cis-galbanum oxathiane
oxane (Firmenich)
 
Notes:
Fischetti (1980) described this material as having a “styrallyl acetate-like odour” and “green, raspberry, rhubarb taste”. Mosciano, et.al. Report that this material has a “sulfuraceous, onion/garlic with a green vegetable nuance” odor and a “green, raw vegetable-like with meaty nuances” taste at 15ppm. Primary use is in Fruit flavors although it probably also finds use in Vegetable and Condiment flavors. Camps (1985) indicates that this material is closest in odor profile to 2-methyl-4-propyl-1, 3-oxathiane (Fema: 3578) (although perhaps more green), which is considered to be a key organoleptic constituent of Yellow Passion Fruit. Normal use levels in finished consumer product: 0.02~6ppm.
  • Alfrebro
    • Alfrebro LLC
      Let's get reacquainted
      Building great taste with aroma chemicals, extracts, and distillates
      The Alfrebro brand was established in the early 1900s by Alex Fries & Brothers, a Cincinnati Flavor Company. In 1980, the brand was re-launched as an aroma chemical manufacturer. Since its inception, Alfrebro’s primary focus has been to provide quality natural and high value synthetic chemicals.
      Email: Sarah Forbis
      Email: Sales
      Voice: 513-539-3021
      Fax: 513-539-7372
      US Voice: 513-539-7373
      Newsroom
      Product(s):
      2-Methyl-4-Propyl-1.3-Oxathiane 0.1% in ETOH, Natural
       
  • Azelis
    • Azelis UK Life Sciences
      Chemical Distribution
      Azelis is a leading global distributor of speciality chemicals.
      Azelis is a leading global speciality chemicals distributor. We provide a diverse range of products and innovative services to more than 20,000 customers. Our in-depth local knowledge is supported by an international structure and value-added services including high levels of technical support and tailored solutions.
      Email: Graham Bott
      Voice: +32 3 613 01 20
      Fax: +32 3 613 01 21
      United Kingdom+44 (0) 1992 82 55 55
      United Kingdom+44 (0) 1992 82 55 66
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      Services
      Product(s):
      OXANE
       
  • Berjé
    • Berjé Inc.
      The solution is clear
      Where the world comes to its senses - Berjé is a global distributor of Essential Oils and Aromatic Chemicals.
      Berjé is a family-owned business that has been in operation for six decades. The company's origins and strength lie in a profound understanding of the supply and the quality of the diverse raw materials consumed by the flavor and fragrance industries. This base was expanded upon more than two decades ago to include fragrance production. The company's unparalleled raw material expertise is focused on the supply of essential oils and aromatic chemicals. This is supported by our long-standing relationships with a worldwide fabric of producers ensuring the greatest prospects for uninterrupted supply in markets that are often volatile and unpredictable.
      Email: For Information
      Email: For Sales
      Voice: 973-748-8980
      Fax: 973-680-9618
      Market Report
      Specialties
      Product(s):
      2-Methyl-4-Propyl 1,3 Oxathiane
       
  • Charkit Chemical
    • Charkit Chemical Corporation
      The Specialty Chemical Specialists
      Explore this website to discover the products and services that Charkit provides for your industry and please contact us directly to find out how we can be of service to you.
      Since 1982, Charkit has been committed to expanding the markets we serve and our roster of products and services continues to grow with us. Personal care ingredients now include a substantial array of luxury and exotic components. Substantial inroads have been made in the nutraceutical and resins markets, with a growing roster of versatile and unique ingredients. And we continue to lead the way in our traditional markets such as Metal and Water Treatment, Imaging, Flavor & Fragrance, Aroma and Food. Our Pharmaceutical offerings continue to expand, still anchored by the Boronic Derivatives that meet the demands of Suzuki coupling reactions.
      Email: Sales
      Voice: 203-299-3220
      Fax: 203-299-1355
      News
      Products List: View
      Product(s):
      METHYL PROPYL OXATHIANE
       
