|
Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless to pale yellow clear liquid (est) |
| Assay: | 99.00 to 100.00 %
|
| Food Chemicals Codex Listed: | Yes |
| Specific Gravity: | 0.93900 to 0.94200 @ 20.00 °C.
|
| Pounds per Gallon - (est).: | 7.823 to 7.848
|
| Refractive Index: | 1.40700 to 1.41100 @ 20.00 °C.
|
| Melting Point: | -35.00 to -34.00 °C. @ 760.00 mm Hg
|
| Boiling Point: | 184.00 to 186.00 °C. @ 760.00 mm Hg
|
| Boiling Point: | 112.00 to 113.00 °C. @ 50.00 mm Hg
|
| Vapor Pressure: | 0.452000 mmHg @ 25.00 °C. (est) |
| Vapor Density: | 3.5 ( Air = 1 ) |
| Flash Point: | 192.00 °F. TCC ( 88.89 °C. )
|
| logP (o/w): | 1.390 |
| Soluble in: |
| | alcohol | | | ether | | | water, 1.86e+004 mg/L @ 25 °C (est) |
| Insoluble in: |
| | water |
Organoleptic Properties:
| |
| Odor Type: cheesy |
| |
| | acidic sweaty rancid |
Odor Description: at 1.00 % in propylene glycol. | sickening putrid acidic sweaty rancid |
| |
| | acidic sharp cheesy sour milky tobacco fruity |
Odor Description:
| Acidic and sharp, cheese-like, sour milky, tobacco, with fruity nuances Mosciano, Gerard P&F 19, No. 2, 55, (1994) |
| |
| |
| Flavor Type: acidic |
| |
| | acidic dairy milky cheesy |
Taste Description: at 100.00 ppm. | Acidic, dairy-like with milky and cheese nuances Mosciano, Gerard P&F 19, No. 2, 55, (1994) |
| |
| Odor and/or flavor descriptions from others (if found). |
| |
| Alfrebro |
| VALERIC ACID NATURAL |
| Odor Description: | Unpleasant, Penetrating, Rancid |
| |
| |
Cosmetic Information:
Suppliers:
| Alfrebro |
| VALERIC ACID NATURAL
Odor: Unpleasant, Penetrating, Rancid |
| Augustus Oils |
| N Valeric Acid
|
| Services |
| Beijing Lys Chemicals |
| Valeric acid
|
| Berjé |
| N-Valeric Acid
|
| Media |
| Charkit Chemical |
| VALERIC ACID V0050 FEMA 3101
|
| Ernesto Ventós |
| PENTANOIC ACID
Odor: BUTIRIC |
| Frutarom |
| VALERIC ACID
KOSHER Flavor: Acidic, Rancid, Sweaty, Putrid |
| CBD Offering |
| Glentham Life Sciences |
| Valeric acid
|
| Grau Aromatics |
| VALERIC ACID FCC
|
| IFF |
| VALERIC ACID
KOSHER Flavor: Acidic, Rancid, Sweaty, Putrid |
| Indukern F&F |
| VALERIC ACID
|
| Lluch Essence |
| VALERIC ACID
|
| M&U International |
| NAT. VALERIC ACID
|
| Moellhausen |
| PENTANOIC ACID
|
| Nagar Haveli Perfumes & Aromatics |
| Valeric Acid 98 % (min)
Natural |
| Penta International |
| VALERIC ACID FCC
|
| Penta International |
| VALERIC ACID NATURAL
|
| Penta International |
| VALERIC ACID
|
| Prodasynth |
| VALERIC ACID
(> 99%) |
| R C Treatt & Co Ltd |
| Valeric Acid
|
| Reincke & Fichtner |
| Valeric Acid
|
| Sigma-Aldrich |
| Valeric acid natural, ≥98%, FG
Odor: cheese; acidic; sour |
| Certified Food Grade Products |
| Sigma-Aldrich |
| Valeric acid, ≥99%, FCC, FG
Odor: animal; earthy |
| SRS Aromatics |
| VALERIC ACID FCC
|
| Synerzine |
| Valeric Acid
|
| Taytonn ASCC |
| Valeric Acid
Odor: Sweaty, Rancid, Putrid |
| TCI AMERICA |
| For experimental / research use only. |
| Valeric Acid >98.0%(GC)(T)
|
| WholeChem |
| Valeric acid
|
Safety Information:
| Preferred SDS: View |
| European information : |
| Most important hazard(s): | | C N - Corrosive, Dangerous for the environment. |
R 34 - Causes burns. R 52/53 - Harmful to qauatic organisms, may cause long-term adverse effects in the aquatic environment. S 01/02 - Keep locked up and out of the reach of children. S 20/21 - When using do not eat, drink or smoke. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 28 - After contact with skin, wash immediately with plenty of water. S 36/37/39 - Wear suitable clothing, gloves and eye/face protection. S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet.
