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Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless to orange clear liquid (est) |
| Assay: | 99.00 to 100.00 % sum of isomers
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| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.91700 to 0.92300 @ 25.00 °C.
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| Pounds per Gallon - (est).: | 7.630 to 7.680
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| Refractive Index: | 1.50400 to 1.51300 @ 20.00 °C.
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| Boiling Point: | 180.00 °C. @ 1.00 mm Hg
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| Boiling Point: | 331.00 to 333.00 °C. @ 760.00 mm Hg
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| Acid Value: | 3.00 max. KOH/g
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| Vapor Pressure: | 0.000137 mmHg @ 25.00 °C. (est) |
| Flash Point: | 312.00 °F. TCC ( 155.56 °C. )
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| logP (o/w): | 4.624 (est) |
| Soluble in: |
| | alcohol | | | oils | | | water, 0.4912 mg/L @ 25 °C (est) |
| Insoluble in: |
| | water |
Organoleptic Properties:
| |
| Odor Type: citrus |
| |
| | orange sweet fresh waxy juicy |
Odor Description: at 10.00 % in dipropylene glycol. | orange sweet fresh waxy juicy |
| |
| Odor and/or flavor descriptions from others (if found). |
| |
| Ernesto Ventós |
| SINENSAL NATURAL (EX ORANGE) |
| Odor Description: | CITRIC, SWEET, FRESH, WAXY |
| |
| Prodasynth |
| SINENSAL, NATURAL (EX-ORANGE) (ALPHA+BETA > 20%) |
| Odor Description: | CITRIC, SWEET, FRESH, WAXY |
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| |
Cosmetic Information:
Suppliers:
| Artiste |
| Sinensal Natural
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| BOC Sciences |
| For experimental / research use only. |
| 2,6-Dimethyl-10-methylenedodeca-2,6,11-trien-1-al
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| Citrus and Allied Essences |
| Sinensal 18/20% ex orange (natural)
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| Market Report |
| Ernesto Ventós |
| SINENSAL NATURAL (EX ORANGE)
Odor: CITRIC, SWEET, FRESH, WAXY |
| Florida Chemical |
| Sinensals
|
| Frutarom |
| Natural Sinensal 20%
KOSHER Flavor: fatty, reminiscent of orange |
| IFF |
| Natural Sinensal 20%
KOSHER Flavor: fatty, reminiscent of orange |
| Lluch Essence |
| SINENSAL NATURAL EX-ORANGE
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| Penta International |
| SINENSAL ALPHA NATURAL
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| Penta International |
| SINENSAL NATURAL MIXTURE OF ALPHA AND BETA
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| Prodasynth |
| SINENSAL, NATURAL (EX-ORANGE)
(ALPHA+BETA > 20%) Odor: CITRIC, SWEET, FRESH, WAXY |
| Reincke & Fichtner |
| beta-Sinensal natural
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| SRS Aromatics |
| SINENSAL NATURAL EX ORANGE
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Safety Information:
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| Hazards identification |
| |
| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
| |
| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
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Not determined
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| Dermal Toxicity: |
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Not determined
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| Inhalation Toxicity: |
|
Not determined
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Safety in Use Information:
| Category: | flavor and fragrance agents |
| RIFM Fragrance Material Safety Assessment: Search |
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
| Recommendation for beta-sinensal usage levels up to: | | | 4.0000 % in the fragrance concentrate.