  • Firmenich
    • Firmenich Inc.
      We Create
      We create perfumes and flavors for the World's most desirable brands.
      Firmenich is the largest privately-owned company in the perfume and flavor business. Swiss and family owned, we have created many of the world’s favorite perfumes for over 100 years and produced a number of the most well known flavors we enjoy each day.
      US Email: Fred Keifer
      US Voice: +1 609 452 1000
      US Fax: +1 609 452 6077
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      Product(s):
      969380 Oxane min 59%
      A unique material that is well worth the time to study its effects in perfume blends. Obviously good in citrus and exotic fruity notes but wonderful in jasmin, rose and muguet florals, as well as, in green aldehydic perfumes. Traces of OXANE will add unique effects to any fragrance creation.
       
       
Synonyms   Articles   Notes   Search
Fragrance Demo Formulas    Flavor Demo Formulas
(2R,4S)-2-methyl-4-propyl-1,3-oxathiane (Click)
CAS Number: 59323-76-1Picture of molecule
ECHA EINECS - REACH Pre-Reg: 261-699-8
FDA UNII: K3U570395A
Nikkaji Web: J24.392B
XlogP3-AA: 2.70 (est)
Molecular Weight: 160.27972000
Formula: C8 H16 O S
NMR Predictor: Predict (works with chrome or firefox)
Also(can) Contains: trans-galbanum oxathiane
Category: flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
IBM Patents: Obtain
Pubchem Patents: Search
PubMed: Search
NCBI: Search
FEMA Number: 3578  cis-2-methyl-4-propyl-1,3-oxathiane
Synonyms   Articles   Notes   Search   Top
Physical Properties:
Appearance: colorless to pale yellow clear liquid (est)
Assay: 98.00 to 100.00 % 
Food Chemicals Codex Listed: No
Specific Gravity: 0.97000 to 0.98200 @  25.00 °C.
Pounds per Gallon - (est).: 8.071 to  8.171
Refractive Index: 1.47500 to 1.48500 @  20.00 °C.
Boiling Point: 218.00 to  220.00 °C. @ 760.00 mm Hg
Acid Value: 5.00 max. KOH/g
Vapor Pressure: 0.123000 mm/Hg @ 25.00 °C. (est)
Vapor Density: 5.5 ( Air = 1 )
Flash Point: 122.00 °F. TCC ( 50.00 °C. )
logP (o/w): 2.990 (est)
Soluble in:
 alcohol
 water, 672.1 mg/L @ 25 °C (est)
Insoluble in:
 water
Stability:
 antiperspirant
 cream
 deodorant
 detergent powder
 shampoo
 soap
 talcum powder
Synonyms   Articles   Notes   Search   Top
Organoleptic Properties:
Odor Type: tropical
Odor Strength: medium ,
recommend smelling in a 1.00 % solution or less
 sulfurous  green  galbanum  fruity  tropical  pineapple  onion  
Odor Description:
at 1.00 % in dipropylene glycol. 
sulfurous green galbanum fruity tropical pineapple
Luebke, William tgsc, (1996)
 green  sulfurous  tropical  fruity  
Taste Description:
green, sulfurous, tropical fruity
Substantivity: 56 Hour(s)
  
