6-methyl quinoline
6-methylquinoline
 
Notes:
Flavouring ingredient
  • Augustus Oils
    • Augustus Oils Ltd
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      A wealth of experience, expertise and knowledge has allowed Augustus to bridge the gulf in expectation and trust between growers and users of natural ingredients. The Company works in partnership with customers on the one hand, and growers, farmers and distillers on the other. Both users and producers can then focus on exactly what they do best, while skilled Augustus technicians closely monitor and control the delivered product. This ensures users can have the confidence that they will receive the best raw materials suited to their requirements.
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      13-68000 6-METHYLQUINOLINE
       
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  • Synerzine
    • Synerzine, Inc.
      Innovation. Customization. Aroma Ingredients.
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      Product(s):
      W1389 6-Methyl Quinoline
       
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      Product(s):
      M0416 6-Methylquinoline >98.0%(GC)(T)
       
Synonyms   Articles   Notes   Search
CAS Number: 91-62-3Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 202-084-6
FDA UNII: K14453I13N
Nikkaji Web: J800A
Beilstein Number: 0110336
MDL: MFCD00006804
CoE Number: 2339
XlogP3: 2.60 (est)
Molecular Weight: 143.18873000
Formula: C10 H9 N
BioActivity Summary: listing
NMR Predictor: Predict (works with chrome or firefox)
Category: flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
PubMed: Search
NCBI: Search
JECFA Food Flavoring: 1302  6-methylquinoline
DG SANTE Food Flavourings: 14.042  6-methylquinoline
FEMA Number: 2744 6-methylquinoline
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF):91-62-3 ; 6-METHYLQUINOLINE
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Physical Properties:
Appearance: pale yellow to amber brown clear liquid (est)
Assay: 98.00 to 100.00 % 
Food Chemicals Codex Listed: No
Specific Gravity: 1.06000 to 1.06600 @  25.00 °C.
Pounds per Gallon - (est).: 8.820 to  8.870
Specific Gravity: 1.06300 to 1.07100 @  20.00 °C.
Pounds per Gallon - est.: 8.856 to 8.922
Refractive Index: 1.61100 to 1.61700 @  20.00 °C.
Melting Point: -22.00 °C. @ 760.00 mm Hg
Boiling Point: 259.00 to  261.00 °C. @ 760.00 mm Hg
Vapor Pressure: 0.022000 mmHg @ 25.00 °C. (est)
Flash Point: > 230.00 °F. TCC ( > 110.00 °C. )
logP (o/w): 2.570
Soluble in:
 alcohol
 dipropylene glycol
 water, 631.1 mg/L @ 25 °C (est)
Insoluble in:
 water
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Organoleptic Properties:
 
Odor Type: animal
 
Odor Strength: high ,
recommend smelling in a 1.00 % solution or less
 
Substantivity: 400 hour(s) at 10.00 % in dipropylene glycol
 
 leathery  tonka  castoreum  tobacco  civet  fecal  
Odor Description:
at 1.00 % in dipropylene glycol. 
leather tonka castoreum tobacco civet fecal
Luebke, William tgsc, (1990)
 
 
Flavor Type: animal
 
 animal  tonka  naphthyl  tobacco  anisic  phenolic  
Taste Description:
sweet animal tonka naphthyl tobacco anisic phenolic
Luebke, William tgsc, (1990)
 
Odor and/or flavor descriptions from others (if found).
 
