(E,Z)-2,6-dodecadienal
2-trans-6-cis-dodecadienal
 
Notes:
Used as a food additive [EAFUS]
  • Bedoukian Research
    • Bedoukian Research, Inc.
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      Product(s):
      341 e,z-2,6-DODECADIEN-1-AL ≥90.0% (trans,cis), Kosher
      SDS
      Powerful. Blends well with citrus and florals to add freshness and watery notes.
      Has application in watermelon, parsley and mushroom flavors.
       
       
  • BOC Sciences
    • BOC Sciences
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      Product(s):
      21662-13-5 (E,Z)-2,6-DODECADIENAL 95.0% (sum of isomers)
       
  • M&U International
    • M&U International LLC
      Steady supply & demand
      Meeting customers increasing demands at home as well as abroad.
      M&U dedicates itself to the development and production of new products as well as continuously promoting those new products. We’ve maintained a steady supply&demand relationship with a large number of manufacturers at home and abroad. We’ve developed an extensive network and because of our relationships with these manufacturers, we’re able to provide a stable supply of great quality materials. We’re located in China’s largest communications hub, Shanghai and in the U.S. near one of the largest sea ports on the East Coast. The strategic locations of our facilities ensure convenient, prompt and secure delivery of our products to our customers.
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      Product(s):
      A0614 E,Z-2,6-Dodecadien-1-al
       
  • Penta International
    • Penta International Corporation
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      For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes.
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      04-87400 TRANS-2-CIS-6-DODECADIENAL
       
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CAS Number: 21662-13-5Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 244-515-0
FDA UNII: 6CPL2532NR
Beilstein Number: 4374899
XlogP3-AA: 3.80 (est)
Molecular Weight: 180.29060000
Formula: C12 H20 O
NMR Predictor: Predict (works with chrome or firefox)
EFSA/JECFA Comments: The chemical name in the UL should be changed to Dodeca-(2E,6Z)-dienal, in accordance with the CAS nr and the most recent speci?cations on stereoisomeric composition (Documentation provided to EFSA nr.10)
Category: flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
PubMed: Search
NCBI: Search
JECFA Food Flavoring: 1197  2-trans-6-cis-dodecadienal
DG SANTE Food Flavourings: 05.120  (E,Z)-2,6-dodecadienal
FEMA Number: 3637 (E,Z)-2,6-dodecadienal
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF):21662-13-5 ; 2-TRANS-6-CIS-DODECADIENAL
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Physical Properties:
Appearance: yellow clear liquid (est)
Assay: 97.50 to 100.00 % sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity: 0.98700 to 0.99300 @  25.00 °C.
Pounds per Gallon - (est).: 8.213 to  8.263
Refractive Index: 1.42500 to 1.43100 @  20.00 °C.
Boiling Point: 130.00 to  131.00 °C. @ 5.00 mm Hg
Boiling Point: 115.00 °C. @ 0.10 mm Hg
Acid Value: 1.50 max. KOH/g
Vapor Pressure: 0.008000 mmHg @ 25.00 °C. (est)
Flash Point: 210.00 °F. TCC ( 98.89 °C. )
logP (o/w): 4.327 (est)
Shelf Life: 36.00 month(s) or longer if stored properly.
Soluble in:
 alcohol
 water, 11.33 mg/L @ 25 °C (est)
Insoluble in:
 water
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Organoleptic Properties:
 
Odor Type: fatty
 
Odor Strength: low ,
recommend smelling in a 10.00 % solution or less
 
 citrus  mandarin  orange  melon  
Odor Description:
at 10.00 % in dipropylene glycol. 
deep citrus mandarin orange melon
 
 fatty  green  aldehydic  spicy  melon  
Odor Description:
Fatty, green, aldehydic with a spice and melon nuance
Mosciano, Gerard P&F 18, No. 3, 53, (1993)
 
 
Flavor Type: green
 
 green  herbal  waxy  aldehydic  
Taste Description:
at 20.00 ppm.  
Green, herbal, waxy and aldehydic
Mosciano, Gerard P&F 18, No. 3, 53, (1993)
 
Odor and/or flavor descriptions from others (if found).
 
