maraniol
2H-1-benzopyran-2-one, 7-ethoxy-4-methyl-
 
Notes:
Used in nut food flavouring
  • BOC Sciences
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      Product(s):
      87-05-8 7-ethoxy-4-Methylcoumarin ≥98%
      7-ethoxy-4-Methylcoumarin is a fluorophore used to monitor functional activity
       
       
  • Endeavour Specialty Chemicals
    • Endeavour Specialty Chemicals Ltd
      Expertise in high impact aroma chemicals
      Endeavour Speciality Chemicals offers high-impact aroma chemicals, at small to medium scale.
      Speciality Chemical has more than 25 years experience of manufacturing high-impact aroma chemicals. With our core expertise in sulfur and heterocyclic chemistries, Endeavours products have applications in a range of industry sectors including flavours and fragrances, pharmaceutical research and material sciences. Endeavour also offer custom synthesis and contract manufacturing services at their UK manufacturing site.
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      Product(s):
      ET0020 7-Ethoxy-4-methylcoumarin 99% F&F
       
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      Product(s):
      13-40950 4-METHYL-7-ETHOXYCOUMARIN
       
  • Robinson Brothers
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      Product(s):
      E0491 7-Ethoxy-4-methylcoumarin >97.0%(GC)
       
  • R C Treatt & Co Ltd
    • R C Treatt and Co Ltd
      Innovative ingredient solutions
      World-leading innovative ingredient solutions provider for the flavour, fragrance and FMCG industries.
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      Product(s):
      7-Ethoxy-4-methylcoumarin
       
Synonyms   Articles   Notes   Search
CAS Number: 87-05-8Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 201-721-5
FDA UNII: ZLV1S0NNZH
Nikkaji Web: J192.643H
Beilstein Number: 0169998
MDL: MFCD00016971
CoE Number: 11870
XlogP3: 2.60 (est)
Molecular Weight: 204.22524000
Formula: C12 H12 O3
BioActivity Summary: listing
NMR Predictor: Predict (works with chrome or firefox)
Category: information only not used for fragrances or flavors
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
PubMed: Search
NCBI: Search
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Physical Properties:
Appearance: colorless crystals (est)
Assay: 98.00 to 100.00 % 
Food Chemicals Codex Listed: No
Melting Point: 114.00 to  116.00 °C. @ 760.00 mm Hg
Boiling Point: 350.00 to  352.00 °C. @ 760.00 mm Hg
Congealing Point: 113.00 °C.
Vapor Pressure: 0.000041 mmHg @ 25.00 °C. (est)
Flash Point: 295.00 °F. TCC ( 146.11 °C. )
logP (o/w): 2.973 (est)
Soluble in:
 alcohol
 water, 235.2 mg/L @ 25 °C (est)
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Organoleptic Properties:
 
Odor Type: nutty
 
 nutty  walnut  
Odor Description:
at 100.00 %. 
nutty walnut
 
Odor and/or flavor descriptions from others (if found).
 
 
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Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: not used anymore
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Suppliers:
BOC Sciences
For experimental / research use only.
7-ethoxy-4-Methylcoumarin ≥98%
Odor: characteristic
Use: 7-ethoxy-4-Methylcoumarin is a fluorophore used to monitor functional activity
Endeavour Specialty Chemicals
7-Ethoxy-4-methylcoumarin 99% F&F
Speciality Chemical Product Groups
ExtraSynthese
For experimental / research use only.
4-Methyl-7-ethoxycoumarin (GC) ≥99%
Penta International
4-METHYL-7-ETHOXYCOUMARIN
R C Treatt & Co Ltd
7-Ethoxy-4-methylcoumarin
Robinson Brothers
7-Ethoxy-4-methylcoumarin F&F
https://www.robinsonbrothers.uk/chemistry-competences
Santa Cruz Biotechnology
For experimental / research use only.
7-Ethoxy-4-methylcoumarin ≥95%
Sigma-Aldrich: Aldrich
For experimental / research use only.
7-Ethoxy-4-methylcoumarin 98%
TCI AMERICA
For experimental / research use only.
7-Ethoxy-4-methylcoumarin >97.0%(GC)
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Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
None - None found.
S 02 - Keep out of the reach of children.
S 20/21 - When using do not eat, drink or smoke.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 - Wear suitable gloves and eye/face protection.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: information only not used for fragrances or flavors
IFRA Critical Effect: Photosensitization
IFRA: View Standard
Recommendation for maraniol usage levels up to:
 PROHIBITED: Should not be used as a fragrance ingredient.
 
