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Category: fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | pale yellow clear liquid (est) |
| Assay: | 90.00 to 100.00 % sum of isomers
|
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.96000 to 0.96900 @ 25.00 °C.
|
| Pounds per Gallon - (est).: | 7.988 to 8.063
|
| Specific Gravity: | 0.96100 to 0.97000 @ 20.00 °C.
|
| Pounds per Gallon - est.: | 8.006 to 8.081
|
| Refractive Index: | 1.46200 to 1.46700 @ 20.00 °C.
|
| Boiling Point: | 225.75 °C. @ 760.00 mm Hg (est)
|
| Vapor Pressure: | 0.085000 mmHg @ 25.00 °C. (est) |
| Flash Point: | 185.00 °F. TCC ( 85.00 °C. )
|
| logP (o/w): | 3.480 |
| Shelf Life: | 36.00 month(s) or longer if stored properly. |
| Storage: | store in cool, dry place in tightly sealed containers, protected from heat and light. |
| Soluble in: |
| | alcohol | | | water, 25.89 mg/L @ 25 °C (est) |
| Insoluble in: |
| | water |
| Stability: |
| | alcoholic lotion | | | antiperspirant | | | deo stick | | | detergent | | | fabric softener | | | hard surface cleaner | | | shampoo | | | soap |
Organoleptic Properties:
| |
| Odor Type: citrus |
| |
| Odor Strength: | medium |
| |
| Substantivity: | 24 hour(s) at 100.00 % |
| |
| | citrus floral green grapefruit gardenia petal |
Odor Description: at 100.00 %. | citrus floral green grapefruit gardenia petal Luebke, William tgsc, (1988) |
| |
| Odor and/or flavor descriptions from others (if found). |
| |
| IFF |
| Citrolate™ |
| Odor Description: | Citrus, grapefruit note also reminiscent of the dry notes of bitter orange oil and melon. Useful in colognes as a freshener to overcome the candy-sweet notes of orange and lemon oil |
| |
| Lluch Essence |
| JAFFARAL |
| Odor Description: | GRAPEFRUIT, RHUBARB , GREEN |
| |
| Perfumery Laboratory |
| CITROLATE ™ IFF (CITROLATE ™ IFF) |
| Odor Description: | Fresh, citrus fragrance with notes of grapefruit, melon and bitter orange |
| |
| Tadimety Aromatics |
| Agrumenyl Acetate |
| Odor Description: | Citrus, Neroli, Grape Fruit |
| |
| |
Cosmetic Information:
Suppliers:
| Augustus Oils |
| Floralate
|
| Services |
| Azelis UK |
| Citrolate™
|
| Ernesto Ventós |
| FLORALATE IFF
Odor: CITRUS, FRUITY, GRAPEFRUIT, DRY |
| Global Essence |
| Jaffaral
|
| IFF |
| Citrolate™
Odor: Citrus, grapefruit note also reminiscent of the dry notes of bitter orange oil and melon. Useful in colognes as a freshener to overcome the candy-sweet notes of orange and lemon oil |
| Kun Shan P&A |
| Floralate
|
| Lluch Essence |
| JAFFARAL
Odor: GRAPEFRUIT, RHUBARB , GREEN |
| M&U International |
| Citrolate (Floralate)
|
| Penta International |
| 2,4-DIMETHYL-3-CYCLOHEXENE-1-METHANYL ACETATE
|
| Perfumery Laboratory |
| CITROLATE ™ IFF (CITROLATE ™ IFF)
Odor: Fresh, citrus fragrance with notes of grapefruit, melon and bitter orange |
| Tadimety Aromatics |
| Agrumenyl Acetate
Odor: Citrus, Neroli, Grape Fruit |
| Taytonn ASCC |
| Floralate
|
| The John D. Walsh Company |
| Floralate
|
| Tianjin Danjun International |
| (3,5-Dimethyl-1-cyclohex-3-enyl)methyl acetat
|
Safety Information:
| European information : |
| Most important hazard(s): | | Xi - Irritant |
R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing.