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| |
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 0.91 (μg/capita/day) |
| Maximised Survey-derived Daily Intakes (MSDI-USA): | 0.50 (μg/capita/day) |
| Structure Class: | I |
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 4. Update in publication number(s): 18 |
| Click here to view publication 4 |
| | average usual ppm | average maximum ppm |
| baked goods: | - | - |
| beverages(nonalcoholic): | - | 10.00000 |
| beverages(alcoholic): | - | - |
| breakfast cereal: | - | - |
| cheese: | - | - |
| chewing gum: | - | - |
| condiments / relishes: | - | - |
| confectionery froastings: | - | - |
| egg products: | - | - |
| fats / oils: | - | - |
| fish products: | - | - |
| frozen dairy: | - | 10.00000 |
| fruit ices: | - | 10.00000 |
| gelatins / puddings: | - | - |
| granulated sugar: | - | - |
| gravies: | - | - |
| hard candy: | - | 10.00000 |
| imitation dairy: | - | - |
| instant coffee / tea: | - | - |
| jams / jellies: | - | - |
| meat products: | - | - |
| milk products: | - | - |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | - | - |
| snack foods: | - | - |
| soft candy: | - | - |
| soups: | - | - |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
Safety References:
| European Food Safety Athority(EFSA): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
| European Food Safety Authority (EFSA) reference(s): |
List of apha, beta-Unsaturated Aldehydes and Ketones representative of FGE.19 substances for Genotoxicity Testing [1] - Statement of the Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF) View page or View pdf |
Flavouring Group Evaluation 201: 2-Alkylated aliphatic acyclic alpha,beta-unsaturated aldehydes and precursors with or without additional double bonds from chemical subgroup 1.1.2 of FGE.19[1] View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 201 Revision 1 (FGE.201Rev1): 2-Alkylated, aliphatic, acyclic alpha,beta-unsaturated aldehydes and precursors, with or without additional double-bonds, from chemical subgroup 1.1.2 of FGE.19. View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 201 Revision 2 (FGE.201Rev2): 2-alkylated, aliphatic, acyclic alpha,beta-unsaturated aldehydes and precursors, with or without additional double-bonds, from chemical subgroup 1.1.2 of FGE.19 View page or View pdf |
| EPI System: | View |
| AIDS Citations: | Search |
| Cancer Citations: | Search |
| Toxicology Citations: | Search |
| EPA Substance Registry Services (TSCA): | 60066-88-8 |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| Laboratory Chemical Safety Summary : | 5281535 |
| National Institute of Allergy and Infectious Diseases: | Data |
| | (2E,6E)-2,6-dimethyl-10-methylidenedodeca-2,6,11-trienal |
| Chemidplus: | 0060066888 |
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| 2,6- | dimethyl-10-methylene dodeca-2,6,11-trien-1-al | | 2,6- | dimethyl-10-methylene-2,6,11-dodecatrien-1-al | | 2,6- | dimethyl-10-methylene-2,6,11-dodecatrienal | | 2,6- | dimethyl-10-methylenedodeca-2,6,11-trien-1-al | | (2E,6E)-2,6- | dimethyl-10-methylidenedodeca-2,6,11-trienal | | 2,6,11- | dodecatrienal, 2,6-dimethyl-10-methylene- | | | sinensal 18/20% ex orange (natural) | | beta- | sinensal natural | | | sinensal natural, mixture of alpha & beta | | | sinensals |
Articles:
| US Patents: | 3,963,783 - 4-Methyl-8-vinyl-4,7- and -4,8-nonadienals |
| PubMed: | Repellent effect of santalol from sandalwood oil against Tetranychus urticae (Acari: Tetranychidae). |
| US Patents: | 3,974,225 - Process for the preparation of unsaturated aldehydes |
| PubMed: | Acaricidal and oviposition deterring effects of santalol identified in sandalwood oil against two-spotted spider mite, Tetranychus urticae Koch (Acari: Tetranychidae). |
| US Patents: | 3,979,425 - Process for the preparation of unsaturated aldehydes |
| PubMed: | California Lomatiums, Part X. Comparison of composition of the hydrodistilled oils from two subspecies of Lomatium mohavense. |
| PubMed: | Citrus fruit flavor and aroma biosynthesis: isolation, functional characterization, and developmental regulation of Cstps1, a key gene in the production of the sesquiterpene aroma compound valencene. |
| PubMed: | Identification of aroma active compounds in orange essence oil using gas chromatography-olfactometry and gas chromatography-mass spectrometry. |
| PubMed: | Volatile constituents of redblush grapefruit (Citrus paradisi) and pummelo (Citrus grandis) peel essential oils from Kenya. |
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