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Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Organoleptic Properties:
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| Odor Type: sulfurous |
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| | cabbage garlic |
Odor Description: at 0.01 % in propylene glycol. | decomposing cabbage garlic |
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| | vegetable oily alliaceous eggy creamy savory |
Odor Description: at 1.00 %. | Vegetable oil, alliaceous, eggy, creamy with savory nuances Mosciano, Gerard P&F 23, No. 6, 31, (1998) |
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| Flavor Type: sulfurous |
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| | sulfurous alliaceous creamy cheesy clean savory meaty |
Taste Description: at 1.00 ppm. | Sulfurous, alliaceous, creamy with a surface-ripened cheese topnote and a clean savory meaty depth Mosciano, Gerard P&F 23, No. 6, 31, (1998) |
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| Odor and/or flavor descriptions from others (if found). |
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| R C Treatt & Co Ltd |
| Methyl mercaptan, 1% in PG Kosher |
| Odor Description: | boiled cabbage Odour threshold in water: 0.02 ppb. |
| Taste Description: | sulfurous Flavour threshold in water: 2 ppb.
Used occasionally in onion, garlic, vegetable and meat flavours. Normal use levels in finished consumer product: 0.005-1 ppm. Council of Europe limits: Foods (1 ppm); Beverages (1 ppm). |
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| Advanced Biotech |
| METHYL MERCAPTAN 1% IN ETOH NATURAL |
| Odor Description: | Alcoholic, Cabbage |
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| Indukern F&F |
| METHYL MERCAPTANE 1%PG |
| Odor Description: | VEGETABLE, SULFUROUS, EGGY, CREAMY |
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Cosmetic Information:
Suppliers:
| Advanced Biotech |
| METHYL MERCAPTAN 1% IN ETOH NATURAL
Odor: Alcoholic, Cabbage |
| Advanced Biotech |
| METHYL MERCAPTAN 1% IN PG NATURAL
Odor: Cabbage, Garlic |
| Advanced Biotech |
| METHYL MERCAPTAN 1% IN VEGETABLE OIL NATURAL
Odor: Cabbage, garlic |
| Alfrebro |
| METHYL MERCAPTAN 1% IN ETHANOL
Odor: Stench |
| Alfrebro |
| METHYL MERCAPTAN NATURAL 1% IN PG
Odor: Stench |
| Augustus Oils |
| Methyl Mercaptan 5% Pg
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| Services |
| Charkit Chemical |
| METHYL MERCAPTAN 1% IN PG FEMA 2716
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| Charkit Chemical |
| METHYL MERCAPTAN 1NCM1124 FEMA 2716
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| Chevron Phillips |
| Methyl Mercaptan
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| Endeavour Specialty Chemicals |
| Methyl mercaptan (10% in Triacetin)
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| Speciality Chemical Product Groups |
| Endeavour Specialty Chemicals |
| Methyl mercaptan (1% in PG)
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| Endeavour Specialty Chemicals |
| Methyl mercaptan (10% in Triethylcitrate)
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| Endeavour Specialty Chemicals |
| Methyl mercaptan (5% in PG)
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| Endeavour Specialty Chemicals |
| Methyl mercaptan 1% in Ethanol
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| Endeavour Specialty Chemicals |
| Methyl mercaptan 1% in Miglyol
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| Indukern F&F |
| METHYL MERCAPTANE 1%PG
Odor: VEGETABLE, SULFUROUS, EGGY, CREAMY |
| Indukern F&F |
| METHYL MERCAPTANE 10% PG
Odor: VEGETABLE, SULFUROUS, EGGY, CREAMY |
| Jinan Enlighten Chemical Technology(Wutong Aroma ) |
| Methanethiol 10%, Kosherk
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| Natural Advantage |
| Methyl Mercaptan Nat, 1% in Corn Oil
Flavor: meaty, rotten, vegetative |
| Riverside Aromatics LTD.is the exclusive distributor for Europe in UK for any non-US based inquiries |
| Natural Advantage |
| Methyl Mercaptan Nat, 1% in Neobee Oil, Artificial
Flavor: meaty, rotten, vegetative |
| Natural Advantage |
| Methyl Mercaptan Nat, 1% in Neobee Oil
Flavor: meaty, rotten, vegetative |
| Natural Advantage |
| Methyl Mercaptan Nat, 1% in PG
Flavor: meaty, rotten, vegetative |
| Penta International |
| METHYL MERCAPTAN 1% IN P.G.