Recommendation for maraniol flavor usage levels up to:
 not for flavor use.
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Safety References:
EPI System: View
AIDS Citations: Search
Cancer Citations: Search
Toxicology Citations: Search
EPA Substance Registry Services (TSCA): 87-05-8
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 66595
National Institute of Allergy and Infectious Diseases: Data
SCCNFP: opinion
WGK Germany: 3
 7-ethoxy-4-methylchromen-2-one
Chemidplus: 0000087058
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References:
 7-ethoxy-4-methylchromen-2-one
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 87-05-8
Pubchem (cid): 66595
Pubchem (sid): 135025586
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Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
CHEMBL: View
HMDB (The Human Metabolome Database): HMDB35095
FooDB: FDB013724
Export Tariff Code: 2932.20.4500
VCF-Online: VCF Volatile Compounds in Food
ChemSpider: View
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Potential Blenders and core components note
 
For Odor
No odor group found for these
 sulfuryl octanoateFL/FR
 sulfuryl butyrateFL/FR
 sulfuryl decanoateFL/FR
 sulfuryl hexanoateFL/FR
 sulfuryl isobutyrateFL/FR
 sulfuryl propionateFL/FR
 valeraldehyde dibutyl acetalFL/FR
 valeraldehyde propylene glycol acetalFL/FR
balsamic
 propyl benzoateFL/FR
bready
 coffee furanoneFL/FR
buttery
 acetyl propionylFL/FR
3,4-hexane dioneFL/FR
camphoreous
 bornyl isobutyrateFL/FR
 butyrophenoneFL/FR
caramellic
 ethyl 2-hydroxy-2-methyl butyrateFL/FR
chocolate
 chocolate pyrazine AFL/FR
2,5-dimethyl pyrazineFL/FR
2-methoxypyrazineFL/FR
cocoa
2-methyl butyraldehydeFL/FR
coconut
alpha-angelica lactoneFL/FR
gamma-heptalactoneFL/FR
 popcorn pyrimidineFL/FR
coumarinic
 coumaneFL/FR
 tonka bean resinoidFR
earthy
2-ethyl-3-methoxypyrazineFL/FR
ethereal
 acetalFL/FR
fatty
 coconut absoluteFL/FR
(Z)-2-octenal 
fermented
 valeraldehydeFL/FR
floral
 boronia butenalFR
para-cresyl laurateFL/FR
ortho-methyl acetophenoneFL/FR
2-phenyl propionaldehyde dimethyl acetalFL/FR
fruity
 allyl 2-ethyl butyrateFL/FR
isoamyl nonanoateFL/FR
 methyl valerateFL/FR
3-methyl-2-butenalFL/FR
 tropical thiazoleFL/FR
2-heptyl furanFL/FR
(E,Z)-2,6-nonadien-1-yl acetateFL/FR
 tiglaldehydeFL/FR
herbal
 saffron pyranoneFR
musty
2-acetyl pyrroleFL/FR
3-acetyl-2,5-dimethyl furanFL/FR
 hazelnut pyrazineFL/FR
 menthofuranFL/FR
naphthyl
ortho-methyl anisoleFL/FR
para-methyl anisoleFL/FR
nutty
3-acetyl pyridineFL/FR
2-acetyl-3-ethyl pyrazineFL/FR
2-acetyl-3-methyl pyrazineFL/FR
2-acetyl-3,5-dimethyl pyrazineFL/FR
2-acetyl-5-methyl furanFL/FR
3,6-cocoa pyrazineFL/FR
3,5-cocoa pyrazineFL/FR
2,3-dimethyl pyrazineFL/FR
4,5-dimethyl-2-ethyl-3-thiazolineFL/FR
2-ethyl pyrazineFL/FR
2-ethyl-4-methyl thiazoleFL/FR
 filbert heptenoneFL/FR
 filbert pyrazineFL/FR
2,6-lutidineFL/FR
2-methyl pyrazineFL/FR
5-methyl quinoxalineFL/FR
2-methyl thio-3,5 or 6-methyl pyrazineFL/FR
2-methyl-3-(methyl thio) pyrazineFL/FR
2-methyl-3-ethoxypyrazineFL/FR
2-methyl-3-propyl pyrazineFL/FR
 nutty cyclohexenoneFL/FR
 nutty quinoxalineFL/FR
ortho-salicylic acidCS
 shoyu pyrazineFL/FR
2,3,5,6-tetramethyl pyrazineFL/FR
2,4,5-trimethyl oxazoleFL/FR
2,3,5-trimethyl pyrazineFL/FR
 vinyl sulfurolFL/FR
popcorn
2-acetyl pyrazineFL/FR
2-acetyl thiazoleFL/FR
roasted
2-acetyl-2-pyrroline 
spicy
3-(2-furyl) acroleinFL/FR
sulfurous
 benzothiazoleFL/FR
 furfuryl thioacetateFL/FR
tobacco
 veltonal (Bedoukian)FR
tonka
 coumarinFR
 tonka bean absoluteFR
 whiskey lactoneFL/FR
woody
 sandalwood oilFL/FR
 
