meat and meat products, including poultry and game (08.0): | 2.00000 | 10.00000 |
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): | 2.00000 | 10.00000 |
Eggs and egg products (10.0): | - | - |
Sweeteners, including honey (11.0): | - | - |
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): | 5.00000 | 25.00000 |
Foodstuffs intended for particular nutritional uses (13.0): | 10.00000 | 50.00000 |
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): | 5.00000 | 25.00000 |
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): | 10.00000 | 50.00000 |
Ready-to-eat savouries (15.0): | 20.00000 | 100.00000 |
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): | 5.00000 | 25.00000 |
Safety References:
European Food Safety Athority(efsa): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
European Food Safety Authority (EFSA) reference(s): |
Flavouring Group Evaluation 3, Revision 1 (FGE.03Rev1): Acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated or unsaturated aldehydes, an ester of a hemiacetal and an orthoester of formic acid, from chemical groups 1, 2 & 4 Commission Regulation (EC) No 1565/2000 of 18 July 2000) [1] - Scientific Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC)on a request from the Commission View page or View pdf |
Flavouring Group Evaluation 61, Revision 1 (FGE.61Rev1): Consideration of aliphatic acetals evaluated by JECFA (57th meeting) structurally related to acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated aldehydes and one orthoester of formic acid evaluated View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 3, Revision 2 (FGE.03Rev2): Acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated or unsaturated aldehydes, an ester of a hemiacetal and an orthoester of formic acid, from chemical groups 1, 2 and 4 View page or View pdf |
EPI System: | View |
EPA Substance Registry Services (TSCA): | 73545-18-3 |
EPA ACToR: | Toxicology Data |
EPA Substance Registry Services (SRS): | Registry |
Laboratory Chemical Safety Summary : | 5364291 |
National Institute of Allergy and Infectious Diseases: | Data |
WISER: | UN 1993 |
WGK Germany: | 2 |
| (Z)-1,1-diethoxyhex-3-ene |
Chemidplus: | 0073545183 |
References:
Other Information:
Potential Blenders and core components note
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For Odor |
animal |
| methyl (E)-2-octenoate | FL/FR |
buttery |
| apple butter fragrance | FR |
camphoreous |
| herbal ethanone | FR |
caramellic |
| maltyl propionate | FL/FR |
chemical |
| propyl propionate | FL/FR |
citrus |
| methyl heptenone | FL/FR |
fatty |
| allyl octanoate | FL/FR |
3- | decen-2-one | FL/FR |
| methyl 2-hexenoate | FL/FR |
fermented |
| hexanal diethyl acetal | FL/FR |
floral |
| citronellyl isovalerate | FL/FR |
gamma- | damascone | FR |
(Z)-alpha- | damascone | FL/FR |
alpha- | damascone | FL/FR |
| ethyl safranate | FR |
| hexyl 2-furoate | FL/FR |
| methyl citronellate | FL/FR |
| phenethyl hexanoate | FL/FR |
2- | phenyl propyl isobutyrate | FL/FR |
| rose butanoate | FL/FR |
