menthyl isovalerate
p-menth-3-yl isovalerate
 
Notes:
russian drug. Flavouring ingredient with a bitter, wood-like taste
  • Penta International
    • Penta International Corporation
      Chemistry innovation
      At Penta, our products and services help businesses do business better.
      For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes.
      US Email: Technical Services
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      US Voice: (973) 740-2300
      US Fax: (973) 740-1839
      Product(s):
      13-14700 L-MENTHYL ISOVALERATE
       
  • Sigma-Aldrich
    • Sigma-Aldrich
      Complete Supply Chain
      The perfect blend of products and services that bring your creativity to life.
      Sigma-Aldrich is a leading Life Science and High Technology company dedicated to providing high-quality, safe and certified flavor ingredients with transparent and easily accessible documentation to customers around the globe. Sigma-Aldrich also provides a suite of analytical tools that allow food analysts to simplify sample preparation, cleanup and analysis steps, while increasing sensitivity to trace ingredients and harmful substances to meet regulations and quality standards.
      Email: Information
      US Email: Sales
      US Voice: 800-244-1173
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      Certified Food Grade Products
      Product(s):
      W266906 Menthyl isovalerate, ≥98%, FG
      SDS
       
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CAS Number: 16409-46-4Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 240-460-1
Nikkaji Web: J286.893H
Beilstein Number: 3200250
MDL: MFCD00045488
CoE Number: 450
XlogP3-AA: 5.00 (est)
Molecular Weight: 240.38656000
Formula: C15 H28 O2
NMR Predictor: Predict (works with chrome or firefox)
Category: flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
PubMed: Search
NCBI: Search
JECFA Food Flavoring: 432  menthyl isovalerate
Flavis Number: 09.455 (Old)
DG SANTE Food Flavourings: 09.455  menthyl isovalerate
FEMA Number: 2669  menthyl isovalerate
FDA Mainterm: MENTHYL ISOVALERATE
FDA Regulation:
FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION
Subpart F--Flavoring Agents and Related Substances
Sec. 172.515 Synthetic flavoring substances and adjuvants.
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Physical Properties:
Appearance: colorless clear oily liquid (est)
Assay: 98.00 to 100.00 % 
Food Chemicals Codex Listed: No
Specific Gravity: 0.90900 @  25.00 °C.
Boiling Point: 260.00 to  262.00 °C. @ 750.00 mm Hg
Vapor Pressure: 0.007000 mm/Hg @ 25.00 °C. (est)
Flash Point: 230.00 °F. TCC ( 110.00 °C. )
logP (o/w): 5.555 (est)
Soluble in:
 alcohol
 water, 0.3057 mg/L @ 25 °C (est)
Insoluble in:
 water
Similar Items: note
allyl valerate
allyl isovalerate
amyl valerate
amyl isovalerate
isoamyl valerate
isoamyl isovalerate
para-anisyl isovalerate
para-anisyl valerate
benzyl valerate
benzyl isovalerate
bornyl valerate
bornyl isovalerate
(-)-bornyl isovalerate
isobornyl isovalerate
S-sec-butyl thioisovalerate
butyl valerate
butyl isovalerate
isobutyl valerate
isobutyl isovalerate
carvyl isovalerate
cinnamyl valerate
cinnamyl isovalerate
citronellyl valerate
citronellyl isovalerate
para-cresyl valerate
para-cresyl isovalerate
cyclohexyl valerate
cyclohexyl isovalerate
cyclotene isovalerate
decyl valerate
decyl isovalerate
ethyl valerate
ethyl isovalerate
eugenyl isovalerate
furfuryl isovalerate
furfuryl valerate
geranyl valerate
geranyl isovalerate
(E)-2-hepten-1-yl isovalerate
heptyl isovalerate
sec-heptyl isovalerate
heptyl valerate
(E)-2-hexen-1-yl valerate
(E)-2-hexen-1-yl isovalerate
(Z)-3-hexen-1-yl valerate
(Z)-3-hexen-1-yl isovalerate
hexyl valerate
hexyl isovalerate
linalyl valerate
linalyl isovalerate
menthyl valerate
methyl 2-methyl valerate
methyl 4-methyl valerate
2-methyl butyl isovalerate
4-methyl pentyl isovalerate
methyl thio isovalerate
methyl valerate
methyl isovalerate
myrtenyl isovalerate
neryl isovalerate
nonyl isovalerate
nonyl valerate
octyl valerate
octyl isovalerate
phenethyl isovalerate
2-phenethyl valerate
3-phenyl propyl isovalerate
phenyl propyl valerate
S-prenyl thioisovalerate
isopropyl thioisovalerate
propyl valerate
propyl isovalerate
isopropyl valerate
isopropyl isovalerate
rhodinyl isovalerate
terpinyl isovalerate
terpinyl valerate
Synonyms   Articles   Notes   Search   Top
Organoleptic Properties:
 
