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Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless to pale yellow clear liquid (est) |
| Assay: | 99.00 to 100.00 %
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| Food Chemicals Codex Listed: | Yes |
| Specific Gravity: | 1.03900 to 1.04400 @ 25.00 °C.
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| Pounds per Gallon - (est).: | 8.646 to 8.687
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| Refractive Index: | 1.56100 to 1.56200 @ 20.00 °C.
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| Melting Point: | 1.50 to 3.50 °C. @ 760.00 mm Hg
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| Boiling Point: | 295.00 to 298.00 °C. @ 760.00 mm Hg
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| Boiling Point: | 170.00 °C. @ 16.00 mm Hg
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| Vapor Pressure: | 0.001030 mmHg @ 25.00 °C. |
| Vapor Density: | 6.8 ( Air = 1 ) |
| Flash Point: | 275.00 °F. TCC ( 135.00 °C. )
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| logP (o/w): | 3.310 |
| Soluble in: |
| | alcohol | | | water, 40 mg/L @ 35 °C (exp) |
| Insoluble in: |
| | water |
| Stability: |
| | cream | | | lipstick | | | non-discoloring in most media | | | shampoo | | | soap |
Organoleptic Properties:
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| Odor Type: earthy |
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| Odor Strength: | medium |
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| Substantivity: | 400 hour(s) at 100.00 % |
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| | sweet fruity cherry earthy mushroom rose plastic |
Odor Description: at 100.00 %. | sweet fruity cherry earthy mushroom rose plastic Luebke, William tgsc, (1987) |
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| Flavor Type: fruity |
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| | fruity cherry fungal plastic mushroom |
Taste Description:
| fruity cherry fungal plastic mushroom Luebke, William tgsc, (1987) |
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| Odor and/or flavor descriptions from others (if found). |
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Cosmetic Information:
Suppliers:
Safety Information:
| Preferred SDS: View |
| European information : |
| Most important hazard(s): | | Xi N - Irritant, Dangerous for the environment. |
R 36/37/38 - Irritating to eyes, respiratory system, and skin. R 51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S 02 - Keep out of the reach of children. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing. S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet.
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| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
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| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Human Experience: |
| 4 % solution: no irritation or sensitization. |
| Oral/Parenteral Toxicity: |
oral-mouse LD50 4300 mg/kg BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
BEHAVIORAL: FOOD INTAKE (ANIMAL) Toksikologicheskii Vestnik. Vol. (1), Pg. 34, 1997.
oral-rat LD50 2500 mg/kg Food and Cosmetics Toxicology. Vol. 16, Pg. 703, 1978.
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| Dermal Toxicity: |
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Not determined
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| Inhalation Toxicity: |
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Not determined
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Safety in Use Information:
| Category: | flavor and fragrance agents |
| RIFM Fragrance Material Safety Assessment: Search |
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
| IFRA Critical Effect: | Dermal sensitization and systemic toxicity |
| IFRA: | View Standard |
| View IFRA Standards Library for complete information. |
| Please review Amendment 49 IFRA documentation for complete information. |
| IFRA RESTRICTION LIMITS IN THE FINISHED PRODUCT (%): |
| Category 1: Products applied to the lips |
| 0.000040 % |
| Category 2: Products applied to the axillae |
