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Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Organoleptic Properties:
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| Odor Type: fruity |
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| Odor Strength: | medium |
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| Substantivity: | 4 hour(s) at 100.00 % |
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| | fresh rummy fruity strawberry apple |
Odor Description: at 100.00 %. | fresh harsh rum fruity strawberry apple Luebke, William tgsc, (1988) |
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| Flavor Type: fruity |
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| | fruity ethereal juicy fruit rummy banana |
Taste Description:
| fruity ethereal juicy fruit rummy banana Luebke, William tgsc, (1988) |
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| Odor and/or flavor descriptions from others (if found). |
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| Alfrebro |
| METHYL PROPIONATE NATURAL |
| Odor Description: | Strawberry, Banana, Apple |
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Cosmetic Information:
Suppliers:
| Alfrebro |
| METHYL PROPIONATE NATURAL
Odor: Strawberry, Banana, Apple |
| Aurochemicals |
| METHYL PROPIONATE, Natural
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| Beijing Lys Chemicals |
| Methyl propionate
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| EMD Millipore |
| For experimental / research use only. |
| Methyl Propionate
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| Ernesto Ventós |
| METHYL PROPIONATE
Odor: FRUITY, REMINISCENT OF RUM |
| Frutarom |
| METHYL PROPIONATE
KOSHER Flavor: Fresh, Fruity, Rum, Sweet |
| CBD Offering |
| Glentham Life Sciences |
| Methyl propionate
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| IFF |
| METHYL PROPIONATE
KOSHER Flavor: Fresh, Fruity, Rum, Sweet |
| Kingchem Laboratories |
| METHYL PROPIONATE, 99.5+%
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| Kingchem Laboratories |
| METHYL PROPIONATE
Odor: Fruity odor reminiscent of rum |
| Lluch Essence |
| METHYL PROPIONATE
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| M&U International |
| Methyl Propionate, Kosher
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| M&U International |
| Nat. Methyl Propionate, Kosher
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| Penta International |
| METHYL PROPIONATE NATURAL
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| Penta International |
| METHYL PROPIONATE
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| Reincke & Fichtner |
| Methyl Propionate
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| Sigma-Aldrich |
| Methyl propionate, ≥98%, FG
Odor: apple; banana; strawberry |
| Certified Food Grade Products |
| Sunaux International |
| Methyl Propionate
|
| Sunaux International |
| nat.Methyl Propionate
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| Taytonn ASCC |
| Methyl Propionate
Odor: Fresh, Fruity, Rum, Sweet |
| TCI AMERICA |
| For experimental / research use only. |
| Methyl Propionate >99.0%(GC)
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| Vigon International |
| Methyl Propionate
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| WEN International |
| METHYL PROPIONATE Natural
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| WholeChem |
| Methyl propionate
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Safety Information:
| Preferred SDS: View |
| European information : |
| Most important hazard(s): | | Xn - Harmful. |
R 11 - Highly flammable. R 20 - Harmful by inhalation. S 02 - Keep out of the reach of children. S 16 - Keep away from sources of ignition - No Smoking. S 23 - Do not breath vapour. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 - Wear suitable gloves and eye/face protection.
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| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
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| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Human Experience: |
| 2 % solution: no irritation or sensitization. |
| Oral/Parenteral Toxicity: |
oral-rat LD50 5000 mg/kg (Moreno, 1977b)
oral-mouse LD50 3460 mg/kg (Lewis,1996)
oral-rabbit LD50 2025 mg/kg (Munch,1972)
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| Dermal Toxicity: |
skin-rabbit LD50 > 5000 mg/kg Food and Chemical Toxicology. Vol. 20, Pg. 765, 1982.
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| Inhalation Toxicity: |
inhalation-mouse LC50 27000 mg/m3 Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 18(3), Pg. 48, 1974.
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Safety in Use Information:
| Category: | flavor and fragrance agents |
| RIFM Fragrance Material Safety Assessment: Search |
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
| Recommendation for methyl propionate usage levels up to: | | | 2.0000 % in the fragrance concentrate.
