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Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless to pale yellow clear liquid (est) |
| Assay: | 95.00 to 100.00 % sum of isomers
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| Food Chemicals Codex Listed: | No |
| Boiling Point: | 197.00 to 198.00 °C. @ 760.00 mm Hg
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| Boiling Point: | 113.00 to 114.00 °C. @ 50.00 mm Hg
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| Vapor Pressure: | 0.515000 mmHg @ 25.00 °C. (est) |
| Flash Point: | 150.00 °F. TCC ( 65.56 °C. )
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| logP (o/w): | 3.200 (est) |
| Soluble in: |
| | alcohol | | | water, 137.2 mg/L @ 25 °C (est) |
| Insoluble in: |
| | water |
Organoleptic Properties:
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| Odor Type: green |
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| Odor Strength: | medium |
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| | green citrus fruity |
Odor Description: at 100.00 %. | green citrus fruity |
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| Odor and/or flavor descriptions from others (if found). |
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Cosmetic Information:
Suppliers:
Safety Information:
| Preferred SDS: View |
| European information : |
| Most important hazard(s): | | None - None found. |
S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes.
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| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
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| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
oral-mouse LD50 2700 ul/kg
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| Dermal Toxicity: |
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Not determined
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| Inhalation Toxicity: |
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Not determined
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Safety in Use Information:
| Category: | flavor and fragrance agents |
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
| Recommendation for dextro-limonene oxide usage levels up to: | | | 2.0000 % in the fragrance concentrate.
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| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 24 |
| Click here to view publication 24 |
| | average usual ppm | average maximum ppm |
| baked goods: | - | - |
| beverages(nonalcoholic): | 0.10000 | 0.50000 |
| beverages(alcoholic): | 0.20000 | 1.00000 |
| breakfast cereal: | - | - |
| cheese: | - | - |
| chewing gum: | 1.00000 | 5.00000 |
| condiments / relishes: | - | - |
| confectionery froastings: | - | - |
| egg products: | - | - |
| fats / oils: | - | - |
| fish products: | - | - |
| frozen dairy: | - | - |
| fruit ices: | - | - |
| gelatins / puddings: | 0.20000 | 1.00000 |
| granulated sugar: | - | - |
| gravies: | - | - |
| hard candy: | 0.50000 | 2.50000 |
| imitation dairy: | - | - |
| instant coffee / tea: | - | - |
| jams / jellies: | - | - |
| meat products: | - | - |
| milk products: | - | - |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | - | - |
| snack foods: | - | - |
| soft candy: | - | - |
| soups: | - | - |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
Safety References:
References:
| | (4R)-1-methyl-3-prop-1-en-2-yl-7-oxabicyclo[4.1.0]heptane |
| NIST Chemistry WebBook: | Search Inchi |
| Canada Domestic Sub. List: | 203719-54-4 |
| Pubchem (cid): | 441245 |
| Pubchem (sid): | 9480 |
Other Information:
Potential Blenders and core components note
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| For Odor |
| No odor group found for these |
| | tagete oil rwanda | |
| aldehydic |
| | dodecanal (aldehyde C-12 lauric) | FL/FR |
| (Z)-4- | dodecenal | FL/FR |
| | green hexanal | FL/FR |
| | undecanal | FL/FR |
| anisic |
| | amyl furoate | FL/FR |
| citrus |
| | citral diethyl acetal | FL/FR |
| | citral dimethyl acetal | FL/FR |
| (R)- | citronellyl nitrile | FR |