| 0.0028 % |
| Category 3: Products applied to the face/body using fingertips |
| 0.00020 % |
| Category 4: Products related to fine fragrance |
| 0.012 % |
| | Category 5: Products applied to the face and body using the hands (palms), primarily leave-on |
| Category 5A: Body lotion products applied to the body using the hands (palms), primarily leave-on |
| 0.0023 % |
| Category 5B: Face moisturizer products applied to the face using the hands (palms), primarily leave-on |
| 0.00024 % |
| Category 5C: Hand cream products applied to the hands using the hands (palms), primarily leave-on |
| 0.00032 % |
| Category 5D: Baby Creams, baby Oils and baby talc |
| 0.000081 % |
| Category 6: Products with oral and lip exposure |
| 0.0023 % |
| | Category 7: Products applied to the hair with some hand contact |
| Category 7A: Rinse-off products applied to the hair with some hand contact |
| 0.00093 % |
| Category 7B: Leave-on products applied to the hair with some hand contact |
| 0.00093 % |
| Category 8: Products with significant anogenital exposure |
| 0.000081 % |
| Category 9: Products with body and hand exposure, primarily rinse off |
| 0.0037 % |
| | Category 10: Household care products with mostly hand contact |
| Category 10A: Household care excluding aerosol products (excluding aerosol/spray products) |
| 0.0037 % |
| Category 10B: Household aerosol/spray products |
| 0.0037 % |
| | Category 11: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate |
| Category 11A: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure |
| 0.000081 % |
| Category 11B: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure |
| 0.000081 % |
| Category 12: Products not intended for direct skin contact, minimal or insignificant transfer to skin |
| 0.24 % |
| | Notes: |
| IFRA FLAVOR REQUIREMENTS: |
Due to the possible ingestion of small amounts of fragrance ingredients from their use in products in Categories 1 and 6, materials must not only comply with IFRA Standards but must also be recognized as safe as a flavoring ingredient as defined by the IOFI Code of Practice (www.iofi.org). For more details see chapter 1 of the Guidance for the use of IFRA Standards. |
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| Maximised Survey-derived Daily Intakes (MSDI-EU): | 0.49 (μg/capita/day) |
| Maximised Survey-derived Daily Intakes (MSDI-USA): | 241.00 (μg/capita/day) |
| Structure Class: | III |
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 3 |
| Click here to view publication 3 |
| | average usual ppm | average maximum ppm |
| baked goods: | - | 25.00000 |
| beverages(nonalcoholic): | - | 8.30000 |
| beverages(alcoholic): | - | - |
| breakfast cereal: | - | - |
| cheese: | - | - |
| chewing gum: | 85.00000 | 160.00000 |
| condiments / relishes: | - | - |
| confectionery froastings: | - | - |
| egg products: | - | - |
| fats / oils: | - | - |
| fish products: | - | - |
| frozen dairy: | - | 5.60000 |
| fruit ices: | - | 5.60000 |
| gelatins / puddings: | - | - |
| granulated sugar: | - | - |
| gravies: | - | - |
| hard candy: | - | 23.00000 |
| imitation dairy: | - | - |
| instant coffee / tea: | - | - |
| jams / jellies: | - | - |
| meat products: | - | - |
| milk products: | - | - |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | - | - |
| snack foods: | - | - |
| soft candy: | - | - |
| soups: | - | - |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
Safety References:
References:
Other Information:
Potential Blenders and core components note
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| For Odor |
| No odor group found for these |
| 2- | acetonyl-5-methyl furan | |
| anisic |
| para- | acetanisole | FL/FR |
| balsamic |
| | benzyl cinnamate | FL/FR |
| (E)- | benzyl tiglate | FL/FR |
| | methyl (E)-cinnamate | FL/FR |
| | methyl cinnamate | FL/FR |
| | terpinyl cinnamate | FL/FR |
| berry |
| | raspberry ketone methyl ether | FL/FR |
| camphoreous |
| | butyrophenone | FL/FR |
| earthy |
| | benzyl tiglate | FL/FR |
| | heptanal cyclic acetal with glycerol | FL/FR |
| | heptanal glyceryl acetal | FL/FR |
| | methyl undecylenate | FL/FR |
