methyl heptine carbonate
methyl 2-octynoate
 
Notes:
Blends well with orris notes. Flavouring ingredient
  • ACS International
    • ACS International GmbH
      Creativity Beyond Chemistry
      Production • Distribution • Sourcing • Logistics • Consulting
      Our hybrid business model, combining manufacturing with sourcing and exclusive distribution agreements, results in a superior level of purchasing power that when added to our global warehouse network with locations near all major flavor and fragrance industry compounding centers around the globe, make A.C.S. International your one-stop sourcing partner.
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      Product(s):
      78905 Methyl Heptine Carbonate
       
  • Augustus Oils
    • Augustus Oils Ltd
      The Premier Supplier
      Augustus Oils Ltd, in harmony with nature - to present it at its best...
      A wealth of experience, expertise and knowledge has allowed Augustus to bridge the gulf in expectation and trust between growers and users of natural ingredients. The Company works in partnership with customers on the one hand, and growers, farmers and distillers on the other. Both users and producers can then focus on exactly what they do best, while skilled Augustus technicians closely monitor and control the delivered product. This ensures users can have the confidence that they will receive the best raw materials suited to their requirements.
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      Product(s):
      Methyl 2-Octynate
       
  • Bedoukian Research
    • Bedoukian Research, Inc.
      Perfecting the Art of Chemistry
      Working closely with our customers to meet their requirements.
      Dr. Paul Bedoukian founded the company in 1972 to fill a niche as a supplier of high quality specialty aroma molecules. Today, we offer more than 350 high impact aroma chemicals, while providing custom manufacturing services to the pharmaceutical, agrochemical, and specialty chemical industries.
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      Product(s):
      483 METHYL HEPTINE CARBONATE ≥98.0%, Kosher
      SDS
      Very powerful, outdoors, violet foliage, fresh green vegetable odor. Useful in a wide range of odor types.
      Melon type flavors, especially cantaloupe and strawberry. Useful for a variety of tea flavors.
       
       
  • Berjé
    • Berje Inc.
      Where the world comes to its senses
      Where the world comes to its senses - Berjé is a global distributor of Essential Oils and Aromatic Chemicals.
      Berjé is a family-owned business that has been in operation for six decades. The company's origins and strength lie in a profound understanding of the supply and the quality of the diverse raw materials consumed by the flavor and fragrance industries. This base was expanded upon more than two decades ago to include fragrance production. The company's unparalleled raw material expertise is focused on the supply of essential oils and aromatic chemicals. This is supported by our long-standing relationships with a worldwide fabric of producers ensuring the greatest prospects for uninterrupted supply in markets that are often volatile and unpredictable.
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      Product(s):
      Methyl Heptine Carbonate
       
  • BOC Sciences
    • BOC Sciences
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      Product(s):
      111-12-6 Methyl Heptine Carbonate 98.0%
       
  • Indukern F&F
  • Lluch Essence
    • Lluch Essence S.L.
      A family company dedicated to sales and distribution
      Flexibility, availability, price and quality.
      Flexibility, availability, price and quality make LLUCH ESSENCE S.L. one of Europe’s references when it comes to essential oils and aroma chemicals, and it is now well known all around the world.
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      METHYL HEPTINE CARBONATE
       
  • M&U International
    • M&U International LLC
      Steady supply & demand
      Meeting customers increasing demands at home as well as abroad.
      M&U dedicates itself to the development and production of new products as well as continuously promoting those new products. We’ve maintained a steady supply&demand relationship with a large number of manufacturers at home and abroad. We’ve developed an extensive network and because of our relationships with these manufacturers, we’re able to provide a stable supply of great quality materials. We’re located in China’s largest communications hub, Shanghai and in the U.S. near one of the largest sea ports on the East Coast. The strategic locations of our facilities ensure convenient, prompt and secure delivery of our products to our customers.
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      Product(s):
      A0204 Methyl Heptine Carbonate, Kosher
       
  • Moellhausen
  • O'Laughlin Industries
    • O'Laughlin Industries Inc.
      Manufacturer of chemicals and ingredients used in flavors, fragrances, food, beverages and cosmetics
      Leading the Flavor and Fragrance Industry since 1980.
      O'Laughlin was established in 1980 by its owner and chief executive Michael O'Laughlin, when he moved to Beijing, China and established a small office. Since then it has grown to be a world class producer of chemicals, with significant production facilities in China, and distribution and sales in all major world markets.
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      Product(s):
      772-3133 METHYL 2 ?OCTYNOATE
       
  • Penta International
    • Penta International Corporation
      Chemistry innovation
      At Penta, our products and services help businesses do business better.
      For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes.
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      Product(s):
      13-50000 METHYL HEPTINE CARBONATE
       
  • Sigma-Aldrich
  • SRS Aromatics
    • SRS Aromatics Ltd
      For over 25 years
      Bringing flavour and fragrance into your world.
      As suppliers / distributors of ingredients to the fragrance and flavour industries, our goal is to provide high quality materials at competitive prices with an exceptional level of service. Established in 1984, SRS Aromatics Ltd is an independent family owned business which has become very well-respected within the fragrance and flavour industry as a reliable and trustworthy partner. Over the years this has allowed the company to develop strong relationships with many global manufacturers; several of whom we represent in the UK. A core aim of our business is to work extremely closely with both our suppliers and customers to maximise service levels with minimum disruption to supply.
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      METHYL HEPTINE CARBONATE
       
