6-hydroxydihydrotheaspirane (mixture of isomers)
6-hydroxy-2,6,10,10-tetramethyl-1-oxaspiro[4.5]decane (mixture of isomers)
 
Notes:
None found
  • Penta International
    • Penta International Corporation
      Chemistry innovation
      At Penta, our products and services help businesses do business better.
      For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes.
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      Product(s):
      08-61850 6-HYDROXYDIHYDROTHEASPIRANE, Kosher
       
  • Synerzine
    • Synerzine, Inc.
      Innovation. Customization. Aroma Ingredients.
      Synerzine is a leading supplier of flavor and fragrance ingredients.
      Synerzine expresses what we have grown to embody as an organization - the synergy and connection between raw ingredients, science, technology, and the final product. Our experienced team is passionate about bringing our customers high-quality innovative ingredients that they can trust.
      Building upon our 44 year history, the Synerzine team provides customers around the globe with convenient access to over 1200 high-quality aroma ingredients. We actively engage with customers to add a wide array of new products and services on a regular basis. Our aim is to delight every customer with our exceptional services, large product selection, customization and the highest quality and safety standards. We provide our customers with true value designed to help them bring their products to market faster.
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      Product(s):
      W08210 6-Hydroxydihydrotheaspirane
       
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CAS Number: 65620-50-0Picture of molecule3D/inchi
Nikkaji Web: J1.539.233I
MDL: MFCD00238525
CoE Number: 11917
XlogP3-AA: 2.50 (est)
Molecular Weight: 212.33268000
Formula: C13 H24 O2
NMR Predictor: Predict (works with chrome or firefox)
EFSA/JECFA Comments: (EFFA, 2006k). 46-53 % trans isomer (CASrn 65620-50-0), 44-51 % cis isomer (CASrn 57967-68-7) , 0-2 % Isospiranol (CASrn 54344-69-3) Specifications (EFFA, 2006; EFFA. 2010). 46-53% trans isomer (CASrn 65620-50-0), 44-51% cis isomer (CASrn 57967-68-7) , 0-2% Isospiranol (CASrn 54344-69-3).
Category: flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
PubMed: Search
NCBI: Search
JECFA Food Flavoring: 1648  6-hydroxydihydrotheaspirane
FLAVIS Number: 13.076 (Old)
DG SANTE Food Flavourings: 13.076  6-hydroxydihydrotheaspirane
FEMA Number: 3549  6-hydroxydihydrotheaspirane
FDA:No longer provide for the use of these seven synthetic flavoring substances
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Physical Properties:
Appearance: colorless clear liquid (est)
Assay: 97.00 to 100.00 % sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity: 0.99900 to 1.00500 @  25.00 °C.
Pounds per Gallon - (est).: 8.313 to  8.363
Refractive Index: 1.48100 to 1.48700 @  20.00 °C.
Boiling Point: 272.00 to  274.00 °C. @ 760.00 mm Hg
Vapor Pressure: 0.003000 mm/Hg @ 25.00 °C. (est)
Flash Point: > 230.00 °F. TCC ( > 110.00 °C. )
logP (o/w): 2.832 (est)
Soluble in:
 alcohol
 water, very slightly
 water, 161 mg/L @ 25 °C (est)
Insoluble in:
 water
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Organoleptic Properties:
 
Odor Type: herbal
 
Odor Strength: medium ,
recommend smelling in a 10.00 % solution or less
 
 camphoreous  pine  woody  earthy  green  woody  
Odor Description:
at 10.00 % in dipropylene glycol. 
camphor pine woody earthy green woody
 
 camphoreous  pine  earthy  green  cooling  woody  
Odor Description:
Camphoreous, piney, earthy, green, cooling and woody
Mosciano, Gerard P&F 20, No. 4, 23, (1995)
 
 
Flavor Type: camphoreous
 
 camphoreous  woody  green  cooling  minty  earthy  tropical  
Taste Description:
at 20.00 ppm.  
Camphoreous, woody, green, cooling and minty with a fenchyl and tropical nuance
Mosciano, Gerard P&F 20, No. 4, 23, (1995)
 
Odor and/or flavor descriptions from others (if found).
 