fruity |
| allyl 10-undecenoate | FL/FR |
| allyl 3,5,5-trimethyl hexanoate | FL/FR |
| allyl amyl glycolate | FR |
| allyl butyrate | FL/FR |
| allyl cinnamate | FL/FR |
| allyl cyclohexyl acetate | FL/FR |
| allyl cyclohexyl butyrate | FL/FR |
| allyl cyclohexyl propionate | FL/FR |
| allyl heptanoate | FL/FR |
| allyl hexanoate | FL/FR |
| allyl isovalerate | FL/FR |
| allyl phenoxyacetate | FL/FR |
| allyl propionate | FL/FR |
| allyl salicylate | FR |
| allyl sorbate | FL/FR |
| amyl 2-methyl butyrate | FL/FR |
iso | amyl 2-methyl butyrate | FL/FR |
| amyl butyrate | FL/FR |
| amyl hexanoate | FL/FR |
iso | amyl hexanoate | FL/FR |
| amyl isobutyrate | FL/FR |
iso | amyl isobutyrate | FL/FR |
| amyl isovalerate | FL/FR |
iso | amyl isovalerate | FL/FR |
iso | amyl octanoate | FL/FR |
iso | amyl propionate | FL/FR |
| amyl propionate | FL/FR |
iso | amyl valerate | FL/FR |
| amyl valerate | FL/FR |
| apple crotonate | FR |
| apple ketal | FL/FR |
| benzyl ethyl ether | FL/FR |
| benzyl isovalerate | FL/FR |
| benzyl propionate | FL/FR |
iso | butyl 2-butenoate | FL/FR |
iso | butyl acetate | FL/FR |
iso | butyl butyrate | FL/FR |
| butyl butyrate | FL/FR |
iso | butyl furyl propionate | FL/FR |
| butyl hexanoate | FL/FR |
iso | butyl hexanoate | FL/FR |
| butyl isobutyrate | FL/FR |
iso | butyl isobutyrate | FL/FR |
| butyl isovalerate | FL/FR |
iso | butyl isovalerate | FL/FR |
| butyl valerate | FL/FR |
| cherry pentenoate | FL/FR |
| cinnamyl isobutyrate | FL/FR |
| cyclohexyl butyrate | FL/FR |
| cyclohexyl hexanoate | FL/FR |
| cyclohexyl isovalerate | FL/FR |
(E)-alpha- | damascone | FL/FR |
| diethyl malonate | FL/FR |
| ethyl (E)-2-decenoate | FL/FR |
| ethyl (Z)-4-octenoate | FL/FR |
| ethyl 2-methyl butyrate | FL/FR |
| ethyl 3-(2-furyl) propanoate | FL/FR |
| ethyl 3-hexenoate | FL/FR |
| ethyl 3-hydroxyhexanoate | FL/FR |
| ethyl 3-methyl valerate | FL/FR |
| ethyl 3,5,5-trimethyl hexanoate | FR |
| ethyl acetoacetate | FL/FR |
| ethyl butyrate | FL/FR |
| ethyl cyclohexane propionate | FL/FR |
| ethyl heptanoate | FL/FR |
| ethyl hexanoate | FL/FR |
| ethyl isovalerate | FL/FR |
| ethyl levulinate | FL/FR |
| ethyl propionate | FL/FR |
| ethyl valerate | FL/FR |
| fruity ketal | FL/FR |
| geranyl 2-methyl butyrate | FL/FR |
| geranyl acetoacetate | FL/FR |
| geranyl isovalerate | FL/FR |
| grape butyrate | FL/FR |
| green acetate | FR |
4- | heptanone | FL/FR |
| heptyl isobutyrate | FL/FR |
(Z)-3- | hexen-1-yl isobutyrate | FL/FR |
(Z)-3- | hexenal dimethyl acetal | |
| hexyl (E)-tiglate | FL/FR |
| hexyl acetate | FL/FR |
| hexyl formate | FL/FR |
| linalyl hexanoate | FL/FR |
| methyl (Z)-4-octenoate | FL/FR |
| methyl 2-methyl butyrate | FL/FR |
| methyl 2-methyl valerate | FL/FR |
| methyl 4-methyl valerate | FL/FR |
2- | methyl butyl isovalerate | FL/FR |
| methyl butyrate | FL/FR |
| methyl hexanoate | FL/FR |
| methyl isobutyrate | FL/FR |
| methyl isovalerate | FL/FR |
| methyl propionate | FL/FR |
| methyl valerate | FL/FR |
| nonyl isovalerate | FL/FR |