  • Synerzine
    • Synerzine, Inc.
      Innovation. Customization. Aroma Ingredients.
      Synerzine is a leading supplier of flavor and fragrance ingredients.
      Synerzine expresses what we have grown to embody as an organization - the synergy and connection between raw ingredients, science, technology, and the final product. Our experienced team is passionate about bringing our customers high-quality innovative ingredients that they can trust.
      Building upon our 44 year history, the Synerzine team provides customers around the globe with convenient access to over 1200 high-quality aroma ingredients. We actively engage with customers to add a wide array of new products and services on a regular basis. Our aim is to delight every customer with our exceptional services, large product selection, customization and the highest quality and safety standards. We provide our customers with true value designed to help them bring their products to market faster.
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      Product(s):
      W1430 Methyl 2-octynoate
       
  • TCI AMERICA
    • TCI AMERICA
      Moving Your Chemistry Forward
      We continuously strive to advance our technology.
      With East & West Coast distribution centers, count on TCI to deliver products quickly and reliably. Over 30,000 Reagents available today in benchtop to bulk quantities. We also offer custom synthesis solutions. Sign up for a TCI account today for fast and free shipping!
      Tokyo Chemical Industry Co., Ltd. (TCI) is a leading worldwide manufacturer of specialty organic chemicals founded in 1946. TCI provides organic laboratory chemicals as well as pharmaceutical, cosmetic and functional materials. More than 70 years of synthesis experience and multi-purpose plants enable TCI to offer more than 30,000 products as well as custom synthesis.
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      Product(s):
      O0239 Methyl 2-Octynoate >98.0%(GC)
      SDS
       
  • The John D. Walsh Company
    • The John D. Walsh Company, Inc
      Suppliers Since 1942
      Supplying the fragrance and flavor industry with high quality products.
      The John D. Walsh Company, Inc. has evolved from its beginnings as an agent/broker into a distributor of essential oils, aroma chemicals, concretes and absolutes. We currently represent the following companies, as their North American distributor: Destilerias Munoz Galvez, S.A. International Flavors & Fragrances PFW Aroma Chemicals B.V. Innospec Widnes Limited Hydrodiffusion de Guatemala, S. A. DSM Nutritional Products The John D. Walsh Company, Inc. is proud to be a founding member of IFEAT, an active member of IFRA, North America, and a corporate sponsor of the WFFC.
      Email: Information
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      Voice: 973-962-1400
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      Firmenich Flavor Phone:973-962-1888
      Firmenich Flavor Fax:973-962-1898
      History
      Product(s):
      Methyl Heptine Carbonate
      SDS
       
  • The Lermond Company
    • The Lermond Company
      Your Sourcing Resource
      The Lermond family has been sourcing raw materials for the flavor and fragrance industry for nearly 7 decades.
      The Lermond Company is a women-owned distributor of raw materials primarily servicing the flavor and fragrance industry. For three generations, members of the Lermond family have been integral sourcing partners for the North American flavor and fragrance industry. We supply high quality essential oils, aroma chemicals, absolutes, concretes, resinoids and floral waters from around the world to the global industry.
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      Email: Tara
      Email: Erica
      Voice: 201-896-3300
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      Product(s):
      41380 METHYL HEPTINE CARBONATE
       
  • R C Treatt & Co Ltd
    • R C Treatt and Co Ltd
      Innovative ingredient solutions
      World-leading innovative ingredient solutions provider for the flavour, fragrance and FMCG industries.
      We offer innovative and trend-setting product concepts for our customers, collaborating with them to create true value for their products.
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      Methyl Heptine Carbonate
       
  • Ernesto Ventós
  • Vigon International
    • Vigon International
      Passion for Simplicity
      Manufacturer and supplier of high quality flavor and fragrance ingredients.
      The growth and success of Vigon is due in large part to a unique corporate concept that Vigon has developed and established within the industry: Creative Partnerships. This partnership concept has been and continues to be the foundation and guiding principle for all of Vigon's activities.
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      Product(s):
      500890 Folione FCC (Methyl Heptyne Carbonate)
       
  • Zanos
    • Zanos Ltd.
      Distributor of Speciality Chemicals and Natural Ingredients
      Sourcing and supplying quality aroma chemicals and prestige natural ingredients for the flavour and fragrance industry.
      The flavour and fragrance industry's premier source for aroma chemicals and essential oils
      Zanos Ltd. is a B2B supplier of aroma chemicals, speciality chemicals, natural ingredients and vitamins to a diverse range of customers. In Autumn 2020, Stort Chemicals Limited completed their acquisition of Zanos Ltd. Combining our strengths, Stort and Zanos have boosted our respective portfolios of aroma chemicals, speciality chemicals and natural ingredients. With warehousing facilities across the UK, Rotterdam and Hamburg, Zanos is perfectly positioned to dispatch product throughout Europe.
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      Product(s):
      Methyl Heptine Carbonate (MHC)
       