 
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Cosmetic Information:
None found
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Suppliers:
BOC Sciences
For experimental / research use only.
6-Hydroxydihydrotheaspirane
Parchem
6-hydroxydihydrotheaspirane
Penta International
6-HYDROXYDIHYDROTHEASPIRANE, Kosher
Synerzine
6-Hydroxydihydrotheaspirane
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Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: flavor and fragrance agents
Recommendation for 6-hydroxydihydrotheaspirane (mixture of isomers) usage levels up to:
  0.5000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.12 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 0.05 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI): 6700 (μg/person/day)
Threshold of Concern:540 (μg/person/day)
Structure Class: II
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 11
Click here to view publication 11
 average usual ppmaverage maximum ppm
baked goods: --
beverages(nonalcoholic): -0.05000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -0.20000
fruit ices: --
gelatins / puddings: -0.20000
granulated sugar: --
gravies: --
hard candy: --
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: -0.20000
soups: --
sugar substitutes: --
sweet sauces: --
 
Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i).
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm.
 average usage mg/kgmaximum usage mg/kg
Dairy products, excluding products of category 02.0 (01.0): 1.0000010.00000
Fats and oils, and fat emulsions (type water-in-oil) (02.0): --
Edible ices, including sherbet and sorbet (03.0): 1.000005.00000
Processed fruit (04.1): --
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): --
Confectionery (05.0): 100.000001000.00000
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): 2.000004.00000
Bakery wares (07.0): 4.000006.00000
Meat and meat products, including poultry and game (08.0): 1.000002.00000
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): 1.000002.00000
Eggs and egg products (10.0): --
Sweeteners, including honey (11.0): --
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): 1.000002.00000
Foodstuffs intended for particular nutritional uses (13.0): --
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): 10.0000050.00000
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): 10.0000050.00000
Ready-to-eat savouries (15.0): 1.000005.00000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): --
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Safety References:
European Food Safety Athority(efsa): Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
European Food Safety Authority (EFSA) reference(s):
Scientific Opinion on Flavouring Group Evaluation 90 (FGE.90): Consideration of Aliphatic, acyclic and alicyclic terpenoid tertiary alcohols and structurally related substances evaluated by JECFA (68th meeting)FGE.18Rev1 (2009)
View page or View pdf
Statement on List of Representative Substances for Testing. The current Statement lays down a list of substances in sub-groups with representative substances for which additional data are required prior to their evaluation through the Procedure (Regulation (EC) No 1565/2000).
View page or View pdf
Scientific Opinion on Flavouring Group Evaluation 90, Revision 1 (FGE.90Rev1): consideration of six substances evaluated by JECFA (68th meeting) structurally related to aliphatic, alicyclic and aromatic saturated and unsaturated tertiary alcohols, aromatic tertiary alcohols and their esters evaluated by EFSA in FGE.18Rev1 and FGE.75Rev1
View page or View pdf
EPI System: View
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 65428
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 3
 2,6,6,10-tetramethyl-1-oxaspiro[4.5]decan-6-ol
Chemidplus: 0053398906
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References:
 2,6,6,10-tetramethyl-1-oxaspiro[4.5]decan-6-ol
NIST Chemistry WebBook: Search Inchi
Pubchem (cid): 65428
Pubchem (sid): 135022194
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Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
HMDB (The Human Metabolome Database): Search
FooDB: FDB017063
VCF-Online: VCF Volatile Compounds in Food
ChemSpider: View
Wikipedia: View
RSC Learn Chemistry: View
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Potential Blenders and core components note
 
