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Category: fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless clear liquid (est) |
| Assay: | 90.00 to 100.00 %
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| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.86800 to 0.87600 @ 20.00 °C.
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| Pounds per Gallon - est.: | 7.231 to 7.298
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| Boiling Point: | 244.31 °C. @ 760.00 mm Hg (est)
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| Vapor Pressure: | 0.031000 mmHg @ 25.00 °C. (est) |
| Flash Point: | 181.00 °F. TCC ( 82.78 °C. )
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| logP (o/w): | 3.345 |
| Shelf Life: | 24.00 month(s) or longer if stored properly. |
| Storage: | store in cool, dry place in tightly sealed containers, protected from heat and light. |
| Soluble in: |
| | alcohol | | | water, 27.56 mg/L @ 25 °C (est) |
| Insoluble in: |
| | water |
Organoleptic Properties:
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| Odor Type: citrus |
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| Odor Strength: | medium |
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| Substantivity: | 6 hour(s) at 100.00 % |
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| | petitgrain bergamot citrus fresh green woody |
Odor Description: at 100.00 %. | petitgrain bergamot citrus fresh green woody Luebke, William tgsc, (1988) |
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| Odor and/or flavor descriptions from others (if found). |
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| IFF |
| Bergamal |
| Odor Description: | Refreshing, aldehydic, lemon, citronella, verbena note with definite bergamot and dry orange moieties |
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| Taytonn ASCC |
| Bergamal |
| Odor Description: | Aldehydic/ Aldehyde, Citronella, Citrus, Floral |
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| Pell Wall Perfumes |
| Bergamal |
| Odor Description: | aldehydic, verbena, bergamot Also known as alpha-methylene citronellal, this IFF product is described by them as: “Refreshing, aldehydic, lemon, citronella, verbena note with definite bergamot and dry orange moieties.” Very useful to enhance bergamot and other citrus notes. |
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| Perfumery Laboratory |
| BERGAMAL IFF |
| Odor Description: | Refreshing, aldehyde, lemon verbena, with a clear note of bergamot |
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Cosmetic Information:
Suppliers:
| Azelis UK |
| BERGAMAL
|
| Creatingperfume.com |
| Bergamal (IFF)
Odor: Petitgrain, bergamot, citrus, fresh, green, woody. Refreshing, aldehydic, lemon, verbena note with definite bergamot and dry orange |
| Ernesto Ventós |
| BERGAMAL IFF
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| IFF |
| Bergamal
Odor: Refreshing, aldehydic, lemon, citronella, verbena note with definite bergamot and dry orange moieties |
| Indukern F&F |
| BERGAMAL
Odor: ALDEHYDIC, FRESH, CITRUS, LEMON |
| Lluch Essence |
| BERGAMAL
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| M&U International |
| Bergamal
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| Pell Wall Perfumes |
| Bergamal
Odor: aldehydic, verbena, bergamot Use: Also known as alpha-methylene citronellal, this IFF product is described by them as: “Refreshing, aldehydic, lemon, citronella, verbena note with definite bergamot and dry orange moieties.” Very useful to enhance bergamot and other citrus notes. |
| Penta International |
| alpha-METHYLENE CITRONELLAL
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| Perfumery Laboratory |
| BERGAMAL IFF
Odor: Refreshing, aldehyde, lemon verbena, with a clear note of bergamot |
| Taytonn ASCC |
| Bergamal
Odor: Aldehydic/ Aldehyde, Citronella, Citrus, Floral |
| The John D. Walsh Company |
| Bergamal
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Safety Information:
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| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
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| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
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Not determined
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| Dermal Toxicity: |
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Not determined
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| Inhalation Toxicity: |
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Not determined
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Safety in Use Information:
| Category: | fragrance agents |
| RIFM Fragrance Material Safety Assessment: Search |
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
| Recommendation for alpha-methylene citronellal usage levels up to: | | | 10.0000 % in the fragrance concentrate.
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| Recommendation for alpha-methylene citronellal flavor usage levels up to: |
| | not for flavor use.
