methyl phenyl sulfide
methylsulfanylbenzene
 
Notes:
Found in coffee. Flavouring agent for baked and meat products and seaonings. Food additive listed in the Food Additive Database (Jan. 2001)
  • Beijing Lys Chemicals
    • Beijing Lys Chemicals Co, LTD.
      From Grams to Tons
      Fine chemical high-tech company which contains R&D, production, and sales.
      BEIJING LYS CHEMICALS CO, LTD, established in 2004, is a fine chemical high-tech company which contains R&D, production, and sales. We mainly engaged in export and technology development of flavor and fragrance materials and pharmaceutical intermediates. We have nearly 500 kinds of products, from grams to tons, exported to USA, Europe, South Asia and etc. And we custom manufacture new products according to customers’ needs, and serve good quality products and service. Our goal is to become a fine chemical enterprise which could provide special products and services.
      Email: Mr. Jia
      Email: Mr. Guo
      Voice: 86-10-68418738
      Fax: 86-10-68418739
      Mr. Guo86-10-68483445
      Mr. Guo86-10-68418739
      News
      Product(s):
      10802 Methyl Phenyl Sulfide
       
  • BOC Sciences
    • BOC Sciences
      Best of Chemicals Supplier
      Quality supplier of research chemicals and biochemicals including inhibitors, building blocks, GMP Products, impurities and metabolites, APIs for Veterinary, Natural Compounds, ADCs, Stem Cell Molecule and chiral compounds.
      BOC Sciences provides a wide range of services to support the pharmaceutical industry through all stages of drug discovery including Custom Synthesis of those chemicals that are not in stock, Isotope Labeling Service, Chiral Synthesis and Resolution, Bioconjugation, PEGylation services, analytical services.
      BOC Sciences is a brand of BOCSCI Inc. We leverage our wide spectrum of business in the fields of development, manufacturing, marketing, and distribution to help you make best-informed decisions tailored to your evolving needs for premium chemicals. Our complete suite of CRO services spans the entire molecule development pipeline including contract research for target identification, building blocks, compound synthesis, biochemical and cellular analysis, preclinical animal tests, and clinical studies.
      Email: Marketing
      US Email: Marketing
      Email: Sales
      US Email: Sales
      Voice: 1-631-485-4226
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      Product(s):
      100-68-5 Thioanisole
       
  • Penta International
    • Penta International Corporation
      Chemistry innovation
      At Penta, our products and services help businesses do business better.
      For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes.
      US Email: Technical Services
      US Email: Sales
      US Voice: (973) 740-2300
      US Fax: (973) 740-1839
      Product(s):
      13-65330 METHYL PHENYL SULFIDE
       
  • TCI AMERICA
    • TCI AMERICA
      Moving Your Chemistry Forward
      We continuously strive to advance our technology.
      With East & West Coast distribution centers, count on TCI to deliver products quickly and reliably. Over 30,000 Reagents available today in benchtop to bulk quantities. We also offer custom synthesis solutions. Sign up for a TCI account today for fast and free shipping!
      Tokyo Chemical Industry Co., Ltd. (TCI) is a leading worldwide manufacturer of specialty organic chemicals founded in 1946. TCI provides organic laboratory chemicals as well as pharmaceutical, cosmetic and functional materials. More than 70 years of synthesis experience and multi-purpose plants enable TCI to offer more than 30,000 products as well as custom synthesis.
      US Email: Sales
      Email: Technical Support
      Voice: 1-800-423-8616
      Fax: 1- 888-520-1075
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      Product(s):
      T0191 Thioanisole >99.0%(GC)
       