|
| |
| Hazards identification |
| |
| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
| |
| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
oral-mouse LD50 600 mg/kg "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 119, 1982.
intravenous-mouse LD50 1290 mg/kg BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX)
LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Acta Pharmacologica et Toxicologica. Vol. 18, Pg. 141, 1961.
intraperitoneal-mouse LD50 3590 mg/kg Journal of Pharmacy and Pharmacology. Vol. 21, Pg. 85, 1969.
|
| Dermal Toxicity: |
subcutaneous-mouse LD50 3590 mg/kg Journal of Pharmacy and Pharmacology. Vol. 21, Pg. 85, 1969.
|
| Inhalation Toxicity: |
inhalation-mouse LC50 4100 mg/m3/2H "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 119, 1982.
|
Safety in Use Information:
| Category: | flavor and fragrance agents |
| RIFM Fragrance Material Safety Assessment: Search |
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
| |
| Structure Class: | I |
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 3 |
| Click here to view publication 3 |
| | average usual ppm | average maximum ppm |
| baked goods: | - | 8.00000 |
| beverages(nonalcoholic): | - | 1.20000 |
| beverages(alcoholic): | - | - |
| breakfast cereal: | - | - |
| cheese: | - | - |
| chewing gum: | - | - |
| condiments / relishes: | - | - |
| confectionery froastings: | - | - |
| egg products: | - | - |
| fats / oils: | - | - |
| fish products: | - | - |
| frozen dairy: | - | 1.80000 |
| fruit ices: | - | 1.80000 |
| gelatins / puddings: | - | - |
| granulated sugar: | - | - |
| gravies: | - | - |
| hard candy: | - | 2.50000 |
| imitation dairy: | - | - |
| instant coffee / tea: | - | - |
| jams / jellies: | - | - |
| meat products: | - | - |
| milk products: | - | - |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | - | - |
| snack foods: | - | - |
| soft candy: | - | - |
| soups: | - | - |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
Safety References:
| European Food Safety Authority (EFSA) reference(s): |
Flavouring Group Evaluation 9, Revision 1: (FGE.09 Rev1)[1] - Secondary alicyclic saturated and unsaturated alcohols, ketones and esters containing secondary alicyclic alcohols from chemical groups 8 and 30, and an ester of a phenol carboxylic acid from chemical group 25 - Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food View page or View pdf |
Flavouring Group Evaluation 14, Revision 1 (FGE.14Rev1): Phenethyl alcohol, aldehyde, acetals, carboxylic acid and related esters from chemical group 15 and 22 [1] - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food View page or View pdf |
Flavouring Group Evaluation 20, Revision 1 (FGE.20Rev1): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids and related esters from chemical group 23 View page or View pdf |
Flavouring Group Evaluation 18, Revision 1 (FGE. 18 Rev1)[1] : Aliphatic, alicyclic and aromatic saturated and unsaturated tertiary alcohols, aromatic tertiary alcohols and their esters from chemical groups 6 and 8 View page or View pdf |
Flavouring Group Evaluation 7, Revision 2 (FGE.07Rev2) : Saturated and unsaturated aliphatic secondary alcohols, ketones and esters of secondary alcohols and saturated linear or branched-chain carboxylic acids from chemical group 5 View page or View pdf |
Scientific Report of EFSA on the risk assessment of salts of authorised acids, phenols or alcohols for use in food contact materials [1] View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 20, Revision 2 (FGE.20Rev2): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30 View page or View pdf |