For Odor
No odor group found for these
3-benzoyl pyridine 
 vinyl (4-methyl-thiazolyl-2) carbinol 
 octanal propylene glycol acetalFL/FR
alliaceous
 ferula assa-foetida gum oilFL/FR
balsamic
dextro-borneolFL/FR
laevo-borneolFL/FR
isobornyl acetateFL/FR
 bornyl acetateFL/FR
 bornyl formateFL/FR
isobornyl propionateFL/FR
dextro-fenchoneFL/FR
 fir needle oil siberiaFL/FR
 valerian rhizome absoluteFL/FR
camphoreous
 bornyl ethyl ether 
beta-homocyclocitralFL/FR
 fencholFL/FR
laevo-fenchoneFL/FR
 hinoki leaf oilFR
caramellic
2-isobutyl-3-methyl pyrazineFL/FR
citrus
(E+Z)-4,8-dimethyl-3,7-nonadien-2-yl acetateFL/FR
alpha-methylene citronellalFR
 neroli ketoneFR
 ocimene quintoxideFL/FR
coconut
delta-heptalactoneFL/FR
earthy
5-cyclopropyl-3(or 2),4-dimethyl octahydro-4,7-methanoinden-5-ol 
5-ethyl-3(or 2),4-dimethyl octahydro-4,7-methanoinden-5-ol 
(-)-alpha-fencholFL/FR
1-nonen-3-olFL/FR
1-octen-3-olFL/FR
ethereal
 cyclohexyl formateFL/FR
fatty
 allyl octanoateFL/FR
floral
 cyclohexyl ethyl alcoholFL/FR
alpha-damasconeFL/FR
 dihydrocarvyl acetateFL/FR
 geranium dihydropyranFR
 linalool oxideFL/FR
beta-ocimeneFL/FR
 octyl acetateFL/FR
 orange leaf absoluteFL/FR
2-phenyl propyl acetateFL/FR
 rose butanoateFL/FR
(R)-styralyl alcoholFL/FR
 ylang ylang flower oil IIIFL/FR
fruity
 amyl formateFL/FR
 apple ketalFL/FR
(E)-beta-damasconeFL/FR
(E)-alpha-damasconeFL/FR
 decen-1-yl cyclopentanoneFL/FR
(Z)-3-octen-1-olFL/FR
2-pentyl furanFL/FR
 propyl hexanoateFL/FR
 tropical trithianeFL/FR
green
 bergoxaneFR
 bicyclogermacrene 
(R)-2-sec-butyl-3-methoxypyrazine 
(S)-2-sec-butyl-3-methoxypyrazine 
 cumin acetaldehydeFL/FR
isocyclocitral (IFF)FL/FR
3-cyclohexyl propyl butyrate 
alpha,alpha-dimethyl benzyl alcoholFL/FR
alpha-elemolFL/FR
 fern absolute 
 ferula galbaniflua gum extractFL/FR
 fresh nitrileFR
 galbanum oilFL/FR
 galbanum resinoidFL/FR
 galbanum resinoid replacerFR
 geranium absoluteFL/FR
1-heptanolFL/FR
(Z)-3-hepten-1-olFL/FR
 hexanal (aldehyde C-6)FL/FR
(Z)-3-hexen-1-yl acetoacetateFL/FR
(E)-2-hexen-1-yl salicylateFR
(Z)-3-hexen-1-yl tiglateFL/FR
(S)-1-hexen-3-ol 
(R)-1-hexen-3-ol 
 manzanate (Givaudan)FL/FR
para-methyl hydratropaldehydeFL/FR
 octanal dimethyl acetalFL/FR
1-phenyl-2-pentanolFL/FR
 rose furan epoxideFL/FR
 terpinyl propionateFL/FR
3,5,5-trimethyl hexanolFL/FR
2,4,8-trimethyl-5-oxatricyclo(6.2.1.0*2,6*)undecaneFR
1,5-undecadien-4-ol 
 valerian rhizome oil CO2 extract chinaFL/FR
herbal
 bornyl salicylateFR
 camphene carbinyl acetateFR
(+)-alpha-campholenic aldehydeFL/FR
 canarium luzonicum oilFL/FR
1,4-cineoleFL/FR
isodihydrolavandulalFL/FR
 dimethyl cyclormol (IFF)FR
 geranic oxideFL/FR
 hyssop oilFL/FR
 myrtenolFL/FR
 pine hexanolFR
alpha-pineneFL/FR
 pinocarveolFL/FR
 rosemary absoluteFL/FR
 sabinene hydrateFL/FR
 sage oleoresinFL/FR
 theaspiraneFL/FR
 tricyclo(5.2.1.02,6)dec-3-enyl acetateFR
 valerian rhizome oilFL/FR
melon
(Z)-6-nonenalFL/FR
mentholic
 cornmint oil chinaFL/FR
dextro,laevo-mentholFL/FR
(±)-isomenthoneFL/FR
 peppermint cyclohexanoneFL/FR
minty
dextro-dihydrocarvoneFL/FR
trans-para-menthan-2-oneFL/FR
 pennyroyal oil fractionsFL/FR
 peppermint absoluteFL/FR
 peppermint oil americaFL/FR
 peppermint oil idahoFL/FR
isopropyl tiglateFL/FR
isopulegolFL/FR
 spearmint oil americaFL/FR
mossy
 oakmoss absoluteFL/FR
nutty
5-ethyl-4-methyl thiazole 
orris
isoeugenyl formateFL/FR
spicy
 caryophylleneFL/FR
beta-caryophylleneFL/FR
isocyclogeraniol (IFF)FR
 myrtenalFL/FR
2-octanolFL/FR
 mango thiolFL/FR
terpenic
para-menthatriene 
tropical
2-tropical oxathianeFL/FR
waxy
 nonyl acetateFL/FR
 octyl isobutyrateFL/FR
woody
isobornyl isovalerateFL/FR
beta-cadinene 
 campheneFL/FR
(+)-campheneFL/FR
 dihydro-beta-iononeFL/FR
3(or 2),4-dimethyl-5-vinyl octahydro-4,7-methanoinden-5-ol 
5,5a,6,7,8,8a-hexahydro-6,6,7,8,8-pentamethyl-4H-indeno[5,4-D]isoxazole 
6-methoxy-1,6,7-trimethyl octahydro-4,7-methanoindene + 5-methoxy-2,4,5-trimethyl octahydro-4,7-methan 
beta-terpineolFL/FR
 