|
| |
| Hazards identification |
| |
| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
| |
| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
|
Not determined
|
| Dermal Toxicity: |
|
Not determined
|
| Inhalation Toxicity: |
|
Not determined
|
Safety in Use Information:
| Category: | fragrance agents |
| RIFM Fragrance Material Safety Assessment: Search |
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
| Recommendation for 2,4-dimethyl-3-cyclohexene-1-methanyl acetate usage levels up to: | | | 5.0000 % in the fragrance concentrate.
|
| |
| Recommendation for 2,4-dimethyl-3-cyclohexene-1-methanyl acetate flavor usage levels up to: |
| | not for flavor use.
|
Safety References:
References:
Other Information:
Potential Blenders and core components note
| |
| For Odor |
| No odor group found for these |
| 2- | ethyl-N-methyl-N-(3-methyl phenyl) butyramide | FR |
| aldehydic |
| iso | butyraldehyde | FL/FR |
| | decanal (aldehyde C-10) | FL/FR |
| 6,7,8- | decen-1-ol | FR |
| | dodecanal (aldehyde C-12 lauric) | FL/FR |
| (Z)-4- | dodecenal | FL/FR |
| | mandarine undecenal | FL/FR |
| 3- | methyl-4-hexyl oxybutyraldehyde | FR |
| | nonanal (aldehyde C-9) | FL/FR |
| | TMH aldehyde | FR |
| | tridecanal | FL/FR |
| balsamic |
| | abies alba cone oil | FR |
| | cinnamyl formate | FL/FR |
| citronella |
| 4,8- | dimethyl-7-nonen-2-ol | FR |
| citrus |
| | acetaldehyde citronellyl methyl acetal | FR |
| | benzyl anthranilate | FR |
| | bergamot oil | FL/FR |
| | bergamot oil bergaptene reduced italy | FL/FR |
| | bergamot oil turkey | FL/FR |
| beta- | bisabolol | FL/FR |
| | citral diethyl acetal | FL/FR |
| | citral dimethyl acetal | FL/FR |
| | citrus floral green fragrance | FR |
| | citrus ocimenol | FR |
| | citrus specialty | FR |
| | dihydromyrcenol | FL/FR |
| | dimethyl octenone | FR |
| | dodecane nitrile | FR |
| 2- | dodecanone | FL/FR |
| citrus | floral fragrance | FR |
| | grapefruit indene | FR |
| | grapefruit mercaptan | FL/FR |
| | grapefruit nitrile | FR |
| | grapefruit oil c.p. (citrus paradisi var. red blush) | |
| | grapefruit oil c.p. california | FL/FR |
| | grapefruit oil CO2 extract (citrus paradisi macf. var. falvedo) | FL/FR |
| | grapefruit oil terpeneless | FL/FR |
| | grapefruit pentanol | FR |
| | lime octadienal | FR |
| | lime oil distilled mexico | FL/FR |
| | mandarin oil | FL/FR |
| | mandarin oil italy | FL/FR |
| 3- | methyl-4-(2-methyl butyl oxy) butyraldehyde | FR |
| | myrmac aldehyde | FR |
| | nonanal dimethyl acetal | FL/FR |
| (+)- | nootkatone | FL/FR |
| sweet | orange peel oil c.p. brazil | FL/FR |
| sweet | orange peel oil terpeneless | FL/FR |
| | rhubafuran | FR |
| alpha- | terpinyl methyl ether | FL/FR |
| (E)-2- | tetradecenal | FL/FR |
| 2- | tetradecenal | FL/FR |
| (±)-2,4,8- | trimethyl-7-nonen-2-ol | FL/FR |
| | valencene | FL/FR |
| | verbena fragrance | FR |
| ethereal |
| | ethyl acetate | FL/FR |
| fatty |
| 2- | decenal | FL/FR |