 
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Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: perfuming agents
Synonyms   Articles   Notes   Search   Top
Suppliers:
Augustus Oils
Para Methyl Quinolene
Services
EMD Millipore
For experimental / research use only.
6-Methylquinoline
Indukern F&F
6-METHYL QUINOLINE
Odor: ANIMAL, LEATHER, TONKA, CIVET
Jalor-Chem
For experimental / research use only.
6-methylquinoline
Moellhausen
6-METHYL QUINOLEINE
Odor: Animalic; Earthy
OQEMA
Paramethylquinolene
Parchem
6-methyl quinoline
Penta International
6-METHYLQUINOLINE
Perfumer Supply House
6-Methyl Quinoline
Odor: A leathery, animalic, fecal note reminiscent of castoreum or civet. In dilution, smells of tobacco
Sigma-Aldrich
6-Methylquinoline, ≥98%, FG
Certified Food Grade Products
Synerzine
6-Methyl Quinoline
TCI AMERICA
For experimental / research use only.
6-Methylquinoline >98.0%(GC)(T)
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Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
Xn - Harmful.
R 22 - Harmful if swallowed.
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
R 40 - Limited evidence of a carcinogenic effect.
S 02 - Keep out of the reach of children.
S 20/21 - When using do not eat, drink or smoke.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Human Experience:
2 % solution: no irritation or sensitization.
Oral/Parenteral Toxicity:
oral-rat LD50  800 mg/kg
(Soviet Toxicologic Center, 1984)

oral-rat LD50  1260 mg/kg
(Moreno, 1976y)

oral-rat LD50  800 mg/kg
BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 28(12), Pg. 56, 1984.

Dermal Toxicity:
skin-rabbit LD50 5000 mg/kg
Food and Cosmetics Toxicology. Vol. 17, Pg. 871, 1979.

Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: flavor and fragrance agents
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for 6-methyl quinoline usage levels up to:
  1.0000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.32 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 0.01 (μg/capita/day)
Structure Class: III
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
 average usual ppmaverage maximum ppm
baked goods: -1.80000
beverages(nonalcoholic): -0.22000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -1.40000
fruit ices: -1.40000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: -1.80000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
 
Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i).
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm.
 average usage mg/kgmaximum usage mg/kg
Dairy products, excluding products of category 02.0 (01.0): 0.0240019.00000
Fats and oils, and fat emulsions (type water-in-oil) (02.0): 2.90000-
Edible ices, including sherbet and sorbet (03.0): -9.70000
Processed fruit (04.1): --
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): --
Confectionery (05.0): 2.9000029.00000
Chewing gum (05.0): --
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): 5.00000-
Bakery wares (07.0): 1.5000013.00000
Meat and meat products, including poultry and game (08.0): --
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): --
Eggs and egg products (10.0): --
Sweeteners, including honey (11.0): --
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): 1.20000-
Foodstuffs intended for particular nutritional uses (13.0): --
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): 0.00058-
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): --
Ready-to-eat savouries (15.0): --
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): --
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Safety References:
European Food Safety Athority(EFSA): Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
European Food Safety Authority (EFSA) reference(s):
Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) related to Flavouring Group Evaluation 24 (FGE.24): Pyridine, pyrrole, indole and quinoline derivatives from chemical group 28 (Commission Regulation (EC) No 1565/2000 of 18 July 2000)
View page or View pdf
Pyridine, pyrrole, indole and quinoline derivatives from chemical group 28 Flavouring Group Evaluation 24, Revision 1 - Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC)
View page or View pdf
Flavouring Group Evaluation 77 (FGE77) [1] - Consideration of Pyridine, Pyrrole and Quinoline Derivatives evaluated by JECFA (63rd meeting) structurally related to Pyridine, Pyrrole, Indole and Quinoline Derivatives evaluated by EFSA in FGE.24Rev1 (2008)
View page or View pdf
Statement on List of Representative Substances for Testing. The current Statement lays down a list of substances in sub-groups with representative substances for which additional data are required prior to their evaluation through the Procedure (Regulation (EC) No 1565/2000).
View page or View pdf
Scientific opinion on Flavouring Group Evaluation 24, Revision 2 (FGE.24Rev2): Pyridine, pyrrole, indole and quinoline derivatives from chemical group 28
View page or View pdf
Scientific Opinion on Flavouring Group Evaluation 77, Revision 2 (FGE.77Rev2): Consideration of Pyridine, Pyrrole and Quinoline Derivatives evaluated by JECFA (63rd meeting) structurally related to Pyridine, Pyrrole, Indole and Quinoline Derivatives evaluated by EFSA in FGE.24Rev2 (2013)
View page or View pdf
Scientific opinion on flavouring group evaluation 77, revision 3 (FGE.77Rev3): consideration of pyridine, pyrrole and quinoline derivatives evaluated by JECFA (63rd meeting) structurally related to pyridine, pyrrole, indole and quinoline derivatives evaluated by EFSA in FGE.24Rev2
View page or View pdf
EPI System: View
Chemical Carcinogenesis Research Information System: Search
Cancer Citations: Search
Toxicology Citations: Search
Carcinogenic Potency Database: Search
EPA GENetic TOXicology: Search
EPA Substance Registry Services (TSCA): 91-62-3
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 7059
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 3
 6-methylquinoline
Chemidplus: 0000091623
EPA/NOAA CAMEO: hazardous materials
RTECS: VC0550000 for cas# 91-62-3
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References:
 6-methylquinoline
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 91-62-3
Pubchem (cid): 7059
Pubchem (sid): 134971581
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Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS): View
CHEMBL: View
HMDB (The Human Metabolome Database): HMDB33115
FooDB: FDB011115
Export Tariff Code: 2933.49.7000
VCF-Online: VCF Volatile Compounds in Food
ChemSpider: View
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Potential Blenders and core components note
 