Flavouring Group Evaluation 9, Revision 2 (FGE.09Rev2): Secondary alicyclic saturated and unsaturated alcohols, ketones and esters containing secondary alicyclic alcohols from chemical group 8 and 30, and an ester of a phenol derivative from chemical group 25 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 20, Revision 3(FGE.20Rev3): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30 View page or View pdf |
Scientific Opinion on the safety and efficacy of straight-chain primary aliphatic alcohols/aldehydes/acids, acetals and esters with esters containing saturated alcohols and acetals containing saturated aldehydes (chemical group 1) when used as flavourings for all animal species View page or View pdf |
| EPI System: | View |
| NIOSH International Chemical Safety Cards: | search |
| AIDS Citations: | Search |
| Cancer Citations: | Search |
| Toxicology Citations: | Search |
| EPA Substance Registry Services (TSCA): | 109-52-4 |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| Laboratory Chemical Safety Summary : | 7991 |
| National Institute of Allergy and Infectious Diseases: | Data |
| WISER: | UN 3265 |
| WGK Germany: | 1 |
| | pentanoic acid |
| Chemidplus: | 0000109524 |
| EPA/NOAA CAMEO: | hazardous materials |
| RTECS: | 109-52-4 |
References:
Other Information:
Potential Blenders and core components note
| |
| For Odor |
| No odor group found for these |
| iso | valeraldehyde diethyl acetal | FL/FR |
| iso | butyric acid | FL/FR |
| | cyclohexyl acetic acid | FL/FR |
| 2- | ethyl butyric acid | FL/FR |
| | hibiscus rosa-sinensis flower extract | CS |
| 2- | methyl butyric acid | FL/FR |
| 2- | methyl-2-pentenoic acid | FL/FR |
| aldehydic |
| | acetyl nonyryl | FL/FR |
| balsamic |
| | terpinyl butyrate | FL/FR |
| | valerian rhizome absolute | FL/FR |
| burnt |
| | rum ether | FL/FR |
| buttery |
| | acetoin | FL/FR |
| | acetyl butyryl | FL/FR |
| | acetyl propionyl | FL/FR |
| | butyl butyryl lactate | FL/FR |
| 2,3- | heptane dione | FL/FR |
| caramellic |
| | levulinic acid | FL/FR |
| cheesy |
| | butyric acid | FL/FR |
| | heptanoic acid | FL/FR |
| 2- | methyl hexanoic acid | FL/FR |
| S-( | methyl thio) butyrate | FL/FR |
| 2- | methyl valeric acid | FL/FR |
| 2- | methyl-2-hexenoic acid | FR |
| iso | valeric acid | FL/FR |
| coconut |
| | coconut decanone methyl | FR |
| delta- | decalactone | FL/FR |
| gamma- | octalactone | FL/FR |
| delta- | octalactone | FL/FR |
| para- | vanillic acid | FL/FR |
| ethereal |
| | decyl propionate | FL/FR |
| fatty |
| | allyl cyclohexyl hexanoate | FL/FR |
| iso | butyl undecylenate | FL/FR |
| | coconut absolute | FL/FR |
| (Z)- | dairy lactone | FL/FR |
| | decanoic acid | FL/FR |
| | hexanoic acid | FL/FR |
| 4- | methyl octanoic acid | FL/FR |
| | octanoic acid | FL/FR |
| (Z)-3- | octen-1-ol | FL/FR |
| floral |
| | neryl isovalerate | FL/FR |
| | phenethyl hexanoate | FL/FR |
| fruity |
| | allyl cyclohexyl acetate | FL/FR |
| | allyl propionate | FL/FR |
| | amyl valerate | FL/FR |
| | cyclohexyl carboxylic acid | FL/FR |
| | dihydroactinidolide | FL/FR |
| | ethyl lactate | FL/FR |
| | filbert hexenone | FL/FR |
| 4- | heptanone | FL/FR |
| (E)-2- | hepten-1-yl acetate | FL/FR |
| | hexyl isovalerate | FL/FR |
| | methyl (Z)-5-octenoate | FL/FR |
| | methyl 4-methyl valerate | FL/FR |
| 2- | methyl butyl acetate | FL/FR |
| 2- | methyl butyl isovalerate | FL/FR |