For Flavor
 
No flavor group found for these
 acetyl acetaldehyde dimethyl acetalFL
2-acetyl-2-pyrroline 
 bornyl isobutyrateFL/FR
 butyramideFL
 butyrophenoneFL/FR
 chocolate pyrazine AFL/FR
 chocolate pyrazine BFL
 coumaneFL/FR
 cyclohexyl methyl pyrazineFL
2,5-diethyl thiazoleFL
2,5-diethyl-4-methyl thiazoleFL
6,7-dihydro-2,3-dimethyl-5H-cyclopentapyrazineFL
 dimethyl dihydrocyclopentapyrazineFL
2,5-dimethyl thiazoleFL
 ethyl 2-hydroxy-2-methyl butyrateFL/FR
2-ethyl-3-methoxypyrazineFL/FR
(Z+E)-5-ethyl-4-methyl-2-(2-butyl) thiazolineFL
(Z+E)-5-ethyl-4-methyl-2-(2-methyl propyl) thiazolineFL
3-(2-furyl) acroleinFL/FR
(E,E)-2,4-heptadien-1-olFL
2-hexyl-5 or 6-keto-1,4-dioxaneFL
2-methoxypyrazineFL/FR
 methyl 2-(methyl thio) acetateFL
2-methyl-3-(methyl thio) pyrazineFL/FR
2-methyl-3-ethoxypyrazineFL/FR
(Z)-2-octenal 
 peanut dithiazineFL
2-propyl pyridineFL
 pyrroleFL
para-salicylic acidFL
 sulfuryl butyrateFL/FR
 sulfuryl decanoateFL/FR
 sulfuryl hexanoateFL/FR
 sulfuryl isobutyrateFL/FR
 thiazoleFL
 valeraldehyde propylene glycol acetalFL/FR
5-acetyl-2,3-dihydro-1,4-thiazineFL
 sulfuryl formateFL
 sulfuryl octanoateFL/FR
 sulfuryl propionateFL/FR
 valeraldehyde dibutyl acetalFL/FR
alliaceous
2-methyl thioacetaldehydeFL
 tropical thiazoleFL/FR
anisic
ortho-methyl acetophenoneFL/FR
bready
2-propionyl thiazoleFL
burnt
2-methyl quinoxalineFL
2,4,5-trimethyl oxazoleFL/FR
buttery
 butyroinFL
3,4-hexane dioneFL/FR
camphoreous
ortho-methyl anisoleFL/FR
coffee
 difurfuryl etherFL
2-ethyl-4-methyl thiazoleFL/FR
2-isopropyl pyrazineFL
corn chip
2-acetyl thiazoleFL/FR
2-acetyl-2-thiazolineFL
 popcorn pyrimidineFL/FR
creamy
alpha-angelica lactoneFL/FR
earthy
2-methyl-3-propyl pyrazineFL/FR
ethereal
 allyl 2-ethyl butyrateFL/FR
fatty
 coconut absoluteFL/FR
(E,E)-2,4-decadienalFL
2-heptyl furanFL/FR
(E,E)-2,4-nonadienalFL
fishy
4,5-dimethyl thiazoleFL
fruity
2,4-hexadien-1-olFL
 methyl valerateFL/FR
3-methyl-2-butenalFL/FR
2-phenyl propionaldehyde dimethyl acetalFL/FR
 propyl benzoateFL/FR
 tiglaldehydeFL/FR
fusel
2-methyl butyraldehydeFL/FR
green
 dihydroxyacetophenone (mixed isomers)FL
2,5-dimethyl thiopheneFL
4-methyl thiazoleFL