| 1- | nonen-3-ol | FL/FR |
| 3- | octanol | FL/FR |
| 1- | octen-3-ol | FL/FR |
| 1- | octen-3-one | FL/FR |
| ethereal |
| | cyclohexyl formate | FL/FR |
| fatty |
| (E)-2- | decenal | FL/FR |
| | methyl 10-undecenoate | FL/FR |
| fermented |
| | butyl laevo-lactate | FL/FR |
| floral |
| alpha- | amyl cinnamyl acetate | FL/FR |
| iso | butyl salicylate | FL/FR |
| | cassie absolute | FL/FR |
| para- | cresyl acetate | FL/FR |
| beta- | damascenone | FL/FR |
| 6,8- | dimethyl-2-nonanol | FR |
| | herbal pyran | FR |
| para- | methyl acetophenone | FL/FR |
| | mimosa absolute | FL/FR |
| | mimosa absolute france | FL/FR |
| | mimosa absolute india | FL/FR |
| | nonyl octanoate | FL/FR |
| | octyl acetate | FL/FR |
| | phenethyl butyl ether | FR |
| 2- | phenyl propionaldehyde dimethyl acetal | FL/FR |
| 2- | phenyl propionaldehyde ethylene glycol acetal | FR |
| para- | tolualdehyde propylene glycol acetal | FL/FR |
| fruity |
| | allyl 2-ethyl butyrate | FL/FR |
| | allyl benzoate | FR |
| | allyl isovalerate | FL/FR |
| bitter | almond oil | FL/FR |
| iso | amyl 2-methyl butyrate | FL/FR |
| | amyl butyrate | FL/FR |
| para- | anisyl propionate | FL/FR |
| | benzaldehyde | FL/FR |
| | benzaldehyde / methyl anthranilate schiff's base | FR |
| | benzaldehyde glycrol acetal | FL/FR |
| | bread thiophene | FL/FR |
| | butyl propionate | FL/FR |
| | cherry oxyacetate | FL/FR |
| | cherry pentenoate | FL/FR |
| | cherry propanol | FL/FR |
| | cyclohexyl cinnamate | FL/FR |
| 2,2- | dimethyl-6,8-nonadien-3-ol | |
| 4- | ethyl benzaldehyde | FL/FR |
| | ethyl benzoyl acetate | FL/FR |
| | ethyl isovalerate | FL/FR |
| | ethyl methyl-para-tolyl glycidate | FL/FR |
| | heptyl isobutyrate | FL/FR |
| 3- | methyl-2-butenal | FL/FR |
| | octyl propionate | FL/FR |
| | prunus amygdalus amara seed extract | FL/FR |
| para- | tolualdehyde | FL/FR |
| meta- | tolualdehyde | FL/FR |
| | tolualdehydes (mixed o,m,p) | FL/FR |
| fungal |
| 1- | decen-3-ol | FL/FR |
| | methyl 2-furoate | FL/FR |
| green |
| | butyl lactate | FL/FR |
| | earthy acetal | FL/FR |
| (Z)-3- | hexen-1-yl benzoate | FL/FR |
| (Z)-3- | hexen-1-yl tiglate | FL/FR |
| (Z)- | leaf acetal | FL/FR |
| | lilac acetaldehyde | FL/FR |
| | melon acetal | FL/FR |
| (E)-2- | pentenal | FL/FR |
| | phenethyl isopropyl ether | FR |
| | phenyl acetaldehyde dimethyl acetal | FL/FR |
| 1,5- | undecadien-4-ol | |
| 3- | octanone | FL/FR |
| laevo- | perillaldehyde | FL/FR |
| honey |
| | phenethyl furoate | FL/FR |
| metallic |
| 1,4- | dipentyl-6,8-dioxabicyclo(3.2.1)octane | FR |
| 3- | octen-2-ol | FL/FR |
| (R)-1- | octen-3-ol | FL/FR |
| 1- | octen-3-yl butyrate | FL/FR |
| naphthyl |
| 2,4- | dimethyl benzaldehyde | FL/FR |
| | nutty cyclohexenone | FL/FR |
| phenolic |
| 2'- | hydroxyacetophenone | FL/FR |
| powdery |
| para- | anisyl acetate | FL/FR |
| spicy |
| para- | anisyl formate | FL/FR |
| (E)- | cinnamyl isovalerate | FL/FR |
| | cinnamyl isovalerate | FL/FR |
| para- | methoxycinnamaldehyde | FL/FR |
| (E)-para- | methoxycinnamaldehyde | FL/FR |
| waxy |
| | methyl laurate | FL/FR |
| (Z)-3- | nonen-1-ol | FL/FR |
| woody |
| | spicy pentanone | FL/FR |
| yeasty |
| 2- | octen-4-one | FL/FR |
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| For Flavor |
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| No flavor group found for these |
| para- | anisyl propionate | FL/FR |
| | benzyl tiglate | FL/FR |
| | butyrophenone | FL/FR |
| 2,2- | dimethyl-6,8-nonadien-3-ol | |
| | earthy acetal | FL/FR |
| | ethyl 2-phenyl-3-furoate | FL |
| 4- | ethyl benzaldehyde | FL/FR |
| | furfural diethyl acetal | FL |
| | heptanal cyclic acetal with glycerol | FL/FR |
| | heptanal glyceryl acetal | FL/FR |
| (E)-para- | methoxycinnamaldehyde | FL/FR |
| | methyl (E)-cinnamate | FL/FR |
| | methyl furfuracrylate | FL |
| tris( | methyl thio) methane | FL |
| | nonyl octanoate | FL/FR |
| 1,5- | octadien-3-ol | FL |
| (E)-2- | penten-1-ol | FL |
| 2- | pentyl-1-buten-3-one | FL |
| | phenethyl furoate | FL/FR |
| para- | tolualdehyde propylene glycol acetal | FL/FR |
| 1,5- | undecadien-4-ol | |
| anisic |
| para- | acetanisole | FL/FR |