| | methyl butyrate | FL/FR |
| | octyl heptanoate | FL/FR |
| | pineapple hydroxyhexanoate | FL/FR |
| | prenyl hexanoate | FL/FR |
| | propyl butyrate | FL/FR |
| | propyl heptanoate | FL/FR |
| | propyl isobutyrate | FL/FR |
| | sorbyl butyrate | FL/FR |
| gamma- | undecalactone (aldehyde C-14 (so-called)) | FL/FR |
| green |
| iso | amyl 3-(2-furan) propionate | FL/FR |
| iso | butyl methyl ketone | FL/FR |
| | geranic acid | FL/FR |
| 3- | heptanone | FL/FR |
| | heptyl acetate | FL/FR |
| | hexanal (aldehyde C-6) | FL/FR |
| (Z)-3- | hexen-1-yl 2-methyl butyrate | FL/FR |
| (E)-2- | hexen-1-yl butyrate | FL/FR |
| (R)-1- | hexen-3-ol | |
| (E)-2- | hexenal | FL/FR |
| herbal |
| iso | amyl heptanoate | FL/FR |
| | benzyl octanoate | FL/FR |
| | rue flower oil colombia | |
| | rue oil | FL/FR |
| | rue oil cuba | FL/FR |
| honey |
| | phenoxyacetic acid | FL/FR |
| | phenyl pyruvic acid | FL/FR |
| nutty |
| | nutty quinoxaline | FL/FR |
| oily |
| | butter acids | FL/FR |
| | petal pyranone | FL/FR |
| spicy |
| | clove bud concrete | FR |
| | cumin seed oil | FL/FR |
| (±)-1,2,5,6- | tetrahydrocuminic acid | FL/FR |
| | ethyl 3-mercaptobutyrate | FL/FR |
| | ethyl methyl mercaptopropionate | FL/FR |
| waxy |
| 9- | decenoic acid | FL/FR |
| 2- | methyl heptanoic acid | FL/FR |
| | nonanoic acid | FL/FR |
| 2- | nonanol | FL/FR |
| delta- | tetradecalactone | FL/FR |
| 2- | tridecanone | FL/FR |
| | undecanoic acid | FL/FR |
| |
| For Flavor |
| |
| No flavor group found for these |
| | allyl cyclohexyl hexanoate | FL/FR |
| | amyl valerate | FL/FR |
| | benzyl octanoate | FL/FR |
| iso | butyl undecylenate | FL/FR |
| | decyl propionate | FL/FR |
| 2,5- | dithiahexane | FL |
| | ethyl 3-mercaptobutyrate | FL/FR |
| | ethyl cyclohexyl carboxylate | FL |
| (E,E)-2,4- | heptadien-1-ol | FL |
| (E)-2- | hepten-1-yl acetate | FL/FR |
| (R)-1- | hexen-3-ol | |
| (Z)-3- | hexenoic acid | FL |
| 3- | mercapto-3-methyl butyl formate | FL |
| 3- | methyl crotonic acid | FL |
| 5- | methyl hexanoic acid | FL |
| S- | methyl thiopropionate | FL |
| 4- | methyl valeric acid | FL |
| 3- | methyl-2-cyclopenten-1-one | FL |
| | octyl heptanoate | FL/FR |
| | phenoxyacetic acid | FL/FR |
| | prenyl hexanoate | FL/FR |
| | rue flower oil colombia | |
| (±)-1,2,5,6- | tetrahydrocuminic acid | FL/FR |
| | thiamine hydrochloride | FL |
| iso | valeraldehyde diethyl acetal | FL/FR |
| | valeraldehyde diethyl acetal | FL |
|
| iso | amyl 3-(2-furan) propionate | FL/FR |
| 3-( | methyl thio) methyl thiophene | FL |
| acetic |
| | formic acid | FL |
| acidic |
| iso | butyric acid | FL/FR |
| 2- | ethyl butyric acid | FL/FR |
| | levulinic acid | FL/FR |
| | propionic acid | FL |
| aldehydic |
| | acetyl nonyryl | FL/FR |
| alliaceous |
| | allyl propionate | FL/FR |
| berry |
| | prunus spinosa extract | FL |
| bitter |
| | glyceryl tributyrate | FL |
| burnt |
| | rum ether | FL/FR |
| buttery |
| 2,3- | heptane dione | FL/FR |
| 2- | methyl valeric acid | FL/FR |
| (E)-2- | pentenoic acid | FL |
| caramellic |
| | pyruvaldehyde | FL |
| | pyruvic acid | FL |
| cheesy |
| (E)-2,4- | dimethyl-2-pentenoic acid | FL |
| | hexanoic acid | FL/FR |
| 3- | hydroxy-5-methyl-2-hexanone | FL |
| iso | valeric acid | FL/FR |
| coconut |
| delta- | decalactone | FL/FR |
| delta- | octalactone | FL/FR |
| creamy |
| | acetoin | FL/FR |
| | acetoin butyrate | FL |
| | acetyl butyryl | FL/FR |
| | butyl butyryl lactate | FL/FR |
| 2- | methyl-4-pentenoic acid | FL |
| | triacetin | FL |