For Flavor
 
No flavor group found for these
 benzyl disulfideFL
 bicyclogermacrene 
dextro-borneolFL/FR
 bornyl formateFL/FR
(R)-2-sec-butyl-3-methoxypyrazine 
(S)-2-sec-butyl-3-methoxypyrazine 
beta-cadinene 
(+)-campheneFL/FR
3-cyclohexyl propyl butyrate 
5-cyclopropyl-3(or 2),4-dimethyl octahydro-4,7-methanoinden-5-ol 
alpha,alpha-dimethyl benzyl alcoholFL/FR
(E+Z)-4,8-dimethyl-3,7-nonadien-2-yl acetateFL/FR
3(or 2),4-dimethyl-5-vinyl octahydro-4,7-methanoinden-5-ol 
alpha-elemolFL/FR
5-ethyl-3(or 2),4-dimethyl octahydro-4,7-methanoinden-5-ol 
5-ethyl-4-methyl thiazole 
isoeugenyl formateFL/FR
 fern absolute 
(Z)-3-hepten-1-olFL/FR
5,5a,6,7,8,8a-hexahydro-6,6,7,8,8-pentamethyl-4H-indeno[5,4-D]isoxazole 
(Z)-3-hexen-1-yl acetoacetateFL/FR
(R)-1-hexen-3-ol 
(S)-1-hexen-3-ol 
6-methoxy-1,6,7-trimethyl octahydro-4,7-methanoindene + 5-methoxy-2,4,5-trimethyl octahydro-4,7-methan 
 octanal propylene glycol acetalFL/FR
2-phenyl propyl acetateFL/FR
 rose furan epoxideFL/FR
(R)-styralyl alcoholFL/FR
beta-terpineolFL/FR
2-tropical oxathianeFL/FR
1,5-undecadien-4-ol 
alliaceous
 ferula assa-foetida gum oilFL/FR
balsamic
isobornyl propionateFL/FR
 fir needle oil siberiaFL/FR
camphoreous
laevo-borneolFL/FR
 bornyl acetateFL/FR
 bornyl ethyl ether 
 campheneFL/FR
(-)-alpha-fencholFL/FR
 fencholFL/FR
laevo-fenchoneFL/FR
 geranic oxideFL/FR
 pinocarveolFL/FR
cooling
1,4-cineoleFL/FR
beta-homocyclocitralFL/FR
dextro-fenchoneFL/FR
 manzanate (Givaudan)FL/FR
dextro,laevo-mentholFL/FR
 peppermint oil americaFL/FR
 sabinene hydrateFL/FR
 theaspiraneFL/FR
 WS-3FL
creamy
 octyl isobutyrateFL/FR
earthy
1-nonen-3-olFL/FR
fatty
 allyl octanoateFL/FR
(Z)-3-octen-1-olFL/FR
floral
 dihydrocarvyl acetateFL/FR
 orange leaf absoluteFL/FR
 ylang ylang flower oil IIIFL/FR
fruity
 amyl formateFL/FR
 apple ketalFL/FR
alpha-damasconeFL/FR
(E)-alpha-damasconeFL/FR
(E)-beta-damasconeFL/FR
 decen-1-yl cyclopentanoneFL/FR
1-phenyl-2-pentanolFL/FR
 propyl hexanoateFL/FR
 rose butanoateFL/FR
 tropical trithianeFL/FR
 valerian rhizome absoluteFL/FR
 valerian rhizome oilFL/FR
 valerian rhizome oil CO2 extract chinaFL/FR
green
3-benzoyl pyridine 
2-isobutyl-3-methyl pyrazineFL/FR
(+)-alpha-campholenic aldehydeFL/FR