| | citronitrile (Symrise) | FR |
| iso | decyl acetate | FR |
| 2- | dodecanone | FL/FR |
| | lemon verbena oil | |
| | limonene aldehyde | FR |
| | limonene oxide | FL/FR |
| | litsea cubeba fruit oil | FL/FR |
| | methyl heptenone | FL/FR |
| (Z+E)-2- | methyl-2-(4-methyl-3-pentenyl) cyclopropane carbaldehyde | FL/FR |
| 1- | methyl-4-methyl ethenyl cyclohexene sulfurized | FL/FR |
| alpha- | methylene citronellal | FR |
| | petitgrain specialty | FR |
| | tangerine acetate | FR |
| creamy |
| 3- | heptyl dihydro-5-methyl-2(3H)-furanone | FL/FR |
| earthy |
| | spathulenol | |
| ethereal |
| | ethyl 4-pentenoate | FL/FR |
| fatty |
| 6- | methyl-5-hepten-2-one propylene glycol acetal | FL/FR |
| floral |
| | aglaia odorata absolute | FR |
| iso | amyl angelate | FL/FR |
| alpha- | amyl cinnamaldehyde | FL/FR |
| | bursera graveolens wood oil | FL/FR |
| | cassis cyclohexene | FR |
| | citronellol | FL/FR |
| | citronellyl acetate | FL/FR |
| | coriander seed oil terpeneless | FL/FR |
| | dihydrocitronellyl ethyl ether | FR |
| | dimethyl benzyl carbinyl butyrate | FL/FR |
| | geranyl tiglate | FL/FR |
| | jasmin absolute egypt (from concrete) | FL/FR |
| | magnolia flower oil CO2 extract | FL/FR |
| | menthadienyl formate | FR |
| | methyl benzyl acetate (mixed ortho-,meta-,para-) | FL/FR |
| | methyl nerate | |
| | muguet specialty | FR |
| (E)- | nerolidol | FL/FR |
| | nonan-3-yl acetate | FL/FR |
| | petitgrain fragrance | FR |
| | petitgrain oil paraguay | FL/FR |
| | terpinyl formate | FL/FR |
| (E)-2,5,9- | trimethyl-4,9-decadien-1-al | FR |
| fruity |
| iso | amyl 2-methyl butyrate | FL/FR |
| para- | anisyl propionate | FL/FR |
| | balsam specialty | FR |
| iso | butyl 2-methyl butyrate | FL/FR |
| | ethyl citronellate | FL/FR |
| | methyl acetoacetate | FL/FR |
| 2- | methyl butyl isovalerate | FL/FR |
| sesqui | phellandrene | |
| | tropical specialty | FR |
| green |
| iso | butyl heptanoate | FL/FR |
| iso | butyl methyl ketone | FL/FR |
| | citrus carbaldehyde / methyl anthranilate schiff's base | FR |
| black | currant bud absolute replacer | FL/FR |
| | dicyclopentadiene propionate | FR |
| | green carboxylate | FR |
| | herbal cyclohexane | FR |
| | hexyl tiglate | FL/FR |
| (2- | methoxy-1-methyl butyl) benzene | FR |
| | octanal diethyl acetal | FL/FR |
| | octanal dimethyl acetal | FL/FR |
| (E)-2- | octen-1-ol | FL/FR |
| herbal |
| iso | amyl heptanoate | FL/FR |
| | artemisia ludoviciana oil | FR |
| | buchu mercaptan acetate | FL/FR |
| | bursera graveolens wood | |
| | butyl levulinate | FL/FR |
| | chamomile propionate | FR |
| | chamomile valerate | FR |
| | dimethyl benzyl carbinyl crotonate | FL/FR |
| 2- | dodecenal | FL/FR |
| | linalyl formate | FL/FR |
| | marigold absolute (tagetes patula) | FR |
| 1-para- | menthen-9-yl acetate | FL/FR |
| 6- | methoxy-2,6-dimethyl octanal | FR |
| (1S,5R)- | myrtenyl acetate | FL/FR |
| | myrtle oil | FL/FR |
| 3- | octanon-1-ol | FL/FR |
| beta-sesqui | phellandrene | |
| | rue flower oil colombia | |
| | rue oil | FL/FR |
| | rue oil cuba | FL/FR |
| | tagete oil CO2 extract | FL/FR |
| | tagete oil egypt | FL/FR |
| | tagete oil turkey | FL/FR |
| | tagete oil zambia | FL/FR |
| | tricyclodecenyl isobutyrate | FR |
| | tricyclodecenyl propionate | FR |
| minty |
| laevo- | carvone | FL/FR |
| | carvyl acetate | FL/FR |
| | dihydrocarveol | FL/FR |
| orris |
| | orris capronate | FL/FR |
| terpenic |
| alpha- | phellandrene | FL/FR |
| waxy |
| | decanal dimethyl acetal | FL/FR |
| 3- | decanone | FL/FR |
| woody |
| | bamboo fragrance | FR |
| 2- | decalinyl acetate | FR |
| | humulus lupulus extract | FL/FR |
| | patchouli absolute | FR |
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| For Flavor |
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| No flavor group found for these |
| iso | amyl angelate | FL/FR |
| | amyl furoate | FL/FR |
| para- | anisyl propionate | FL/FR |
| | benzyl methyl tiglate | FL |
| | bursera graveolens wood | |
| | bursera graveolens wood oil | FL/FR |
| iso | butyl heptanoate | FL/FR |
| beta- | cubebene | FL |