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| Penta International |
| METHYL MERCAPTAN 5% IN PROPYLENE GLYCOL
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| Penta International |
| METHYL MERCAPTAN NATURAL 1% IN ETHANOL
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| Penta International |
| METHYL MERCAPTAN NATURAL 5% IN ETHANOL
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| Penta International |
| METHYL MERCAPTAN NATURAL 5% IN P.G.
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| Penta International |
| METHYL MERCAPTAN NATURAL 1% IN NEOBEE
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| Penta International |
| METHYL MERCAPTAN NATURAL 1% IN PG
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| Penta International |
| METHYL MERCAPTAN NATURAL 10% IN BENZYL ALCOHOL
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| R C Treatt & Co Ltd |
| Methyl mercaptan 1% in Miglyol
Kosher |
| R C Treatt & Co Ltd |
| Methyl mercaptan, 1% in PG
Kosher Odor: boiled cabbage Use: Odour threshold in water: 0.02 ppb. Flavor: sulfurous Flavour threshold in water: 2 ppb.
Used occasionally in onion, garlic, vegetable and meat flavours. Normal use levels in finished consumer product: 0.005-1 ppm. Council of Europe limits: Foods (1 ppm); Beverages (1 ppm). |
| R C Treatt & Co Ltd |
| Methyl mercaptan, 1% in Triacetin
Kosher Odor: boiled cabbage Use: Odour threshold in water: 0.02 ppb. Flavor: sulfurous Flavour threshold in water: 2 ppb.
Used occasionally in onion, garlic, vegetable and meat flavours. Normal use levels in finished consumer product: 0.005-1 ppm. Council of Europe limits: Foods (1 ppm); Beverages (1 ppm). |
| R C Treatt & Co Ltd |
| Methyl mercaptan, 10% in TEC
Kosher Odor: boiled cabbage Use: Odour threshold in water: 0.02 ppb. Flavor: sulfurous Flavour threshold in water: 2 ppb.
Used occasionally in onion, garlic, vegetable and meat flavours. Normal use levels in finished consumer product: 0.005-1 ppm. Council of Europe limits: Foods (1 ppm); Beverages (1 ppm). |
| R C Treatt & Co Ltd |
| Methyl mercaptan, 10% in Triacetin
Kosher Odor: boiled cabbage Use: Odour threshold in water: 0.02 ppb. Flavor: sulfurous Flavour threshold in water: 2 ppb.
Used occasionally in onion, garlic, vegetable and meat flavours. Normal use levels in finished consumer product: 0.005-1 ppm. Council of Europe limits: Foods (1 ppm); Beverages (1 ppm). |
| R C Treatt & Co Ltd |
| Methyl mercaptan, 5% in PG
Halal, Kosher Odor: boiled cabbage Use: Odour threshold in water: 0.02 ppb. Flavor: sulfurous Flavour threshold in water: 2 ppb.
Used occasionally in onion, garlic, vegetable and meat flavours. Normal use levels in finished consumer product: 0.005-1 ppm. Council of Europe limits: Foods (1 ppm); Beverages (1 ppm). |
| Riverside Aromatics |
| METHYL MERCAPTAN, NATURAL, 1% IN PG
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| Robertet |
| METHYL MERCAPTAN 1% PG Natural (EU)
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| Seasons and Harvest / Crop calendar |
| Robinson Brothers |
| Methyl mercaptan (10% in Triacetin)
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| https://www.robinsonbrothers.uk/chemistry-competences |
| Robinson Brothers |
| Methyl mercaptan (1% in PG)
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| Robinson Brothers |
| Methyl mercaptan (10% in Triethylcitrate)
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| Robinson Brothers |
| Methyl mercaptan (5% in PG)
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| Robinson Brothers |
| Methyl mercaptan 1% in Ethanol
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| Robinson Brothers |
| Methyl mercaptan 1% in Miglyol
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| Sigma-Aldrich: Aldrich |
| For experimental / research use only. |
| Methanethiol 98.0%
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| SRS Aromatics |
| METHYL MERCAPTAN 10 %
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| Taytonn ASCC |
| Methyl Mercaptan (1% In PG)
Odor: Meaty, Savoury, Sulphurous |
| Taytonn ASCC |
| Methyl Mercaptan (10% IN Tac)
Odor: Sulphurous, Meaty, Savoury |
| Tengzhou Xiang Yuan Aroma Chemicals |
| Methyl Mercaptan
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| The Lermond Company |
| METHYL MERCAPTAN 1% PG
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Safety Information:
| Preferred SDS: View |
| European information : |
| Most important hazard(s): | | T N - Toxic, Dangerous for the environment. |
R 12 - Extremely flammable. R 23 - Toxic by inhalation. R 50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S 01/02 - Keep locked up and out of the reach of children. S 16 - Keep away from sources of ignition - No Smoking. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 - Wear suitable clothing, gloves and eye/face protection. S 60 - This material and its container must be disposed of as hazardous waste. S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet.
