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Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless to pale yellow clear oily liquid (est) |
| Assay: | 98.00 to 100.00 %
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| Food Chemicals Codex Listed: | Yes |
| Specific Gravity: | 1.10400 to 1.10700 @ 20.00 °C.
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| Pounds per Gallon - (est).: | 9.197 to 9.222
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| Refractive Index: | 1.52300 to 1.52600 @ 20.00 °C.
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| Melting Point: | 7.00 to 8.00 °C. @ 760.00 mm Hg
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| Boiling Point: | 263.00 to 270.00 °C. @ 760.00 mm Hg
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| Acid Value: | 1.00 max. KOH/g
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| Vapor Pressure: | 0.009000 mmHg @ 25.00 °C. (est) |
| Flash Point: | > 230.00 °F. TCC ( > 110.00 °C. )
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| logP (o/w): | 2.801 (est) |
| Soluble in: |
| | alcohol | | | water, 489.9 mg/L @ 25 °C (est) |
| Insoluble in: |
| | water |
| Similar Items: note |
| hexyl para-anisate |
| methyl para-anisate |
Organoleptic Properties:
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| Odor Type: anisic |
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| | anisic tarragon fruity |
Odor Description: at 100.00 %. | aniseed tarragon fruity |
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| | sweet anisic licorice fruity spicy cherry floral powdery |
Odor Description:
| Sweet anisic, licorice, fruity, spice, cherry, floral and powdery Mosciano, Gerard P&F 18, No. 2, 38, (1993) |
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| |
| Flavor Type: anise |
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| | anise sweet fruity licorice grape cherry |
Taste Description: at 30.00 ppm. | Anise, sweet, fruity, licorice, grape and cherry like Mosciano, Gerard P&F 18, No. 2, 38, (1993) |
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| Odor and/or flavor descriptions from others (if found). |
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Cosmetic Information:
Suppliers:
Safety Information:
| Preferred SDS: View |
| European information : |
| Most important hazard(s): | | None - None found. |
S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes.
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| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
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| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Human Experience: |
| 4 % solution: no irritation or sensitization. |
| Oral/Parenteral Toxicity: |
oral-rat LD50 2040 mg/kg (Levenstein, 1975l)
oral-rat LD50 2040 mg/kg Food and Cosmetics Toxicology. Vol. 14, Pg. 757, 1976.
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| Dermal Toxicity: |
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Not determined
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| Inhalation Toxicity: |
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Not determined
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Safety in Use Information:
| Category: | flavor and fragrance agents |
| RIFM Fragrance Material Safety Assessment: Search |
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