Synonyms   Articles   Notes   Search   Top
Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: perfuming agents
Synonyms   Articles   Notes   Search   Top
Suppliers:
Alfrebro
2-Methyl-4-Propyl-1.3-Oxathiane 0.1% in ETOH, Natural
Azelis
OXANE
Services
Berjé
2-Methyl-4-Propyl 1,3 Oxathiane
Specialties
Charkit Chemical
METHYL PROPYL OXATHIANE
Ernesto Ventós
OXANE FIRMENICH 969380
Odor: EXOTIC FRUIT
Firmenich
Oxane
min 59%
Odor: An extremely powerful ingredient with a tropical green passion fruit note and a grapefruit-like tartness
Use: A unique material that is well worth the time to study its effects in perfume blends. Obviously good in citrus and exotic fruity notes but wonderful in jasmin, rose and muguet florals, as well as, in green aldehydic perfumes. Traces of OXANE will add unique effects to any fragrance creation.
Indukern F&F
OXANE
Odor: SULFUROUS, GREEN, FRUITY, TROPICAL
CROP CALENDAR
Parchem
cis-galbanum oxathiane
Symrise
Methylpropyl oxathiane-2,4,1,3
Flavor: green, sulfurous, tropical fruity
Useful in: fruity citrus, fruity yellow, fruity tropical.
Symrise
Oxanthia 50% in TEC
Odor: powerful and diffusive, resembling zesty citrus characters and green tropical fruit notes, passion fruit, grapefruit, cassis, mandarin-tangerine
Use: Stable in: body lotion (very good), shampoo (good), soap (good), ap roll-on (poor), powder (poor), cleaner citric (poor), cleaner apc (good), bleach (poor).
Tengzhou Xiang Yuan Aroma Chemicals
(Z)-2-Methyl-4-propyl-1,3-oxathiane
Vigon International
Oxane 50% In TEC
Odor: An extremely powerful ingredient with a tropical green passion fruit note and a grapefruit-like tartness
Synonyms   Articles   Notes   Search   Top
Safety Information:
European information :
Most important hazard(s):
Xi - Irritant
R 10 - Flammable.
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
S 02 - Keep out of the reach of children.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50  6000 mg/kg

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
Synonyms   Articles   Notes   Search   Top
Safety in Use Information:
Category: flavor and fragrance agents
Recommendation for cis-galbanum oxathiane usage levels up to:
  0.2000 % in the fragrance concentrate.
 
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 11
Click here to view publication 11
 average usual ppmaverage maximum ppm
baked goods: -0.10000
beverages(nonalcoholic): -0.05000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -0.10000
fruit ices: --
gelatins / puddings: -0.10000
granulated sugar: --
gravies: --
hard candy: --
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: -0.10000
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: -0.10000
soups: --
sugar substitutes: --
sweet sauces: --
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Safety References:
EPI System: View
EPA Substance Registry Services (TSCA): 59323-76-1
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 101010
National Institute of Allergy and Infectious Diseases: Data
WISER: UN 1993
WGK Germany: 2
 (2R,4S)-2-methyl-4-propyl-1,3-oxathiane
Chemidplus: 0059323761
Synonyms   Articles   Notes   Search   Top
References:
 (2R,4S)-2-methyl-4-propyl-1,3-oxathiane
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 59323-76-1
Pubchem (cid): 101010
Pubchem (sid): 135058324
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Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
CHEBI: View
CHEMBL: View
HMDB (The Human Metabolome Database): Search
VCF-Online: VCF Volatile Compounds in Food
ChemSpider: View
Read: Under the conditions of intended use - New developments in the FEMA GRAS program and the safety assessment of flavor ingredients
Read: A GRAS assessment program for flavor ingredients
Read: Sensory testing for flavorings with modifying properties. Food Technology
Read: Criteria for the safety evaluation of flavoring substances
Read: A procedure for the safety evaluation of natural flavor complexes used as ingredients in food: essential oils
Read: FEMA Expert Panel: 30 Years of safety evaluation for the flavor industry
Read: Consumption ratio and food predominance of flavoring materials
Synonyms   Articles   Notes   Search   Top
Potential Blenders and core components note
 