| pineapple hydroxyhexanoate | FL/FR |
| pineapple pentenoate | FL/FR |
iso | propyl 2-methyl butyrate | FL/FR |
| propyl butyrate | FL/FR |
iso | propyl butyrate | FL/FR |
| propyl heptanoate | FL/FR |
| propyl hexanoate | FL/FR |
iso | propyl hexanoate | FL/FR |
iso | propyl isobutyrate | FL/FR |
iso | propyl isovalerate | FL/FR |
| propyl isovalerate | FL/FR |
iso | propyl propionate | FL/FR |
| tetrahydrofurfuryl butyrate | FL/FR |
| tropical ionone | FL/FR |
2- | undecanone | FL/FR |
| vanilla carboxylate | FL/FR |
green |
iso | amyl 3-(2-furan) propionate | FL/FR |
| butyl heptanoate | FL/FR |
| cognac heptanone | FL/FR |
| ethyl (E,Z)-2,4-decadienoate | FL/FR |
| ethyl (E)-4-decenoate | FL/FR |
| galbanum oxyacetate | FR |
| galbascone (IFF) | FR |
| heptyl formate | FL/FR |
(Z)-3- | hexen-1-yl 2-methyl butyrate | FL/FR |
(E)-2- | hexen-1-yl acetate | FL/FR |
(Z)-3- | hexen-1-yl acetate | FL/FR |
(E)-2- | hexen-1-yl butyrate | FL/FR |
(Z)-3- | hexen-1-yl butyrate | FL/FR |
(E)-2- | hexen-1-yl isovalerate | FL/FR |
(Z)-3- | hexen-1-yl isovalerate | FL/FR |
(Z)-3- | hexen-1-yl methyl carbonate | FL/FR |
(Z)-3- | hexen-1-yl propionate | FL/FR |
(E)-2- | hexen-1-yl propionate | FL/FR |
(Z)-3- | hexen-1-yl valerate | FL/FR |
(E)-2- | hexen-1-yl valerate | FL/FR |
3- | hexenal | FL/FR |
(Z)-3- | hexenal | FL/FR |
3- | hexenyl 2-methyl butyrate | FL/FR |
| hexyl 2-methyl butyrate | FL/FR |
| hexyl butyrate | FL/FR |
| hexyl isobutyrate | FL/FR |
| hexyl octanoate | FL/FR |
| manzanate (Givaudan) | FL/FR |
(Z)-5- | octen-1-yl propionate | FL/FR |
(E)-2- | pentenal | FL/FR |
| phenoxyethyl isobutyrate | FL/FR |
| pineapple heptadienone 10% | FR |
| propyl tiglate | FL/FR |
| sorbyl isobutyrate | FL/FR |
herbal |
| benzyl octanoate | FL/FR |
3- | octyl acetate | FL/FR |
| tagete oil india | FL/FR |
nutty |
2- | methyl-3-ethoxypyrazine | FL/FR |
spicy |
| apple spice fragrance | FR |
| cinnamyl isovalerate | FL/FR |
sulfurous |
| ethyl methyl mercaptopropionate | FL/FR |
| mango thiol | FL/FR |
tropical |
| ethyl (Z)-3-hexenoate | FL/FR |
cis- | galbanum oxathiane | FL/FR |
| tropical 3-thiobutyrate | FL/FR |
2- | tropical oxathiane | FL/FR |
waxy |
| allyl nonanoate | FL/FR |
| ethyl decanoate | FL/FR |
| nonyl acetate | FL/FR |
(E)-2- | tridecen-1-yl acetate | FL/FR |
woody |
iso | bornyl isovalerate | FL/FR |
| marine formate | FR |
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For Flavor |
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No flavor group found for these |
| allyl 10-undecenoate | FL/FR |
| allyl 3,5,5-trimethyl hexanoate | FL/FR |
| allyl cinnamate | FL/FR |
| allyl cyclohexyl butyrate | FL/FR |
| allyl cyclohexyl valerate | FL |
| allyl sorbate | FL/FR |
| amyl 2-methyl butyrate | FL/FR |
iso | amyl 3-methyl thiopropionate | FL |
| amyl isobutyrate | FL/FR |
| amyl isovalerate | FL/FR |
| amyl propionate | FL/FR |
| amyl valerate | FL/FR |
| benzyl ethyl ether | FL/FR |
| benzyl octanoate | FL/FR |
| citronellyl isovalerate | FL/FR |
| cyclohexyl butyrate | FL/FR |