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Safety References:
References:
Other Information:
Potential Blenders and core components note
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| For Odor |
| No odor group found for these |
| | octanal propylene glycol acetal | FL/FR |
| aldehydic |
| | dodecanal (aldehyde C-12 lauric) | FL/FR |
| | green hexanal | FL/FR |
| | undecanal | FL/FR |
| balsamic |
| | betula pubescens bud oil | FL/FR |
| | fir balsam absolute | FR |
| | fir balsam concrete | FR |
| | fir tree fragrance | FR |
| | valerian rhizome absolute | FL/FR |
| citrus |
| | bergamot acetoacetate | FR |
| | bergamot oil bergaptene reduced italy | FL/FR |
| | citral diethyl acetal | FL/FR |
| | citral dimethyl acetal | FL/FR |
| | citronellal oxime | FR |
| (R)- | citronellyl nitrile | FR |
| iso | decyl acetate | FR |
| | dihydromyrcenyl acetate | FR |
| | lime oil distilled terpeneless | FL/FR |
| | lime oil fractions | FR |
| | limonene aldehyde | FR |
| | litsea cubeba fruit oil | FL/FR |
| | methyl heptenone | FL/FR |
| 1- | methyl-4-methyl ethenyl cyclohexene sulfurized | FL/FR |
| | myrcenyl acetate | FL/FR |
| | neroli ketone | FR |
| | petitgrain combava oil | FR |
| | tangerine acetate | FR |
| alpha- | terpinyl methyl ether | FL/FR |
| earthy |
| | octyl phenyl acetate | FL/FR |
| fatty |
| 6- | methyl-5-hepten-2-one propylene glycol acetal | FL/FR |
| floral |
| | bigarade oxide | FR |
| | bois de rose oil brazil | FL/FR |
| | cilantro herb oil egypt | FL/FR |
| | citronellol | FL/FR |
| (S)- | citronellyl acetate | FL/FR |
| | citronellyl anthranilate | FL/FR |
| | citronellyl formate | FL/FR |
| | coranol (Firmenich) | FR |
| | dihydrocitronellyl ethyl ether | FR |
| | dihydrolinalool | FL/FR |
| 3,6- | dimethyl-3-octanol | FL/FR |
| | ethyl ethyl anthranilate | FL/FR |
| | ethyl linalool | FR |
| | ethyl linalyl acetal | FR |
| | ethyl linalyl acetate | FR |
| | ethyl linalyl ether | FL/FR |
| | glycoacetal | FR |
| | ho leaf oil | FR |
| | ho wood oil | FR |
| | karo karounde absolute | FR |
| | leerall | FR |
| | linalool | FL/FR |
| | linalool oxide | FL/FR |
| | linalyl anthranilate | FL/FR |
| | linalyl benzoate | FL/FR |
| | linalyl butyrate | FL/FR |
| | linalyl propionate | FL/FR |
| | melaleuca ericifolia leaf oil | FR |
| (E)- | nerolidol | FL/FR |
| | neryl isovalerate | FL/FR |
| | orange leaf absolute | FL/FR |
| bitter | orangeflower water absolute | FL/FR |
| | petitgrain cedrat oil | FL/FR |
| | terpinyl isobutyrate | FL/FR |
| | tetrahydrolinalool | FL/FR |
| | tetrahydrolinalyl acetate | FR |
| fruity |
| | apple ketal | FL/FR |
| iso | butyl 2-methyl butyrate | FL/FR |
| | butyl anthranilate | FL/FR |
| | cyclohexyl crotonate | FR |
| 2- | cyclopentyl cyclopentanone | FL/FR |
| 1,4- | dibutyl-6,8-dioxabicyclo(3.2.1)octane | FR |
| 1,4- | diisopropyl-6,8-dioxabicyclo(3.2.1)octane | FR |
| (R)-gamma- | dodecalactone | FL/FR |
| | ethyl methyl anthranilate | FL/FR |
| | grapefruit acetal | FR |
| | linalyl isobutyrate | FL/FR |
| | methyl acetoacetate | FL/FR |
| | nerolidyl isobutyrate | FR |
| | ocimen-1-yl acetate | FR |
| green |
| | bergoxane | FR |
| | bicyclogermacrene | |
| | citral / diisotridecyl acetal | FR |