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| Maximised Survey-derived Daily Intakes (MSDI-EU): | 9.30 (μg/capita/day) |
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 3 |
| Click here to view publication 3 |
| | average usual ppm | average maximum ppm |
| baked goods: | - | 130.00000 |
| beverages(nonalcoholic): | - | 20.00000 |
| beverages(alcoholic): | - | - |
| breakfast cereal: | - | - |
| cheese: | - | - |
| chewing gum: | - | - |
| condiments / relishes: | - | - |
| confectionery froastings: | - | - |
| egg products: | - | - |
| fats / oils: | - | - |
| fish products: | - | - |
| frozen dairy: | - | 29.00000 |
| fruit ices: | - | 29.00000 |
| gelatins / puddings: | - | - |
| granulated sugar: | - | - |
| gravies: | - | - |
| hard candy: | - | 96.00000 |
| imitation dairy: | - | - |
| instant coffee / tea: | - | - |
| jams / jellies: | - | - |
| meat products: | - | - |
| milk products: | - | - |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | - | - |
| snack foods: | - | - |
| soft candy: | - | - |
| soups: | - | - |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
Safety References:
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | methyl propanoate | | nat. | methyl propionate | | | methyl propionate, natural | | | methyl propylate | | | methylpropanoate | | | methylpropionate | | | propanoic acid methyl ester | | | propanoic acid, methyl ester | | | propionic acid methyl ester | | | propionic acid, methyl ester |
Articles:
| Info: | Volatile Flavor Components in Bogyojosaeng and Suhong Cultivars of Strawberry (Fragaria ananassa Duch.) |
| PubMed: | Iridium(I) PNP complexes in the sp³ C-H bond activation of methyl propanoate and related esters. |
| PubMed: | Carbonylation of ethene catalysed by Pd(II)-phosphine complexes. |
| PubMed: | Synthesis of methyl propanoate by Baeyer-Villiger monooxygenases. |
| PubMed: | Mikania glomerata: Phytochemical, Pharmacological, and Neurochemical Study. |
| PubMed: | Crystal structures of (μ2-η(2),η(2)-4-hydroxybut-2-yn-1-yl 2-bromo-2-methylpropanoate-κ(4) C (2),C (3):C (2),C (3))bis[tricarbonylcobalt(II)](Co-Co) and [μ2-η(2),η(2)-but-2-yne-1,4-diyl bis(2-bromo-2-methyl-propanoate)-κ(4) C (2),C (3):C (2),C (3)]bis[tricarbonylcobalt(II)](Co-Co). |
| PubMed: | Theoretical study of the rate constants for the hydrogen atom abstraction reactions of esters with (•)OH radicals. |
| PubMed: | Reactions of Cl atoms with alkyl esters: kinetic, mechanism and atmospheric implications. |
| PubMed: | Endophytic fungi producing of esterases: evaluation in vitro of the enzymatic activity using pH indicator. |
| PubMed: | Elucidation of the upper pathway of alicyclic musk Romandolide degradation in OECD screening tests with activated sludge. |
| PubMed: | Applicability of non-halogenated methyl propionate to microencapsulation. |
| PubMed: | Theoretical and kinetic study of the hydrogen atom abstraction reactions of esters with H(O.)2 radicals. |
| PubMed: | Gas signatures from Escherichia coli and Escherichia coli-inoculated human whole blood. |
| PubMed: | Redirecting catalysis from proteolysis to perhydrolysis in subtilisin Carlsberg. |
| PubMed: | Determination of odor release in hydrocolloid model systems containing original or carboxylated cellulose at different pH values using static headspace gas chromatographic (SHS-GC) analysis. |
| PubMed: | High-temperature measurements of the reactions of OH with small methyl esters: methyl formate, methyl acetate, methyl propanoate, and methyl butanoate. |
| PubMed: | Solvent- or temperature-controlled diastereoselective aldol reaction of methyl phenylacetate. |
| PubMed: | Transferable force field for carboxylate esters: application to fatty acid methylic ester phase equilibria prediction. |
| PubMed: | Benzyl 2-{4-[2-(4-chloro-benzoyl-amino)-eth-yl]phen-oxy}-2-methyl-propionate. |
| PubMed: | Volatile compounds responsible for aroma of Jutrzenka liquer wine. |
| PubMed: | Atmospheric chemistry of two biodiesel model compounds: methyl propionate and ethyl acetate. |
| PubMed: | Characterization of odor-active compounds of various cherry wines by gas chromatography-mass spectrometry, gas chromatography-olfactometry and their correlation with sensory attributes. |
| PubMed: | The first example of main-chain cyclic azobenzene polymers. |
| PubMed: | An engineered methanogenic pathway derived from the domains Bacteria and Archaea. |
| PubMed: | Effect of nitroethane, dimethyl-2-nitroglutarate and 2-nitro-methyl-propionate on ruminal methane production and hydrogen balance in vitro. |
| PubMed: | Absolute configuration of methyl isoeichlerialactone. |
