geranyl 2-methyl butyrate
geranyl 2-methylbutyrate
 
Notes:
Used as a food additive [EAFUS]
  • BOC Sciences
    • BOC Sciences
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      BOC Sciences is a brand of BOCSCI Inc. We leverage our wide spectrum of business in the fields of development, manufacturing, marketing, and distribution to help you make best-informed decisions tailored to your evolving needs for premium chemicals. Our complete suite of CRO services spans the entire molecule development pipeline including contract research for target identification, building blocks, compound synthesis, biochemical and cellular analysis, preclinical animal tests, and clinical studies.
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      Product(s):
      68705-63-5 Geranyl 2-methyl Butyrate
       
  • Penta International
    • Penta International Corporation
      Chemistry innovation
      At Penta, our products and services help businesses do business better.
      For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes.
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      Product(s):
      07-17100 GERANYL-2-METHYLBUTYRATE
       
  • Synerzine
    • Synerzine, Inc.
      Innovation. Customization. Aroma Ingredients.
      Synerzine is a leading supplier of flavor and fragrance ingredients.
      Synerzine expresses what we have grown to embody as an organization - the synergy and connection between raw ingredients, science, technology, and the final product. Our experienced team is passionate about bringing our customers high-quality innovative ingredients that they can trust.
      Building upon our 44 year history, the Synerzine team provides customers around the globe with convenient access to over 1200 high-quality aroma ingredients. We actively engage with customers to add a wide array of new products and services on a regular basis. Our aim is to delight every customer with our exceptional services, large product selection, customization and the highest quality and safety standards. We provide our customers with true value designed to help them bring their products to market faster.
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      Product(s):
      W0700 Geranyl Methyl Ethyl Acetate
       
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CAS Number: 68705-63-5Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 272-100-4
FDA UNII: MRW7QH0M9I
Nikkaji Web: J261.162G
XlogP3-AA: 4.90 (est)
Molecular Weight: 238.37062000
Formula: C15 H26 O2
NMR Predictor: Predict (works with chrome or firefox)
Also(can) Contains: neryl 2-methyl butyrate
EFSA/JECFA Comments: CASrn refers to (E)-isomer. Register name to be changed accordingly and in accordance with optical isomerism.
Category: flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
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Google Scholar: with word "volatile"Search
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Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
JECFA Food Flavoring: 1820  (E)-geranyl 2-methylbutyrate
FLAVIS Number: 09.382 (Old)
DG SANTE Food Flavourings: 09.382  geranyl 2-methylbutyrate
FEMA Number: 4122  geranyl 2-methylbutyrate
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF):68705-63-5 ; GERANYL 2-METHYLBUTYRATE
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Physical Properties:
Appearance: colorless clear liquid (est)
Assay: 95.00 to 100.00 % sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity: 0.98700 to 0.90300 @  25.00 °C.
Pounds per Gallon - (est).: 8.213 to  7.514
Refractive Index: 1.43900 to 1.44300 @  20.00 °C.
Boiling Point: 312.00 to  313.00 °C. @ 760.00 mm Hg
Vapor Pressure: 0.001000 mmHg @ 25.00 °C. (est)
Flash Point: 194.00 °F. TCC ( 90.00 °C. )
logP (o/w): 5.276 (est)
Soluble in:
 alcohol
 water, 0.2633 mg/L @ 25 °C (est)
Insoluble in:
 water
Similar Items: note
isoamyl 2-methyl butyrate
amyl 2-methyl butyrate
benzyl 2-methyl butyrate
bornyl 2-methyl butyrate
butyl 2-methyl butyrate
isobutyl 2-methyl butyrate
citronellyl 2-methyl butyrate
ethyl 2-hydroxy-2-methyl butyrate
(±)-ethyl 3-acetoxy-2-methyl butyrate
(±)-ethyl 3-hydroxy-2-methyl butyrate
ethyl 2-methyl butyrate
furfuryl 2-methyl butyrate
heptyl 2-methyl butyrate
(E)-2-hexen-1-yl 2-methyl butyrate
(Z)-3-hexen-1-yl 2-methyl butyrate
3-hexen-1-yl 2-methyl butyrate
hexyl 2-methyl butyrate
methyl 3-acetoxy-2-methyl butyrate
2-methyl butyl 2-methyl butyrate
methyl 2-methyl butyrate
octyl 2-methyl butyrate
propyl 2-methyl butyrate
isopropyl 2-methyl butyrate
propylene glycol di-2-methyl butyrate
propylene glycol mono-2-methyl butyrate
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Organoleptic Properties:
 