| (Z)-3- | octen-1-ol | FL/FR |
| floral |
| | acetaldehyde dibutyl acetal | FL/FR |
| | amyl benzoate | FL/FR |
| | amyl salicylate | FL/FR |
| | anisyl propanal / methyl anthranilate schiff's base | FR |
| | bois de rose oil brazil | FL/FR |
| | boronia concrete | FL/FR |
| alpha- | butyl cinnamaldehyde | FL/FR |
| | cassis oxime 10% | FR |
| | citronellyl acetate | FL/FR |
| | citronellyl propionate | FL/FR |
| | coriander seed oil CO2 extract | FL/FR |
| | cumin carbinol | FR |
| | dictamnus hispanicus oil | FR |
| | dihydrocarvyl acetate | FL/FR |
| (±)-2,3- | dihydrofarnesol | FL/FR |
| | dihydroisojasmonate methyl ester | FR |
| | dimethyl benzyl carbinol | FL/FR |
| | dimethyl benzyl carbinyl butyrate | FL/FR |
| 6,8- | dimethyl-2-nonanol | FR |
| 2,4- | dimethyl-3-cyclohexene-1-methanol | FR |
| | ethyl phenoxyacetate | FR |
| | farnesol | FL/FR |
| | farnesyl acetate | FL/FR |
| | floral butanal | FR |
| | floral undecenone | FR |
| | gardenia absolute | FR |
| | gardenia acetal | FR |
| | gardenia amide | FR |
| | gardenia concrete | FR |
| | gardenia decalone | FR |
| | gardenia pentyl acetate | FR |
| | geranium oil | FL/FR |
| | geranium oil africa | FL/FR |
| | geranyl acetone | FL/FR |
| | geranyl formate | FL/FR |
| (Z)-4- | hepten-2-yl salicylate | FR |
| (Z)-3- | hexen-1-yl salicylate | FL/FR |
| alpha- | hexyl cinnamaldehyde | FL/FR |
| | hexyl lactate | FL/FR |
| | hyacinth oil | FR |
| | hydrangea fragrance | FR |
| | hydroxycitronellal diethyl acetal | FL/FR |
| | hydroxycitronellal propylene glycol acetal | FL/FR |
| | jasmin cyclopentanol | FR |
| | jonquil absolute | FR |
| | lilac absolute | FR |
| | lily fragrance | FR |
| | lily propanol | FR |
| | linalool | FL/FR |
| | linalyl phenyl acetate | FL/FR |
| | lotus fragrance | FR |
| | magnolia indene | FR |
| (2- | methoxy-1-methyl propyl) benzene | FR |
| (3- | methoxy-2-methyl propyl) benzene | FR |
| | methoxycitronellal | FR |
| 1-(2- | methyl allyl oxy)-2-methyl butane | FR |
| | mimosa absolute | FL/FR |
| | mimosa absolute france | FL/FR |
| | mimosa absolute india | FL/FR |
| | muguet dienal | FR |
| | muguet nitrile | FR |
| | nerol | FL/FR |
| | neroli oil CO2 extract | FL/FR |
| | neroli oil tunisia | FL/FR |
| | nerolidol | FL/FR |
| (E)- | nerolidol | FL/FR |
| | nerolidyl acetate | FL/FR |
| | neryl acetate | FL/FR |
| | neryl isovalerate | FL/FR |
| | ocean propanal | FL/FR |
| | ocean propanal / methyl anthranilate schiff's base | FR |
| | orange leaf absolute | FL/FR |
| bitter | orangeflower absolute tunisia | FL/FR |
| | orchid specialty | FR |
| | palmarosa oil | FL/FR |
| | papaya isobutyrate | FL/FR |
| | peony acetonitrile | FR |
| | petitgrain concrete | FR |
| | petitgrain lemon oil | FL/FR |
| | petitgrain oil morocco | FL/FR |
| | phenyl acetaldehyde dicitronellyl acetal | FR |
| | phenyl acetaldehyde diisobutyl acetal | FL/FR |
| 2- | phenyl propionaldehyde ethylene glycol acetal | FR |
| | rhodinyl formate | FL/FR |