Odor Type: fruity
 
Odor Strength: medium
 
Substantivity: 96 hour(s) at 100.00 %
 
 fruity  cooling  sweet  woody  
Odor Description:
at 100.00 %. 
fruity cooling sweet woody
 
 fruity  cooling  sweet  woody  
Odor Description:
Fruity, cooling, sweet and woody
Mosciano, Gerard P&F 15, No. 3, 51, (1990)
 
 
Flavor Type: fruity
 
 fruity  sweet  tutti frutti  
Taste Description:
at 80.00 ppm.  
Fruity, sweet, with a tutti frutti background
Mosciano, Gerard P&F 15, No. 3, 51, (1990)
 
Odor and/or flavor descriptions from others (if found).
 
 
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Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: perfuming agents
Synonyms   Articles   Notes   Search   Top
Suppliers:
Bell Flavors & Fragrances
Menthyl Isovalerate
BOC Sciences
For experimental / research use only.
Menthyl Isovalerate
Inoue Perfumery
L-MENTHYL ISOVALERATE
Penta International
L-MENTHYL ISOVALERATE
Reincke & Fichtner
Menthyl Isovalerate
Sigma-Aldrich
Menthyl isovalerate, ≥98%, FG
Odor: woody; fruity; sweet
Certified Food Grade Products
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Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
Xi - Irritant
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 - Wear suitable gloves and eye/face protection.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Human Experience:
1 % solution: no irritation or sensitization.
Oral/Parenteral Toxicity:
oral-rat LD50  > 5000 mg/kg
Food and Chemical Toxicology. Vol. 20, Pg. 735, 1982.

Dermal Toxicity:
skin-rabbit LD50 > 5000 mg/kg
Food and Chemical Toxicology. Vol. 20, Pg. 735, 1982.

Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: flavor and fragrance agents
Recommendation for menthyl isovalerate usage levels up to:
  1.0000 % in the fragrance concentrate.
 
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
 average usual ppmaverage maximum ppm
baked goods: -18.00000
beverages(nonalcoholic): -5.00000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -2.90000
fruit ices: -2.90000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: -7.40000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
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Safety References:
Flavor & Extract Manufacturers Association (FEMA) reference(s):
The FEMA GRAS assessment of alicyclic substances used as flavor ingredients. View pdf
EPI System: View
Cancer Citations: Search
Toxicology Citations: Search
EPA Substance Registry Services (TSCA): 16409-46-4
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 565690
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 2
 (5-methyl-2-propan-2-ylcyclohexyl) 3-methylbutanoate
Chemidplus: 0016409464
RTECS: OT0720000 for cas# 16409-46-4
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References:
 (5-methyl-2-propan-2-ylcyclohexyl) 3-methylbutanoate
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 16409-46-4
Pubchem (cid): 565690
Pubchem (sid): 134992586
Pherobase: View
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Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
FDA Everything Added to Food in the United States (EAFUS): View
HMDB (The Human Metabolome Database): HMDB37211
FooDB: FDB016218
Export Tariff Code: 2915.60.0000
VCF-Online: VCF Volatile Compounds in Food
ChemSpider: View
Wikipedia: View
RSC Learn Chemistry: View
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Potential Blenders and core components note
 