Odor Type: fruity
 
Odor Strength: medium
 
 fruity  apple  rose  
Odor Description:
at 100.00 %. 
fruity apple rose
 
Odor and/or flavor descriptions from others (if found).
 
 
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Cosmetic Information:
None found
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Suppliers:
BOC Sciences
For experimental / research use only.
Geranyl 2-methyl Butyrate
Penta International
GERANYL-2-METHYLBUTYRATE
Synerzine
Geranyl Methyl Ethyl Acetate
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Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: flavor and fragrance agents
Recommendation for geranyl 2-methyl butyrate usage levels up to:
  8.0000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.012 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): ND (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI): 2300 (μg/person/day)
Threshold of Concern:1800 (μg/person/day)
Structure Class: I
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 22
Click here to view publication 22
 average usual ppmaverage maximum ppm
baked goods: 10.0000050.00000
beverages(nonalcoholic): 5.0000025.00000
beverages(alcoholic): --
breakfast cereal: 5.0000025.00000
cheese: 7.0000035.00000
chewing gum: --
condiments / relishes: 5.0000025.00000
confectionery froastings: 10.0000050.00000
egg products: --
fats / oils: 5.0000025.00000
fish products: 2.0000010.00000
frozen dairy: 7.0000035.00000
fruit ices: 10.0000050.00000
gelatins / puddings: 5.0000025.00000
granulated sugar: --
gravies: 20.00000100.00000
hard candy: --
imitation dairy: 7.0000035.00000
instant coffee / tea: --
jams / jellies: 5.0000025.00000
meat products: 2.0000010.00000
milk products: 7.0000035.00000
nut products: --
other grains: 5.0000025.00000
poultry: 2.0000010.00000
processed fruits: 7.0000035.00000
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: 5.0000025.00000
snack foods: 10.0000050.00000
soft candy: --
soups: 5.0000025.00000
sugar substitutes: --
sweet sauces: 5.0000025.00000
 
Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i).
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm.
 average usage mg/kgmaximum usage mg/kg
Dairy products, excluding products of category 02.0 (01.0): 7.0000035.00000
Fats and oils, and fat emulsions (type water-in-oil) (02.0): 5.0000025.00000
Edible ices, including sherbet and sorbet (03.0): 10.0000050.00000
Processed fruit (04.1): 7.0000035.00000
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): --
Confectionery (05.0): 10.0000050.00000
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): 5.0000025.00000
Bakery wares (07.0): 10.0000050.00000
Meat and meat products, including poultry and game (08.0): 2.0000010.00000
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): 2.0000010.00000
Eggs and egg products (10.0): --
Sweeteners, including honey (11.0): --
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): 5.0000025.00000
Foodstuffs intended for particular nutritional uses (13.0): 10.0000050.00000
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): --
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): 10.0000050.00000
Ready-to-eat savouries (15.0): 20.00000100.00000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): 5.0000025.00000
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Safety References:
European Food Safety Athority(efsa): Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
European Food Safety Authority (EFSA) reference(s):
Flavouring Group Evaluation 202: 3-Alkylated aliphatic acyclic alpha,beta-unsaturated aldehydes and precursors with or without additional double bonds from chemical subgroup 1.1.3 of FGE.19[1]
View page or View pdf
Scientific Opinion on Flavouring Group Evaluation 95 (FGE.95): Consideration of aliphatic, linear or branched-chain saturated and unsaturated alcohols, aldehydes, acids and related esters evaluated by JECFA (69th meeting) structurally related to esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids evaluated by EFSA in FGE.05Rev1 (2008)
View page or View pdf
EPI System: View
EPA Substance Registry Services (TSCA): 68705-63-5
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 6437648
National Institute of Allergy and Infectious Diseases: Data
 [(2E)-3,7-dimethylocta-2,6-dienyl] 2-methylbutanoate
Chemidplus: 0068705635
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References:
 [(2E)-3,7-dimethylocta-2,6-dienyl] 2-methylbutanoate
NIST Chemistry WebBook: Search Inchi
Pubchem (cid): 6437648
Pubchem (sid): 135067184
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Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS): View
HMDB (The Human Metabolome Database): HMDB32291
FooDB: FDB009482
VCF-Online: VCF Volatile Compounds in Food
ChemSpider: View
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Potential Blenders and core components note
 