| | rose butanoate | FL/FR |
| laevo- | rose oxide | FL/FR |
| (Z)- | rose oxide | FL/FR |
| | rose pyran | FR |
| | styralyl formate | FL/FR |
| | sweet pea absolute | FR |
| | terpinyl formate | FL/FR |
| | terpinyl isobutyrate | FL/FR |
| | tetrahydrolinalyl acetate | FR |
| 5- | tricyclodecenyl acetate | FR |
| (E)-2,5,9- | trimethyl-4,9-decadien-1-al | FR |
| | undecanal dimethyl acetal | FR |
| | verdyl acetate | FR |
| | violet methyl carbonate | FR |
| | ylang ylang flower oil III | FL/FR |
| fresh |
| 3-(3- | propen-2-yl phenyl) butanal | FR |
| fruity |
| | benzyl methyl ether | FL/FR |
| iso | butyl methyl anthranilate | FL/FR |
| | citronellyl isobutyrate | FL/FR |
| | cyclohexyl crotonate | FR |
| | diethyl sebacate | FL/FR |
| | dimethyl succinate | FL/FR |
| | ethyl 3-hydroxyhexanoate | FL/FR |
| | ethyl isobutyrate | FL/FR |
| | ethyl methyl-para-tolyl glycidate | FL/FR |
| | grape butyrate | FL/FR |
| | grapefruit acetal | FR |
| | heptanal cyclic ethylene acetal | FR |
| | peach pivalate | FR |
| | solanone | FL/FR |
| | tropical ionone | FL/FR |
| 2- | undecenal | FL/FR |
| (E)-2- | undecenal | FL/FR |
| fungal |
| | jasmin nonane | FR |
| green |
| iso | amyl 3-(2-furan) propionate | FL/FR |
| iso | butyl benzyl carbinol | FL/FR |
| | chrysanthemum oxide | FL/FR |
| | citrus carbaldehyde / methyl anthranilate schiff's base | FR |
| 3,7- | dimethyl-6-octenoic acid | FL/FR |
| | earthy acetal | FL/FR |
| | flower hexene | FR |
| | green carboxylate | FR |
| | green cyclopropionate | FR |
| (Z)-3- | hexen-1-yl acetoacetate | FL/FR |
| (Z)-3- | hexen-1-yl angelate | FR |
| | hexen-1-yl oxypropane nitrile | FR |
| (Z)-3- | hexen-1-yl pyruvate | FL/FR |
| | hexyl (Z)-tiglate | FL/FR |
| | hyacinth absolute | FL/FR |
| | ivy dioxolane | FR |
| | melon acetal | FL/FR |
| | melon nonenoate | FL/FR |
| (2- | methoxy-1-methyl butyl) benzene | FR |
| [(4E,4Z)-5- | methoxy-3-methyl-4-penten-1-yl] benzene | FR |
| | methyl cyclocitrone (IFF) | FR |
| para- | methyl hydratropaldehyde | FL/FR |
| | methyl octine carbonate | FL/FR |
| 4- | methyl-4-phenyl pentanone | FR |
| (Z)-5- | octen-1-ol | FL/FR |
| | octyl oxyacetaldehyde | FR |
| | pelargonium graveolens stem leaf extract | FR |
| | phenyl acetaldehyde solution | FL/FR |
| herbal |
| 6- | acetoxydihydrotheaspirane | FL/FR |
| | chrysanthemum ketone | FR |
| | clary sage absolute | FL/FR |
| | coriander oleoresin | FL/FR |
| | dihexyl (E)-fumarate | FR |
| | linalyl acetate | FL/FR |
| 2- | methyl butyl salicylate | FL/FR |
| (1S,5R)- | myrtenyl acetate | FL/FR |
| 3- | octyl acetate | FL/FR |
| | phenyl acetaldehyde diisoamyl acetal | FR |
| alpha- | terpinyl acetate | FL/FR |
| medicinal |
| | kunzea ericoides leaf oil | FR |
| (Z)-6- | nonen-1-yl acetate | FL/FR |
| (Z)-6- | nonenal | FL/FR |
| spicy |
| | cinnamyl propionate | FL/FR |
| iso | cyclogeraniol (IFF) | FR |
| | spicy carbonate | FR |
| sulfurous |
| | grapefruit menthane | FL/FR |
| tea |