| Recommendation for ethyl para-anisate usage levels up to: | | | 4.0000 % in the fragrance concentrate.
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| |
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 9.10 (μg/capita/day) |
| Maximised Survey-derived Daily Intakes (MSDI-USA): | 2.00 (μg/capita/day) |
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 3 |
| Click here to view publication 3 |
| | average usual ppm | average maximum ppm |
| baked goods: | - | 7.20000 |
| beverages(nonalcoholic): | - | 2.60000 |
| beverages(alcoholic): | - | - |
| breakfast cereal: | - | - |
| cheese: | - | - |
| chewing gum: | - | - |
| condiments / relishes: | - | - |
| confectionery froastings: | - | - |
| egg products: | - | - |
| fats / oils: | - | - |
| fish products: | - | - |
| frozen dairy: | - | 0.96000 |
| fruit ices: | - | 0.96000 |
| gelatins / puddings: | - | - |
| granulated sugar: | - | - |
| gravies: | - | - |
| hard candy: | - | 8.80000 |
| imitation dairy: | - | - |
| instant coffee / tea: | - | - |
| jams / jellies: | - | - |
| meat products: | - | - |
| milk products: | - | - |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | - | - |
| snack foods: | - | - |
| soft candy: | - | - |
| soups: | - | - |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
Safety References:
| Flavor & Extract Manufacturers Association (FEMA) reference(s): |
| The FEMA GRAS assessment of hydroxyl- and alkoxy-substituted benzyl derivatives used as flavor ingredients. View pdf |
| European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
| European Food Safety Authority (EFSA) reference(s): |
Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) on a request from the Commission related to Flavouring Group Evaluation 20 (FGE.20): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical group 23 View page or View pdf |
Flavouring Group Evaluation 52 (FGE.52): Consideration of hydroxy- and alkoxy-substituted benzyl derivatives evaluated by JECFA (57th meeting) structurally related to benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters evaluated by EFSA in FGE.20 (2005) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC) View page or View pdf |
Flavouring Group Evaluation 20, Revision 1 (FGE.20Rev1): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids and related esters from chemical group 23 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 20, Revision 2 (FGE.20Rev2): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 20, Revision 3(FGE.20Rev3): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30 View page or View pdf |
| EPI System: | View |
| AIDS Citations: | Search |
| Cancer Citations: | Search |
| Toxicology Citations: | Search |
| EPA Substance Registry Services (TSCA): | 94-30-4 |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| Laboratory Chemical Safety Summary : | 60979 |
| National Institute of Allergy and Infectious Diseases: | Data |
| WGK Germany: | 2 |
| | ethyl 4-methoxybenzoate |
| Chemidplus: | 0000094304 |
| RTECS: | BZ4697000 for cas# 94-30-4 |
References:
Other Information:
Potential Blenders and core components note
| |
| For Odor |
| No odor group found for these |
| 4- | methyl-2-(1-methyl-1-butenyl)-1,3-dioxolane | |
| 2,2,3- | trimethyl cyclopentane ethanol | |
|
| | dehydro-ar-ionene | |
| anise |
| | anise oleoresin | FL/FR |
| | anise seed oil | FL/FR |