Bedoukian Research
e,z-2,6-DODECADIEN-1-AL ≥90.0% (trans,cis), Kosher
Odor Description: A fatty, green, aldehydic character with spice, melon undertones
Powerful. Blends well with citrus and florals to add freshness and watery notes.
Taste Description: green
Has application in watermelon, parsley and mushroom flavors.
 
 
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Cosmetic Information:
None found
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Suppliers:
Bedoukian Research
e,z-2,6-DODECADIEN-1-AL
≥90.0% (trans,cis), Kosher
Odor: A fatty, green, aldehydic character with spice, melon undertones
Use: Powerful. Blends well with citrus and florals to add freshness and watery notes.
Flavor: green
Has application in watermelon, parsley and mushroom flavors.
BOC Sciences
For experimental / research use only.
(E,Z)-2,6-DODECADIENAL 95.0% (sum of isomers)
M&U International
E,Z-2,6-Dodecadien-1-al
Parchem
(E,Z)-2,6-dodecadien-1-al
Penta International
TRANS-2-CIS-6-DODECADIENAL
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Safety Information:
European information :
Most important hazard(s):
None - None found.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for (E,Z)-2,6-dodecadienal usage levels up to:
  0.5000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.012 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 0.009 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI): 1800 (μg/person/day)
Threshold of Concern:1800 (μg/person/day)
Structure Class: I
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 12
Click here to view publication 12
 average usual ppmaverage maximum ppm
baked goods: --
beverages(nonalcoholic): -2.00000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: -0.02000
fish products: --
frozen dairy: --
fruit ices: --
gelatins / puddings: -2.00000
granulated sugar: --
gravies: -5.00000
hard candy: --
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: -0.02000
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: -0.01000
snack foods: -0.01000
soft candy: -2.00000
soups: -0.01000
sugar substitutes: --
sweet sauces: --
 
Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i).
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm.
 average usage mg/kgmaximum usage mg/kg
Dairy products, excluding products of category 02.0 (01.0): 5.7000012.00000
Fats and oils, and fat emulsions (type water-in-oil) (02.0): 1.5000014.25000
Edible ices, including sherbet and sorbet (03.0): 0.900002.98000
Processed fruit (04.1): --
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): 5.000005.03000
Confectionery (05.0): --
Chewing gum (05.0): --
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): 4.8000011.55000
Bakery wares (07.0): 8.0000019.07000
Meat and meat products, including poultry and game (08.0): --
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): 0.900002.98000
Eggs and egg products (10.0): 0.900002.98000
Sweeteners, including honey (11.0): 0.900002.98000
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): 2.000005.00000
Foodstuffs intended for particular nutritional uses (13.0): --
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): 2.000004.43000
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): 1.000002.00000
Ready-to-eat savouries (15.0): 2.500004.50000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): 0.900002.98000
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Safety References:
Flavor & Extract Manufacturers Association (FEMA) reference(s):
The FEMA GRAS assessment of alpha,beta-unsaturated aldehydes and related substances used as flavor ingredients. View pdf
European Food Safety Athority(EFSA): Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
European Food Safety Authority (EFSA) reference(s):
EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF)
View page or View pdf
Scientific Opinion on Flavouring Group Evaluation 200, Revision 1 (FGE.200 Rev.1): 74 a,ß-unsaturated aliphatic aldehydes and precursors from chemical subgroup 1.1.1 of FGE.19
View page or View pdf
Scientific Opinion on Flavouring Group Evaluation 70, Revision 1 (FGE.70Rev1): consideration of aliphatic, linear, a,ß-unsaturated, di- and trienals and related alcohols, acids and esters evaluated by JECFA (61st-68th-69th meeting)
View page or View pdf
EPI System: View
AIDS Citations: Search
Cancer Citations: Search
Toxicology Citations: Search
EPA Substance Registry Services (TSCA): 21662-13-5
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 6430759
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 2
 (2E,6Z)-dodeca-2,6-dienal
Chemidplus: 0021662135
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References:
 (2E,6Z)-dodeca-2,6-dienal
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 21662-13-5
Pubchem (cid): 6430759
Pubchem (sid): 135263324
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Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS): View
HMDB (The Human Metabolome Database): HMDB32531
FooDB: FDB010401
Export Tariff Code: 2912.19.9000
VCF-Online: VCF Volatile Compounds in Food
ChemSpider: View
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Potential Blenders and core components note
 