For Odor
fatty
3-decen-2-oneFL/FR
fermented
 hexanal diethyl acetalFL/FR
floral
 apple blossom fragranceFR
 benzyl isobutyrateFL/FR
 cassis buteneoneFR
 citronellal diisotridecyl acetalFR
 citronellyl acetateFL/FR
(S)-citronellyl acetateFL/FR
 citronellyl anthranilateFL/FR
 citronellyl hexanoateFL/FR
(E)-citronellyl tiglateFL/FR
beta-damascenoneFL/FR
alpha-damasconeFL/FR
gamma-damasconeFR
(Z)-alpha-damasconeFL/FR
delta-damasconeFL/FR
 dimethyl benzyl carbinyl acetateFL/FR
 ethyl linalyl acetateFR
 ethyl ortho-anisateFL/FR
 ethyl safranateFR
 geraniolFL/FR
 geranyl isobutyrateFL/FR
 geranyl propionateFL/FR
 geranyl valerateFL/FR
 methyl citronellateFL/FR
 phenethyl isobutyrateFL/FR
 phenethyl isovalerateFL/FR
 phenethyl propionateFL/FR
2-phenethyl valerateFL/FR
 pomaroseFR
 rhodinyl butyrateFL/FR
fruity
 acetaldehyde hexyl isoamyl acetalFL/FR
 allyl heptanoateFL/FR
 allyl isononylateFR
 allyl propionateFL/FR
 amyl 2-methyl butyrateFL/FR
 amyl isobutyrateFL/FR
 amyl isovalerateFL/FR
isoamyl valerateFL/FR
 apple cider fragranceFR
baked apple fragranceFR
red apple fragranceFR
green apple fragranceFR
 apple ketalFL/FR
 apple specialtyFR
 benzyl isovalerateFL/FR
 benzyl propionateFL/FR
6-benzyl-2,6-dimethyl-2-cyclohexen-1-one 
 butyl isovalerateFL/FR
isobutyl isovalerateFL/FR
 cyclohexyl butyrateFL/FR
 cyclohexyl isovalerateFL/FR
(E)-beta-damascenoneFL/FR
(E)-alpha-damasconeFL/FR
 eriocephalus punctulatus flower oilFR
 ethyl 2-methyl butyrateFL/FR
 ethyl 3-methyl valerateFL/FR
 ethyl isovalerateFL/FR
(E)-ethyl tiglateFL/FR
 ethyl valerateFL/FR
 fruity ketalFL/FR
 geranyl butyrateFL/FR
 geranyl isovalerateFL/FR
(Z)-3-hexen-1-yl isobutyrateFL/FR
(Z)-3-hexenal dimethyl acetal 
 hexyl formateFL/FR
 hexyl isovalerateFL/FR
2-methyl butyl butyrateFL/FR
 methyl butyrateFL/FR
 methyl isovalerateFL/FR
 methyl valerateFL/FR
 nonyl isovalerateFL/FR
 octyl formateFL/FR
 propyl 2-methyl butyrateFL/FR
 propyl heptanoateFL/FR
isopropyl isobutyrateFL/FR
 propyl isovalerateFL/FR
isopropyl isovalerateFL/FR
(E,E)-5,6,7,7-tetramethyl-2,5-octadien-4-oneFR
green
 butyl heptanoateFL/FR
 ethyl (E,Z)-2,4-decadienoateFL/FR
 galbascone (IFF)FR
 green note propionateFL/FR
(Z)-3-hexen-1-yl 2-methyl butyrateFL/FR
(Z)-3-hexen-1-yl acetateFL/FR
(Z)-3-hexen-1-yl butyrateFL/FR
(E)-2-hexen-1-yl butyrateFL/FR
(E)-2-hexen-1-yl propionateFL/FR
(Z)-3-hexen-1-yl valerateFL/FR
(E)-2-hexen-1-yl valerateFL/FR
(Z)-3-hexenalFL/FR
(Z)-3-hexenal diethyl acetalFL/FR
(E)-2-hexenal propylene glycol acetalFL/FR
3-hexenyl 2-methyl butyrateFL/FR
 hexyl 2-methyl butyrateFL/FR
 hexyl butyrateFL/FR
 hexyl isobutyrateFL/FR
 hexyl phenyl acetateFL/FR
 methyl (E)-3-hexenoateFL/FR
3-octyl formateFL/FR
(E)-2-pentenalFL/FR
 pineapple heptadienone 10%FR
 propyl tiglateFL/FR
herbal
 geranium cyclohexaneFR
 geranyl octanoateFL/FR
 linalyl formateFL/FR
powdery
 applelide (IFF)FR
sulfurous
 ethyl methyl mercaptopropionateFL/FR
waxy
 dihydrocitronellyl acetateFL/FR
 ethyl decanoateFL/FR
 ethyl nonanoateFL/FR
winey
 butyl angelateFL/FR
woody
 marine formateFR
lariciu pine needle oilFR
 santalyl butyrateFL/FR
 