| | decanal dimethyl acetal | FL/FR |
| 3- | decanone | FL/FR |
| (±)-(cis+trans)-1,2- | dihydroperillaldehyde | FL |
| | dimethyl benzyl carbinyl crotonate | FL/FR |
| (Z)-4- | dodecenal | FL/FR |
| | ethyl 4-pentenoate | FL/FR |
| | lemon verbena oil | |
| | limonene oxide | FL/FR |
| | linalyl formate | FL/FR |
| | magnolia flower oil CO2 extract | FL/FR |
| 3- | mercaptooctanal | FL |
| | methyl acetoacetate | FL/FR |
| | methyl benzyl acetate (mixed ortho-,meta-,para-) | FL/FR |
| | methyl nerate | |
| (Z+E)-2- | methyl-2-(4-methyl-3-pentenyl) cyclopropane carbaldehyde | FL/FR |
| 6- | methyl-5-hepten-2-one propylene glycol acetal | FL/FR |
| | nonan-3-yl acetate | FL/FR |
| 3- | octanon-1-ol | FL/FR |
| beta-sesqui | phellandrene | |
| sesqui | phellandrene | |
| | rue flower oil colombia | |
| | spathulenol | |
| | tagete oil rwanda | |
|
| | althaea officinalis root tincture | FL |
| citrus |
| | citral diethyl acetal | FL/FR |
| | citral dimethyl acetal | FL/FR |
| | dehydronootkatone | FL |
| | litsea cubeba fruit oil | FL/FR |
| 1- | methyl-4-methyl ethenyl cyclohexene sulfurized | FL/FR |
| creamy |
| | althaea officinalis root extract | FL |
| dusty |
| | ethyl citronellate | FL/FR |
| fatty |
| 2- | dodecanone | FL/FR |
| 2- | dodecenal | FL/FR |
| (E)-2- | octen-1-ol | FL/FR |
| floral |
| | citronellol | FL/FR |
| | citronellyl acetate | FL/FR |
| | dimethyl benzyl carbinyl butyrate | FL/FR |
| | geranyl tiglate | FL/FR |
| | jasmin absolute egypt (from concrete) | FL/FR |
| fruity |
| iso | amyl 2-methyl butyrate | FL/FR |
| | buchu mercaptan acetate | FL/FR |
| iso | butyl 2-methyl butyrate | FL/FR |
| black | currant bud absolute replacer | FL/FR |
| 3- | heptyl dihydro-5-methyl-2(3H)-furanone | FL/FR |
| 1-para- | menthen-9-yl acetate | FL/FR |
| 2- | methyl butyl isovalerate | FL/FR |
| | tagete oil CO2 extract | FL/FR |
| | tagete oil turkey | FL/FR |
| | tagete oil zambia | FL/FR |
| | terpinyl formate | FL/FR |
| green |
| iso | butyl methyl ketone | FL/FR |
| | dihydrocarveol | FL/FR |
| (E)-2- | heptenal | FL |
| | hexyl tiglate | FL/FR |
| | methyl heptenone | FL/FR |
| (E)- | nerolidol | FL/FR |
| (E,E)-2,6- | nonadienal | FL |
| 2,4- | octadienal | FL |
| | octanal diethyl acetal | FL/FR |
| | octanal dimethyl acetal | FL/FR |
| herbal |
| iso | amyl heptanoate | FL/FR |
| | butyl levulinate | FL/FR |
| | coriander seed oil terpeneless | FL/FR |
| | green hexanal | FL/FR |
| | petitgrain oil paraguay | FL/FR |
| | rue oil | FL/FR |
| | rue oil cuba | FL/FR |
| | tagete oil egypt | FL/FR |
| minty |
| laevo- | carvone | FL/FR |
| | carvyl acetate | FL/FR |
| orris |
| | orris capronate | FL/FR |
| soapy |
| | dodecanal (aldehyde C-12 lauric) | FL/FR |
| spicy |
| | myrtle oil | FL/FR |
| terpenic |
| alpha- | phellandrene | FL/FR |
| tropical |
| alpha- | amyl cinnamaldehyde | FL/FR |
| waxy |
| | undecanal | FL/FR |
| woody |
| | humulus lupulus extract | FL/FR |
| (1S,5R)- | myrtenyl acetate | FL/FR |
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Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| 7-oxa | bicyclo[4.1.0]heptane, 1-methyl-4-(1-methylethenyl)-, (4R)- (9CI) | | D-1,2- | epoxy-p-menth-8-ene | | dextro-1,2- | epoxy-para-menth-8-ene | | D-1,2- | epoxylimonene | | dextro-1,2- | epoxylimonene | | (+)- | limonene 1,2-epoxide | | D- | limonene 1,2-epoxide | | dextro- | limonene 1,2-epoxide | | D- | limonene 1,2-oxide | | dextro- | limonene 1,2-oxide | | D- | limonene epoxide | | dextro- | limonene epoxide | | D- | limonene monoxide | | dextro- | limonene monoxide | | (+)- | limonene oxide | | D- | limonene oxide | | (4R)- | limonene-1,2-epoxide | | D-8-p- | menthene-1,2-epoxide | | dextro-8-para- | menthene-1,2-epoxide | | L-8-p- | menthene-1,2-epoxide | | (4R)-1- | methyl-3-(1-methyl ethenyl)-7-oxabicyclo(4.1.0)heptane | | (4R)-1- | methyl-3-(1-methyl vinyl)-7-oxabicyclo(4.1.0)heptane | | (4R)-1- | methyl-3-(prop-1-en-2-yl)-7-oxabicyclo(4.1.0)heptane | | (4R)-1- | methyl-3-prop-1-en-2-yl-7-oxabicyclo[4.1.0]heptane |
Articles:
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