For Odor
No odor group found for these
7-methyl coumarin replacerFR
amber
 ambrette seed absoluteFL/FR
animal
 animal fragranceFR
isobutyl quinolineFR
isobutyl quinolineFR
2-isobutyl quinolineFR
6-tert-butyl-meta-cresolFL/FR
para-methyl tetrahydroquinolineFL/FR
 procavia capensis excrete absoluteFR
 skatoleFL/FR
1,2,3,4-tetrahydroquinolineFR
balsamic
 amyl phenyl acetateFL/FR
 pine needle absoluteFL/FR
burnt
 amber oilFR
caramellic
 immortelle absoluteFL/FR
cereal
 bran absoluteFR
chocolate
isoamyl phenyl acetateFL/FR
coconut
 coconut decanone methylFR
 coconut naphthalenoneFL/FR
gamma-heptalactoneFL/FR
coumarinic
 coumaneFL/FR
 phthalideFL/FR
 tonka bean oleoresinFR
 tonka bean resinoidFR
 tonka furanoneFL/FR
 tonka ketoneFR
 tonkavertFR
creamy
para-vanillyl alcoholFL/FR
floral
alpha-amyl cinnamyl acetateFL/FR
 boronia butenalFR
 citronellolFL/FR
delta-damasconeFL/FR
 dimethyl octanolFL/FR
 floral methanolFR
 orris pyridine 25% IPMFR
 tobacco flower absoluteFR
fruity
alpha-amyl cinnamyl isovalerateFL/FR
 cyclohexanone diethyl acetalFL/FR
(Z)-beta-damasconeFL/FR
(E)-beta-damasconeFL/FR
beta-damasconeFL/FR
 ethyl 3-hydroxyhexanoateFL/FR
 leather propionateFR
 osmanthus flower absoluteFL/FR
fungal
 methyl 2-furoateFL/FR
green
 narcissus flower absoluteFR
 oakmoss oilFR
 phenoxyacetaldehyde 50% in benzyl alcoholFR
 syringaldehydeFL/FR
hay
 beeswax absoluteFL/FR
 hay absoluteFR
 tobacco leaf absoluteFL/FR
 woodruff absoluteFR
 matricaria chamomilla flower oilFL/FR
 methyl nicotinateFL/FR
 saffron indenoneFL/FR
 safranalFL/FR
 theaspiraneFL/FR
 thyme undecaneFR
 yerba mate absoluteFL/FR
honey
 phenyl acetic acidFL/FR
leathery
4-tert-butyl phenolCS
 castoreum absoluteFL/FR
 leather cyclohexanolFR
marine
 marine pyridineFR
musk
 musk amberolFR
musty
ketoisophoroneFL/FR
nutty
2,3-dimethyl pyrazineFL/FR
phenolic
2'-hydroxyacetophenoneFL/FR
popcorn
2-acetyl pyridineFL/FR
powdery
para-anisyl acetateFL/FR
smoky
alpha-ethoxy-ortho-cresolFL/FR
 cuminyl alcoholFL/FR
N,N-diethyl octanamideFR
4-methyl guaiacolFL/FR
 myrtenalFL/FR
tobacco
para-cresyl isovalerateFL/FR
3-ethyl pyridineFL/FR
 methyl benzoxoleFL/FR
 tobacco concreteFR
(E,E/E,Z)-tobacco cyclohexenoneFL/FR
 veltonal (Bedoukian)FR
tonka
6-amyl-alpha-pyroneFL/FR
 coumarinFR
 deertongue absoluteFR
 deertongue oleoresinFR
 flouve absoluteFR
gamma-hexalactoneFL/FR
7-methyl coumarinCS
 mint lactoneFL/FR
 octahydrocoumarinFL/FR
 saffron resinoidFL/FR
 tonka bean absoluteFR
 tonka undecanoneFR
 whiskey lactoneFL/FR
tropical
 genet absoluteFL/FR
vanilla
 propenyl guaetholFL/FR
woody
 amber decatrieneFR
alpha-cedrene epoxideFR
isolongifolene ketoneFR
 methyl cedryl ketoneFL/FR
 tobacarol (IFF)FR
 tobacco noneneFR
 woody dioxolaneFR
 woody etherFR
 
