sassafras acetate
toscanol (Givaudan)
 
Notes:
None found
  • Augustus Oils
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      16510-27-3 1-Cyclopropylmethyl-4-methoxybenzene
       
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      Toscanol is a versatile product that is particularly useful where regulatory restrictions inhibit the amounts of the more traditional anisic ingredients or where a longer lasting anisic quality is needed. Typical usage level is from 0.1% to as much as 5% when a strongly anisic quality is required, the material has good tenacity (two days on a smelling strip), it is stable in almost all media and can be used in soaps and candles effectively.
       
       
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Fragrance Demo Formulas
CAS Number: 16510-27-3Picture of molecule3D/inchi
FDA UNII: B5O4EJ2WVY
XlogP3: 3.70 (est)
Molecular Weight: 162.23178000
Formula: C11 H14 O
NMR Predictor: Predict (works with chrome, Edge or firefox)
Category: flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
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Perfumer and Flavorist: Search
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JECFA Food Flavoring: 2190  1-cyclopropanemethyl-4-methoxybenzene
FEMA Number: 4759 1-cyclopropanemethyl-4-methoxybenzene
FDA:No longer provide for the use of these seven synthetic flavoring substances
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Physical Properties:
Appearance: colorless clear liquid (est)
Assay: 98.00 to 100.00 % 
Food Chemicals Codex Listed: No
Specific Gravity: 0.98600 to 0.99000 @  25.00 °C.
Pounds per Gallon - (est).: 8.205 to  8.238
Refractive Index: 1.52200 to 1.52600 @  20.00 °C.
Boiling Point: 240.00 to  241.00 °C. @ 760.00 mm Hg (est)
Vapor Pressure: 0.059000 mmHg @ 25.00 °C. (est)
Vapor Density: 5.6 ( Air = 1 )
Flash Point: 235.00 °F. TCC ( 112.78 °C. )
logP (o/w): 3.492 (est)
Soluble in:
 alcohol
Insoluble in:
 water
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Organoleptic Properties:
 
Odor Type: anisic
 
Odor Strength: high ,
recommend smelling in a 10.00 % solution or less
 
Substantivity: 36 hour(s) at 10.00 % in dipropylene glycol
 
 sweet  anisic  tarragon  anise  spicy  sassafrass  licorice black licorice  root beer  herbal  
Odor Description:
at 10.00 % in dipropylene glycol. 
sweet anisic tarragon anise spicy sassafrass black licorice root beer herbal
Luebke, William tgsc, (2017)
 
 
Flavor Type: tarragon
 
 sweet  spicy  root beer  licorice black licorice  sassafrass  tarragon  anise  herbal  
Taste Description:
sweet spicy root beer black licorice sassafrass tarragon anise herbal
Luebke, William tgsc, (2017)
 
Odor and/or flavor descriptions from others (if found).
 
Givaudan
Toscanol®
Odor Description: Anisic, Green, Liqueur like, Herbaceous
Powerful and linear anisic, sweet-spicy note of estragole (methyl chavicol), Licorice and Sassafras oil character with a touch of Saffran, Myrtle, Opopanax and Carvi Seeds. Toscanol can be used in all kind of accords to add anisic agrestic and aromatic character. Useful in Fine Fragrance and in Consumer Products as a substitute for Basil oil, tarragon oil, synthetic estragole (methyl chavicol) and Safrole.
 
Pell Wall Perfumes
Toscanol
Odor Description: Green-anis, sweet, spicy, liquorice, basil. Powerful
Toscanol is a versatile product that is particularly useful where regulatory restrictions inhibit the amounts of the more traditional anisic ingredients or where a longer lasting anisic quality is needed. Typical usage level is from 0.1% to as much as 5% when a strongly anisic quality is required, the material has good tenacity (two days on a smelling strip), it is stable in almost all media and can be used in soaps and candles effectively.
 