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| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
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| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
unreported-mammal (species unspecified) LD50 60670 ug/kg Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 16(6), Pg. 46, 1972.
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| Dermal Toxicity: |
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Not determined
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| Inhalation Toxicity: |
inhalation-mouse LC50 6530 ug/m3/2H Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 16(6), Pg. 46, 1972.
inhalation-rat LC50 675 ppm GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
KIDNEY, URETER, AND BLADDER: URINE VOLUME INCREASED Personal Communication from H.B. Lackey, Chemical Products Div., Crown Zellerbach, Camas, WA 98607, June 9, 1978Vol. 09JUN1978,
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Safety in Use Information:
| Category: | flavor and fragrance agents |
| RIFM Fragrance Material Safety Assessment: Search |
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
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| Maximised Survey-derived Daily Intakes (MSDI-EU): | 54.00 (μg/capita/day) |
| Structure Class: | I |
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 3 |
| Click here to view publication 3 |
| | average usual ppm | average maximum ppm |
| baked goods: | 0.15000 | 1.00000 |
| beverages(nonalcoholic): | - | 0.56000 |
| beverages(alcoholic): | - | - |
| breakfast cereal: | - | - |
| cheese: | - | - |
| chewing gum: | - | - |
| condiments / relishes: | - | - |
| confectionery froastings: | - | - |
| egg products: | - | - |
| fats / oils: | - | - |
| fish products: | - | - |
| frozen dairy: | 0.13000 | 1.00000 |
| fruit ices: | 0.13000 | 1.00000 |
| gelatins / puddings: | - | - |
| granulated sugar: | - | - |
| gravies: | - | - |
| hard candy: | 0.13000 | 1.00000 |
| imitation dairy: | - | - |
| instant coffee / tea: | - | - |
| jams / jellies: | - | - |
| meat products: | - | - |
| milk products: | - | - |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | - | - |
| snack foods: | - | - |
| soft candy: | - | - |
| soups: | - | - |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
Safety References:
| European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
| European Food Safety Authority (EFSA) reference(s): |
Flavouring Group Evaluation 8 (FGE.08)[1]: Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical group 20 View page or View pdf |
Flavouring Group Evaluation 8, Revision 1 (FGE.08Rev1): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 8, Revision 3 (FGE.08Rev3): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 08, Revision 4 (FGE.08Rev4): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30 View page or View pdf |
Scientific Opinion on the safety and efficacy of aliphatic and aromatic mono- and di-thiols and mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups (chemical group 20) when used as flavourings for all animal species View page or View pdf |
Safety of methanethiol [12.003] when used as a feed additive for all animal species View page or View pdf |
| EPI System: | View |
| NIOSH International Chemical Safety Cards: | search |
| NIOSH Pocket Guide: | search |
| AIDS Citations: | Search |
| Cancer Citations: | Search |
| Toxicology Citations: | Search |
| EPA Substance Registry Services (TSCA): | 74-93-1 |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| Laboratory Chemical Safety Summary : | 878 |
| National Institute of Allergy and Infectious Diseases: | Data |
| WISER: | UN 1064 |
| WGK Germany: | 3 |
| | methanethiol |
| Chemidplus: | 0000074931 |
| EPA/NOAA CAMEO: | hazardous materials |
| RTECS: | 74-93-1 |
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | mercaptomethane | | | methane thiol | | | methanethiol | | | methyl mercaptan 1% PG natural | | | methyl mercaptan 1% in ETOH natural | | | methyl mercaptan 1% in PG natural | | | methyl mercaptan 1% in vegetable oil natural | | | methyl mercaptan 10% in triacetin | | | methyl mercaptan 10% TEC synthetic | | | methyl mercaptan, 1% in PG | | | methyl mercaptan, 1% in triacetin | | | methyl mercaptan, 10% in TEC | | | methyl mercaptan, 10% in triacetin | | | methyl mercaptan, 5% in PG | | | methyl mercaptan, natural 1% in corn oil | | | methyl mercaptan, natural 1% in neobee | | | methyl mercaptan, natural 1% in P.G. | | | methyl mercaptan, natural 10% in benzyl alcohol | | | methyl mercaptan, natural 5% in ethanol | | | methyl mercaptan, natural 5% in neobee | | | methyl mercaptan, natural 5% in P.G. | | | methyl sulfhydrate | | | methyl thioalcohol | | | methyl thiol | | | methyl-mercaptan | | | thiomethane | | | thiomethanol | | | thiomethyl alcohol |
Articles:
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