| | citrus carbaldehyde / methyl anthranilate schiff's base | FR |
| alpha- | elemol | FL/FR |
| | fresh nitrile | FR |
| | galbanum oil | FL/FR |
| | galbanum oleoresin | FL/FR |
| | galbanum resinoid | FL/FR |
| | green carboxylate | FR |
| 1- | heptanol | FL/FR |
| (E)-2- | hexen-1-yl salicylate | FR |
| dextro- | limonene oxide | FL/FR |
| para- | methyl hydratropaldehyde | FL/FR |
| | octanal diethyl acetal | FL/FR |
| | octanal dimethyl acetal | FL/FR |
| (E)-2- | octen-1-ol | FL/FR |
| | terpinyl propionate | FL/FR |
| | valerian rhizome oil CO2 extract china | FL/FR |
| herbal |
| | bergamot mint herb oil | FR |
| | bornyl salicylate | FR |
| (+)-alpha- | campholenic aldehyde | FL/FR |
| | canarium luzonicum oil | FL/FR |
| | clary octenone | FR |
| | cuminyl acetate | FL/FR |
| iso | dihydrolavandulal | FL/FR |
| 2- | dodecenal | FL/FR |
| | herbal carene | FR |
| 6- | hydroxydihydrotheaspirane (mixture of isomers) | FL/FR |
| | linalyl acetate | FL/FR |
| | linalyl formate | FL/FR |
| | linalyl isovalerate | FL/FR |
| | nonisyl formate | FR |
| 3- | octyl acetate | FL/FR |
| | petitgrain heptane | FR |
| | terpineol acetate | FL/FR |
| | tricyclo(5.2.1.02,6)dec-3-enyl acetate | FR |
| | valerian rhizome oil | FL/FR |
| | valerian rhizome oil china | FL/FR |
| melon |
| (Z)-6- | nonenal | FL/FR |
| minty |
| (-)-iso | pulegol | FL/FR |
| iso | pulegol | FL/FR |
| 2,4,4,6- | tetramethyl cyclohexa-2,5-diene-1-one | FR |
| mossy |
| | oakmoss absolute | FL/FR |
| orris |
| iso | eugenyl formate | FL/FR |
| pine |
| | pine oil 85 | FR |
| spicy |
| | cubeb oil | FL/FR |
| iso | cyclogeraniol (IFF) | FR |
| 2,5- | dimethyl bicyclo(3.2.1)-2-octen-3-yl acetate + 1,4-dimethyl bicyclo(3.2.1)-2-octen-3-yl acetate | FR |
| 2- | octanol | FL/FR |
| black | pepper oil CO2 extract | FL/FR |
| | zanthoxylum piperitum fruit absolute CO2 extract | FL/FR |
| terpenic |
| | juniper branch oil | FR |
| alpha- | phellandrene | FL/FR |
| waxy |
| | decanal dimethyl acetal | FL/FR |
| woody |
| | bruyere root absolute | FR |
| beta- | cadinene | |
| alpha- | farnesene | FL/FR |
| alpha- | farnesene isomer | FL/FR |
| | frankincense resinoid replacer | FR |
| | humulus lupulus extract | FL/FR |
| | moss naphthaleneol | FR |
| (±)- | tetrahydronootkatone | FL/FR |
| | xanthoxylum alatum roxb. oil | FR |
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| For Flavor |
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| No flavor group found for these |
| | betula pubescens bud oil | FL/FR |
| | bicyclogermacrene | |
| beta- | cadinene | |
| | cuminyl acetate | FL/FR |
| 2- | cyclopentyl cyclopentanone | FL/FR |
| | decanal dimethyl acetal | FL/FR |
| (R)-gamma- | dodecalactone | FL/FR |
| alpha- | elemol | FL/FR |
| | ethyl ethyl anthranilate | FL/FR |
| | ethyl linalyl ether | FL/FR |
| | ethyl methyl anthranilate | FL/FR |
| iso | eugenyl formate | FL/FR |
| | methyl acetoacetate | FL/FR |
| 6- | methyl-5-hepten-2-one propylene glycol acetal | FL/FR |
| | octanal propylene glycol acetal | FL/FR |
| | octyl phenyl acetate | FL/FR |
| | terpineol acetate | FL/FR |
| | terpinyl isobutyrate | FL/FR |
| (±)- | tetrahydronootkatone | FL/FR |
| dextro- | limonene oxide | FL/FR |
| 6- | hydroxydihydrotheaspirane (mixture of isomers) | FL/FR |