For Flavor
 
No flavor group found for these
 amyl phenyl acetateFL/FR
6-tert-butyl-meta-cresolFL/FR
 capsicum oleoresinFL
 coconut naphthalenoneFL/FR
 coumaneFL/FR
 cyclohexanone diethyl acetalFL/FR
2,6-dimethoxy-4-vinyl phenolFL
alpha-ethoxy-ortho-cresolFL/FR
 fig leaf absoluteFL
2-furfurylidene butyraldehydeFL
7-methoxycoumarinFL
 methyl nicotinateFL/FR
para-methyl tetrahydroquinolineFL/FR
 pine needle absoluteFL/FR
2-propyl pyridineFL
 skatoleFL/FR
 tonka furanoneFL/FR
(R)-tonka furanoneFL
beta-damasconeFL/FR
brown
 beeswax absoluteFL/FR
caramellic
3-ethyl pyridineFL/FR
 methyl 2-furoateFL/FR
citrus
ketoisophoroneFL/FR
cocoa
 syringaldehydeFL/FR
coconut
 octahydrocoumarinFL/FR
cooling
 theaspiraneFL/FR
corn
2-acetyl pyridineFL/FR
coumarinic
 phthalideFL/FR
creamy
6-amyl-alpha-pyroneFL/FR
 dihydrocoumarinFL
gamma-hexalactoneFL/FR
 mint lactoneFL/FR
para-vanillyl alcoholFL/FR
earthy
alpha-amyl cinnamyl acetateFL/FR
fatty
 dimethyl octanolFL/FR
floral
isoamyl phenyl acetateFL/FR
 citronellolFL/FR
 phenyl acetic acidFL/FR
fruity
alpha-amyl cinnamyl isovalerateFL/FR
para-anisyl acetateFL/FR
(Z)-beta-damasconeFL/FR
(E)-beta-damasconeFL/FR
 ethyl 3-hydroxyhexanoateFL/FR
 osmanthus flower absoluteFL/FR
grassy
 tobacco leaf absoluteFL/FR
green
 immortelle absoluteFL/FR
hay
 genet absoluteFL/FR
herbal
 matricaria chamomilla flower oilFL/FR
 saffron indenoneFL/FR
 yerba mate absoluteFL/FR
lactonic
gamma-heptalactoneFL/FR
leathery
 castoreum absoluteFL/FR
minty
 myrtenalFL/FR
naphthyl
2'-hydroxyacetophenoneFL/FR
nutty
2,3-dimethyl pyrazineFL/FR
 methyl benzoxoleFL/FR
(E,E/E,Z)-tobacco cyclohexenoneFL/FR
phenolic
para-cresyl isovalerateFL/FR
spicy
 cuminyl alcoholFL/FR
 levisticum officinale oleoresinFL
 paprika oleoresinFL
sweet
 saffron resinoidFL/FR
vanilla
4-methyl guaiacolFL/FR
 propenyl guaetholFL/FR
woody
 ambrette seed absoluteFL/FR
delta-damasconeFL/FR
 methyl cedryl ketoneFL/FR
 safranalFL/FR
 whiskey lactoneFL/FR
 
