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Category: flavoring agents and cosmetic fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless clear liquid (exp) |
| Assay: | 95.00 to 100.00 %
|
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.82200 to 0.83100 @ 25.00 °C.
|
| Pounds per Gallon - (est).: | 6.840 to 6.915
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| Refractive Index: | 1.37800 to 1.38600 @ 20.00 °C.
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| Melting Point: | -100.00 °C. @ 760.00 mm Hg
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| Boiling Point: | 102.00 to 104.00 °C. @ 760.00 mm Hg
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| Boiling Point: | 32.00 to 33.00 °C. @ 50.00 mm Hg
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| Acid Value: | 1.00 max. KOH/g
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| Vapor Pressure: | 27.600000 mmHg @ 25.00 °C. |
| Vapor Density: | 4.1 ( Air = 1 ) |
| Flash Point: | -5.00 °F. TCC ( -20.56 °C. )
|
| logP (o/w): | 0.840 |
| Shelf Life: | 12.00 month(s) or longer if stored properly. |
| Storage: | store in cool, dry place in tightly sealed containers, protected from heat and light. |
| Soluble in: |
| | alcohol | | | aliphatic alcohols | | | ethyl ether | | | water, 1.954e+004 mg/L @ 25 °C (est) | | | water, 4.40E+04 mg/L @ 25 °C (exp) |
Organoleptic Properties:
| |
| Odor Type: ethereal |
| |
| Odor Strength: | high , recommend smelling in a 1.00 % solution or less |
| |
| Substantivity: | < 1 hour(s) at 100.00 % |
| |
| | ethereal green nutty earthy sweet vegetable |
Odor Description: at 1.00 % in propylene glycol. | ether green nut earthy sweet vegetable Luebke, William tgsc, (2017) |
| |
| |
| Flavor Type: nutty |
| |
| | nutty earthy vegetable |
Taste Description:
| nutty earthy vegetable Luebke, William tgsc, (2017) |
| |
| Odor and/or flavor descriptions from others (if found). |
| |
| Lluch Essence |
| ACETALDEHYDE DIETHYL ACETAL |
| Odor Description: | ETHEREAL, EARTHY, GREEN |
| Taste Description: | nutty |
| |
| |
Cosmetic Information:
Suppliers:
| Advanced Biotech |
| ACETAL 30-35% IN ETOH NATURAL
Odor: Alcoholic, Whisky, nutty |
| Advanced Biotech |
| ACETAL NATURAL
98% min. Odor: Whisky, nutty |
| Alfrebro |
| ACETAL NATURAL 30 - 35% IN ETHANOL
Odor: Strong, fruity |
| Augustus Oils |
| Acetal
|
| Services |
| Axxence Aromatic |
| ACETAL 98%, Natural
Kosher |
| Sustainability |
| Beijing Lys Chemicals |
| Acetal
|
| Charkit Chemical |
| ACETAL FEMA 2002
|
| CJ Latta & Associates |
| ACETALS
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| Ernesto Ventós |
| ACETAL (ACETALDEHYDE DIETHYL ACETAL)
Odor: EARTHY,ETHEREAL,GREEN,NUTTY,SWEET |
| Excellentia International |
| Acetal Natural
|
| Fleurchem |
| acetal natural
|
| Frutarom |
| ACETAL (1,1-DIETHOXYETHANE)
KOSHER Flavor: Green, Nutty, Earthy, Sweet, Vegetable |
| CBD Offering |
| IFF |
| ACETAL (1,1-DIETHOXYETHANE)
KOSHER Flavor: Green, Nutty, Earthy, Sweet, Vegetable |
| Indukern F&F |
| ACETAL
Odor: ETHEREAL, FRUITY |
| Inoue Perfumery |
| ACETALDEHYDE DIETHYL ACETAL
|
| Jiangyin Healthway |
| Acetal Natural99%
|
| New functional food ingredients |
| Keva |
| 1,1-DIETHOXYETHANE
Odor: Fruity, green |
| Lluch Essence |
| 1,1-DIETHOXYETHANE ® PFW
|
| Lluch Essence |
| ACETAL NATURAL 98%
|
| Lluch Essence |
| ACETALDEHYDE DIETHYL ACETAL
Odor: ETHEREAL, EARTHY, GREEN |
| M&U International |
| Acetal, Kosher
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| M&U International |
| Nat. Acetal
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| Natural Advantage |
| Acetal Nat, 35% in OH
Flavor: alcoholic, ethereal, fruity, green, nutty, sweet |
| Riverside Aromatics LTD.is the exclusive distributor for Europe in UK for any non-US based inquiries |
| Natural Advantage |
| Acetal-98 Nat
Flavor: alcoholic, ethereal, fruity, green, nutty, sweet |