Synonyms   Articles   Notes   Search
Fragrance Demo Formulas    Flavor Demo Formulas
CAS Number: 111-12-6Picture of molecule3D/inchi
Other(deleted CASRN): 53073-28-2
ECHA EINECS - REACH Pre-Reg: 203-836-6
FDA UNII: 0TTP6YT2T3
Nikkaji Web: J22.135J
Beilstein Number: 1756887
MDL: MFCD00009530
CoE Number: 481
XlogP3-AA: 3.20 (est)
Molecular Weight: 154.20898000
Formula: C9 H14 O2
BioActivity Summary: listing
NMR Predictor: Predict (works with chrome, Edge or firefox)
Category: flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
PubMed: Search
NCBI: Search
JECFA Food Flavoring: 1357  methyl 2-octynoate
DG SANTE Food Flavourings: 09.158  methyl 2-octynoate
FEMA Number: 2729 methyl 2-octynoate
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF):111-12-6 ; METHYL 2-OCTYNOATE
FDA Regulation:
FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION
Subpart F--Flavoring Agents and Related Substances
Sec. 172.515 Synthetic flavoring substances and adjuvants.
Synonyms   Articles   Notes   Search   Top
Physical Properties:
Appearance: colorless to pale yellow clear liquid (est)
Assay: 99.00 to 100.00 % 
Halogens: Chlorine free
Food Chemicals Codex Listed: Yes
Specific Gravity: 0.91900 to 0.92400 @  25.00 °C.
Pounds per Gallon - (est).: 7.647 to  7.689
Refractive Index: 1.44600 to 1.44900 @  20.00 °C.
Boiling Point: 217.00 to  220.00 °C. @ 760.00 mm Hg
Boiling Point: 75.00 °C. @ 4.00 mm Hg
Acid Value: 1.00 max. KOH/g
Saponification Value: 96.00 to 104.00
Vapor Pressure: 0.125000 mmHg @ 25.00 °C. (est)
Flash Point: 192.00 °F. TCC ( 88.89 °C. )
logP (o/w): 3.220 (est)
Shelf Life: 12.00 month(s) or longer if stored properly.
Storage: store in cool, dry place in tightly sealed containers, protected from heat and light.
Soluble in:
 alcohol
 dipropylene glycol
 fixed oils
 water, 433.9 mg/L @ 25 °C (est)
Insoluble in:
 water
 glycerin
Stability:
 non-discoloring in most media
Similar Items: note
allyl heptine carbonate
isoamyl heptine carbonate
butyl heptine carbonate
Synonyms   Articles   Notes   Search   Top
Organoleptic Properties:
 
Odor Type: green
 
Odor Strength: high ,
recommend smelling in a 1.00 % solution or less
 
Substantivity: 240 hour(s) at 100.00 %
 
 green  leafy  waxy  violet  cucumber  
Odor Description:
at 1.00 % in dipropylene glycol. 
green leafy waxy violet cucumber
Luebke, William tgsc, (1986)
 
 green  vegetable  fruity  fatty  waxy  cucumber  melon  violet leaf  floral  
Odor Description:
Green, vegetative, fruity, fatty, waxy, cucumber, melon and violet leaf-like with floral nuances
Mosciano, Gerard P&F 22, No. 1, 57, (1997)
 
 
Flavor Type: green
 
 green  vegetable  fatty  fruity  melon rind  cucumber  mushroom  dairy  
Taste Description:
at 15.00 ppm.  
Green, vegetative, fatty, fruity, rindy, melon and cucumber with mushroom and dairy nuances
Mosciano, Gerard P&F 22, No. 1, 57, (1997)
 
Odor and/or flavor descriptions from others (if found).
 
Bedoukian Research
METHYL HEPTINE CARBONATE ≥98.0%, Kosher
Odor Description: green, violet, vegetable, hay-like
Very powerful, outdoors, violet foliage, fresh green vegetable odor. Useful in a wide range of odor types.
Taste Description: Strong, sweet melon character
Melon type flavors, especially cantaloupe and strawberry. Useful for a variety of tea flavors.
 
Givaudan
Folione®
Odor Description: Powerful, Green, Leaf like, Floral
Folione, used in traces, produces violet-leaf and cucumber notes. It blends extremely well with products in the orris family like the Isoraldeines and ionones.
 
 
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Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: perfuming agents
Synonyms   Articles   Notes   Search   Top
Suppliers:
ACS International
Methyl Heptine Carbonate
Operational Capabilities
Apple Flavor & Fragrance
Methyl heptine carbonate
Augustus Oils
Methyl 2-Octynate
Services
Bedoukian Research
METHYL HEPTINE CARBONATE
≥98.0%, Kosher
Odor: green, violet, vegetable, hay-like
Use: Very powerful, outdoors, violet foliage, fresh green vegetable odor. Useful in a wide range of odor types.
Flavor: Strong, sweet melon character
Melon type flavors, especially cantaloupe and strawberry. Useful for a variety of tea flavors.
Berjé
Methyl Heptine Carbonate
Media
Best Value Chem
Methyl Heptine Carbonate
Odor: Powerful,Green,Leaf like,Floral
BOC Sciences
For experimental / research use only.
Methyl Heptine Carbonate 98.0%
Ernesto Ventós
METHYL HEPTINE CARBONATE II
Odor: GREEN, FLORAL, VIOLET, CUCUMBER
Ernesto Ventós
METHYL HEPTINE CARBONATE
Odor: GREEN, FLORAL, VIOLET, CUCUMBER
Givaudan
Folione®
Odor: Powerful, Green, Leaf like, Floral
Use: Folione, used in traces, produces violet-leaf and cucumber notes. It blends extremely well with products in the orris family like the Isoraldeines and ionones.
Indukern F&F
METHYL HEPTINE CARBONATE
Lluch Essence
METHYL HEPTINE CARBONATE
M&U International
Methyl Heptine Carbonate, Kosher
Moellhausen
METHYL HEPTYNE CARBONATE
O'Laughlin Industries
METHYL 2 ?OCTYNOATE
Penta International
METHYL HEPTINE CARBONATE
R C Treatt & Co Ltd
Methyl Heptine Carbonate
Santa Cruz Biotechnology
For experimental / research use only.
Methyl 2-octynoate
Sigma-Aldrich
Methyl 2-octynoate, ≥99%, FCC, FG
Odor: green; vegetable; violet
Certified Food Grade Products
SRS Aromatics
METHYL HEPTINE CARBONATE
Synerzine
Methyl 2-octynoate
TCI AMERICA
For experimental / research use only.
Methyl 2-Octynoate >98.0%(GC)
The John D. Walsh Company
Methyl Heptine Carbonate
The Lermond Company
METHYL HEPTINE CARBONATE
Vigon International
Folione FCC (Methyl Heptyne Carbonate)
Odor: Powerful, Green, Leaf like, Floral
Zanos
Methyl Heptine Carbonate (MHC)
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Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
Xn - Harmful.
R 22 - Harmful if swallowed.
R 38 - Irritating to skin.
R 43 - May cause sensitisation by skin contact.
S 02 - Keep out of the reach of children.
S 20/21 - When using do not eat, drink or smoke.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 - Wear suitable gloves and eye/face protection.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Flammable liquids (Category 4), H227
Acute toxicity, Oral (Category 4), H302
Skin irritation (Category 2), H315
GHS Label elements, including precautionary statements
 