Synonyms   Articles   Notes   Search   Top
Potential Uses:
 amberFR
 animalFR
 balsamFR
 castoreumFR
 civetFR
 earthFR
 greenFR
 hay new mown hayFR
 leatherFR
 lilacFR
 linden flowerFR
 mossFR
 ocean seaFR
 tobaccoFR
 tonka beanFR
Synonyms   Articles   Notes   Search   Top
Occurrence (nature, food, other): note
 tea leaf
Search Trop  Picture
 whiskey
Search  Picture
Synonyms   Articles   Notes   Search   Top
Synonyms:
 khinaldin
6-methylchinolin
6-methylquinoline
 paramethylquinolene
 quinoline, 6-methyl-
Synonyms   Articles   Notes   Search   Top
Articles:
PubMed: Heterocyclic Aromatic Hydrocarbons Show Estrogenic Activity upon Metabolization in a Recombinant Transactivation Assay.
PubMed: Genotoxicity of heterocyclic PAHs in the micronucleus assay with the fish liver cell line RTL-W1.
PubMed: Molecules of the quinoline family block tau self-aggregation: implications toward a therapeutic approach for Alzheimer's disease.
PubMed: Synthesis and in-vitro antimicrobial activity of secondary and tertiary amines containing 2-chloro-6-methylquinoline moiety.
PubMed: 4-Azido-2-chloro-6-methyl-quinoline.
PubMed: Novel chalcones derived from 2-chloro-3-formyl-6-methylquinoline.
PubMed: Heterocyclic compounds: toxic effects using algae, daphnids, and the Salmonella/microsome test taking methodical quantitative aspects into account.
PubMed: Tetra-μ-benzoato-bis-[(6-methyl-quino-line)-copper(II)].
PubMed: Inclusion of quinolines by binaphthol: structures and selectivity.
PubMed: Chloride-sensitive fluorescent indicators.
PubMed: The formation of 1-hydroxymethylnaphthalene and 6-hydroxymethylquinoline by both oxidative and reductive routes in Cunninghamella elegans.
PubMed: Hydroxylation and biodegradation of 6-methylquinoline by pseudomonads in aqueous and nonaqueous immobilized-cell bioreactors.
PubMed: The hepatic metabolism of two methylquinolines.
PubMed: Uptake and biotransformation of 6,7-dimethylquinoline and 6,8-dimethylquinoline by rainbow trout (Salmo gairdneri).
PubMed: Studies on antibiotic biosynthesis by protoplasts and resting cells of Streptomyces echinatus. Part II. Effect of chromophore precursors.
PubMed: Directed biosynthesis of novel derivatives of echinomycin. II. Purification and structure elucidation.
PubMed: Directed biosynthesis of novel derivatives of echinomycin by Streptomyces echinatus. I. Effect of exogenous analogues of quinoxaline-2-carboxylic acid on the fermentation.
PubMed: Study of artificial flavouring substances for mutagenicity in the Salmonella/microsome, Basc and micronucleus tests.
PubMed: Carcinogenicities of quinoline derivatives in F344 rats.
PubMed: Toxic interaction of mixtures of two coal conversion effluent components (resorcinol and 6-methylquinoline) to Daphnia magna.
PubMed: Determination of quinomethionate (6-methylquinoline-2,3-diyldithiocarbonate) residues in crops by in situ fluorometry.
PubMed: [Production and purification of quinoline bases. 6. Modified arrangement of 6-methylquinoline-N-oxide in the 4 position].
PubMed: Some derivatives of 6-methylquinoline.
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