| aromatic |
| para- | cresyl acetate | FL/FR |
| laevo- | perillaldehyde | FL/FR |
| balsamic |
| (E)- | benzyl tiglate | FL/FR |
| berry |
| | heptyl isobutyrate | FL/FR |
| | raspberry ketone methyl ether | FL/FR |
| bitter |
| | methyl ethoxypyrazine | FL |
| buttery |
| | butyl laevo-lactate | FL/FR |
| caramellic |
| | methyl 2-furoate | FL/FR |
| cherry |
| para- | methoxycinnamaldehyde | FL/FR |
| coffee |
| | difurfuryl ether | FL |
| cooling |
| iso | butyl salicylate | FL/FR |
| creamy |
| | acetyl ethyl carbinol | FL |
| para- | methyl acetophenone | FL/FR |
| earthy |
| alpha- | amyl cinnamyl acetate | FL/FR |
| 1- | decen-3-ol | FL/FR |
| 1- | nonen-3-ol | FL/FR |
| 1,8- | octane dithiol | FL |
| 1- | octen-3-one | FL/FR |
| | tamarind distillates | FL |
| 2- | thienyl disulfide | FL |
| estery |
| | octyl propionate | FL/FR |
| ethereal |
| | allyl 2-ethyl butyrate | FL/FR |
| fatty |
| 2- | acetonyl-5-methyl furan | |
| | dimethyl sulfoxide | FL |
| (Z)-3- | hexen-1-yl benzoate | FL/FR |
| fermented |
| | methyl thio isovalerate | FL |
| | allyl isovalerate | FL/FR |
| bitter | almond oil | FL/FR |
| iso | amyl 2-methyl butyrate | FL/FR |
| | amyl butyrate | FL/FR |
| para- | anisyl acetate | FL/FR |
| | benzaldehyde | FL/FR |
| | benzaldehyde glycrol acetal | FL/FR |
| | bread thiophene | FL/FR |
| | butyl propionate | FL/FR |
| | cherry oxyacetate | FL/FR |
| | cherry pentenoate | FL/FR |
| | cherry propanol | FL/FR |
| | cinnamyl isovalerate | FL/FR |
| (E)- | cinnamyl isovalerate | FL/FR |
| | cyclohexyl cinnamate | FL/FR |
| | ethyl benzoyl acetate | FL/FR |
| | ethyl isovalerate | FL/FR |
| | ethyl methyl-para-tolyl glycidate | FL/FR |
| | lilac acetaldehyde | FL/FR |
| 3- | methyl-2-butenal | FL/FR |
| 2- | phenyl propionaldehyde dimethyl acetal | FL/FR |
| | spicy pentanone | FL/FR |
| | terpinyl cinnamate | FL/FR |
| meta- | tolualdehyde | FL/FR |
| | tolualdehydes (mixed o,m,p) | FL/FR |
| green |
| | butyl lactate | FL/FR |
| | cyclohexyl formate | FL/FR |
| (Z)-3- | hexen-1-yl tiglate | FL/FR |
| (Z)- | leaf acetal | FL/FR |
| | melon acetal | FL/FR |
| (E)-2- | pentenal | FL/FR |
| | phenyl acetaldehyde dimethyl acetal | FL/FR |
| mushroom |
| 3- | octanone | FL/FR |
| 3- | octen-2-ol | FL/FR |
| 1- | octen-3-ol | FL/FR |
| (R)-1- | octen-3-ol | FL/FR |
| 1- | octen-3-yl butyrate | FL/FR |
| musty |
| 3- | octanol | FL/FR |
| naphthyl |
| 2,4- | dimethyl benzaldehyde | FL/FR |
| 2'- | hydroxyacetophenone | FL/FR |
| nutty |
| | nutty cyclohexenone | FL/FR |
| | prunus amygdalus amara seed extract | FL/FR |
| powdery |
| | powdery ketone | FL |
| spicy |
| para- | anisyl formate | FL/FR |
| | benzyl cinnamate | FL/FR |
| | cassie absolute | FL/FR |
| | methyl cinnamate | FL/FR |
| para- | tolualdehyde | FL/FR |
| sulfurous |
| 1-( | methyl thio)-2-butanone | FL |
| 2- | naphthyl mercaptan | FL |
| tea |
| red rooibos | tea leaf distillates | FL |
| vegetable |
| 2- | octen-4-one | FL/FR |
| waxy |
| (E)-2- | decenal | FL/FR |
| | methyl 10-undecenoate | FL/FR |
| | methyl laurate | FL/FR |
| | methyl undecylenate | FL/FR |
| | mimosa absolute | FL/FR |
| | mimosa absolute france | FL/FR |
| | mimosa absolute india | FL/FR |
| (Z)-3- | nonen-1-ol | FL/FR |
| | octyl 2-furoate | FL |
| | octyl acetate | FL/FR |
| woody |
| beta- | damascenone | FL/FR |
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Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | benzene, 1,1'-(oxybis(methylene))bis- | | | benzene, 1,1'-[oxybis(methylene)]bis- | | | benzene, 1,1'-oxybis(methylene- | | | benzene,1'-[oxybis(methylene)]bis- | | | benzyl ether | | | benzyl oxide | | | di benzyl ether | | | dibenzyl ether FCC | | | dibenzyl oxide | | | dibenzylether | | | ether, dibenzyl | | 1,1-oxybis | methylene, bis benzene | | 1,1'-oxybis( | methylene) benzene | | 1,1'-(oxybis( | methylene)) bisbenzene | | 1,1-(oxybis( | methylene))bisbenzene | | 1,1'-(oxybis( | methylene))bisbenzene | | 1,1'-[oxybis( | methylene)]dibenzene | | | phenylmethoxymethylbenzene | | | plasticator BA | | | plastikator BA |
Articles:
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