| citrus |
| | bergamot oil bergaptene reduced italy | FL/FR |
| | citral diethyl acetal | FL/FR |
| | citral dimethyl acetal | FL/FR |
| | lime oil distilled terpeneless | FL/FR |
| | linalool | FL/FR |
| | litsea cubeba fruit oil | FL/FR |
| 1- | methyl-4-methyl ethenyl cyclohexene sulfurized | FL/FR |
| | myrcenyl acetate | FL/FR |
| | petitgrain cedrat oil | FL/FR |
| fatty |
| 2- | dodecenal | FL/FR |
| (E)-2- | octen-1-ol | FL/FR |
| floral |
| | bois de rose oil brazil | FL/FR |
| | citronellol | FL/FR |
| (S)- | citronellyl acetate | FL/FR |
| | dihydrolinalool | FL/FR |
| | linalyl acetate | FL/FR |
| | linalyl anthranilate | FL/FR |
| | linalyl butyrate | FL/FR |
| | linalyl isobutyrate | FL/FR |
| | orange leaf absolute | FL/FR |
| bitter | orangeflower water absolute | FL/FR |
| | tetrahydrolinalool | FL/FR |
| fruity |
| | apple ketal | FL/FR |
| iso | butyl 2-methyl butyrate | FL/FR |
| | butyl anthranilate | FL/FR |
| | citronellyl anthranilate | FL/FR |
| | citronellyl formate | FL/FR |
| | linalyl benzoate | FL/FR |
| | linalyl isovalerate | FL/FR |
| | neryl isovalerate | FL/FR |
| | valerian rhizome absolute | FL/FR |
| | valerian rhizome oil | FL/FR |
| | valerian rhizome oil china | FL/FR |
| | valerian rhizome oil CO2 extract china | FL/FR |
| green |
| (+)-alpha- | campholenic aldehyde | FL/FR |
| | canarium luzonicum oil | FL/FR |
| alpha- | farnesene | FL/FR |
| alpha- | farnesene isomer | FL/FR |
| | galbanum oil | FL/FR |
| | galbanum oleoresin | FL/FR |
| | galbanum resinoid | FL/FR |
| | linalool oxide | FL/FR |
| | methyl heptenone | FL/FR |
| para- | methyl hydratropaldehyde | FL/FR |
| (E)- | nerolidol | FL/FR |
| (Z)-6- | nonenal | FL/FR |
| | oakmoss absolute | FL/FR |
| | octanal diethyl acetal | FL/FR |
| | octanal dimethyl acetal | FL/FR |
| 3- | octyl acetate | FL/FR |
| | terpinyl propionate | FL/FR |
| herbal |
| | cilantro herb oil egypt | FL/FR |
| iso | dihydrolavandulal | FL/FR |
| 3,6- | dimethyl-3-octanol | FL/FR |
| | green hexanal | FL/FR |
| | linalyl formate | FL/FR |
| | linalyl propionate | FL/FR |
| minty |
| (-)-iso | pulegol | FL/FR |
| iso | pulegol | FL/FR |
| nutty |
| | peanut oxazole | FL |
| soapy |
| | dodecanal (aldehyde C-12 lauric) | FL/FR |
| solvent |
| 1- | heptanol | FL/FR |
| spicy |
| | cubeb oil | FL/FR |
| 2- | octanol | FL/FR |
| black | pepper oil CO2 extract | FL/FR |
| | zanthoxylum piperitum fruit absolute CO2 extract | FL/FR |
| terpenic |
| alpha- | phellandrene | FL/FR |
| waxy |
| | undecanal | FL/FR |
| | humulus lupulus extract | FL/FR |
| alpha- | terpinyl methyl ether | FL/FR |
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Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | bergamal (IFF) | | 3,7- | dimethyl-2-methylene oct-6-enal | | 3,7- | dimethyl-2-methylene octa-6-enal | | 3,7- | dimethyl-2-methylene-6-octen-1-al | | 3,7- | dimethyl-2-methylene-6-octenal | | 3,7- | dimethyl-2-methylene-oct-6-enal | | 3,7- | dimethyl-2-methyleneoct-6-enal | | 3,7- | dimethyl-2-methyleneocta-6-enal | | 3,7- | dimethyl-2-methylideneoct-6-enal | | alpha- | methylene citronellal | | a- | methylenecitronellal | | 6- | octenal, 3,7-dimethyl-2-methylene- |
Articles:
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