For Odor
aldehydic
aldehydic
6,7,8-decen-1-olFR
(Z)-4-dodecenalFL/FR
 fresh carbaldehydeFR
isofreshalFR
 mandarine undecenalFL/FR
3-methyl-4-hexyl oxybutyraldehydeFR
 octanal (aldehyde C-8)FL/FR
 octane nitrileFR
 undecanalFL/FR
(Z)-8-undecenalFR
10-undecenal (aldehyde C-11 undecylenic)FL/FR
amber
 amber caraneFR
 angelica root oilFL/FR
anise
sweet fennel seed oilFL/FR
anisic
 ocimum basilicum herb oilFL/FR
 ocimum basilicum leaf oil americaFL/FR
 ocimum basilicum leaf oil CO2 extractFL/FR
balsamic
 guaiyl acetateFL/FR
citrus
 aldehydic nitrileFR
 citralFL/FR
 citrus specialtyFR
 citrus unshiu peel oilFL/FR
(E)-4-decenalFL/FR
(Z)-7-decenalFR
4-decenalFL/FR
2,4-dimethyl-3-cyclohexene-1-methanyl acetateFR
 lime pyranFR
 limonene aldehydeFR
 marine decadienalFR
 nonyl anthranilate 
 octanal glycol acetalFR
alpha-sinensalFL/FR
2-tetradecenalFL/FR
 tetrahydrocitralFL/FR
earthy
5-cyclopropyl-3(or 2),4-dimethyl octahydro-4,7-methanoinden-5-ol 
 decanolFL/FR
3-decen-2-oneFL/FR
 methyl 2-hexenoateFL/FR
6-methyl-5-hepten-2-one propylene glycol acetalFL/FR
2-nonenalFL/FR
(E)-2-nonenalFL/FR
2-octenalFL/FR
floral
alpha-amyl cinnamaldehyde diethyl acetalFR
isoamyl salicylateFL/FR
 citronellyl acetateFL/FR
 cyclamen propanalFR
4-(1-cyclopenten-1-yl)-1-butanol 
beta-damascenoneFL/FR
 dihydrojasmoneFL/FR
2,4-dimethyl-alpha-allyl-3-cyclohexene methanol 
4,6-dimethyl-alpha-allyl-3-cyclohexene methanol 
 linaloolFL/FR
 mimosa absolute moroccoFL/FR
 nonanolFL/FR
 ocean propanalFL/FR
 octahydro-4,7-methano-1H-indene-5-acetaldehyde + 6-methyl-octahydro-4,7-methano-indene-5-carbaldehydFR
 petitgrain mandarin oil terpenelessFL/FR
clementine petitgrain oilFL/FR
fruity
isoamyl octanoateFL/FR
 ethyl methyl anthranilateFL/FR
 methyl 2-methyl butyrateFL/FR
 methyl 3-nonenoateFL/FR
 octen-1-yl cyclopentanoneFL/FR
(E)-2-undecenalFL/FR
green
 cilantro leaf oilFL/FR
 cumin acetaldehydeFL/FR
isocyclocitral (IFF)FL/FR
 green carbaldehydeFR
 heptanal (aldehyde C-7)FL/FR
(Z)-4-heptenalFL/FR
2-heptyl furanFL/FR
 hexanal (aldehyde C-6)FL/FR
(Z)-3-hexen-1-yl oxyacetaldehydeFR
(E)-2-hexenalFL/FR
(Z)-3-hexenalFL/FR
alpha-hexyl cinnamaldehyde dimethyl acetalFR
2,4-ivy carbaldehydeFL/FR
3,5-ivy carbaldehydeFL/FR
 ivy carbaldehydeFL/FR
2,4-ivy carbaldehyde / methyl anthranilate schiff's baseFR
1-methoxy-2,7-octadiene 
 nerol oxideFL/FR
(E,Z)-3,6-nonadien-1-olFL/FR
(E)-2-nonen-1-olFL/FR
(Z)-2-nonen-1-olFL/FR
2-nonene nitrileFR
(E)-2-octen-1-yl acetateFL/FR
 olive oil absoluteFL/FR
(E,E)-sorbyl acetate 
1,5-undecadien-4-yl acetate 
herbal
 anthemis nobilis flower extractFL/FR
 anthemis nobilis flower oil romanFL/FR
sweet basil absoluteFL/FR
1,4-cineoleFL/FR
 clary sage oil franceFL/FR
2-dodecenalFL/FR
 geranium cyclohexaneFR
 hyssop oilFL/FR
 linalyl octanoateFL/FR
3-octyl acetateFL/FR
curled parsley seed oilFL/FR
 rosmarinus officinalis extractFL/FR
 rosmarinus officinalis tinctureFL/FR
 salvia sclarea oilFL/FR
minty
(-)-menthoneFL/FR
mossy
 oakmoss absoluteFL/FR
muguet
4-isobutyl 1-(3-methoxy-2-propen-1-yl) benzeneFR
4-ethyl 1-(3-methoxy-2-propen-1-yl) benzeneFR
4-methyl 1-(3-methoxy-2-propen-1-yl) benzeneFR
4-propyl 1-(3-methoxy-2-propen-1-yl) benzeneFR
soapy
 methyl anthranilate / hexyl cinnamaldehyde schiff's baseFR
spicy
 cumin seed absoluteFL/FR
 cuminaldehydeFL/FR
waxy
 decanal diethyl acetalFL/FR
9-decenoic acidFL/FR
1-dodecanolFL/FR
 heptyl octanoateFL/FR
2,4-nonadien-1-olFL/FR
 octanolFL/FR
 octyl isobutyrateFL/FR
 propyl decanoateFL/FR
 