| PubMed: | tert-Butyl 2-(4-chloro-benzo-yl)-2-methyl-propanoate. |
| PubMed: | tert-Butyl 2-benzoyl-2-methyl-propanoate. |
| PubMed: | On the low volatility of cyclic esters: an infrared spectroscopy comparison between dimers of gamma-butyrolactone and methyl propionate. |
| PubMed: | Effect of methylene spacers on the spectral, electrochemical, and structural properties of bis(4,4'-disubstituted-2,2'-bipyridyl) ruthenium(II) dye analogues. |
| PubMed: | Controllable nanostructured surface modification on quantum dot for biomedical application in aqueous medium. |
| PubMed: | Diphenylphosphine containing macromolecules in the methoxycarbonylation of ethene: the effect of macromolecular architecture on the selectivity of the reaction. |
| PubMed: | Theoretical studies on structures and spectroscopic properties of self-assembled bis(2,4,8,10-tetramethyl-9-methoxycarbonylethyldipyrrin-3-yl)methane with Co(II). |
| PubMed: | Polymer producing palladium complexes of unidentate phosphines in the methoxycarbonylation of ethene. |
| PubMed: | Poly[(μ(2)-2-hydr-oxy-2-methyl-propionato-κO,O:O)(μ(2)-2-hydr-oxy-2-methyl-propionato-κO:κO)dioxido-uranium(VI)]. |
| PubMed: | Facile functionalization of multilayer fullerenes (carbon nano-onions) by nitrene chemistry and "grafting from" strategy. |
| PubMed: | In-situ polymerization at the interfaces of micelles: a "grafting from" method to prepare micelles with mixed coronal chains. |
| PubMed: | New polyethylene macroinitiators and their subsequent grafting by atom transfer radical polymerization. |
| PubMed: | Kinetic studies of fusarium solani pisi cutinase used in a gas/solid system: transesterification and hydrolysis reactions. |
| PubMed: | One- and two-dimensional direct chiral liquid chromatographic determination of mixtures of diclofop-Acid and diclofop-methyl herbicides. |
| PubMed: | 2-Methyl-2-(4-nitro-phen-oxy)propanoic acid. |
| PubMed: | Methyl 3-(4-{6-methyl-4-[3-(trifluoro-meth-yl)phen-yl]pyridazin-3-yl-oxy}phen-yl)propanoate. |
| PubMed: | Opposite signs of capacitive microsensor signals upon exposure to the enantiomers of methyl propionate compounds. |
| PubMed: | Effects of short-chain nitrocompounds against Campylobacter jejuni and Campylobacter coli in vitro. |
| PubMed: | Correlating volatile compounds, sensory attributes, and quality parameters in stored fresh-cut cantaloupe. |
| PubMed: | Solvent as a competitive inhibitor for Candida antarctica lipase B. |
| PubMed: | Ester versus polyketone formation in the palladium-diphosphine catalyzed carbonylation of ethene. |
| PubMed: | Isolation and characterization of dihydromonacolin-MV from Monascus purpureus for antioxidant properties. |
| PubMed: | Recognition of small polar molecules with an ionic crystal of alpha-Keggin-type polyoxometalate with a macrocation. |
| PubMed: | NMR spectroscopy and MALDI-TOF MS characterisation of end-functionalised PVP oligomers prepared with different esters as chain transfer agents. |
| PubMed: | Behaviour of [PdH(dppe)2]X (X=CF3SO3-, SbF6-, BF4-) as proton or hydride donor: relevance to catalysis. |
| PubMed: | Effect of oil substitution in chiral microemulsion electrokinetic chromatography. |
| PubMed: | Solid/gas biocatalysis: an appropriate tool to study the influence of organic components on kinetics of lipase-catalyzed alcoholysis. |
| PubMed: | Alcoholysis catalyzed by Candida antarctica lipase B in a gas/solid system: effects of water on kinetic parameters. |
| PubMed: | Alcoholysis of acylpalladium(II) complexes relevant to the alternating copolymerization of ethene and carbon monoxide and the alkoxycarbonylation of alkenes: the importance of Cis-coordinating phosphines. |
| PubMed: | Total synthesis of Elisabethin A: intramolecular Diels-Alder reaction under biomimetic conditions. |
| PubMed: | Determination of PNU-248686A, a novel matrix metalloproteinase inhibitor, in human plasma by liquid chromatography-tandem mass spectrometry, following protein precipitation in the 96-well plate format. |
| PubMed: | Water plays a different role on activation thermodynamic parameters of alcoholysis reaction catalyzed by lipase in gaseous and organic media. |
| PubMed: | Gas-phase reactivity of the O=P(OCH3)2+ phosphonium ion with aliphatic esters in a quadrupole ion trap. Spontaneous elimination of ketenes. |
| PubMed: | Alcoholysis catalyzed by Candida antarctica lipase B in a gas/solid system obeys a Ping Pong Bi Bi mechanism with competitive inhibition by the alcohol substrate and water. |
| PubMed: | Identification and effects of interaction phytotoxic compounds from exudate of Cistus ladanifer leaves. |