For Odor
No odor group found for these
 amchoor powder 
aldehydic
 citrus carbaldehydeFR
 decanal (aldehyde C-10)FL/FR
 dodecanal (aldehyde C-12 lauric)FL/FR
amber
 ambroxanFL/FR
animal
 animal carbolactoneFR
 costus valerolactoneFR
para-cresyl caprylateFL/FR
anise
 anise seed oilFL/FR
anisic
 ocimum basilicum herb oilFL/FR
balsamic
isoamyl benzoateFL/FR
 amyris wood oilFL/FR
siam benzoin resinoidFL/FR
 benzyl benzoateFL/FR
 benzyl salicylateFL/FR
 cinnamyl alcoholFL/FR
 clover nitrileFR
 fir balsam absoluteFR
 fir needle oil siberiaFL/FR
3-phenyl propyl alcoholFL/FR
camphoreous
 camphor tree bark oilFL/FR
caramellic
 strawberry furanoneFL/FR
citrus
 dihydromyrcenolFL/FR
 grapefruit pentanolFR
 waxy nitrileFR
floral
 benzyl alcoholFL/FR
 bois de rose oil brazilFL/FR
 citronellyl acetateFL/FR
 cyclamen aldehydeFL/FR
 cyclohexyl ethyl alcoholFL/FR
 floral pyranolFR
 gardenia decaloneFR
 geranyl acetateFL/FR
(E)-geranyl acetoneFL/FR
 heliotropyl diethyl acetalFR
(Z)-3-hexen-1-yl salicylateFL/FR
alpha-hexyl cinnamaldehydeFL/FR
 hyacinth etherFR
 karo karounde absoluteFR
 leerallFR
laevo-linaloolFL/FR
 linalool oxideFL/FR
 methyl dihydrojasmonateFL/FR
 mimosa absolute franceFL/FR
 muguet carboxaldehydeFR
 muguet octadienolFR
 neryl acetateFL/FR
 ocean propanalFL/FR
 orris pyridine 25% IPMFR
 phenethyl acetateFL/FR
 phenethyl salicylateFL/FR
(E)-2,5,9-trimethyl-4,9-decadien-1-alFR
 violet methyl carbonateFR
fruity
 allyl amyl glycolateFR
gamma-decalactoneFL/FR
 green acetateFR
 raspberry ketone methyl etherFL/FR
gamma-undecalactone (aldehyde C-14 (so-called))FL/FR
green
 acetaldehyde ethyl phenethyl acetalFL/FR
green cognac oilFL/FR
 cortex pyridineFL/FR
para-dimethyl hydroquinoneFL/FR
(Z)-3-hexen-1-yl benzoateFL/FR
 hexyl 2-methyl butyrateFL/FR
 hexyl tiglateFL/FR
2,4-ivy carbaldehydeFL/FR
english ivy leaf absoluteFR
(Z)-leaf acetalFL/FR
 melon nonenoateFL/FR
 methyl heptine carbonateFL/FR
 methyl octine carbonateFL/FR
 narcissus flower absoluteFR
(E,Z)-2,6-nonadien-1-olFL/FR
(E,Z)-2,6-nonadienalFL/FR
 phenyl acetaldehydeFL/FR
 phenyl acetaldehyde dimethyl acetalFL/FR
3-phenyl propionaldehydeFL/FR
 styralyl acetateFL/FR
herbal
 carum carvi fruit oilFL/FR
 clary sage oil franceFL/FR
 daucus carota fruit oilFL/FR
 lavender absolute bulgariaFL/FR
honey
 phenyl acetic acidFL/FR
marine
green algae absoluteFL/FR
melon
 melon heptenalFL/FR
 watermelon ketoneFR
mossy
 oakmoss absoluteFL/FR
 veramoss (IFF)FR
powdery
para-anisyl alcoholFL/FR
spicy
 cubeb oilFL/FR
 cumin seed oilFL/FR
 cuminaldehydeFL/FR
 levisticum officinale root oilFL/FR
black pepper oilFL/FR
 pimenta acris leaf oilFL/FR
terpenic
 frankincense oilFL/FR
 juniperus communis fruit oilFL/FR
alpha-terpineolFL/FR
thujonic
 thuja occidentalis leaf oilFL/FR
tonka
 flouve absoluteFR
 tonka bean absoluteFR
waxy
 decyl acetateFL/FR
1-dodecanolFL/FR
 ethyl laurateFL/FR
1-undecanolFL/FR
woody
 cistus twig/leaf oilFL/FR
 myrtenyl isobutyrate 
 patchouli ethanoneFR
 santallFR
 spruce needle oil canadaFL/FR
 tobacarol (IFF)FR
 vetiver oil haitiFL/FR
 woody acetateFR
(Z)-woody amyleneFR
 woody propanolFR
 