 
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Cosmetic Information:
None found
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Suppliers:
Augustus Oils
Toscanol
Services
BOC Sciences
For experimental / research use only.
1-Cyclopropylmethyl-4-methoxybenzene
Givaudan
Toscanol®
Odor: Anisic, Green, Liqueur like, Herbaceous
Use: Powerful and linear anisic, sweet-spicy note of estragole (methyl chavicol), Licorice and Sassafras oil character with a touch of Saffran, Myrtle, Opopanax and Carvi Seeds. Toscanol can be used in all kind of accords to add anisic agrestic and aromatic character. Useful in Fine Fragrance and in Consumer Products as a substitute for Basil oil, tarragon oil, synthetic estragole (methyl chavicol) and Safrole.
Lluch Essence
TOSCANOL
Pell Wall Perfumes
Toscanol
Odor: Green-anis, sweet, spicy, liquorice, basil. Powerful
Use: Toscanol is a versatile product that is particularly useful where regulatory restrictions inhibit the amounts of the more traditional anisic ingredients or where a longer lasting anisic quality is needed. Typical usage level is from 0.1% to as much as 5% when a strongly anisic quality is required, the material has good tenacity (two days on a smelling strip), it is stable in almost all media and can be used in soaps and candles effectively.
Penta International
1-CYCLOPROPYLMETHYL-4-METHOXY BENZENE
PerfumersWorld
Toscanol
Perfumery Laboratory
TOSKANOL® 25% in IPM Givaudan (TOSCANOL® Givaudan)
Odor: sweet, anisic, fresh
The Perfumers Apprentice
Toscanol (G)
Odor: Aniseed,green,liqueur,herbaceous
Use: an be used in all kinds of accords to add agrestic and aromatic character.
Vigon International
Toscanol
Odor: sweet anisic tarragon anise spicy sassafrass black licorice root beer herbal
Use: Luebke, William tgsc, (2017)
Flavor: sweet spicy root beer black licorice sassafrass tarragon anise herbal
Luebke, William tgsc, (2017)
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Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, Oral (Category 5), H303
Acute toxicity, dermal (Category 5), H313
Skin corrosion/irritation (Category 3), H316
Skin sensitisation (Category 1), H317
Acute aquatic toxicity (Category 2), H401
Chronic aquatic toxicity (Category 2), H411
GHS Label elements, including precautionary statements
 
Pictogramexclamation-mark.jpg
 
Signal word Danger
Hazard statement(s)
H303 - May be harmfulif swallowed
H313 - May be harmful in contact with skin
H316 - Causes mild skin irritation
H317 - May cause an allergic skin reaction
H401 - Toxic to aquatic life
H411 - Toxic to aquatic life with long lasting effects
Precautionary statement(s)
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 - Wash skin thouroughly after handling.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P302 + P352 - IF ON SKIN: wash with plenty of soap and water.
P312 - Call a POISON CENTER or doctor/physician if you feel unwell.
P333 + P313 - IF SKIN irritation or rash occurs: Get medical advice/attention.
P362 - Take off contaminated clothing and wash before reuse.
P391 - Collect spillage. Hazardous to the aquatic environment
P501 - Dispose of contents/ container to an approved waste disposal plant.
Oral/Parenteral Toxicity:
oral-rat LD50  > 2000 mg/kg
Dispose of contents/ container to an approved waste disposal plant.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for sassafras acetate usage levels up to:
  5.0000 % in the fragrance concentrate.
 
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 26
Click here to view publication 26
 average usual ppmaverage maximum ppm
baked goods: 1.200006.00000
beverages(nonalcoholic): 0.400002.00000
beverages(alcoholic): 4.0000020.00000
breakfast cereal: 1.200008.00000
cheese: --
chewing gum: 4.00000100.00000
condiments / relishes: --
confectionery froastings: 1.8000010.00000
egg products: --
fats / oils: --
fish products: --
frozen dairy: 1.200008.00000
fruit ices: 1.200008.00000
gelatins / puddings: 1.8000010.00000
granulated sugar: --
gravies: --
hard candy: 1.200008.00000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: 1.200008.00000
soups: --
sugar substitutes: --
sweet sauces: --
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Safety References:
EPI System: View
AIDS Citations: Search
Cancer Citations: Search
Toxicology Citations: Search
EPA Substance Registry Services (TSCA): 16510-27-3
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 6422476
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 2
 1-(cyclopropylmethyl)-4-methoxybenzene
Chemidplus: 0016510273
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References:
 1-(cyclopropylmethyl)-4-methoxybenzene
NIST Chemistry WebBook: Search Inchi
Pubchem (cid): 6422476
Pubchem (sid): 135306551
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Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
CHEBI: View
CHEMBL: View
HMDB (The Human Metabolome Database): Search
ChemSpider: View
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Potential Blenders and core components note
 