| gamma- | undecalactone (aldehyde C-14 (so-called)) | FL/FR |
| para- | vanillic acid | FL/FR |
| dairy |
| | dairy flavor | FL |
| | methyl (Z)-5-octenoate | FL/FR |
| 4- | pentenoic acid | FL |
| ethereal |
| 4- | hexen-3-one | FL |
| fatty |
| | butter acids | FL/FR |
| | coconut absolute | FL/FR |
| (Z)- | dairy lactone | FL/FR |
| | dimethyl sulfoxide | FL |
| 4- | methyl octanoic acid | FL/FR |
| | nonanoic acid | FL/FR |
| (Z)-3- | octen-1-ol | FL/FR |
| (E)-2- | octenoic acid | FL |
| 2- | tridecanone | FL/FR |
| fermented |
| | methyl thio isovalerate | FL |
| fishy |
| | trimethyl amine | FL |
| floral |
| | terpinyl butyrate | FL/FR |
| fruity |
| | allyl cyclohexyl acetate | FL/FR |
| | cyclohexyl carboxylic acid | FL/FR |
| | dihydroactinidolide | FL/FR |
| | ethyl 3-oxohexanoate | FL |
| | ethyl lactate | FL/FR |
| | filbert hexenone | FL/FR |
| | furfuryl isovalerate | FL |
| | furfuryl valerate | FL |
| 4- | heptanone | FL/FR |
| | methyl 4-methyl valerate | FL/FR |
| 2- | methyl butyl acetate | FL/FR |
| 2- | methyl butyl isovalerate | FL/FR |
| 2- | methyl butyric acid | FL/FR |
| | neryl isovalerate | FL/FR |
| | pineapple hydroxyhexanoate | FL/FR |
| | propyl butyrate | FL/FR |
| | propyl isobutyrate | FL/FR |
| | sorbyl butyrate | FL/FR |
| | valerian rhizome absolute | FL/FR |
| fusel |
| | methyl butyrate | FL/FR |
| green |
| iso | butyl methyl ketone | FL/FR |
| | geranic acid | FL/FR |
| | heptanal 2,3-butane diol acetal | FL |
| | heptyl acetate | FL/FR |
| | hexanal (aldehyde C-6) | FL/FR |
| (Z)-3- | hexen-1-yl 2-methyl butyrate | FL/FR |
| (E)-2- | hexen-1-yl butyrate | FL/FR |
| (E)-2- | hexenal | FL/FR |
| | hexyl isovalerate | FL/FR |
| 3-(5- | methyl-2-furyl) butanal | FL |
| herbal |
| iso | amyl heptanoate | FL/FR |
| | rue oil | FL/FR |
| | rue oil cuba | FL/FR |
| ketonic |
| 3- | heptanone | FL/FR |
| lactonic |
| gamma- | octalactone | FL/FR |
| meaty |
| 2- | methyl 3-(methyl thio) furan | FL |
| 12- | methyl tridecanal | FL |
| milky |
| malted | milk flavor | FL |
| musty |
| S-( | methyl thio) butyrate | FL/FR |
| nutty |
| | nutty quinoxaline | FL/FR |
| oily |
| 2- | methyl hexanoic acid | FL/FR |
| | petal pyranone | FL/FR |
| phenolic |
| | phenyl pyruvic acid | FL/FR |
| soapy |
| | decanoic acid | FL/FR |
| | octanoic acid | FL/FR |
| sour |
| | acetic acid | FL |
| | butyric acid | FL/FR |
| 2,4- | dimethyl-2-pentenoic acid | FL |
| 3- | methyl valeric acid | FL |
| 2- | methyl-2-pentenoic acid | FL/FR |
| spicy |
| | cumin seed oil | FL/FR |
| sulfurous |
| | ethyl methyl mercaptopropionate | FL/FR |
| | methyl 4-(methyl thio) butyrate | FL |
| sweet |
| | cyclohexyl acetic acid | FL/FR |
| toasted |
| | acetyl propionyl | FL/FR |
| waxy |
| 9- | decenoic acid | FL/FR |
| | heptanoic acid | FL/FR |
| 2- | methyl heptanoic acid | FL/FR |
| 2- | nonanol | FL/FR |
| | phenethyl hexanoate | FL/FR |
| | propyl heptanoate | FL/FR |
| delta- | tetradecalactone | FL/FR |
| | undecanoic acid | FL/FR |
| |
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | butane carboxylic acid | | 1- | butane carboxylic acid | | | butane-1-carboxylic acid | | | butanecarboxylic acid | | 1- | butanecarboxylic acid | | | kyselina valerova | | | LEA | | | pentanic acid | | | pentanoic acid | | 1- | pentanoic acid | | N- | pentanoic acid | | | pentoic acid | | | propyl acetic acid | | | propylacetic acid | | | valerianic acid | | | valeriansaeure | | N- | valeric acid | | | valeric acid FCC | | | valeric acid, natural | | | valericacid |
Articles:
|