| | camellia oleifera leaf extract | FL/FR |
| terpenic |
| (E,E)-2,6-allo | ocimene | FL/FR |
| waxy |
| | decanal dimethyl acetal | FL/FR |
| 3- | decanone | FL/FR |
| 1- | undecanol | FL/FR |
| |
| For Flavor |
| |
| No flavor group found for these |
| | acetaldehyde dibutyl acetal | FL/FR |
| 6- | acetoxydihydrotheaspirane | FL/FR |
| | amyl benzoate | FL/FR |
| | boronia concrete | FL/FR |
| iso | butyl methyl anthranilate | FL/FR |
| beta- | cubebene | FL |
| | decanal dimethyl acetal | FL/FR |
| 3- | decanone | FL/FR |
| | dihydronootkatone | FL |
| (Z)-4- | dodecenal | FL/FR |
| | earthy acetal | FL/FR |
| | grapefruit oil c.p. (citrus paradisi var. red blush) | |
| (Z)-3- | hexen-1-yl acetoacetate | FL/FR |
| | hexyl (Z)-tiglate | FL/FR |
| | hyacinth absolute | FL/FR |
| | hydroxycitronellal propylene glycol acetal | FL/FR |
| | linalyl phenyl acetate | FL/FR |
| 4- | mercapto-4-methyl-2-pentanol | FL |
| 2- | methyl butyl salicylate | FL/FR |
| | nerolidyl acetate | FL/FR |
| (E,E)-2,6-allo | ocimene | FL/FR |
| | phenyl acetaldehyde solution | FL/FR |
| | solanone | FL/FR |
| | styralyl formate | FL/FR |
| | terpinyl isobutyrate | FL/FR |
| 2- | tetradecenal | FL/FR |
|
| iso | amyl 3-(2-furan) propionate | FL/FR |
| alpha- | butyl cinnamaldehyde | FL/FR |
| aldehydic |
| iso | butyraldehyde | FL/FR |
| | nonanal (aldehyde C-9) | FL/FR |
| 1- | undecanol | FL/FR |
| amber |
| iso | butyl benzyl carbinol | FL/FR |
| aromatic |
| | amyl salicylate | FL/FR |
| citrus |
| | bergamot oil | FL/FR |
| | bergamot oil bergaptene reduced italy | FL/FR |
| | bergamot oil turkey | FL/FR |
| beta- | bisabolol | FL/FR |
| | citral diethyl acetal | FL/FR |
| | citral dimethyl acetal | FL/FR |
| | dehydronootkatone | FL |
| | grapefruit mercaptan | FL/FR |
| | grapefruit oil c.p. california | FL/FR |
| | grapefruit oil CO2 extract (citrus paradisi macf. var. falvedo) | FL/FR |
| | grapefruit oil terpeneless | FL/FR |
| | lime oil distilled mexico | FL/FR |
| | linalool | FL/FR |
| | mandarin oil | FL/FR |
| | mandarin oil italy | FL/FR |
| | nerol | FL/FR |
| | neroli oil tunisia | FL/FR |
| (+)- | nootkatone | FL/FR |
| sweet | orange peel oil c.p. brazil | FL/FR |
| sweet | orange peel oil terpeneless | FL/FR |
| | petitgrain lemon oil | FL/FR |
| | petitgrain oil morocco | FL/FR |
| (±)-2,4,8- | trimethyl-7-nonen-2-ol | FL/FR |
| | valencene | FL/FR |
| ethereal |
| | ethyl acetate | FL/FR |
| | ethyl isobutyrate | FL/FR |
| fatty |
| 2- | decenal | FL/FR |
| (E,E)-2,4- | dodecadienal | FL |
| 2- | dodecanone | FL/FR |
| (Z)-3- | octen-1-ol | FL/FR |
| floral |
| | bois de rose oil brazil | FL/FR |
| | cinnamyl propionate | FL/FR |
| | citronellyl acetate | FL/FR |
| | citronellyl propionate | FL/FR |
| | dihydrocarvyl acetate | FL/FR |
| (±)-2,3- | dihydrofarnesol | FL/FR |
| | dimethyl benzyl carbinyl butyrate | FL/FR |
| 3,7- | dimethyl-6-octenoic acid | FL/FR |
| | farnesol | FL/FR |
| | farnesyl acetate | FL/FR |
| | geranium oil | FL/FR |