2-methyl-5-isopropyl pyrazineFL
(E,Z)-2,6-nonadien-1-yl acetateFL/FR
2-vinyl pyrazineFL
lactonic
gamma-heptalactoneFL/FR
meaty
 benzothiazoleFL/FR
musty
2,5-dimethyl pyrazineFL/FR
2-ethoxythiazoleFL
 hazelnut pyrazineFL/FR
 menthofuranFL/FR
 propionaldehydeFL
 shoyu pyrazineFL/FR
2,3,5-trimethyl pyrazineFL/FR
naphthyl
para-methyl anisoleFL/FR
nutty
 acetalFL/FR
3-acetyl pyridineFL/FR
2-acetyl pyrroleFL/FR
3-acetyl-2,5-dimethyl furanFL/FR
2-acetyl-3-ethyl pyrazineFL/FR
2-acetyl-3-methyl pyrazineFL/FR
2-acetyl-3,5-dimethyl pyrazineFL/FR
2-acetyl-5-methyl furanFL/FR
 aconitic acidFL
3,5-cocoa pyrazineFL/FR
3,6-cocoa pyrazineFL/FR
 coffee furanoneFL/FR
3,5-diethyl-2-methyl pyrazineFL
2,5-diethyl-3-methyl pyrazineFL
2,3-dimethyl pyrazineFL/FR
4,5-dimethyl-2-ethyl-3-thiazolineFL/FR
2,4-dimethyl-5-vinyl thiazoleFL
2-ethyl pyrazineFL/FR
1-ethyl-2-acetyl pyrroleFL
 filbert heptenoneFL/FR
 filbert pyrazineFL/FR
european hazelnut oleoresinFL
2,6-lutidineFL/FR
2-methyl pyrazineFL/FR
5-methyl quinoxalineFL/FR
2-methyl thio-3,5 or 6-methyl pyrazineFL/FR
 nutty cyclohexenoneFL/FR
 nutty quinoxalineFL/FR
 nutty thiazoleFL
 peanut oxazoleFL
2,3,5,6-tetramethyl pyrazineFL/FR
 vinyl sulfurolFL/FR
popcorn
2-propionyl-2-thiazolineFL
roasted
2-acetyl pyrazineFL/FR
 furfuryl thioacetateFL/FR
toasted
 acetyl propionylFL/FR
waxy
para-cresyl laurateFL/FR
winey
isoamyl nonanoateFL/FR
5-ethyl-2-methyl pyridineFL
 valeraldehydeFL/FR
 sandalwood oilFL/FR
 whiskey lactoneFL/FR
 
Synonyms   Articles   Notes   Search   Top
Potential Uses:
 chypreFR
 fernFR
 walnutFL
Synonyms   Articles   Notes   Search   Top
Occurrence (nature, food, other): note
 found in nature
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Synonyms:
2H-1-benzopyran-2-one, 7-ethoxy-4-methyl-
 coumarin, 7-ethoxy-4-methyl-
7-ethoxy-4-methyl chromen-2-one
7-ethoxy-4-methyl coumarin
7-ethoxy-4-methyl-2-oxo-2H-chromene
7-ethoxy-4-methyl-2H-1-benzopyran-2-one
7-ethoxy-4-methyl-2H-chromen-2-one
7-ethoxy-4-methylchromen-2-one
7-ethoxy-4-methylcoumarin
 ethyl 4-methylumbelliferyl ether
 maraniol
4-methyl-7-ethoxycoumarin
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