For Odor
No odor group found for these
 dehydro-ar-ionene 
anise
 anise oleoresinFL/FR
 anise seed oilFL/FR
star anise seed oil chinaFL/FR
 anise seed oil colombiaFL/FR
star anise seed oil terpenelessFL/FR
 estragon absoluteFR
sweet fennel absoluteFL/FR
sweet fennel oleoresinFL/FR
anisic
ortho-acetanisoleFL/FR
para-acetanisoleFL/FR
 amyl furoateFL/FR
(Z)-anethol 
para-anisyl phenyl acetateFL/FR
para-anisyl propanalFR
 dihydroanetholFL/FR
 estragoleFL/FR
 ethyl para-anisateFL/FR
 ocimum basilicum herb oilFL/FR
 ocimum basilicum herb oil egyptFL/FR
 ocimum basilicum leaf oil americaFL/FR
 ocimum basilicum leaf oil CO2 extractFL/FR
 ocimum basilicum leaf oil indiaFL/FR
 ocotea cymbarum oil 
caramellic
 caramel pentadioneFL/FR
floral
 anise indeneFR
 anisyl propanal / methyl anthranilate schiff's baseFR
 autumn carboxylateFR
 dictamnus hispanicus oilFR
 hawthorn acetateFR
ortho-methyl acetophenoneFL/FR
fruity
para-anisyl methyl ketoneFL/FR
 berry hexanoateFR
1,4-diethyl-6,8-dioxabicyclo(3.2.1)octaneFR
 ethyl 2-ethyl acetoacetateFL/FR
(E,E)-ethyl sorbateFL/FR
green
 tiglaldehydeFL/FR
herbal
american elder flower absoluteFR
 floral nitrileFR
 petitgrain heptaneFR
 tricyclo(5.2.1.02,6)dec-3-enyl acetateFR
licorice
(E)-anetholFL/FR
sweet basil oleoresinFL/FR
 licorice fragranceFR
 ocimum basilicum 
medicinal
meta-dimethyl hydroquinoneFL/FR
minty
 carvoneFL/FR
 ethyl salicylateFL/FR
bitter fennel flower oil lithuania 
bitter fennel seed oil lithuaniaCS
 methyl salicylateFL/FR
musty
2-acetyl pyrroleFL/FR
spicy
 artemisia dracunculus herb oilFL/FR
2,4-dimethyl-alpha-isopropyl-3-cyclohexene-1-methanol 
 root beer fragranceFR
 safroleCS
isosafrole 
 sassafras albidum bark tincture (safrol free)FL/FR
 sassafras albidum leaf (safrole-free) 
 sassafras fragranceFR
white sassafras oilFL/FR
 tarragon oil replacerFL/FR
vanilla
 ethyl vanillinFL/FR
woody
 patchouli ethanoneFR
 
For Flavor
 
No flavor group found for these
 amyl furoateFL/FR
(Z)-anethol 
 carvoneFL/FR
 dehydro-ar-ionene 
4-ethyl anisoleFL
bitter fennel flower oil lithuania 
 fleabane oil (erigeron canadensis)FL
 ocotea cymbarum oil 
isosafrole 
white sassafras oilFL/FR
anise
(E)-anetholFL/FR
 anise oleoresinFL/FR
 anise seed oilFL/FR
star anise seed oil chinaFL/FR
 anise seed oil colombiaFL/FR
star anise seed oil terpenelessFL/FR
 ethyl para-anisateFL/FR
sweet fennel absoluteFL/FR
sweet fennel oleoresinFL/FR
anisic
para-acetanisoleFL/FR
para-anisyl phenyl acetateFL/FR
ortho-methyl acetophenoneFL/FR
 ocimum basilicum herb oil egyptFL/FR
caramellic
 caramel pentadioneFL/FR
chemical
meta-dimethyl hydroquinoneFL/FR
fruity
 ethyl 2-ethyl acetoacetateFL/FR
(E,E)-ethyl sorbateFL/FR
(E,E)-methyl sorbateFL
 tiglaldehydeFL/FR
herbal
 chervil flavorFL
 dihydroanetholFL/FR
 ocimum basilicum herb oilFL/FR
 ocimum basilicum leaf oil americaFL/FR
 ocimum basilicum leaf oil CO2 extractFL/FR
 ocimum basilicum leaf oil indiaFL/FR
licorice
sweet basil oleoresinFL/FR
2-butyl-3-methyl pyrazineFL
 estragoleFL/FR
black licorice flavorFL
 licorice flavorFL
 ocimum basilicum 
minty
 birch beer flavorFL
 ethyl salicylateFL/FR
 methyl salicylateFL/FR
nutty
2-acetyl pyrroleFL/FR
powdery
ortho-acetanisoleFL/FR
 powdery ketoneFL
spicy
para-anisyl methyl ketoneFL/FR
 artemisia dracunculus herb oilFL/FR
2,4-dimethyl-alpha-isopropyl-3-cyclohexene-1-methanol 
 root beer flavorFL
 root beer float flavorFL
 sarsaparilla flavorFL
 sassafras albidum bark extract (safrol free)FL
 sassafras albidum bark tincture (safrol free)FL/FR
 sassafras albidum extract (safrole-free)FL
 sassafras albidum leaf (safrole-free) 
 sassafras flavorFL
 tarragon oil replacerFL/FR
vanilla
 ethyl vanillinFL/FR
 
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Potential Uses:
 aniseFR
 caraway seedFL/FR
 myrtle oil replacerFR
 opoponaxFR
 saffronFR
 sassafrasFR
 spiceFR
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Occurrence (nature, food, other): note
 not found in nature
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Synonyms:
 anisole, p-(cyclopropylmethyl)-
 benzene, 1-(cyclopropylmethyl)-4-methoxy-
1-cyclopropanemethyl-4-methoxybenzene
1-cyclopropyl methyl-4-methoxybenzene
1-(cyclopropyl methyl)-4-methoxybenzene
1-cyclopropylmethyl-4-methoxybenzene
1-(cyclopropylmethyl)-4-(methyloxy)benzene
1-(cyclopropylmethyl)-4-methoxybenzene
4-(cyclopropylmethyl)phenyl methyl ether
 toscanol (Givaudan)
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