For Flavor
 
No flavor group found for these
 acetaldehyde hexyl isoamyl acetalFL/FR
 amyl 2-methyl butyrateFL/FR
 amyl isobutyrateFL/FR
 amyl isovalerateFL/FR
6-benzyl-2,6-dimethyl-2-cyclohexen-1-one 
 butyl angelateFL/FR
 cyclohexyl butyrateFL/FR
(E)-beta-damascenoneFL/FR
(Z)-alpha-damasconeFL/FR
 dihydrocitronellyl acetateFL/FR
 ethyl 3-methyl valerateFL/FR
 ethyl ortho-anisateFL/FR
 geranyl octanoateFL/FR
 geranyl valerateFL/FR
 heptyl 2-methyl butyrateFL
 hexanal diethyl acetalFL/FR
(E)-3-hexenalFL
(Z)-3-hexenal diethyl acetalFL/FR
(Z)-3-hexenal dimethyl acetal 
(E)-2-hexenal dimethyl acetalFL
(E)-2-hexenal propylene glycol acetalFL/FR
2-hexyl acetateFL
 linalyl formateFL/FR
 nonyl isovalerateFL/FR
2-phenethyl valerateFL/FR
 propyl 2-methyl butyrateFL/FR
isopropyl isobutyrateFL/FR
 propyl isovalerateFL/FR
isopropyl isovalerateFL/FR
 propyl tiglateFL/FR
 santalyl butyrateFL/FR
alliaceous
 allyl propionateFL/FR
floral
 citronellyl acetateFL/FR
(S)-citronellyl acetateFL/FR
 citronellyl hexanoateFL/FR
 dimethyl benzyl carbinyl acetateFL/FR
 geraniolFL/FR
 geranyl isobutyrateFL/FR
 methyl citronellateFL/FR
 phenethyl propionateFL/FR
 rhodinyl butyrateFL/FR
fruity
 allyl heptanoateFL/FR
isoamyl valerateFL/FR
 apple ketalFL/FR
 benzyl isobutyrateFL/FR
 benzyl isovalerateFL/FR
 benzyl propionateFL/FR
 butyl heptanoateFL/FR
 butyl isovalerateFL/FR
 citronellyl anthranilateFL/FR
 cyclohexyl isovalerateFL/FR
alpha-damasconeFL/FR
(E)-alpha-damasconeFL/FR
 ethyl 2-methyl butyrateFL/FR
 ethyl isovalerateFL/FR
(E)-ethyl tiglateFL/FR
 ethyl valerateFL/FR
 fruity ketalFL/FR
 geranyl butyrateFL/FR
(Z)-3-hexen-1-yl isobutyrateFL/FR
 hexyl phenyl acetateFL/FR
2-methyl butyl butyrateFL/FR
 methyl isovalerateFL/FR
 methyl valerateFL/FR
 phenethyl isovalerateFL/FR
fusel
 methyl butyrateFL/FR
green
isobutyl isovalerateFL/FR
(E)-citronellyl tiglateFL/FR
3-decen-2-oneFL/FR
 ethyl (E,Z)-2,4-decadienoateFL/FR
 geranyl isovalerateFL/FR
 green note propionateFL/FR