For Flavor
 
No flavor group found for these
 citrus unshiu peel oilFL/FR
4-(1-cyclopenten-1-yl)-1-butanol 
5-cyclopropyl-3(or 2),4-dimethyl octahydro-4,7-methanoinden-5-ol 
9-decen-2-oneFL
4-decenalFL/FR
(Z)-4-dodecenalFL/FR
 epoxy-2-decenalFL
 ethyl methyl anthranilateFL/FR
 furfuryl hexanoateFL
 guaiyl acetateFL/FR
(E,E)-2,4-heptadien-1-olFL
 hexanal butane-2,3-diol acetalFL
 hexyl (E)-2-hexenoateFL
 ivy carbaldehydeFL/FR
3,5-ivy carbaldehydeFL/FR
1-methoxy-2,7-octadiene 
 methyl 2-hexenoateFL/FR
6-methyl octanalFL
6-methyl-5-hepten-2-one propylene glycol acetalFL/FR
 nonyl anthranilate 
2-octenalFL/FR
 propyl decanoateFL/FR
2-propyl pyridineFL
alpha-sinensalFL/FR
2-tetradecenalFL/FR
 tetrahydrocitralFL/FR
1,5-undecadien-4-yl acetate 
(±)-3-(methyl thio) heptanalFL
absinthe
 absinthe flavorFL
aldehydic
 octanal (aldehyde C-8)FL/FR
anise
sweet fennel seed oilFL/FR
citrus
 cilantro leaf oilFL/FR
 citralFL/FR
 linaloolFL/FR
clementine petitgrain oilFL/FR
cooling
1,4-cineoleFL/FR
creamy
 octyl isobutyrateFL/FR
fatty
2,4-decadienalFL
2-dodecenalFL/FR
(E,E)-2,4-heptadienalFL
2-heptyl furanFL/FR
2,4-nonadien-1-olFL/FR
2,4-nonadienalFL
(Z)-2-nonen-1-olFL/FR
2-nonenalFL/FR
10-undecenal (aldehyde C-11 undecylenic)FL/FR
floral
 citronellyl acetateFL/FR
 dihydrojasmoneFL/FR
4,6-dimethyl-alpha-allyl-3-cyclohexene methanol 
2,4-dimethyl-alpha-allyl-3-cyclohexene methanol 
 mimosa absolute moroccoFL/FR
 ocean propanalFL/FR
fruity
isoamyl octanoateFL/FR
 linalyl octanoateFL/FR
 methyl (E)-3-nonenoateFL
 methyl 2-methyl butyrateFL/FR
 methyl 3-nonenoateFL/FR
 octen-1-yl cyclopentanoneFL/FR
 petitgrain mandarin oil terpenelessFL/FR
green
isoamyl salicylateFL/FR
 angelica root oilFL/FR
 cumin acetaldehydeFL/FR
isocyclocitral (IFF)FL/FR
3-decen-2-oneFL/FR
 dihydroxyacetophenone (mixed isomers)FL
 heptanal (aldehyde C-7)FL/FR
(Z)-4-heptenalFL/FR
(E)-2-heptenalFL
2,4-hexadienalFL
(E,E)-2,4-hexadienalFL
 hexanal (aldehyde C-6)FL/FR