| | geranium oil africa | FL/FR |
| | geranyl acetone | FL/FR |
| | linalyl acetate | FL/FR |
| | neroli oil CO2 extract | FL/FR |
| | neryl acetate | FL/FR |
| | ocean propanal | FL/FR |
| | orange leaf absolute | FL/FR |
| bitter | orangeflower absolute tunisia | FL/FR |
| laevo- | rose oxide | FL/FR |
| | tropical ionone | FL/FR |
| | ylang ylang flower oil III | FL/FR |
| fruity |
| | benzyl methyl ether | FL/FR |
| | citronellyl isobutyrate | FL/FR |
| | diethyl sebacate | FL/FR |
| | dimethyl succinate | FL/FR |
| | ethyl 3-hydroxyhexanoate | FL/FR |
| | ethyl methyl-para-tolyl glycidate | FL/FR |
| | hexyl lactate | FL/FR |
| | neryl isovalerate | FL/FR |
| | rhodinyl formate | FL/FR |
| | rose butanoate | FL/FR |
| | terpinyl formate | FL/FR |
| grassy |
| | palmarosa oil | FL/FR |
| green |
| | chrysanthemum oxide | FL/FR |
| | dihydromyrcenol | FL/FR |
| | geranyl formate | FL/FR |
| | grape butyrate | FL/FR |
| (Z)-3- | hexen-1-yl pyruvate | FL/FR |
| (Z)-3- | hexen-1-yl salicylate | FL/FR |
| | melon acetal | FL/FR |
| | melon nonenoate | FL/FR |
| para- | methyl hydratropaldehyde | FL/FR |
| | methyl octine carbonate | FL/FR |
| (E)- | nerolidol | FL/FR |
| | nerolidol | FL/FR |
| | nonanal dimethyl acetal | FL/FR |
| (Z)-6- | nonen-1-yl acetate | FL/FR |
| (Z)-6- | nonenal | FL/FR |
| (Z)-5- | octen-1-ol | FL/FR |
| 3- | octyl acetate | FL/FR |
| | papaya isobutyrate | FL/FR |
| | phenyl acetaldehyde diisobutyl acetal | FL/FR |
| (Z)- | rose oxide | FL/FR |
| herbal |
| | clary sage absolute | FL/FR |
| | coriander oleoresin | FL/FR |
| | coriander seed oil CO2 extract | FL/FR |
| medicinal |
| | dimethyl benzyl carbinol | FL/FR |
| melon |
| | hydroxycitronellal diethyl acetal | FL/FR |
| soapy |
| | dodecanal (aldehyde C-12 lauric) | FL/FR |
| spicy |
| | cinnamyl formate | FL/FR |
| sulfurous |
| | grapefruit menthane | FL/FR |
| 1- | methyl thio-2-propanone | FL |
| tea |
| | camellia oleifera leaf extract | FL/FR |
| waxy |
| | decanal (aldehyde C-10) | FL/FR |
| alpha- | hexyl cinnamaldehyde | FL/FR |
| | mandarine undecenal | FL/FR |
| | mimosa absolute | FL/FR |
| | mimosa absolute france | FL/FR |
| | mimosa absolute india | FL/FR |
| (E)-2- | tetradecenal | FL/FR |
| | tridecanal | FL/FR |
| (E)-2- | undecenal | FL/FR |
| 2- | undecenal | FL/FR |
| woody |
| (1S,5R)- | myrtenyl acetate | FL/FR |
| alpha- | terpinyl acetate | FL/FR |
| alpha- | terpinyl methyl ether | FL/FR |
| |
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | agrumenyl acetate (Tadimety) | | | citrolate (IFF) | | 3- | cyclohexene-1-methanol, 3,5-dimethyl-, acetate | | 3,5- | dimethyl cyclohex-3-ene-1-methyl acetate | | (3,5- | dimethyl-1-cyclohex-3-enyl)methyl acetate | | 2,4- | dimethyl-3-cyclohexene-1-methanyl acetate | | 3,5- | dimethyl-3-cyclohexene-1-methyl acetate | | 3,5- | dimethylcyclohex-3-ene-1-methyl acetate | | | floralate | | | jaffaral |
Articles:
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