Pictogramexclamation-mark.jpg
 
Signal word Warning
Hazard statement(s)
H227 - Combustible liquid
H302 - Harmful if swallowed
H315 - Causes skin irritation
Precautionary statement(s)
P210 - Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P264 - Wash skin thouroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P312 - IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302 + P352 - IF ON SKIN: wash with plenty of soap and water.
P330 - Rinse mouth.
P332 + P313 - IF SKIN irritation occurs: Get medical advice/attention.
P362 - Take off contaminated clothing and wash before reuse.
P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
P403 + P235 - Store in a well-ventilated place. Keep cool.
P501 - Dispose of contents/ container to an approved waste disposal plant.
Human Experience:
1 % solution: no irritation or sensitization.
Oral/Parenteral Toxicity:
oral-rat LD50  1530 mg/kg
Food and Cosmetics Toxicology. Vol. 17, Pg. 375, 1979.

Dermal Toxicity:
skin-rabbit LD50 3300 mg/kg
Food and Cosmetics Toxicology. Vol. 17, Pg. 375, 1979.

Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
IFRA Critical Effect: Dermal sensitization
IFRA fragrance material specification:
 Should not be used such that the level in finished cosmetic products exceeds 0.002%. When used alone level in the finished cosmetic products should not exceed 0.01%. When present in combination, the combined level in the finished product should not exceed 0.01% of which methyl heptine carbonate should not be more than 0.002%
IFRA: View Standard
View IFRA Standards Library for complete information.
Please review Amendment 49 IFRA documentation for complete information.
IFRA RESTRICTION LIMITS IN THE FINISHED PRODUCT (%):
Category 1: Products applied to the lips
0.0085 %
Category 2: Products applied to the axillae
0.0025 %
Category 3: Products applied to the face/body using fingertips
0.051 %
Category 4: Products related to fine fragrance
0.047 %
 Category 5: Products applied to the face and body using the hands (palms), primarily leave-on
Category 5A: Body lotion products applied to the body using the hands (palms), primarily leave-on
0.012 %
Category 5B: Face moisturizer products applied to the face using the hands (palms), primarily leave-on
0.012 %
Category 5C: Hand cream products applied to the hands using the hands (palms), primarily leave-on
0.012 %
Category 5D: Baby Creams, baby Oils and baby talc
0.012 %
Category 6: Products with oral and lip exposure
0.028 %
 Category 7: Products applied to the hair with some hand contact
Category 7A: Rinse-off products applied to the hair with some hand contact
0.096 %
Category 7B: Leave-on products applied to the hair with some hand contact
0.096 %
Category 8: Products with significant anogenital exposure
0.005 %
Category 9: Products with body and hand exposure, primarily rinse off
0.092 %
 Category 10: Household care products with mostly hand contact
Category 10A: Household care excluding aerosol products (excluding aerosol/spray products)
0.33 %
Category 10B: Household aerosol/spray products
0.33 %
 Category 11: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate
Category 11A: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
0.18 %
Category 11B: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
0.18 %
Category 12: Products not intended for direct skin contact, minimal or insignificant transfer to skin
No Restriction
 Notes:
IFRA FLAVOR REQUIREMENTS:

Due to the possible ingestion of small amounts of fragrance ingredients from their use in products in Categories 1 and 6, materials must not only comply with IFRA Standards but must also be recognized as safe as a flavoring ingredient as defined by the IOFI Code of Practice (www.iofi.org). For more details see chapter 1 of the Guidance for the use of IFRA Standards.

 
Maximised Survey-derived Daily Intakes (MSDI-EU): 18.00 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 38.00 (μg/capita/day)
Threshold of Concern:1800 (μg/person/day)
Structure Class: I
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
 average usual ppmaverage maximum ppm
baked goods: -1.40000
beverages(nonalcoholic): -0.15000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: 13.0000020.00000
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -0.30000
fruit ices: -0.30000
gelatins / puddings: 1.700001.70000
granulated sugar: --
gravies: --
hard candy: -1.40000
imitation dairy: --
instant coffee / tea: --
jams / jellies: -0.23000
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
Synonyms   Articles   Notes   Search   Top
Safety References:
Flavor & Extract Manufacturers Association (FEMA) reference(s):
The FEMA GRAS assessment of alpha,beta-unsaturated aldehydes and related substances used as flavor ingredients. View pdf
European Food Safety Athority(EFSA): Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
European Food Safety Authority (EFSA) reference(s):
Scientific Opinion on Flavouring Group Evaluation 71: Consideration of aliphatic, linear, alpha,beta-unsaturated carboxylic acids and related esters
View page or View pdf
Scientific Opinion on Flavouring Group Evaluation 95 (FGE.95): Consideration of aliphatic, linear or branched-chain saturated and unsaturated alcohols, aldehydes, acids and related esters evaluated by JECFA (69th meeting) structurally related to esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids evaluated by EFSA in FGE.05Rev1 (2008)
View page or View pdf
Scientific Opinion on Flavouring Group Evaluation 71 Revision 1 (FGE.71Rev1): consideration of aliphatic, linear, a,ß-unsaturated alcohols, aldehydes, carboxylic acids, and related esters evaluated by JECFA (63rd and 69th meeting) structurally related to flavouring substances evaluated in FGE.05Rev3
View page or View pdf
EPI System: View
AIDS Citations: Search
Cancer Citations: Search
Toxicology Citations: Search
EPA Substance Registry Services (TSCA): 111-12-6
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 8092
National Institute of Allergy and Infectious Diseases: Data
SCCNFP: opinion
WGK Germany: 2
 methyl oct-2-ynoate
Chemidplus: 0000111126
RTECS: RI2735000 for cas# 111-12-6
Synonyms   Articles   Notes   Search   Top
References:
 methyl oct-2-ynoate
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 111-12-6
Pubchem (cid): 8092
Pubchem (sid): 134974862
Synonyms   Articles   Notes   Search   Top
Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS): View
CHEMBL: View
HMDB (The Human Metabolome Database): HMDB31302
FooDB: FDB003354
Export Tariff Code: 2916.19.5000
ChemSpider: View
Synonyms   Articles   Notes   Search   Top
Potential Blenders and core components note
 