 canarium luzonicum oilFL/FR
 cumin acetaldehydeFL/FR
isocyclocitral (IFF)FL/FR
 cyclohexyl ethyl alcoholFL/FR
 cyclohexyl formateFL/FR
dextro-dihydrocarvoneFL/FR
 ferula galbaniflua gum extractFL/FR
 galbanum oilFL/FR
 galbanum resinoidFL/FR
 geranium absoluteFL/FR
 hexanal (aldehyde C-6)FL/FR
(Z)-3-hexen-1-yl tiglateFL/FR
 horseradish oilFL
 linalool oxideFL/FR
para-methyl hydratropaldehydeFL/FR
(Z)-6-nonenalFL/FR
 oakmoss absoluteFL/FR
beta-ocimeneFL/FR
 ocimene quintoxideFL/FR
 octanal dimethyl acetalFL/FR
2-pentyl furanFL/FR
isophoroneFL
isopropyl tiglateFL/FR
 propylene glycol acetone ketalFL
 terpinyl propionateFL/FR
3,5,5-trimethyl hexanolFL/FR
herbal
isodihydrolavandulalFL/FR
 hyssop oilFL/FR
 rosemary absoluteFL/FR
 sage oleoresinFL/FR
lactonic
delta-heptalactoneFL/FR
mentholic
 peppermint cyclohexanoneFL/FR
minty
 cornmint oil chinaFL/FR
trans-para-menthan-2-oneFL/FR
(±)-isomenthoneFL/FR
 myrtenalFL/FR
 myrtenolFL/FR
 pennyroyal oil fractionsFL/FR
 peppermint absoluteFL/FR
 peppermint oil idahoFL/FR
isopulegolFL/FR
 spearmint oil americaFL/FR
mushroom
1-octen-3-olFL/FR
nutty
 peanut oxazoleFL
solvent
1-heptanolFL/FR
spicy
 caryophylleneFL/FR
beta-caryophylleneFL/FR
2-octanolFL/FR
sulfurous
 mango thiolFL/FR
 methyl 2-(methyl thio) butyrateFL
terpenic
para-menthatriene 
waxy
 nonyl acetateFL/FR
 octyl acetateFL/FR
woody
isobornyl acetateFL/FR
isobornyl isovalerateFL/FR
 dihydro-beta-iononeFL/FR
alpha-pineneFL/FR
 vinyl (4-methyl-thiazolyl-2) carbinol 
 
Synonyms   Articles   Notes   Search   Top
Potential Uses:
 berryFR
 mintFR
 pineFR
 raspberryFR
 spiceFR
 tropicalFL
 woodyFR
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Occurrence (nature, food, other): note
 tea black tea
Search Trop  Picture
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Synonyms:
 herbal spirane
6-hydroxy-2,6,10,10-tetramethyl-1-oxaspiro-4,5-decane (mixture of isomers)
6-hydroxy-2,6,10,10-tetramethyl-1-oxaspiro[4.5]decane (mixture of isomers)
1-oxaspiro(4.5)decan-6-ol, 2,6,10,10-tetramethyl-
1-oxaspiro[4.5]decan-6-ol, 2,6,10,10-tetramethyl-
2,6,10,10-tetramethyl-1-oxaspiro(4.5)decan-6-ol
2,6,10,10-tetramethyl-1-oxaspiro[4.5]decan-6-ol
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