For Odor
No odor group found for these
2,2,3-trimethyl cyclopentane ethanol 
amber
 amber naphthofuranFL/FR
anisic
 ethyl para-anisateFL/FR
balsamic
laevo-borneolFL/FR
isobornyl formateFL/FR
 brachyleana hutchinsii wood oilFR
 valerian rhizome absoluteFL/FR
caramellic
 maple furanoneFL/FR
 shoyu furanoneFL/FR
chemical
isobutyl formateFL/FR
 propyl propionateFL/FR
citrus
2-ethyl-1-hexanolFL/FR
coconut
(S)-gamma-hexalactone 
earthy
(Z)-linalool oxide (furanoid)FL/FR
ethereal
 cyclohexyl formateFL/FR
 ethyl acetateFL/FR
isopropyl formateFL/FR
floral
 acetophenoneFL/FR
 benzyl isobutyrateFL/FR
 citronellal diisotridecyl acetalFR
 citronellyl anthranilateFL/FR
beta-iononeFL/FR
2-methyl naphthaleneFL/FR
bitter orangeflower concrete moroccoFR
 rose oil (rosa damascena) russiaFL/FR
 rose oil (rosa damascena) turkeyFL/FR
 terpinyl valerateFL/FR
fruity
isobutyl acetoacetateFL/FR
isobutyl butyrateFL/FR
(R)-gamma-dodecalactoneFL/FR
 ethyl 3-(2-furyl) propanoateFL/FR
 ethyl 3-hydroxyhexanoateFL/FR
 ethyl benzoyl acetateFL/FR
2-ethyl butyl 2-butenoate 
 ethyl butyrateFL/FR
 ethyl isovalerateFL/FR
 ethyl lactateFL/FR
 ethyl propionateFL/FR
(E,E)-ethyl sorbateFL/FR
2-hexen-1-olFL/FR
 lilac lactoneFL/FR
 linalyl isobutyrateFL/FR
 methyl anthranilateFL/FR
 methyl heptanoateFL/FR
2-pentyl isovalerate 
isopropyl 2-methyl butyrateFL/FR
 propyl butyrateFL/FR
 propyl hexanoateFL/FR
isopropyl octanoateFL/FR
 strawberry glycidate 2FL/FR
 tropical iononeFL/FR
 vanilla carboxylateFL/FR
green
isogreen methanoindeneFR
 hexyl isobutyrateFL/FR
(E)-2-octen-1-olFL/FR
2-octen-1-olFL/FR
 rose leaf absolute (rosa centifolia)FL/FR
herbal
2-cyclohexyl cyclohexanoneFR
isodihydrolavandulolFR
(Z)-isodihydrolavandulyl acetateFR
delta-elemeneFL/FR
common tansy flower oilFR
common tansy flower oil dutchFR
 tea leaf absoluteFL/FR
mentholic
 cornmint oilFL/FR
 cornmint oil chinaFL/FR
 cornmint oil indiaFL/FR
 cornmint oil terpenelessFL/FR
(±)-mentholFL/FR
dextro,laevo-mentholFL/FR
dextro-neomentholFL/FR
laevo-mentholFL/FR
dextro,laevo-neomentholFL/FR
neoisomentholFL/FR
(+)-menthoneFL/FR
(±)-isomenthoneFL/FR
laevo-menthyl acetateFL/FR
 menthyl acetateFL/FR
 menthyl acetate racemicFL/FR
 peppermint cyclohexanoneFL/FR
dextro-piperitoneFL/FR
isopulegyl acetateFL/FR
minty
 carvyl propionateFL/FR
 cornmint oil japanFL/FR
 cornmint oil terpenesFR
 mentha piperita extractFL/FR
 mentha piperita flower/leaf/stem extractFL/FR
 mentha piperita flower/leaf/stem waterFR
 mentha piperita herb extract americaFR
 mentha piperita leaf waterFR
 mentha piperita tinctureFL/FR
(±)-menthoneFL/FR
(-)-menthoneFL/FR
2-methyl cyclohexanoneFL/FR
 pennyroyal oilFL/FR
 peppermint absoluteFL/FR
 peppermint distillatesFL/FR
 peppermint fragranceFR
 peppermint leafCS
 peppermint oilFL/FR
 peppermint oil americaFL/FR
 peppermint oil brazilFL/FR
 peppermint oil chinaFL/FR
 peppermint oil CO2 extractFL/FR
 peppermint oil dementholizedFL/FR
 peppermint oil englandFL/FR
 peppermint oil franceFL/FR
 peppermint oil hungaryFL/FR
 peppermint oil idahoFL/FR
 peppermint oil indiaFL/FR
 peppermint oil mongoliaFL/FR
 peppermint oil montanaFL/FR
 peppermint oil moroccoFL/FR
 peppermint oil russiaFL/FR
 peppermint oil special fractionsFL/FR
 peppermint oil tasmaniaFL/FR
 peppermint oil terpenelessFL/FR
 peppermint oil terpenesFR
 peppermint oil willametteFL/FR
 peppermint oil yakimaFL/FR
 peppermint waterFL/FR
laevo-piperitoneFL/FR
isopulegolFL/FR
isopulegoneFL/FR
(R)-(+)-pulegoneFL/FR
musk
 acetyl ethyl tetramethyl tetralin replacerFR
 musk decanolideFR
musty
ketoisophoroneFL/FR
opoponax
 opoponax resinoid replacerFR
spicy
2,5-dimethyl bicyclo(3.2.1)-2-octen-3-yl acetate + 1,4-dimethyl bicyclo(3.2.1)-2-octen-3-yl acetateFR
 ginger root absoluteFL/FR
 grains of paradise oilFL/FR
 methyl heptadienoneFL/FR
(E)-propyl 2-furan acrylateFL/FR
thujonic
common tansy oil canadaFR
tropical
beta-cyclocitralFL/FR
waxy
 ethyl decanoateFL/FR
woody
 agarwood oil (aetoxylon sympetalum)FR
para-tert-butyl cyclohexanoneFR
 cabreuva wood oilFR
 guaiacwood oil 20% in gurjun balsam oilFR
 gurjun balsam oilFR
 homalomena rubescens root oilFR
cis-2-pinanolFR
 sandalwood oil CO2 extractFL/FR
 spikenard oil CO2 extractFL/FR
 