For Odor
No odor group found for these
5-methyloctane-2,3-dione 
aldehydic
 citrus carbaldehydeFR
 decanal (aldehyde C-10)FL/FR
 dodecanal (aldehyde C-12 lauric)FL/FR
2-methyl undecanal (aldehyde C-12 mna)FL/FR
 nonanal (aldehyde C-9)FL/FR
10-undecenal (aldehyde C-11 undecylenic)FL/FR
 dibutyl sulfideFL/FR
 dipropyl disulfideFL/FR
animal
isobutyl quinolineFR
balsamic
isoamyl benzoateFL/FR
 amyris wood oilFL/FR
siam benzoin resinoidFL/FR
 benzyl cinnamateFL/FR
 benzyl salicylateFL/FR
 cinnamyl alcoholFL/FR
 clover nitrileFR
 ethyl cinnamateFL/FR
 fir balsam absoluteFR
3-phenyl propyl alcoholFL/FR
berry
 raspberry ketoneFL/FR
 raspberry ketone acetateFL/FR
 raspberry ketone methyl etherFL/FR
caramellic
2-isobutyl-3-methyl pyrazineFL/FR
 strawberry furanoneFL/FR
chocolate
2,4,5-trimethyl thiazoleFL/FR
citrus
2-ethyl-1-hexanolFL/FR
 grapefruit pentanolFR
 methyl heptenoneFL/FR
 neroli ketoneFR
blood orange oil italyFL/FR
coumarinic
 phthalideFL/FR
dairy
 methyl butyl phenyl acetateFL/FR
earthy
 methyl undecylenateFL/FR
ethereal
1-hexen-3-olFL/FR
2-methyl valeraldehydeFL/FR
fatty
 allyl decanoateFL/FR
 allyl octanoateFL/FR
 butter estersFL/FR
 decanolFL/FR
3-decen-2-oneFL/FR
2-nonen-1-olFL/FR
(E)-2-nonenalFL/FR
2-nonenalFL/FR
(Z)-3-octen-1-olFL/FR
(Z)-2-octenal 
floral
 allyl anthranilateFL/FR
alpha-amyl cinnamaldehydeFL/FR
isoamyl salicylateFL/FR
 benzyl acetateFL/FR
 benzyl alcoholFL/FR
 bois de rose oil brazilFL/FR
isobutyl salicylateFL/FR
 citronellolFL/FR
 citronellyl acetateFL/FR
 coriander seed oilFL/FR
 cuminyl acetaldehydeFL/FR
 cyclamen aldehydeFL/FR
 cyclohexyl ethyl alcoholFL/FR
9-decen-1-olFL/FR
 dimethyl benzyl carbinolFL/FR
 dimethyl benzyl carbinyl acetateFL/FR
 dimethyl benzyl carbinyl butyrateFL/FR
 ethyl phenyl acetateFL/FR
 floral pyranolFR
 gardenia oxideFR
 geraniolFL/FR
 geranium pyranFR
 geranium specialtyFR
 geranyl acetateFL/FR
(E)-geranyl acetoneFL/FR
 geranyl phenyl acetateFL/FR
 heliotropinFL/FR
(Z)-3-hexen-1-yl salicylateFL/FR
alpha-hexyl cinnamaldehydeFL/FR
 ho leaf oilFR
 hyacinth etherFR
 hydroxycitronellalFL/FR
 jasmin pyranoneFL/FR
 leerallFR
 linaloolFL/FR
laevo-linaloolFL/FR
 linalool oxideFL/FR
 methyl dihydrojasmonateFL/FR
 mimosa absolute franceFL/FR
 muguet carboxaldehydeFR
 muguet octadienolFR
 nerolFL/FR
 neryl acetateFL/FR
 nonanolFL/FR
 ocean propanalFL/FR
 orris pyridine 25% IPMFR
 peony alcoholFR
 phenethyl acetateFL/FR
 phenethyl alcoholFL/FR
 phenethyl isobutyrateFL/FR
 phenethyl phenyl acetateFL/FR
 phenethyl propionateFL/FR
 rhodinolFL/FR
 rose butanoateFL/FR
(Z)-rose oxideFL/FR
 tetrahydrolinaloolFL/FR
 violet methyl carbonateFR
fruity
 allyl amyl glycolateFR
isoamyl butyrateFL/FR
 artemisia pallens herb oilFL/FR
 benzyl propionateFL/FR
 butyl butyrateFL/FR
(E)-alpha-damasconeFL/FR
(E)-beta-damasconeFL/FR
gamma-decalactoneFL/FR
 ethyl acetoacetateFL/FR
 green acetateFR
alpha-heptyl cinnamaldehyde 
(E)-2-hexen-1-olFL/FR
2-hexen-1-olFL/FR
 methyl hexanoateFL/FR
(Z)-6-nonenal dimethyl acetalFR
(Z)-3-octen-1-yl propionateFL/FR
