|
Category: flavoring agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless clear liquid (est) |
| Assay: | 97.00 to 100.00 % sum of isomers
|
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 1.00500 to 1.02000 @ 25.00 °C.
|
| Pounds per Gallon - (est).: | 8.363 to 8.487
|
| Refractive Index: | 1.47500 to 1.49000 @ 20.00 °C.
|
| Boiling Point: | 53.00 °C. @ 10.00 mm Hg
|
| Vapor Pressure: | 0.750000 mmHg @ 25.00 °C. (est) |
| Flash Point: | 134.00 °F. TCC ( 56.67 °C. )
|
| logP (o/w): | 0.477 (est) |
| Soluble in: |
| | alcohol | | | fats | | | water, 3.195e+004 mg/L @ 25 °C (est) |
| Insoluble in: |
| | water |
Organoleptic Properties:
| |
| Odor Type: sulfurous |
| |
| | sulfurous roasted onion garlic meaty |
Odor Description: at 0.10 % in propylene glycol. | sulfury roasted onion garlic meaty |
| |
| | sulfurous meaty roasted meaty alliaceous onion garlic |
Odor Description:
| SuIfureous, roasted meat, alliaceous, sauteed onion and garlic Mosciano, Gerard P&F 21, No. 3, 51, (1996) |
| |
| |
| Flavor Type: meaty |
| |
| | meaty savory onion garlic |
Taste Description: at 4.00 ppm. | Meaty, savory, sauteed onion and garlic Mosciano, Gerard P&F 21, No. 3, 51, (1996) |
| |
| Odor and/or flavor descriptions from others (if found). |
| |
| |
Cosmetic Information:
Suppliers:
| Advanced Biotech |
| 2 MERCAPTO 3-BUTANOL
97% min. (mixed isomers) Odor: Onion, meat |
| Ambles Nature et Chimie |
| 2-MERCAPTO-3-BUTANOL
|
| Anhui Suzhou Jinli Aromatic Chemicals |
| 3-mercapto-2-butanol, mixture of isomers
Odor: sulfur, meat. Scallionbroth |
| Beijing Lys Chemicals |
| 2-Mercapto-3-butanol
|
| BOC Sciences |
| For experimental / research use only. |
| 2-Mercapto-3-butanol
|
| DeLong Chemicals America |
| 2-Mercapto-3-butanol, Kosher
|
| Endeavour Specialty Chemicals |
| 2-Mercapto-3-butanol 97% F&F
|
| Speciality Chemical Product Groups |
| Fleurchem |
| 2-mercapto-3-butanol
|
| Jiangyin Healthway |
| 3-Mercapto-2-butanol
|
| New functional food ingredients |
| Jinan Enlighten Chemical Technology(Wutong Aroma ) |
| 2-Mercapto-3-butanol, Kosherk
|
| M&U International |
| 2-MERCAPTO-3-BUTANOL, Kosher
|
| OQEMA |
| 2-Mercapto-3-butanol
|
| Pearlchem Corporation |
| 2-Mercapto-3-butanol
|
| Penta International |
| 3-MERCAPTO-2-BUTANOL
|
| R C Treatt & Co Ltd |
| 2-Mercapto-3-butanol
Halal, Kosher Odor: Catty, ribes-like, with tropical and meaty notes Flavor: tropical Useful in blackcurrant, tropical fruit flavors, meat, onion, savoury & coffee. Council of Europe limits: candies (0.2 ppm). |
| Robinson Brothers |
| 2-Mercapto-3-butanol F&F
|
| https://www.robinsonbrothers.uk/chemistry-competences |
| Sigma-Aldrich |
| 2-Mercapto-3-butanol, mixture of isomers, ≥97%, FG
Odor: sulfurous; meaty; alliaceous (onion, garlic) |
| Certified Food Grade Products |
| Sunaux International |
| 2-Mercapto-3-butanol
|
| Synerzine |
| 2-Mercapto-3-butanol
|
| Tengzhou Jitian Aroma Chemiclal |
| 3-Mercapto-2-butanol
|
| Tengzhou Xiang Yuan Aroma Chemicals |
| 2-Mercapto-3-butanol
|
| Tianjin Danjun International |
| 2-Mercapto-3-butanol
|
| United International |
| 3-Mercapto-2-Butanol
|
| WholeChem |
| 3-Mercapto-2-butanol
|
Safety Information:
| Preferred SDS: View |
| European information : |
| Most important hazard(s): | | Xi - Irritant |
R 36/37/38 - Irritating to eyes, respiratory system, and skin. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
|
| |
| Hazards identification |
| |
| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
| |
| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
|
Not determined
|
| Dermal Toxicity: |
|
Not determined
|
| Inhalation Toxicity: |
|
Not determined
|
Safety in Use Information:
| Category: | flavoring agents |
| Recommendation for (R,S)-2-mercapto-3-butanol usage levels up to: | | | not for fragrance use.