(Z)-3-hexen-1-yl 2-methyl butyrateFL/FR
(Z)-3-hexen-1-yl acetateFL/FR
(E)-2-hexen-1-yl butyrateFL/FR
(Z)-3-hexen-1-yl butyrateFL/FR
(E)-2-hexen-1-yl propionateFL/FR
(E)-2-hexen-1-yl valerateFL/FR
(Z)-3-hexen-1-yl valerateFL/FR
(Z)-3-hexenalFL/FR
3-hexenyl 2-methyl butyrateFL/FR
 hexyl 2-methyl butyrateFL/FR
 hexyl butyrateFL/FR
 hexyl formateFL/FR
 hexyl isobutyrateFL/FR
 hexyl isovalerateFL/FR
 methyl (E)-3-hexenoateFL/FR
 octyl formateFL/FR
(E)-2-pentenalFL/FR
honey
 phenethyl isobutyrateFL/FR
sulfurous
 ethyl methyl mercaptopropionateFL/FR
waxy
 ethyl decanoateFL/FR
 ethyl nonanoateFL/FR
 geranyl propionateFL/FR
3-octyl formateFL/FR
 propyl heptanoateFL/FR
beta-damascenoneFL/FR
delta-damasconeFL/FR
 
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Potential Uses:
 appleFR
 apricotFR
 chypreFR
 fernFR
 peachFR
 peonyFR
 pineappleFR
 raspberryFR
 roseFR
 rose wild rose 
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Occurrence (nature, food, other): note
 carrot root
Search Trop  Picture
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Synonyms:
 butanoic acid, 2-methyl-, (2E)-3,7-dimethyl-2,6-octadien-1-yl ester
 butanoic acid, 2-methyl-, (2E)-3,7-dimethyl-2,6-octadienyl ester
 butyric acid, 2-methyl-, geranyl ester
 dimethyl octa-2,6-dienyl 2-methyl butyrate
(E)-3,7-dimethyl octa-2,6-dienyl 2-methyl butyrate
 dimethyl-2,6-octadienyl 2-methyl butanoic acid
(2E)-3,7-dimethyl-2,6-octadienyl 2-methyl butanoic acid ester
(2E)-3,7-dimethylocta-2,6-dien-1-yl 2-methylbutanoate
(E)-3,7-dimethylocta-2,6-dienyl 2-methylbutyrate
[(2E)-3,7-dimethylocta-2,6-dienyl] 2-methylbutanoate
 geranyl 2-methyl butanoate
 geranyl 2-methylbutanoate
 geranyl 2-methylbutyrate
(E)-geranyl 2-methylbutyrate
 geranyl methyl ethyl acetate
 geranyl-2-methylbutyrate
2-methyl butanoic acid (2E)-3,7-dimethyl-2,6-octadienyl ester
(E)-neryl 2-methyl butyrate
(E)-neryl 2-methylbutyrate
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