(E)-2-hexenalFL/FR
(Z)-3-hexenalFL/FR
2-hexyl pyridineFL
2,4-ivy carbaldehydeFL/FR
 nerol oxideFL/FR
(E,Z)-3,6-nonadien-1-olFL/FR
(E)-2-nonen-1-olFL/FR
(E)-2-nonenalFL/FR
 oakmoss absoluteFL/FR
2,4-octadienalFL
(E,E)-2,4-octadienalFL
(E)-2-octen-1-yl acetateFL/FR
3-octyl acetateFL/FR
(E,E)-sorbyl acetate 
 sorbyl acetateFL
herbal
 anthemis nobilis flower extractFL/FR
 anthemis nobilis flower oil romanFL/FR
sweet basil absoluteFL/FR
 clary sage oil franceFL/FR
 hyssop oilFL/FR
 ocimum basilicum herb oilFL/FR
 ocimum basilicum leaf oil americaFL/FR
 ocimum basilicum leaf oil CO2 extractFL/FR
curled parsley seed oilFL/FR
 rosmarinus officinalis extractFL/FR
 rosmarinus officinalis tinctureFL/FR
 salvia sclarea oilFL/FR
meaty
12-methyl tridecanalFL
minty
(-)-menthoneFL/FR
oily
 olive oil absoluteFL/FR
pungent
 acetaldehydeFL
ripe
(E)-4-decenalFL/FR
soapy
1-dodecanolFL/FR
spicy
 cumin seed absoluteFL/FR
 cuminaldehydeFL/FR
waxy
 decanal diethyl acetalFL/FR
 decanolFL/FR
9-decenoic acidFL/FR
 heptyl octanoateFL/FR
 mandarine undecenalFL/FR
 nonanolFL/FR
 octanolFL/FR
 undecanalFL/FR
(E)-2-undecenalFL/FR
woody
beta-damascenoneFL/FR
 
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Potential Uses:
 aldehydicFR
 citrusFR
 fatFL
 fungusFR
 greenFR
 mandarinFR
 melonFR
 parsley leafFL/FR
 resedaFR
 spiceFR
 waxy 
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Occurrence (nature, food, other): note
 orange peel oil
Search Trop  Picture
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Synonyms:
(2E,6Z)-dodeca-2,6-dienal
(2trans,6cis)-dodeca-2,6-dienal
(E,Z)-2,6-dodecadien-1-al
(E)-2,(Z)-6-dodecadien-1-al
2-trans-6-cis-dodecadien-1-al
2,6-dodecadien-1-al
E,Z-2,6-dodecadien-1-al
trans-2,cis-6-dodecadien-1-al
trans,cis-2,6-dodecadien-1-al
2-trans-6-cis-dodecadienal
trans-2-cis-6-dodecadienal
trans,cis-2,6-dodecadienal
2,6-dodecadienal, (2E,6Z)-
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