For Flavor
 
No flavor group found for these
 acetaldehyde ethyl phenethyl acetalFL/FR
green algae absoluteFL/FR
 cistus twig/leaf oilFL/FR
para-cresyl caprylateFL/FR
 cyclamen aldehydeFL/FR
 cyclohexyl ethyl alcoholFL/FR
 dihydromyrcenolFL/FR
para-dimethyl hydroquinoneFL/FR
 hexyl tiglateFL/FR
2,4-ivy carbaldehydeFL/FR
laevo-linaloolFL/FR
 myrtenyl isobutyrate 
 phenethyl salicylateFL/FR
 thuja occidentalis leaf oilFL/FR
 amchoor powder 
aldehydic
1-undecanolFL/FR
anise
 anise seed oilFL/FR
balsamic
siam benzoin resinoidFL/FR
 benzyl benzoateFL/FR
 benzyl salicylateFL/FR
 fir needle oil siberiaFL/FR
berry
 raspberry ketone methyl etherFL/FR
camphoreous
 camphor tree bark oilFL/FR
caramellic
 strawberry furanoneFL/FR
citrus
alpha-terpineolFL/FR
creamy
gamma-undecalactone (aldehyde C-14 (so-called))FL/FR
fatty
(Z)-3-hexen-1-yl benzoateFL/FR
floral
 bois de rose oil brazilFL/FR
 citronellyl acetateFL/FR
(E)-geranyl acetoneFL/FR
 methyl dihydrojasmonateFL/FR
 neryl acetateFL/FR
 ocean propanalFL/FR
 phenyl acetic acidFL/FR
fruity
isoamyl benzoateFL/FR
para-anisyl alcoholFL/FR
 benzyl alcoholFL/FR
gamma-decalactoneFL/FR
 styralyl acetateFL/FR
fusel
green cognac oilFL/FR
green
 cinnamyl alcoholFL/FR
 cortex pyridineFL/FR
 geranyl acetateFL/FR
(Z)-3-hexen-1-yl salicylateFL/FR
 hexyl 2-methyl butyrateFL/FR
(Z)-leaf acetalFL/FR
 linalool oxideFL/FR
 melon heptenalFL/FR
 melon nonenoateFL/FR
 methyl heptine carbonateFL/FR
 methyl octine carbonateFL/FR
(E,Z)-2,6-nonadien-1-olFL/FR
(E,Z)-2,6-nonadienalFL/FR
 oakmoss absoluteFL/FR
 phenyl acetaldehyde dimethyl acetalFL/FR
3-phenyl propionaldehydeFL/FR
herbal
 carum carvi fruit oilFL/FR
 clary sage oil franceFL/FR
 daucus carota fruit oilFL/FR
 lavender absolute bulgariaFL/FR
 ocimum basilicum herb oilFL/FR
honey
 phenethyl acetateFL/FR
 phenyl acetaldehydeFL/FR
orris
 costus root oilFL
soapy
 dodecanal (aldehyde C-12 lauric)FL/FR
1-dodecanolFL/FR
spicy
 cubeb oilFL/FR
 cumin seed oilFL/FR
 cuminaldehydeFL/FR
 levisticum officinale root oilFL/FR
black pepper oilFL/FR
3-phenyl propyl alcoholFL/FR
 pimenta acris leaf oilFL/FR
terpenic
 juniperus communis fruit oilFL/FR
waxy
 decanal (aldehyde C-10)FL/FR
 decyl acetateFL/FR
 ethyl laurateFL/FR
alpha-hexyl cinnamaldehydeFL/FR
 mimosa absolute franceFL/FR
woody
 ambroxanFL/FR
 amyris wood oilFL/FR
 frankincense oilFL/FR
 spruce needle oil canadaFL/FR
 vetiver oil haitiFL/FR
 