| PCW France |
| 1,1-Diethoxyethane
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| Steps to a fragranced product |
| Penta International |
| ACETALDEHYDE DIETHYL ACETAL NATURAL
|
| Penta International |
| ACETALDEHYDE DIETHYL ACETAL
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| Pfaltz & Bauer |
| For experimental / research use only. |
| Acetaldehyde diethyl acetal
|
| Reincke & Fichtner |
| Acetal
|
| Riverside Aromatics |
| ACETAL, NATURAL
|
| Riverside Aromatics |
| ACETAL, NATURAL
|
| Robertet |
| ACETAL
Pure & Nat |
| Seasons and Harvest / Crop calendar |
| Seqens |
| ACETALDEHYDE DIETHYLACETAL
|
| Sigma-Aldrich |
| Acetal, ≥98%, FG
Odor: honey; green; floral; tart |
| Certified Food Grade Products |
| Sigma-Aldrich |
| Acetal, natural, FG, ≥97%
Odor: honey; green; floral; tart |
| Silverline Chemicals |
| Diethyl Acetal
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| SRS Aromatics |
| 1,1-DIETHOXYETHANE
Odor: Ether, Green, Nut, Earthy, Sweet, Vegetable |
| Taytonn ASCC |
| Acetal
Odor: Earthy, Ethereal, Green, Nutty, Sweet |
| TCI AMERICA |
| For experimental / research use only. |
| Acetal >98.0%(GC)
|
| Ungerer & Company |
| Acetal Natural
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| Vigon International |
| Acetaldehyde Diethyl Acetal Natural
|
| Vigon International |
| Acetaldehyde Diethyl Acetal
Odor: Fruity,Alcoholic,Green,Nutty,Whiskey |
| WEN International |
| ACETAL Natural
|
| WholeChem |
| Acetal
|
Safety Information:
| Preferred SDS: View |
| European information : |
| Most important hazard(s): | | Xi - Irritant |
R 11 - Highly flammable. R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 09 - Keep container in a well-ventilated place. S 16 - Keep away from sources of ignition - No Smoking. S 33 - Take precautionary measures against static discharge. S 37/39 - Wear suitable gloves and eye/face protection.
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| |
| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
Skin irritation (Category 2), H315 Eye irritation (Category 2A), H319
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| GHS Label elements, including precautionary statements |
| |
| Pictogram |   |
| |
| Signal word | Danger |
| Hazard statement(s) |
H225 - Highly Flammable liquid and vapour H315 - Causes skin irritation H319 - Causes serious eye irritation
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| Precautionary statement(s) |
P210 - Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/…/equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P264 - Wash skin thouroughly after handling. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332 + P313 - IF SKIN irritation occurs: Get medical advice/attention. P337 + P313 - IF eye irritation persists: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. P403 + P235 - Store in a well-ventilated place. Keep cool. P501 - Dispose of contents/ container to an approved waste disposal plant.
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| Oral/Parenteral Toxicity: |
oral-rat LD50 4600 mg/kg Medizin und Ernaehrung. Vol. 8, Pg. 244, 1967.
intraperitoneal-rat LD50 900 mg/kg "Industrial Hygiene and Toxicology," 2nd ed., Patty, F.A., ed., New York, John Wiley & Sons, Inc., 1958-63Vol. 2, Pg. 1982, 1963.
oral-rabbit LD50 3545 mg/kg Proceedings of the Society for Experimental Biology and Medicine. Vol. 29, Pg. 730, 1932.
oral-mouse LD50 3500 mg/kg Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 42(3), Pg. 12, 1977.
intraperitoneal-mouse LD50 500 mg/kg National Technical Information Service. Vol. AD277-689
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| Dermal Toxicity: |
|
Not determined
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| Inhalation Toxicity: |
inhalation-rat LCLo 4000 ppm/4H Journal of Industrial Hygiene and Toxicology. Vol. 31, Pg. 343, 1949.