| star | anise seed oil china | FL/FR |
| | anise seed oil colombia | FL/FR |
| star | anise seed oil terpeneless | FL/FR |
| sweet | fennel absolute | FL/FR |
| sweet | fennel oleoresin | FL/FR |
| sweet | fennel seed oil | FL/FR |
| anisic |
| ortho- | acetanisole | FL/FR |
| para- | acetanisole | FL/FR |
| | amyl furoate | FL/FR |
| para- | anisyl phenyl acetate | FL/FR |
| para- | anisyl propanal | FR |
| | dihydroanethol | FL/FR |
| | estragole | FL/FR |
| | methyl para-anisate | FL/FR |
| | ocimum basilicum herb oil | FL/FR |
| 3- | pentyl bicyclo[3.2.1]-6-octen-2-one | FR |
| | sassafras acetate | FL/FR |
| balsamic |
| | butyl cinnamate | FL/FR |
| | ethyl cinnamate | FL/FR |
| | tolu balsam oil | FL/FR |
| berry |
| | raspberry ketone methyl ether | FL/FR |
| caramellic |
| 5- | ethyl-2,3,4,5-tetramethyl-2-cyclohexen-1-one | FL/FR |
| | maple furanone | FL/FR |
| | shoyu furanone | FL/FR |
| cheesy |
| 2- | heptanone | FL/FR |
| chemical |
| iso | butyl formate | FL/FR |
| | propyl propionate | FL/FR |
| citrus |
| 2- | ethyl-1-hexanol | FL/FR |
| coconut |
| | tetrahydrojasmone | FR |
| earthy |
| | pinus sylvestris leaf absolute | FL/FR |
| ethereal |
| | ethyl acetate | FL/FR |
| iso | propyl formate | FL/FR |
| floral |
| | acetophenone | FL/FR |
| | anise indene | FR |
| | anisyl propanal / methyl anthranilate schiff's base | FR |
| | autumn carboxylate | FR |
| | benzyl isobutyrate | FL/FR |
| | boronia absolute | FL/FR |
| | citronellyl anthranilate | FL/FR |
| | dictamnus hispanicus oil | FR |
| 4,6- | dimethyl-alpha-allyl-3-cyclohexene methanol | |
| 2,4- | dimethyl-alpha-allyl-3-cyclohexene methanol | |
| | hawthorn acetate | FR |
| | heliotropyl acetone | FL/FR |
| 2- | hexylidene cyclopentanone | FL/FR |
| | rhodinyl isobutyrate | FL/FR |
| | rose carboxylate | FR |
| | rose oil (rosa damascena) russia | FL/FR |
| | rose oil (rosa damascena) turkey | FL/FR |
| | souroubea specialty | FR |
| | terpinyl valerate | FL/FR |
| | ylang ylang flower oil III | FL/FR |
| fruity |
| para- | anisyl methyl ketone | FL/FR |
| | berry hexanoate | FR |
| iso | butyl acetoacetate | FL/FR |
| | cinnamyl isobutyrate | FL/FR |
| 1,4- | diethyl-6,8-dioxabicyclo(3.2.1)octane | FR |
| | ethyl 3-(2-furyl) propanoate | FL/FR |
| | ethyl 3-hydroxyhexanoate | FL/FR |
| | ethyl benzoyl acetate | FL/FR |
| | ethyl butyrate | FL/FR |
| | ethyl isovalerate | FL/FR |
| | ethyl lactate | FL/FR |
| | ethyl propionate | FL/FR |
| (E,E)- | ethyl sorbate | FL/FR |
| | grapefruit acetal | FR |
| 2- | hexen-1-ol | FL/FR |
| | linalyl isobutyrate | FL/FR |
| | menthyl isovalerate | FL/FR |
| | methyl anthranilate | FL/FR |
| | methyl heptanoate | FL/FR |
| iso | propyl 2-methyl butyrate | FL/FR |
| | propyl butyrate | FL/FR |
| | propyl hexanoate | FL/FR |
| iso | propyl octanoate | FL/FR |
| | strawberry furanone butyrate | FL/FR |
| | strawberry glycidate 2 | FL/FR |
| | tropical ionone | FL/FR |
| | vanilla carboxylate | FL/FR |
| | xanthoxylum fruit oil | FR |
| | hexyl isobutyrate | FL/FR |
| | octanal diethyl acetal | FL/FR |
| 2- | octen-1-ol | FL/FR |
| (E)-2- | octen-1-ol | FL/FR |
| | thuja occidentalis leaf absolute | FR |
| | tiglaldehyde | FL/FR |
| | dimethyl benzyl carbinyl crotonate | FL/FR |
| american | elder flower absolute | FR |
| | floral nitrile | FR |
| | lavender absolute bulgaria | FL/FR |
| | myrtle oil | FL/FR |
| | myrtle oil morocco | FL/FR |