For Flavor
 
No flavor group found for these
 carvyl propionateFL/FR
(R)-gamma-dodecalactoneFL/FR
delta-elemeneFL/FR
2-ethyl butyl 2-butenoate 
 grains of paradise oilFL/FR
(S)-gamma-hexalactone 
 lilac lactoneFL/FR
 limonen-10-yl acetateFL
(Z)-linalool oxide (furanoid)FL/FR
dextro,laevo-neomentholFL/FR
neoisomentholFL/FR
 menthyl acetate racemicFL/FR
2-methyl cyclohexanoneFL/FR
2-pentyl isovalerate 
isopulegoneFL/FR
 spikenard oil CO2 extractFL/FR
acidic
(E)-2-hexenoic acidFL
amber
 amber naphthofuranFL/FR
anise
 ethyl para-anisateFL/FR
berry
2,2,3-trimethyl cyclopentane ethanol 
camphoreous
laevo-borneolFL/FR
caramellic
 maple furanoneFL/FR
 shoyu furanoneFL/FR
citrus
ketoisophoroneFL/FR
cooling
1,3-dihydroxyacetone (dimer)FL
isomentholFL
laevo-mentholFL/FR
dextro,laevo-mentholFL/FR
 menthyl acetateFL/FR
 peppermint oil americaFL/FR
ethereal
 ethyl acetateFL/FR
fatty
2-ethyl-1-hexanolFL/FR
(E)-2-octen-1-olFL/FR
2-octen-1-olFL/FR
floral
 linalyl isobutyrateFL/FR
 rose oil (rosa damascena) russiaFL/FR
 rose oil (rosa damascena) turkeyFL/FR
 tropical iononeFL/FR
fruity
 benzyl isobutyrateFL/FR
isobutyl acetoacetateFL/FR
isobutyl butyrateFL/FR
 citronellyl anthranilateFL/FR
 ethyl 3-(2-furyl) propanoateFL/FR
 ethyl 3-hydroxyhexanoateFL/FR
 ethyl benzoyl acetateFL/FR
 ethyl butyrateFL/FR
 ethyl isovalerateFL/FR
 ethyl lactateFL/FR
 ethyl propionateFL/FR
(E,E)-ethyl sorbateFL/FR
2-furyl pentyl ketoneFL
2-hexen-1-olFL/FR
 methyl anthranilateFL/FR
 methyl heptanoateFL/FR
(E,E)-methyl sorbateFL
(E)-propyl 2-furan acrylateFL/FR
isopropyl 2-methyl butyrateFL/FR
 propyl butyrateFL/FR
isopropyl formateFL/FR
 propyl hexanoateFL/FR
isopropyl octanoateFL/FR
 strawberry glycidate 2FL/FR
 terpinyl valerateFL/FR
 valerian rhizome absoluteFL/FR
 vanilla carboxylateFL/FR
green
 cyclohexyl formateFL/FR
(E)-2-heptenalFL
 hexyl isobutyrateFL/FR
 methyl heptadienoneFL/FR
isophoroneFL
 rose leaf absolute (rosa centifolia)FL/FR
mentholic
 cornmint oilFL/FR
 cornmint oil terpenelessFL/FR
(±)-mentholFL/FR
dextro-neomentholFL/FR
(+)-menthoneFL/FR
 peppermint cyclohexanoneFL/FR
minty
 cornmint oil chinaFL/FR
 cornmint oil indiaFL/FR
 cornmint oil japanFL/FR
 mentha piperita extractFL/FR
 mentha piperita flower/leaf/stem extractFL/FR
 mentha piperita tinctureFL/FR
(±)-isomenthoneFL/FR
(-)-menthoneFL/FR
(±)-menthoneFL/FR
laevo-menthyl acetateFL/FR
 pennyroyal oilFL/FR
 peppermint absoluteFL/FR
 peppermint distillatesFL/FR
 peppermint flavorFL
 peppermint oilFL/FR
 peppermint oil brazilFL/FR
 peppermint oil chinaFL/FR
 peppermint oil CO2 extractFL/FR
 peppermint oil dementholizedFL/FR
 peppermint oil englandFL/FR
 peppermint oil franceFL/FR
 peppermint oil hungaryFL/FR
 peppermint oil idahoFL/FR
 peppermint oil indiaFL/FR
 peppermint oil mongoliaFL/FR
 peppermint oil montanaFL/FR
 peppermint oil moroccoFL/FR
 peppermint oil russiaFL/FR
 peppermint oil special fractionsFL/FR
 peppermint oil tasmaniaFL/FR
 peppermint oil terpenelessFL/FR
 peppermint oil willametteFL/FR
 peppermint oil yakimaFL/FR
 peppermint waterFL/FR
laevo-piperitoneFL/FR
dextro-piperitoneFL/FR
isopulegolFL/FR
(R)-(+)-pulegoneFL/FR
oily
2-methyl naphthaleneFL/FR
powdery
 acetophenoneFL/FR
rummy
isobutyl formateFL/FR
smoky
dextro-xyloseFL
spicy
 ginger root absoluteFL/FR
sulfurous
S-ethyl thioacetateFL
tea
 tea leaf absoluteFL/FR
tropical
beta-cyclocitralFL/FR
 propyl propionateFL/FR
waxy
 ethyl decanoateFL/FR
woody
isobornyl formateFL/FR
beta-iononeFL/FR
isopulegyl acetateFL/FR
 sandalwood oil CO2 extractFL/FR
 