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Safety in Use Information:
| Category: | flavoring agents and cosmetic fragrance agents |
| RIFM Fragrance Material Safety Assessment: Search |
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
| Recommendation for acetal usage levels up to: | | | 0.1000 % in the fragrance concentrate.
|
| |
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 200.00 (μg/capita/day) |
| Maximised Survey-derived Daily Intakes (MSDI-USA): | 640.00 (μg/capita/day) |
| Threshold of Concern: | 1800 (μg/person/day) |
| Structure Class: | I |
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 3. Update in publication number(s): 29 |
| Click here to view publication 3 |
| | average usual ppm | average maximum ppm |
| baked goods: | 65.00000 | 120.00000 |
| beverages(nonalcoholic): | 5.00000 | 11.00000 |
| beverages(alcoholic): | 109.00000 | 154.00000 |
| breakfast cereal: | - | - |
| cheese: | - | - |
| chewing gum: | 155.00000 | 155.00000 |
| condiments / relishes: | - | - |
| confectionery froastings: | - | - |
| egg products: | - | - |
| fats / oils: | 2.00000 | 3.00000 |
| fish products: | - | - |
| frozen dairy: | 36.00000 | 73.00000 |
| fruit ices: | - | - |
| gelatins / puddings: | 36.00000 | 67.00000 |
| granulated sugar: | - | - |
| gravies: | - | - |
| hard candy: | 4.00000 | 39.00000 |
| imitation dairy: | - | - |
| instant coffee / tea: | - | - |
| jams / jellies: | - | - |
| meat products: | - | - |
| milk products: | - | - |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | - | - |
| snack foods: | - | - |
| soft candy: | 33.00000 | 56.00000 |
| soups: | - | - |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
Safety References:
| European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
| European Food Safety Authority (EFSA) reference(s): |
Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) related to Flavouring Group Evaluation 3 (FGE.03); Acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated aldehydes, and a orthoester of formic acid, from chemical groups 1 and 2 (Commission Regulation (EC) No 1565/2000 of 18 July 2000) View page or View pdf |
Flavouring Group Evaluation 3, Revision 1 (FGE.03Rev1): Acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated or unsaturated aldehydes, an ester of a hemiacetal and an orthoester of formic acid, from chemical groups 1, 2 & 4 Commission Regulation (EC) No 1565/2000 of 18 July 2000) [1] - Scientific Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC)on a request from the Commission View page or View pdf |
Flavouring Group Evaluation 61 (FGE.61): Consideration of aliphatic acyclic acetals evaluated by JECFA (57th meeting) structurally related to acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated aldehydes, and an orthoester of formic acid evaluated by EFSA in FGE.03 (2004) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) View page or View pdf |
Flavouring Group Evaluation 61, Revision 1 (FGE.61Rev1): Consideration of aliphatic acetals evaluated by JECFA (57th meeting) structurally related to acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated aldehydes and one orthoester of formic acid evaluated View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 3, Revision 2 (FGE.03Rev2): Acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated or unsaturated aldehydes, an ester of a hemiacetal and an orthoester of formic acid, from chemical groups 1, 2 and 4 View page or View pdf |
Scientific Opinion on the safety and efficacy of straight-chain primary aliphatic alcohols/aldehydes/acids, acetals and esters with esters containing saturated alcohols and acetals containing saturated aldehydes (chemical group 1) when used as flavourings for all animal species View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 61 Revision 2 (FGE.61Rev2): consideration of aliphatic acetals evaluated by JECFA (57th, 63rd and 68th meetings) structurally related to acetals evaluated by EFSA in FGE.03Rev2 View page or View pdf |
| EPI System: | View |
| NIOSH International Chemical Safety Cards: | search |
| AIDS Citations: | Search |
| Cancer Citations: | Search |
| Toxicology Citations: | Search |
| EPA Substance Registry Services (TSCA): | 105-57-7 |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| Laboratory Chemical Safety Summary : | 7765 |
| National Institute of Allergy and Infectious Diseases: | Data |
| WISER: | UN 1088 |
| WGK Germany: | 2 |
| | 1,1-diethoxyethane |
| Chemidplus: | 0000105577 |
| EPA/NOAA CAMEO: | hazardous materials |
| RTECS: | 105-57-7 |
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | acetal | | | acetal (1,1-diethoxyethane) | | | acetal (acetaldehyde diethyl acetal) | | | acetal (natural) | | | acetal 30-35% in ETOH natural | | | acetal natural | | | acetaldehyde diethyl acetal | | | acetaldehyde diethylacetal | | | acetaldehyde ethyl acetal | | 1,1- | diethoxy-ethane | | 1,1- | diethoxyethane | | | diethyl acetal | | | diethylacetal | | | ethane, 1,1-diethoxy- | | | ethylidine diethyl ether |
Articles:
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