|
| |
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 4.00 (μg/capita/day) |
| NOEL (No Observed Effect Level): | 1.9 (mg/kg bw per day) |
| Structure Class: | I |
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 10 |
| Click here to view publication 10 |
| | average usual ppm | average maximum ppm |
| baked goods: | - | 0.20000 |
| beverages(nonalcoholic): | - | - |
| beverages(alcoholic): | - | - |
| breakfast cereal: | - | - |
| cheese: | - | - |
| chewing gum: | - | - |
| condiments / relishes: | - | - |
| confectionery froastings: | - | - |
| egg products: | - | - |
| fats / oils: | - | - |
| fish products: | - | - |
| frozen dairy: | - | - |
| fruit ices: | - | - |
| gelatins / puddings: | - | - |
| granulated sugar: | - | - |
| gravies: | - | 0.20000 |
| hard candy: | - | - |
| imitation dairy: | - | - |
| instant coffee / tea: | - | - |
| jams / jellies: | - | - |
| meat products: | - | 0.20000 |
| milk products: | - | - |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | - | - |
| snack foods: | - | - |
| soft candy: | - | - |
| soups: | - | 0.20000 |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
Safety References:
| European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
| European Food Safety Authority (EFSA) reference(s): |
Flavouring Group Evaluation 8 (FGE.08)[1]: Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical group 20 View page or View pdf |
Flavouring Group Evaluation 8, Revision 1 (FGE.08Rev1): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 8, Revision 3 (FGE.08Rev3): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 08, Revision 4 (FGE.08Rev4): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
| EPI System: | View |
| AIDS Citations: | Search |
| Cancer Citations: | Search |
| Toxicology Citations: | Search |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| Laboratory Chemical Safety Summary : | 641834 |
| National Institute of Allergy and Infectious Diseases: | Data |
| WISER: | UN 3336 |
| WGK Germany: | 3 |
| | (2R,3S)-3-sulfanylbutan-2-ol |
| Chemidplus: | 0037887040 |
References:
Other Information:
Potential Blenders and core components note
| |
| For Odor |
| alliaceous |
| | dibutyl sulfide | FL/FR |
| | dimethyl trisulfide | FL/FR |
| | methyl furfuryl disulfide | FL/FR |
| coffee |
| | coffee difuran | FL/FR |
| | furfuryl mercaptan | FL/FR |
| fermented |
| | ethyl (E)-2-crotonate | FL/FR |
| moldy |
| | strawberry furanone methyl ether | FL/FR |
| nutty |
| 2- | methyl-3-(methyl thio) pyrazine | FL/FR |
| spicy |
| | ethyl vinyl ketone | FL/FR |
| | cocoa essence | FL/FR |
| | ethyl 2-mercaptopropionate | FL/FR |
| | ethyl 3-mercaptobutyrate | FL/FR |
| | ethyl methyl mercaptopropionate | FL/FR |
| | ferula assa-foetida absolute | FL/FR |
| | furfuryl thioacetate | FL/FR |
| 2- | mercaptopropionic acid | FL/FR |
| 2- | methyl 5-(methyl thio) furan | FL/FR |
| 2-( | methyl thio) phenol | FL/FR |
| 4- | tropical oxathiane | FL/FR |
| |
| For Flavor |
| |
| No flavor group found for these |
| 4- | acetyl-2-methyl pyrimidine | FL |
| | allyl methyl trisulfide | FL |
| | allyl propyl trisulfide | FL |
| 1,2- | butane dithiol | FL |
| | diethyl trisulfide | FL |
| (Z+E)-2,5- | dimethyl-3-tetrahydrofuran thiol | FL |
| (Z+E)-2,5- | dimethyl-3-thioacetoxytetrahydrofuran | FL |
| 2,5- | dimethyl-3-thiofuroyl furan | FL |
| | dipropyl sulfide | FL |
| | ethyl 3-mercaptobutyrate | FL/FR |