(Z)-6-octenal 
 strawberry glycidate 1 (aldehyde C-16 (so-called))FL/FR
gamma-undecalactone (aldehyde C-14 (so-called))FL/FR
green
 acetaldehyde butyl phenethyl acetalFL/FR
 acetaldehyde di-(Z)-3-hexen-1-yl acetalFL/FR
 acetaldehyde dipropyl acetalFL/FR
 acetaldehyde ethyl phenethyl acetalFL/FR
 artichoke leaf 
 bromstyrolCS
isobutyl methyl ketoneFL/FR
2-isobutyl thiazoleFL/FR
 cortex pyridineFL/FR
3,5,6-neocyclocitralFR
3,7-dimethyl-6-octenoic acidFL/FR
2-ethylidene-6-methyl-cis-3-heptenal 
 galbanum decatrieneFL/FR
 galbanum oilFL/FR
1-heptanolFL/FR
 heptyl cinnamateFL/FR
2-heptyl furanFL/FR
(Z)-2-hexen-1-olFL/FR
(Z)-3-hexen-1-olFL/FR
(Z)-3-hexen-1-yl (E)-crotonateFL/FR
(Z)-3-hexen-1-yl acetateFL/FR
(Z)-3-hexen-1-yl benzoateFL/FR
(Z)-3-hexen-1-yl hexanoateFL/FR
(Z)-3-hexen-1-yl lactateFL/FR
(Z)-3-hexen-1-yl methyl carbonateFL/FR
 hexen-1-yl oxypropane nitrileFR
(Z)-3-hexen-1-yl tiglateFL/FR
3-hexenalFL/FR
 hexoxyacetaldehyde dimethyl acetalFR
 hexyl heptanoateFL/FR
 hexyl tiglateFL/FR
 lawsonia inermis leaf oil CO2 extractFR
(Z)-leaf acetalFL/FR
 melon nonenoateFL/FR
 methyl octine carbonateFL/FR
 narcissus flower absoluteFR
 nerol oxideFL/FR
(Z,Z)-3,6-nonadien-1-olFL/FR
(E,Z)-3,6-nonadien-1-olFL/FR
3,6-nonadien-1-olFL/FR
(E,Z)-2,6-nonadien-1-olFL/FR
(E,Z)-2,6-nonadien-1-yl acetateFL/FR
3,6-nonadien-1-yl acetateFL/FR
(E,Z)-2,6-nonadienalFL/FR
(E,Z)-2,6-nonadienal diethyl acetalFL/FR
(Z)-2-nonen-1-olFL/FR
(E)-3-nonen-1-olFL/FR
(Z)-5-octen-1-olFL/FR
(E)-2-octen-1-yl acetateFL/FR
(Z)-5-octen-1-yl propionateFL/FR
 olive oil absoluteFL/FR
1-penten-3-olFL/FR
 phenyl acetaldehydeFL/FR
 phenyl acetaldehyde dimethyl acetalFL/FR
3-phenyl propionaldehydeFL/FR
isopropyl phenyl propionaldehydeFR
 rosa damascena leaf absoluteFR
 rosacyanthinFR
 rose leaf absolute (rosa centifolia)FL/FR
 styralyl acetateFL/FR
 violet leaf absoluteFL/FR
 violet leaf oil (viola odorata)FL/FR
hay
 beeswax absoluteFL/FR
herbal
sweet basil absoluteFL/FR
3-butylidene phthalideFL/FR
 clary sage oil franceFL/FR
 daucus carota fruit oilFL/FR
 herbal heptaneFR
 lavender absolute bulgariaFL/FR
 linalyl acetateFL/FR
 lovage tinctureFL/FR
honey
 methyl phenyl acetateFL/FR
marine
green algae absoluteFL/FR
 marine pyridineFR
melon
 melon heptenalFL/FR
(Z)-6-nonenalFL/FR
 watermelon ketoneFR
minty
isopulegyl formateFL/FR
mossy
 oakmoss absoluteFL/FR
 veramoss (IFF)FR
musty
 cocoa butenalFL/FR
naphthyl
beta-naphthyl ethyl etherFL/FR
powdery
para-anisyl alcoholFL/FR
spicy
 cuminaldehydeFL/FR
black currant bud absoluteFL/FR
 methyl isoeugenolFL/FR
3-(methyl thio) hexanolFL/FR
terpenic
alpha-terpineolFL/FR
tonka
 tonka bean absoluteFR
vanilla
 vanilla bean absolute (vanilla planifolia)FL/FR
 vanillyl acetateFL/FR
waxy
isoamyl decanoateFL/FR
1-dodecanolFL/FR
 ethyl myristateFL/FR
2,4-nonadien-1-olFL/FR
 orris rhizome oil CO2 extractFL/FR
1-undecanolFL/FR
woody
alpha-farneseneFL/FR
alpha-farnesene isomerFL/FR
 santallFR
 tobacarol (IFF)FR
 vetiver oil haitiFL/FR
 woody acetateFR
(Z)-woody amyleneFR
yeasty
2-octen-4-oneFL/FR
 