Synonyms   Articles   Notes   Search   Top
Potential Uses:
 appleFR
 apricotFR
 balsamFR
 cranberryFR
 currant blackFR
 melon watermelon muskmelon cantaloupe 
 mintFR
 peachFR
 peppermintFR
 pineappleFR
 pruneFR
 valerianFL/FR
Synonyms   Articles   Notes   Search   Top
Occurrence (nature, food, other): note
 mint
Search Trop  Picture
 nutmeg seed
Search Trop  Picture
 peppermint leaf
Search Trop  Picture
 peppermint oil
Search Trop  Picture
Synonyms   Articles   Notes   Search   Top
Synonyms:
 butanoic acid, 3-methyl-, 5-methyl-2-(1-methylethyl)cyclohexyl ester
 menth-3-yl isovalerate
p-menth-3-yl isovalerate
para-menth-3-yl isovalerate
 menthol isovalerate
 menthyl 3-menthyl butyrate
 menthyl 3-menthylbutyrate
 menthyl 3-methyl butanoate
 menthyl 3-methylbutanoate
 menthyl isopentanoate
 menthyl isovalerianate
 mentyl isovalerate
(1alpha,2beta,5alpha)-3-methyl butanoic acid 5-methyl-2-(1-methyl ethyl) cyclohexyl ester
3-methyl butanoic acid 5-methyl-2-(1-methyl ethyl) cyclohexyl ester
5-methyl-2-(1-methyl ethyl) cyclohexyl 3-methyl butanoate
5-methyl-2-(1-methylethyl)cyclohexyl 3-methylbutanoate
(5-methyl-2-propan-2-ylcyclohexyl) 3-methylbutanoate
3-methylbutanoic acid 5-methyl-2-(1-methylethyl)cyclohexyl ester
1-isopropyl-4-methyl cyclohex-2-yl 3-methyl butanoate
1-isopropyl-4-methylcyclohex-2-yl 3-methylbutanoate
isovaleric acid, p-menth-3-yl ester
 validol
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