sulfuryl formate
2-(5-methyl-1,3-thiazol-4-yl)ethyl formate
 
Notes:
Used as a food additive [EAFUS]
  • BOC Sciences
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      Product(s):
      90731-56-9 4-Methyl-5-thiazolylethyl formate
       
  • DeLong Chemicals America
    • DeLong Chemicals America
      Custom Manufacturing
      Supplier of aroma chemicals, pharmaceutical and specialty chemical intermediates.
      DeLong Chemicals America, LLC is an extension of Shijiazhuang Lida Chemical Co, Ltd to North America, a leading supplier and manufacturer of aroma chemicals, serving the industries of food, tobacco and perfume, while also providing intermediates, custom synthesis and custom manufacturing for pharmaceutical and specialty chemical industries.
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      Product(s):
      1106 2-(5-Methyl-1,3-thiazol-4-yl)ethyl formate, Kosher
       
  • Glentham Life Sciences
  • Penta International
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      For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes.
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      19-87085 SULFURYL FORMATE
       
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CAS Number: 90731-56-9Picture of molecule3D/inchi
FDA UNII: 64NY5Q2QR9
Nikkaji Web: J24.664F
Molecular Weight: 171.21913000
Formula: C7 H9 O2 N S
NMR Predictor: Predict (works with chrome or firefox)
Category: flavoring agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
JECFA Food Flavoring: 1751  2-(5-methyl-4-thiazolyl)ethyl formate
FEMA Number: 4275 2-(5-methyl-1,3-thiazol-4-yl)ethyl formate
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF):90731-56-9 ; 2-(4-METHYL-5-THIAZOLYL)ETHYL FORMATE
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Physical Properties:
Appearance: colorless to yellow clear liquid (est)
Assay: 95.00 to 100.00 % 
Food Chemicals Codex Listed: No
Specific Gravity: 1.21500 to 1.22100 @  25.00 °C.
Pounds per Gallon - (est).: 10.110 to 10.160
Refractive Index: 1.51800 to 1.52400 @  20.00 °C.
Boiling Point: 155.00 to  156.00 °C. @ 760.00 mm Hg
Acid Value: 2.00 max. KOH/g
Vapor Pressure: 0.003000 mmHg @ 25.00 °C. (est)
Flash Point: 256.00 °F. TCC ( 124.44 °C. )
logP (o/w): 0.615 (est)
Soluble in:
 alcohol
 water, slightly
 water, 2758 mg/L @ 25 °C (est)
Insoluble in:
 water
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Organoleptic Properties:
Odor Strength: high ,
recommend smelling in a 0.10 % solution or less
 
Odor Description:
at 0.10 % in propylene glycol. 
nutty brown
 
Odor and/or flavor descriptions from others (if found).
 
 
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Cosmetic Information:
None found
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Suppliers:
BOC Sciences
For experimental / research use only.
4-Methyl-5-thiazolylethyl formate
DeLong Chemicals America
2-(5-Methyl-1,3-thiazol-4-yl)ethyl formate, Kosher
Glentham Life Sciences
4-Methyl-5-thiazolylethyl formate
Inoue Perfumery
SULFURYL FORMATE
Penta International
SULFURYL FORMATE
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Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: flavoring agents
Recommendation for sulfuryl formate usage levels up to:
 not for fragrance use.
 
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 23
Click here to view publication 23
 average usual ppmaverage maximum ppm
baked goods: --
beverages(nonalcoholic): 0.100000.25000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: 0.100000.15000
fruit ices: --
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: --
imitation dairy: 0.100000.15000
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: 0.100000.15000
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
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Safety References:
EPI System: View
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 12833143
National Institute of Allergy and Infectious Diseases: Data
 2-(5-methyl-1,3-thiazol-4-yl)ethyl formate
Chemidplus: 0090731569
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References:
 2-(5-methyl-1,3-thiazol-4-yl)ethyl formate
NIST Chemistry WebBook: Search Inchi
Pubchem (cid): 12833143
Pubchem (sid): 135287801
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Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS): View
HMDB (The Human Metabolome Database): HMDB32420
FooDB: FDB009863
ChemSpider: View
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Potential Blenders and core components note
 
For Odor
No odor group found for these
 sulfuryl octanoateFL/FR
 sulfuryl butyrateFL/FR
 sulfuryl decanoateFL/FR
 sulfuryl hexanoateFL/FR
 sulfuryl isobutyrateFL/FR
 sulfuryl propionateFL/FR
green
2-heptyl furanFL/FR
nutty
2-acetyl-3-methyl pyrazineFL/FR
3,6-cocoa pyrazineFL/FR
 filbert heptenoneFL/FR
 nutty quinoxalineFL/FR
roasted
2-acetyl-2-pyrroline 
sulfurous
 furfuryl thioacetateFL/FR
 
For Flavor
 
No flavor group found for these
2-acetyl-2-pyrroline 
6,7-dihydro-2,3-dimethyl-5H-cyclopentapyrazineFL
 dimethyl dihydrocyclopentapyrazineFL
2,5-dimethyl thiazoleFL
 sulfuryl butyrateFL/FR
 sulfuryl decanoateFL/FR
 sulfuryl hexanoateFL/FR
 sulfuryl isobutyrateFL/FR
 sulfuryl octanoateFL/FR
 sulfuryl propionateFL/FR
fatty
2-heptyl furanFL/FR
fishy
4,5-dimethyl thiazoleFL
nutty
2-acetyl-3-methyl pyrazineFL/FR
3,6-cocoa pyrazineFL/FR
 filbert heptenoneFL/FR
 nutty quinoxalineFL/FR
popcorn
2-propionyl-2-thiazolineFL
roasted
 furfuryl thioacetateFL/FR
 
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Potential Uses:
None Found
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Occurrence (nature, food, other): note
 not found in nature
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Synonyms:
2-(5-methyl-1,3-thiazol-4-yl)ethyl formate
2-(5-methyl-4-thiazolyl)ethyl formate
2-(4-methyl-5-thiazolyl) ethyl formate
2-(4-methyl-5-thiazolyl)ethyl formate
5-thiazoleethanol, 4-methyl-, 5-formate
5-thiazoleethanol, 4-methyl-, formate
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Articles:
 None found yet.
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