| 2- | ethyl-3-methyl thiopyrazine | FL |
| | methyl butyl sulfide | FL |
| | methyl dihydrofuran thiol | FL |
| | methyl methane thiosulfonate | FL |
| 2- | methyl-3-(methyl thio) pyrazine | FL/FR |
| 3-((2- | methyl-3-furyl)thio)-4-heptanone | FL |
| 4-((2- | methyl-3-furyl)thio)-5-nonanone | FL |
| iso | propyl disulfide | FL |
| | thioacetic acid | FL |
|
| 3,7- | dimethyl-2,6-octadien-1-yl cyclopropyl carboxamide | FL |
| 2- | methyl-1-methyl thio-2-butene | FL |
| alliaceous |
| | allyl disulfide | FL |
| | allyl mercaptan | FL |
| | allyl thiopropionate | FL |
| | benzyl mercaptan | FL |
| 1,3- | butane dithiol | FL |
| | cyclopentyl mercaptan | FL |
| | dicyclohexyl disulfide | FL |
| | dimethyl trisulfide | FL/FR |
| | leek oil | FL |
| 3- | mercapto-2-pentanone | FL |
| 2- | methyl thioacetaldehyde | FL |
| 3- | tetrahydrothiophenone | FL |
| | truffle sulfide | FL |
| chocolate |
| | cocoa essence | FL/FR |
| coffee |
| | coffee difuran | FL/FR |
| | furfuryl mercaptan | FL/FR |
| | methyl furfuryl disulfide | FL/FR |
| | methyl furfuryl thiol | FL |
| eggy |
| iso | propyl mercaptan | FL |
| fruity |
| 4- | tropical oxathiane | FL/FR |
| garlic |
| | allyl methyl sulfide | FL |
| | garlic oleoresin | FL |
| green |
| | dibutyl sulfide | FL/FR |
| meaty |
| 2,6- | dimethyl thiophenol | FL |
| 1,1- | ethane dithiol 1% in ethanol 94.5% / ethyl acetate 4% | FL |
| 2- | mercaptopropionic acid | FL/FR |
| 2-( | methyl thio) phenol | FL/FR |
| | methyl thiofuryl butanal | FL |
| bis(2- | methyl-3-furyl) disulfide | FL |
| S-(2- | methyl-3-furyl) ethane thioate | FL |
| 2- | methyl-3-tetrahydrofuran thiol | FL |
| 2- | methyl-3-thioacetoxytetrahydrofuran | FL |
| | propyl 2-mercaptopropionate | FL |
| 2- | pyridinyl methane thiol | FL |
| | thialdine | FL |
| ortho- | thiocresol | FL |
| moldy |
| | strawberry furanone methyl ether | FL/FR |
| musty |
| | ethyl (E)-2-crotonate | FL/FR |
| 2- | methyl 5-(methyl thio) furan | FL/FR |
| nutty |
| | nutty thiazole | FL |
| onion |
| | ethyl 2-mercaptopropionate | FL/FR |
| | furfuryl isopropyl sulfide | FL |
| | methionol | FL |
| | methyl propyl disulfide | FL |
| | methyl propyl trisulfide | FL |
| | propyl thioacetate | FL |
| phenolic |
| 2- | ethyl benzene thiol | FL |
| roasted |
| | ethyl 3-(furfuryl thio) propionate | FL |
| | furfuryl thioacetate | FL/FR |
| seafood |
| 1,4- | dithiane | FL |
| spicy |
| | ethyl vinyl ketone | FL/FR |
| sulfurous |
| | allyl sulfide | FL |
| 2,3- | butane dithiol | FL |
| | butyl mercaptan | FL |
| | diallyl polysulfides | FL |
| | diallyl tetrasulfide | FL |
| | ethyl methyl mercaptopropionate | FL/FR |
| S- | ethyl thioacetate | FL |
| | ferula assa-foetida absolute | FL/FR |
| | furfuryl methyl sulfide | FL |
| | furfuryl thiopropionate | FL |
| 3- | mercapto-2-methyl pentanal | FL |
| | methyl 4-(methyl thio) butyrate | FL |
| 2- | methyl thiophene | FL |
| 2- | naphthyl mercaptan | FL |
| | roasted butanol | FL |
| |
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| (R,S)-2- | butanol, 3-mercapto- | | (R,S)-3- | hydroxy-2-butane thiol | | (R,S)-2- | hydroxy-3-butane thiol | | (R,S)-2- | hydroxy-3-butanethiol | | (R,S)-2- | mercapto 3-butanol | | (R,S)-3- | mercapto-2-butanol | | (theta,S)-3- | mercapto-2-butanol | | 2- | mercapto-3-butanol | | (R*,S*)-3- | mercaptobutan-2-ol | | (2R,3S)-3- | sulfanylbutan-2-ol | | | thionol-935 (IFF) |
Articles:
|