For Flavor
 
No flavor group found for these
 acetaldehyde di-(Z)-3-hexen-1-yl acetalFL/FR
green algae absoluteFL/FR
 allyl anthranilateFL/FR
2-ethylidene-6-methyl-cis-3-heptenal 
alpha-heptyl cinnamaldehyde 
 heptyl cinnamateFL/FR
(Z)-3-hexen-1-yl (E)-crotonateFL/FR
 hexyl heptanoateFL/FR
2-methyl-3-heptanoneFL
3-methyl-3-pentanolFL
2,4,6-nonatrienalFL
(E)-3-nonen-1-olFL/FR
1,5-octadien-3-olFL
(Z)-6-octenal 
(Z)-2-octenal 
isopulegyl formateFL/FR
aldehydic
 nonanal (aldehyde C-9)FL/FR
1-undecanolFL/FR
alliaceous
 allyl thiopropionateFL
 dipropyl disulfideFL/FR
apple
(E,Z)-2,6-nonadien-1-olFL/FR
balsamic
siam benzoin resinoidFL/FR
 benzyl salicylateFL/FR
 ethyl cinnamateFL/FR
berry
 raspberry ketoneFL/FR
 raspberry ketone acetateFL/FR
 raspberry ketone methyl etherFL/FR
brown
 beeswax absoluteFL/FR
caramellic
 strawberry furanoneFL/FR
celery
3-butylidene phthalideFL/FR
cherry
 heliotropinFL/FR
citrus
laevo-linaloolFL/FR
 linaloolFL/FR
 nerolFL/FR
blood orange oil italyFL/FR
alpha-terpineolFL/FR
cooling
isobutyl salicylateFL/FR
coumarinic
 phthalideFL/FR
creamy
 butter estersFL/FR
 jasmin pyranoneFL/FR
gamma-undecalactone (aldehyde C-14 (so-called))FL/FR
dairy
 methyl butyl phenyl acetateFL/FR
estery
 ethyl acetoacetateFL/FR
fatty
 allyl octanoateFL/FR
(E,E)-2,4-decadienalFL
2-ethyl-1-hexanolFL/FR
2-heptyl furanFL/FR
(Z)-3-hexen-1-yl benzoateFL/FR
2,4-nonadien-1-olFL/FR
2,4-nonadienalFL
(E,E)-2,4-nonadienalFL
2-nonen-1-olFL/FR
(Z)-2-nonen-1-olFL/FR
2-nonenalFL/FR
(Z)-3-octen-1-olFL/FR
10-undecenal (aldehyde C-11 undecylenic)FL/FR
floral
 bois de rose oil brazilFL/FR
 citronellolFL/FR
 citronellyl acetateFL/FR
 dimethyl benzyl carbinyl acetateFL/FR
 dimethyl benzyl carbinyl butyrateFL/FR
3,7-dimethyl-6-octenoic acidFL/FR
 geraniolFL/FR
(E)-geranyl acetoneFL/FR
 geranyl phenyl acetateFL/FR
 linalyl acetateFL/FR
 methyl dihydrojasmonateFL/FR
 methyl phenyl acetateFL/FR
 neryl acetateFL/FR
 ocean propanalFL/FR
 phenethyl alcoholFL/FR
 phenethyl propionateFL/FR
 rhodinolFL/FR
 tetrahydrolinaloolFL/FR
fruity
 allyl decanoateFL/FR
isoamyl benzoateFL/FR
para-anisyl alcoholFL/FR
 artemisia pallens herb oilFL/FR
 benzyl acetateFL/FR
 benzyl alcoholFL/FR
 benzyl propionateFL/FR
 butyl butyrateFL/FR
(E)-alpha-damasconeFL/FR
(E)-beta-damasconeFL/FR
gamma-decalactoneFL/FR
2,4-hexadien-1-olFL
2-hexen-1-olFL/FR
 methyl hexanoateFL/FR
5-methyloctane-2,3-dione 
(Z)-3-octen-1-yl propionateFL/FR
 rose butanoateFL/FR
 strawberry glycidate 1 (aldehyde C-16 (so-called))FL/FR
 styralyl acetateFL/FR
 watermelon distillatesFL
green
 acetaldehyde butyl phenethyl acetalFL/FR
 acetaldehyde dipropyl acetalFL/FR
 acetaldehyde ethyl phenethyl acetalFL/FR
isoamyl salicylateFL/FR
 artichoke leaf 
isobutyl methyl ketoneFL/FR
2-isobutyl thiazoleFL/FR
2-isobutyl-3-methyl pyrazineFL/FR
 cinnamyl alcoholFL/FR
 cocoa butenalFL/FR
 cortex pyridineFL/FR
 cuminyl acetaldehydeFL/FR
 cyclamen aldehydeFL/FR
 cyclohexyl ethyl alcoholFL/FR
3-decen-2-oneFL/FR
 dibutyl sulfideFL/FR
 dihydroxyacetophenone (mixed isomers)FL
alpha-farneseneFL/FR
alpha-farnesene isomerFL/FR
 galbanum decatrieneFL/FR
 galbanum oilFL/FR
 geranyl acetateFL/FR
(E)-2-hexen-1-olFL/FR
(Z)-3-hexen-1-olFL/FR
(Z)-2-hexen-1-olFL/FR
(Z)-3-hexen-1-yl acetateFL/FR
(Z)-3-hexen-1-yl hexanoateFL/FR
(Z)-3-hexen-1-yl lactateFL/FR
(Z)-3-hexen-1-yl methyl carbonateFL/FR
(Z)-3-hexen-1-yl salicylateFL/FR
(Z)-3-hexen-1-yl tiglateFL/FR
1-hexen-3-olFL/FR
3-hexenalFL/FR
2-hexyl pyridineFL
 hexyl tiglateFL/FR
 horseradish oilFL
(Z)-leaf acetalFL/FR
 linalool oxideFL/FR
 melon heptenalFL/FR
 melon nonenoateFL/FR
 methyl heptenoneFL/FR
 methyl octine carbonateFL/FR
4-methyl thiazoleFL
3-(5-methyl-2-furyl) butanalFL
 nerol oxideFL/FR
3,6-nonadien-1-olFL/FR
(E,Z)-3,6-nonadien-1-olFL/FR
(E,Z)-2,6-nonadien-1-yl acetateFL/FR
3,6-nonadien-1-yl acetateFL/FR
(E,Z)-2,6-nonadienalFL/FR
(E,E)-2,6-nonadienalFL
(E,Z)-2,6-nonadienal diethyl acetalFL/FR
(E)-2-nonenalFL/FR
(Z)-6-nonenalFL/FR
 oakmoss absoluteFL/FR
2,4-octadienalFL
(E,E)-2,4-octadienalFL
(Z)-5-octen-1-olFL/FR
(E)-2-octen-1-yl acetateFL/FR
(Z)-5-octen-1-yl propionateFL/FR
4-penten-1-yl acetateFL
1-penten-3-olFL/FR
 phenyl acetaldehyde dimethyl acetalFL/FR
3-phenyl propionaldehydeFL/FR
 rose leaf absolute (rosa centifolia)FL/FR
(Z)-rose oxideFL/FR
 violet leaf absoluteFL/FR
 violet leaf oil (viola odorata)FL/FR
herbal
sweet basil absoluteFL/FR
 clary sage oil franceFL/FR
 coriander seed oilFL/FR
 daucus carota fruit oilFL/FR
 lavender absolute bulgariaFL/FR
 lovage tinctureFL/FR
honey
 ethyl phenyl acetateFL/FR
 phenethyl acetateFL/FR
 phenethyl isobutyrateFL/FR
 phenethyl phenyl acetateFL/FR
 phenyl acetaldehydeFL/FR
medicinal
 dimethyl benzyl carbinolFL/FR
melon
 watermelon concentrateFL
metallic
3-(methyl thio) hexanolFL/FR
nutty
2,4,5-trimethyl thiazoleFL/FR
oily
 olive oil absoluteFL/FR
powdery
beta-naphthyl ethyl etherFL/FR
soapy
 dodecanal (aldehyde C-12 lauric)FL/FR
1-dodecanolFL/FR
solvent
1-heptanolFL/FR
spicy
 benzyl cinnamateFL/FR
 cuminaldehydeFL/FR
black currant bud absoluteFL/FR
 methyl isoeugenolFL/FR
3-phenyl propyl alcoholFL/FR
sulfurous
 potato butanoneFL
tropical
alpha-amyl cinnamaldehydeFL/FR
vanilla
 vanilla bean absolute (vanilla planifolia)FL/FR
 vanillyl acetateFL/FR
vegetable
2-methyl valeraldehydeFL/FR
2-octen-4-oneFL/FR
waxy
isoamyl butyrateFL/FR
isoamyl decanoateFL/FR
 decanal (aldehyde C-10)FL/FR
 decanolFL/FR
9-decen-1-olFL/FR
 ethyl myristateFL/FR
alpha-hexyl cinnamaldehydeFL/FR
 hydroxycitronellalFL/FR
2-methyl undecanal (aldehyde C-12 mna)FL/FR
 methyl undecylenateFL/FR
 mimosa absolute franceFL/FR
(Z,Z)-3,6-nonadien-1-olFL/FR
 nonanolFL/FR
woody
 amyris wood oilFL/FR
 orris rhizome oil CO2 extractFL/FR
 vetiver oil haitiFL/FR
 