| cyclohexyl hexanoate | FL/FR |
(Z)-alpha- | damascone | FL/FR |
| ethyl (Z)-3-hexenoate | FL/FR |
| ethyl 3-methyl valerate | FL/FR |
| ethyl cyclohexane propionate | FL/FR |
| geranyl 2-methyl butyrate | FL/FR |
| geranyl acetoacetate | FL/FR |
| heptyl 2-methyl butyrate | FL |
| hexanal diethyl acetal | FL/FR |
2- | hexenal | FL |
2- | hexenal diethyl acetal | FL |
(Z)-3- | hexenal dimethyl acetal | |
(E)-2- | hexenal dimethyl acetal | FL |
| linalyl hexanoate | FL/FR |
| methyl (Z)-4-octenoate | FL/FR |
| methyl 2-hexenoate | FL/FR |
2- | methyl-3-ethoxypyrazine | FL/FR |
| nonyl isovalerate | FL/FR |
2- | phenyl propyl isobutyrate | FL/FR |
iso | propyl hexanoate | FL/FR |
iso | propyl isobutyrate | FL/FR |
iso | propyl isovalerate | FL/FR |
| propyl isovalerate | FL/FR |
| propyl tiglate | FL/FR |
| sorbyl propionate | FL |
(E)-2- | tridecen-1-yl acetate | FL/FR |
2- | tropical oxathiane | FL/FR |
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iso | amyl 3-(2-furan) propionate | FL/FR |
iso | butyl furyl propionate | FL/FR |
| sorbyl isobutyrate | FL/FR |
alliaceous |
| allyl propionate | FL/FR |
berry |
| heptyl isobutyrate | FL/FR |
caramellic |
| maltyl propionate | FL/FR |
citrus |
| cognac heptanone | FL/FR |
cooling |
| manzanate (Givaudan) | FL/FR |
estery |
| ethyl acetoacetate | FL/FR |
ethereal |
| methyl isobutyrate | FL/FR |
fatty |
| allyl octanoate | FL/FR |
| ethyl (E)-4-decenoate | FL/FR |
| heptyl formate | FL/FR |
floral |
| methyl citronellate | FL/FR |
| tropical ionone | FL/FR |
fruity |
| allyl cyclohexyl acetate | FL/FR |
| allyl cyclohexyl propionate | FL/FR |
| allyl heptanoate | FL/FR |
| allyl hexanoate | FL/FR |
| allyl isovalerate | FL/FR |
| allyl phenoxyacetate | FL/FR |
iso | amyl 2-methyl butyrate | FL/FR |
| amyl butyrate | FL/FR |
| amyl hexanoate | FL/FR |
iso | amyl hexanoate | FL/FR |
iso | amyl isobutyrate | FL/FR |
iso | amyl octanoate | FL/FR |
iso | amyl propionate | FL/FR |
iso | amyl valerate | FL/FR |
| apple ketal | FL/FR |
| benzyl isovalerate | FL/FR |
| benzyl propionate | FL/FR |
iso | butyl acetate | FL/FR |
iso | butyl butyrate | FL/FR |
| butyl butyrate | FL/FR |
| butyl heptanoate | FL/FR |
| butyl hexanoate | FL/FR |
iso | butyl hexanoate | FL/FR |
| butyl isobutyrate | FL/FR |
iso | butyl isobutyrate | FL/FR |
| butyl isovalerate | FL/FR |
| butyl valerate | FL/FR |
| cherry pentenoate | FL/FR |
| cinnamyl isobutyrate | FL/FR |
| cinnamyl isovalerate | FL/FR |
| cyclohexyl isovalerate | FL/FR |
(E)-alpha- | damascone | FL/FR |
alpha- | damascone | FL/FR |
| diethyl malonate | FL/FR |
| ethyl (E)-2-decenoate | FL/FR |
| ethyl (E)-2-octenoate | FL |
| ethyl (Z)-4-octenoate | FL/FR |
| ethyl 2-methyl butyrate | FL/FR |
| ethyl 3-(2-furyl) propanoate | FL/FR |
| ethyl 3-hexenoate | FL/FR |
| ethyl 3-hydroxyhexanoate | FL/FR |
| ethyl butyrate | FL/FR |
| ethyl heptanoate | FL/FR |
| ethyl hexanoate | FL/FR |
| ethyl isovalerate | FL/FR |
| ethyl levulinate | FL/FR |
| ethyl propionate | FL/FR |
| ethyl valerate | FL/FR |
| fruity ketal | FL/FR |