| | tricyclodecenyl isobutyrate | FR |
| honey |
| | methyl phenyl acetate | FL/FR |
| licorice |
| (E)- | anethol | FL/FR |
| | clausena anisata leaf oil | |
| minty |
| bitter | fennel flower oil lithuania | |
| bitter | fennel seed oil lithuania | CS |
| naphthyl |
| beta- | naphthyl methyl ether | FL/FR |
| phenolic |
| | anisole | FL/FR |
| powdery |
| para- | anisyl acetate | FL/FR |
| spicy |
| alpha- | amyl cinnamyl alcohol | FL/FR |
| homo | anisaldehyde | FL/FR |
| | artemisia dracunculus herb oil | FL/FR |
| | cadinadiene | |
| | cananga leaf oil | FR |
| | cinnamyl propionate | FL/FR |
| | croton eluteria bark oil | FL/FR |
| iso | cyclogeraniol (IFF) | FR |
| 2,5- | dimethyl bicyclo(3.2.1)-2-octen-3-yl acetate + 1,4-dimethyl bicyclo(3.2.1)-2-octen-3-yl acetate | FR |
| iso | eugenyl acetate | FL/FR |
| | eugenyl isovalerate | FL/FR |
| (E)-para- | methoxycinnamaldehyde | FL/FR |
| (E)- | propyl 2-furan acrylate | FL/FR |
| terpenic |
| | angelica seed oil | FL/FR |
| waxy |
| | ethyl decanoate | FL/FR |
| woody |
| beta- | caryophyllene alcohol acetate | FL/FR |
| | cyperus root oil (cyperus rotundus) | FR |
| | guaiacwood oil | FL/FR |
| | kaempferia galanga rhizome oil | FL/FR |
| | patchouli ethanone | FR |
| | rhubarb oxirane | FR |
| | spicy pentanone | FL/FR |
| | vetiver oil fractions | FR |
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| For Flavor |
| |
| No flavor group found for these |
| | amyl furoate | FL/FR |
| homo | anisaldehyde | FL/FR |
| | benzyl methyl tiglate | FL |
| | butyl cinnamate | FL/FR |
| | cadinadiene | |
| beta- | caryophyllene alcohol acetate | FL/FR |
| | clausena anisata leaf oil | |
| | dehydro-ar-ionene | |
| | dimethyl benzyl carbinyl crotonate | FL/FR |
| 4- | ethyl anisole | FL |
| O- | ethyl S-(2-furyl methyl) thiocarbonate | FL |
| 5- | ethyl-2,3,4,5-tetramethyl-2-cyclohexen-1-one | FL/FR |
| | eugenyl isovalerate | FL/FR |
| bitter | fennel flower oil lithuania | |
| 2- | hexylidene cyclopentanone | FL/FR |
| (E)-para- | methoxycinnamaldehyde | FL/FR |
| | methyl para-anisate | FL/FR |
| (±)-3-((2- | methyl-3-furyl)thio)-2-butanone | FL |
| | myrtle oil morocco | FL/FR |
| | pinus sylvestris leaf absolute | FL/FR |
|
| | hexyl 3-mercaptobutanoate | FL |
| acidic |
| (E)-2- | hexenoic acid | FL |
| amber |
| | angelica seed oil | FL/FR |
| anise |
| (E)- | anethol | FL/FR |
| | anise oleoresin | FL/FR |
| | anise seed oil | FL/FR |
| star | anise seed oil china | FL/FR |
| | anise seed oil colombia | FL/FR |
| star | anise seed oil terpeneless | FL/FR |
| sweet | fennel absolute | FL/FR |
| sweet | fennel oleoresin | FL/FR |
| sweet | fennel seed oil | FL/FR |
| 4- | methyl-2-(1-methyl-1-butenyl)-1,3-dioxolane | |
| anisic |
| para- | acetanisole | FL/FR |
| para- | anisyl phenyl acetate | FL/FR |
| aromatic |
| | anisole | FL/FR |
| balsamic |
| | ethyl cinnamate | FL/FR |
| | tolu balsam oil | FL/FR |
| berry |
| | heliotropyl acetone | FL/FR |
| | raspberry ketone methyl ether | FL/FR |
| 2,2,3- | trimethyl cyclopentane ethanol | |
| | kaempferia galanga rhizome oil | FL/FR |
| caramellic |
| 5- | ethyl-3,4,5,6-tetramethyl cyclohexen-2-one | FL |
| | maple furanone | FL/FR |
| | shoyu furanone | FL/FR |
| cheesy |
| 2- | heptanone | FL/FR |
| creamy |
| 2,4- | heptadienal | FL |
| ethereal |
| | ethyl acetate | FL/FR |
| fatty |
| 2- | ethyl-1-hexanol | FL/FR |