Synonyms   Articles   Notes   Search   Top
Potential Uses:
 acaciaFR
 apricotFR
 bananaFR
 cucumberFR
 earthFR
 frangipani plumeriaFR
 freesiaFR
 greenFR
 hay new mown hayFR
 honeysuckleFR
 jasminFR
 jonquilFR
 leaf 
 melonFR
 melonFR
 mimosaFR
 orrisFR
 peachFR
 pearFR
 floralFR
 resedaFR
 roseFR
 scandal 
 stephanotisFR
 straw 
 strawberryFR
 sweet peaFR
 teaFL
 tuberoseFR
 violet leafFR
 wallflowerFR
 woodyFR
Synonyms   Articles   Notes   Search   Top
Occurrence (nature, food, other): note
 not found in nature
Synonyms   Articles   Notes   Search   Top
Synonyms:
 folione (Givaudan)
 folione FCC (Givaudan)
 methyl 2-octinate
 methyl 2-octynate
 methyl 2-octynoate
 methyl hept-1-yne-1-carboxylate
 methyl heptin carbonate
 methyl heptine carbonate
 methyl heptyl carbonate
 methyl heptyne carbonate
 methyl oct-2-ynoate
 methyl pentyl acetylene carboxylate
 methyl pentylacetylenecarboxylate
 methyl-N-hept-1-yne-1-carboxylate
 oct-2-ynoic acid methyl ester
2-octynoic acid methyl ester
2-octynoic acid, methyl ester
Synonyms   Articles   Notes   Search   Top
Articles:
PubMed: Determination of suspected allergens in cosmetic products by headspace-programmed temperature vaporization-fast gas chromatography-quadrupole mass spectrometry.
PubMed: Active sensitization and contact allergy to methyl 2-octynoate.
PubMed: Is there evidence that methyl heptine carbonate causes allergic contact dermatitis?
PubMed: Synthesis of seven-membered lactones via nickel- and zinc-catalyzed highly regio- and stereoselective cyclization of 2-iodobenzyl alcohols with propiolates.
PubMed: Allergic contact dermatitis from methyl heptine and methyl octine carbonates.
PubMed: [Cutaneous delayed hypersensitivity to methyl hepatine carbonate in pulmonary tuberculosis].
PubMed: [Methyl heptine carbonate skin test in lung cancer--correlation with stage and prognosis].
PubMed: [Newly recognized primary sensitizers, methyl heptine carbonate and costus root oil to evaluate cutaneous delayed hypersensitivity on various chest diseases (author's transl)].
Synonyms   Articles   Notes   Search   Top
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