| furfuryl valerate | FL |
4- | heptanone | FL/FR |
(Z)-3- | hexen-1-yl isobutyrate | FL/FR |
| hexyl acetate | FL/FR |
| methyl (E)-2-octenoate | FL/FR |
| methyl 2-methyl butyrate | FL/FR |
| methyl 2-methyl valerate | FL/FR |
| methyl 4-methyl valerate | FL/FR |
2- | methyl butyl isovalerate | FL/FR |
| methyl hexanoate | FL/FR |
| methyl isovalerate | FL/FR |
| methyl propionate | FL/FR |
| methyl valerate | FL/FR |
| pineapple hydroxyhexanoate | FL/FR |
| pineapple pentenoate | FL/FR |
iso | propyl 2-methyl butyrate | FL/FR |
iso | propyl butyrate | FL/FR |
| propyl butyrate | FL/FR |
| propyl hexanoate | FL/FR |
iso | propyl propionate | FL/FR |
| rose butanoate | FL/FR |
| tetrahydrofurfuryl butyrate | FL/FR |
| vanilla carboxylate | FL/FR |
fusel |
| methyl butyrate | FL/FR |
green |
| allyl butyrate | FL/FR |
iso | amyl isovalerate | FL/FR |
iso | butyl 2-butenoate | FL/FR |
iso | butyl isovalerate | FL/FR |
3- | decen-2-one | FL/FR |
| ethyl (E,Z)-2,4-decadienoate | FL/FR |
cis- | galbanum oxathiane | FL/FR |
| geranyl isovalerate | FL/FR |
| grape butyrate | FL/FR |
(Z)-3- | hexen-1-yl 2-methyl butyrate | FL/FR |
(Z)-3- | hexen-1-yl acetate | FL/FR |
(E)-2- | hexen-1-yl acetate | FL/FR |
(Z)-3- | hexen-1-yl butyrate | FL/FR |
(E)-2- | hexen-1-yl butyrate | FL/FR |
(Z)-3- | hexen-1-yl isovalerate | FL/FR |
(E)-2- | hexen-1-yl isovalerate | FL/FR |
(Z)-3- | hexen-1-yl methyl carbonate | FL/FR |
(E)-2- | hexen-1-yl propionate | FL/FR |
(Z)-3- | hexen-1-yl propionate | FL/FR |
(Z)-3- | hexen-1-yl valerate | FL/FR |
(E)-2- | hexen-1-yl valerate | FL/FR |
3- | hexenal | FL/FR |
(Z)-3- | hexenal | FL/FR |
(E)-2- | hexenal diethyl acetal | FL |
3- | hexenyl 2-methyl butyrate | FL/FR |
| hexyl (E)-tiglate | FL/FR |
| hexyl 2-furoate | FL/FR |
| hexyl 2-methyl butyrate | FL/FR |
| hexyl butyrate | FL/FR |
| hexyl formate | FL/FR |
| hexyl isobutyrate | FL/FR |
| hexyl octanoate | FL/FR |
| methyl heptenone | FL/FR |
4- | methyl-2-pentenal | FL |
(Z)-5- | octen-1-yl propionate | FL/FR |
3- | octyl acetate | FL/FR |
(E)-2- | pentenal | FL/FR |
| phenoxyethyl isobutyrate | FL/FR |
herbal |
| tagete oil india | FL/FR |
sulfurous |
| ethyl methyl mercaptopropionate | FL/FR |
| mango thiol | FL/FR |
| methyl 4-(methyl thio) butyrate | FL |
| tropical 3-thiobutyrate | FL/FR |
tropical |
| propyl propionate | FL/FR |
waxy |
| allyl nonanoate | FL/FR |
| ethyl decanoate | FL/FR |
| nonyl acetate | FL/FR |
| phenethyl hexanoate | FL/FR |
| propyl heptanoate | FL/FR |
2- | undecanone | FL/FR |
woody |
iso | bornyl isovalerate | FL/FR |
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Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
(Z)-1,1- | diethoxyhex-3-ene | cis-1,1- | diethoxyhex-3-ene | (Z)-3- | hexen-1-al diethyl acetal | cis-3- | hexen-1-al diethyl acetal | cis-3- | hexenal DEA | cis-3- | hexenal diethyl acetal | cis-3- | hexenal, diethyl acetal | 3- | hexene, 1,1-diethoxy-, (3Z)- | 3- | hexene, 1,1-diethoxy-, (Z)- |
Articles:
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