| (E)-2- | octen-1-ol | FL/FR |
| 2- | octen-1-ol | FL/FR |
| 2,4- | undecadienal | FL |
| floral |
| | cinnamyl propionate | FL/FR |
| 2,4- | dimethyl-alpha-allyl-3-cyclohexene methanol | |
| 4,6- | dimethyl-alpha-allyl-3-cyclohexene methanol | |
| | linalyl isobutyrate | FL/FR |
| | methyl phenyl acetate | FL/FR |
| | rhodinyl isobutyrate | FL/FR |
| | rose oil (rosa damascena) russia | FL/FR |
| | rose oil (rosa damascena) turkey | FL/FR |
| | tropical ionone | FL/FR |
| | ylang ylang flower oil III | FL/FR |
| fruity |
| para- | anisyl acetate | FL/FR |
| | benzyl isobutyrate | FL/FR |
| | boronia absolute | FL/FR |
| iso | butyl acetoacetate | FL/FR |
| | cinnamyl isobutyrate | FL/FR |
| | citronellyl anthranilate | FL/FR |
| | ethyl 3-(2-furyl) propanoate | FL/FR |
| | ethyl 3-hydroxyhexanoate | FL/FR |
| | ethyl benzoyl acetate | FL/FR |
| | ethyl butyrate | FL/FR |
| | ethyl isovalerate | FL/FR |
| | ethyl lactate | FL/FR |
| | ethyl propionate | FL/FR |
| (E,E)- | ethyl sorbate | FL/FR |
| 2- | furyl pentyl ketone | FL |
| 2- | hexen-1-ol | FL/FR |
| | menthyl isovalerate | FL/FR |
| | methyl anthranilate | FL/FR |
| | methyl heptanoate | FL/FR |
| (E,E)- | methyl sorbate | FL |
| (E)- | propyl 2-furan acrylate | FL/FR |
| iso | propyl 2-methyl butyrate | FL/FR |
| | propyl butyrate | FL/FR |
| iso | propyl formate | FL/FR |
| | propyl hexanoate | FL/FR |
| iso | propyl octanoate | FL/FR |
| | spicy pentanone | FL/FR |
| | strawberry furanone butyrate | FL/FR |
| | strawberry glycidate 2 | FL/FR |
| | terpinyl valerate | FL/FR |
| | tiglaldehyde | FL/FR |
| | vanilla carboxylate | FL/FR |
| green |
| (E)-2- | heptenal | FL |
| (E,E)-2,4- | hexadienal | FL |
| | hexyl isobutyrate | FL/FR |
| | octanal diethyl acetal | FL/FR |
| herbal |
| | dihydroanethol | FL/FR |
| | lavender absolute bulgaria | FL/FR |
| | ocimum basilicum herb oil | FL/FR |
| licorice |
| 2- | butyl-3-methyl pyrazine | FL |
| | estragole | FL/FR |
| naphthyl |
| beta- | naphthyl methyl ether | FL/FR |
| powdery |
| ortho- | acetanisole | FL/FR |
| | acetophenone | FL/FR |
| | powdery ketone | FL |
| rummy |
| iso | butyl formate | FL/FR |
| spicy |
| alpha- | amyl cinnamyl alcohol | FL/FR |
| para- | anisyl methyl ketone | FL/FR |
| | artemisia dracunculus herb oil | FL/FR |
| | croton eluteria bark oil | FL/FR |
| iso | eugenyl acetate | FL/FR |
| 4- | methyl biphenyl | FL |
| | myrtle oil | FL/FR |
| sulfurous |
| S- | ethyl thioacetate | FL |
| tarragon |
| | sassafras acetate | FL/FR |
| tropical |
| | propyl propionate | FL/FR |
| waxy |
| | ethyl decanoate | FL/FR |
| woody |
| | guaiacwood oil | FL/FR |
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Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | anisic acid ethyl ester | | p- | anisic acid ethyl ester | | para- | anisic acid ethyl ester | | | benzoic acid, 4-methoxy-, ethyl ester | | | ethyl 4-methoxybenzoate | | | ethyl anisate | | | ethyl anisate natural | | | ethyl p methoxy benzoate (ethyl p anisate) | | | ethyl p-anisate | | | ethyl p-anisate natural | | | ethyl p-methoxy benzoate | | | ethyl p-methoxybenzoate | | | ethyl para-methoxybenzoate | | | ethyl4-methoxybenzoate | | 4- | methoxybenzoic acid ethyl ester | | p- | methoxybenzoic acid ethyl ester | | para- | methoxybenzoic acid ethyl ester |
Articles:
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