| PubMed: | Stereoselective synthesis of iso-dolaproine via dynamic kinetic resolution. |
| PubMed: | Systematic studies on synthesis, structural elucidation, and biological evaluation of A-ring diastereomers of 2-methyl-1alpha,25-dihydroxyvitamin D(3) and 20-epi-2-methyl-1alpha,25-dihydroxyvitamin D(3). |
| PubMed: | Syntheses of carbon-11 labeled piperidine esters as potential in vivo substrates for acetylcholinesterase. |
| PubMed: | [Interpretation of the resonance Raman spectrum of cytochrome P-450]. |
| PubMed: | Determination of remifentanil, an ultra-short-acting opioid anesthetic, in rat blood by high performance liquid chromatography with ultraviolet detection. |
| PubMed: | Methyl propionate radical cation. |
| PubMed: | Seed Dormancy in Red Rice (Oryza sativa) (IX. Embryo Fructose-2,6-Bisphosphate during Dormancy Breaking and Subsequent Germination). |
| PubMed: | Purification and characterization of a carboxylesterase from Pseudomonas sp. KWI-56. |
| PubMed: | Determination of remifentanil in human and dog blood by HPLC with UV detection. |
| PubMed: | Seed Dormancy in Red Rice : VIII. Embryo Acidification during Dormancy-Breaking and Subsequent Germination. |
| PubMed: | Gas phase transesterification reactions catalyzed by lipolytic enzymes. |
| PubMed: | Enhancement of the CDC ovitrap with hay infusions for daily monitoring of Aedes aegypti populations. |
| PubMed: | The effect of short term feeding of the antioxidant triethyleneglycol-bis-3(3-tert-butyl-4-hydroxy-5-methyl)propionate on serum thyrotropin and thyroid hormones in the male rat. |
| PubMed: | Effect of peroxisome proliferators on intrachromosomal and interchromosomal recombination in yeast. |
| PubMed: | Species differences in the chirality of the carbonyl reduction of [14C] fenofibrate in laboratory animals and humans. |
| PubMed: | [Synthesis of carbon-14 labeled 1-acetoxyethyl 2-(2-fluoro-4-biphenyl)propionate (14C-FP 83)]. |
| PubMed: | Observations concerning the nature of sites of anaesthetic action in Gammarus. |
| PubMed: | Factors affecting oviposition site preference by Toxorhynchites splendens in the laboratory. |
| PubMed: | Purification and characterization of 3-hydroxyisobutyrate dehydrogenase from rabbit liver. |
| PubMed: | Local anesthetic action of carboxylic esters: evidence for the significance of molecular volume and for the number of sites involved. |
| PubMed: | Properties of the Mg-Protoporphyrin IX Monomethyl Ester (Oxidative) Cyclase System. |
| PubMed: | Ethyl acrylate-induced gastric toxicity. II. Structure-toxicity relationships and mechanism. |
| PubMed: | Proposed structure for the noncovalently associated heme prosthetic group of dissimilatory nitrite reductases. Configuration of substituents of acrylochlorin. |
| PubMed: | Evaluation of selected hypolipidemic agents for the induction of peroxisomal enzymes and peroxisome proliferation in the rat liver. |
| PubMed: | Induction of hamster hepatic peroxisomal beta-oxidation and peroxisome proliferation-associated 80000 mol. wt. polypeptide by hypolipidemic drugs. |
| PubMed: | Uricosuric effect of fenofibrate in healthy volunteers. |
| PubMed: | [Chemistry of phenoxyacetic acid esters of oxyalkyltheophyllines and 1-(theophyllin-7-yl)-ethyl-2-[2-(p-chlorophenoxy)-2-methyl-propionate] (etofylline clofibrate), a novel antilipaemic agent (author's transl)]. |
| PubMed: | Volatiles produced by microorganisms isolated from refrigerated chicken at spoilage. |
| PubMed: | Antilipidemic drugs. Part 4: The metabolic fate of the hypolipidemic agent isopropyl-[4'-(p-chlorobenzoyl)-2-phenoxy-2-methyl]-protionate (LF 178) in rats, dog and man. |
| PubMed: | Antilipidemic drugs. Part 3: On the synthesis of 14C-radiolabelled isopropyl-[4'-chlorobenzoyl)-2-phenoxy-2-methyl]-propionate (LF-178). |
| PubMed: | Antilipidemic drugs. Part 2: Experimental study of a new potent hypolipidemic drug, isopropyl-[4'-(p-chlorobenzoyl)-2-phenoxy-2-methyl]-propionate (LF178). |
| PubMed: | Antilipidemic drugs. Part 6: LF 178 in man. A preliminary note on a multicenter investigation bearing on 393 subjects with pure or mixed forms of hyperlipidemia. |
| PubMed: | Atilipidemic drugs. Part 5: Evaluation of the hypolipidemic effect of LF 178 in 191 patients affected by the atherogenic form of endogenous hyperlipoproteinemia (types IIa, IIb and IV). |
| PubMed: | The oxidation products of crude mesobilirubinogen. |
| PubMed: | Influence of ethyl-2 [chlorophenoxy]--2--methyl propionate [atromid--s] on liposoluble vitamins. |
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