Synonyms   Articles   Notes   Search   Top
Potential Uses:
 agrumen 
 aldehydicFR
 amaryllis 
 amberFR
 animalFR
 appleFR
 apple crabapple 
 ash mountain ash 
 balsamFR
 bark 
 boxwood 
 boxwood blossom 
 boxwoodberry 
 cabochard 
 calamusFR
 celeryFL/FR
 chamomileFR
 champaca champakFR
 cherry wildFL
 chervil 
 cilantroFL/FR
 citrusFR
 clematisFR
 cloudberry bakeapple 
 cognacFR
 cortex 
 cypressFR
 daffodil narcissusFR
 earth humusFR
 eglantine sweet briarFR
 evergreenFR
 fagoniaFR
 fern fougereFR
 figFR
 fir 
 fir needle pine needleFL/FR
 fixer 
 foliage 
 forestFR
 forest pine forestFR
 fresh & cleanFR
 fruitFR
 fruit tropical fruit 
 galbanumFL/FR
 gardeniaFR
 geraniumFR
 gingerFR
 grass sweetFR
 greenFR
 green grassFR
 green leafFR
 hops houblonFL/FR
 hyacinth jacintheFR
 hydrangeaFR
 ivyFR
 jasminFR
 jonquil narcissus jonquillaFR
 kewda 
 lavenderFR
 autumnFR
 lemonFR
 limeFR
 lotusFR
 mimosaFR
 muguet lily of the valleyFR
 muskFR
 narcissus narcisseFR
 natural 
 nutFL
 oakmoss mousse de chene mossFR
 ocean sea 
 opoponaxFL/FR
 orangeFR
 orange bitterFL/FR
 oreganoFL/FR
 palmarosaFL/FR
 pansyFR
 parsleyFL/FR
 passion fruitFR
 patchouliFR
 pepper 
 pepper greenFL
 pineFR
 pizzaFR
 privet 
 privet blossom 
 rain springFR
 reseda mignonetteFR
 rhubarbFR
 roseFR
 rose geraniumFR
 sandalwoodFR
 seaweedFL/FR
 spruceFL/FR
 stem 
 strawberry leaf 
 tea greenFR
 tomatoFL
 tomato leafFR
 tropicalFL
 vegetable 
 verbenaFR
 vetiverFR
 vine 
 weedy 
 woodyFR
 wormwood absinthiumFL/FR
 yewFR
Synonyms   Articles   Notes   Search   Top
Natural Occurrence in: note
 clary sage
GRIN Trop Picture
 passion fruit yellow
GRIN Trop Picture
 pineapple
 whiskey
 wine white wine
Synonyms   Articles   Notes   Search   Top
Synonyms:
cis-galbanum oxathiane
 methyl propyl oxathiane natural
2-methyl-4-propyl 1,3 oxathiane
(2R,4S)-rel-2-methyl-4-propyl-1,3-oxathiane
cis-2-methyl-4-propyl-1,3-oxathiane
2-methyl-4-propyl-1.3-oxathiane 0.1% in ETOH natural
 methylpropyl oxathiane-2,4,1,3
 oxane (Firmenich)
 oxane 50% in TEC (Firmenich)
 oxanthia 50% in TEC (Symrise)
1,3-oxathiane, 2-methyl-4-propyl-, (2R,4S)-
cis-tropathiane
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Synonyms   Articles   Notes   Search   Top
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