Synonyms   Articles   Notes   Search
CAS Number: 100-68-5Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 202-878-2
FDA UNII: BB4K737YF4
Nikkaji Web: J3.592K
Beilstein Number: 1904179
MDL: MFCD00008559
CoE Number: 11533
XlogP3: 2.70 (est)
Molecular Weight: 124.20576000
Formula: C7 H8 S
NMR Predictor: Predict (works with chrome or firefox)
Category: flavoring agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist: Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
PubMed: Search
NCBI: Search
JECFA Food Flavoring: 459  methyl phenyl sulfide
DG SANTE Food Flavourings: 12.162  methyl phenyl sulfide
FEMA Number: 3873 methyl phenyl sulfide
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF):100-68-5 ; METHYL PHENYL SULFIDE
Synonyms   Articles   Notes   Search   Top
Physical Properties:
Appearance: colorless to pale yellow clear liquid (est)
Assay: 98.00 to 100.00 % 
Food Chemicals Codex Listed: No
Specific Gravity: 0.95800 to 0.96800 @  25.00 °C.
Pounds per Gallon - (est).: 7.972 to  8.055
Refractive Index: 1.53200 to 1.55100 @  20.00 °C.
Melting Point: -15.00 °C. @ 760.00 mm Hg
Boiling Point: 188.00 to  193.00 °C. @ 760.00 mm Hg
Vapor Pressure: 0.662000 mmHg @ 25.00 °C. (est)
Flash Point: 135.00 °F. TCC ( 57.22 °C. )
logP (o/w): 2.740
Soluble in:
 alcohol
 oils
 water, 442.6 mg/L @ 25 °C (est)
 water, 506 mg/L @ 25 °C (exp)
Insoluble in:
 water
Synonyms   Articles   Notes   Search   Top
Organoleptic Properties:
 
Odor Type: solvent
 
 solvent  spicy  woody  sawdust  
Odor Description:
at 0.10 % in propylene glycol. 
toluene solvent spicy woody sawdust
 
 solvent  spicy  pungent  woody  sawdust  
Odor Description:
at 0.10 % in ethyl alcohol.  
Toluene solvent, spicy, pungent, woody sawdust
Mosciano, Gerard P&F 24, No. 6, 10, (1999)
 
 
Flavor Type: solvent
 
 solvent  woody  coffee roasted coffee  
Taste Description:
at 0.02 - 0.50 ppm. 
Solventy, woody, roasted coffee
Mosciano, Gerard P&F 24, No. 6, 10, (1999)
 
Odor and/or flavor descriptions from others (if found).
 
 
Synonyms   Articles   Notes   Search   Top
Cosmetic Information:
None found
Synonyms   Articles   Notes   Search   Top
Suppliers:
Beijing Lys Chemicals
Methyl Phenyl Sulfide
BOC Sciences
For experimental / research use only.
Thioanisole
EMD Millipore
For experimental / research use only.
Methyl Phenyl Sulfide
Parchem
methyl phenyl sulfide
Penta International
METHYL PHENYL SULFIDE
Santa Cruz Biotechnology
For experimental / research use only.
Thioanisole
Sigma-Aldrich
For experimental / research use only.
Thioanisole analytical standard
TCI AMERICA
For experimental / research use only.
Thioanisole >99.0%(GC)
Tengzhou Jitian Aroma Chemiclal
Methyl Phenyl Sulfide
Synonyms   Articles   Notes   Search   Top
Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
Xn - Harmful.
R 22 - Harmful if swallowed.
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
S 02 - Keep out of the reach of children.
S 20/21 - When using do not eat, drink or smoke.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
intravenous-mouse LD50  56 mg/kg
U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#00184

oral-rat LD50  891 mg/kg
Pesticide Biochemistry and Physiology. Vol. 1, Pg. 356, 1971.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
Synonyms   Articles   Notes   Search   Top
Safety in Use Information:
Category: flavoring agents
Recommendation for methyl phenyl sulfide usage levels up to:
 not for fragrance use.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.012 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 0.40 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI): ND (μg/person/day)
Threshold of Concern:540 (μg/person/day)
Structure Class: II
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 18
Click here to view publication 18
 average usual ppmaverage maximum ppm
baked goods: 0.060001.00000
beverages(nonalcoholic): 0.200002.00000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: 0.010000.04000
fish products: --
frozen dairy: --
fruit ices: --
gelatins / puddings: 0.100001.00000
granulated sugar: --
gravies: 0.100001.00000
hard candy: --
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: 0.400004.00000
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: 0.500001.00000
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
Synonyms   Articles   Notes   Search   Top
Safety References:
European Food Safety Athority(EFSA): Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
European Food Safety Authority (EFSA) reference(s):
Flavouring Group Evaluation 8 (FGE.08)[1]: Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical group 20
View page or View pdf
Flavouring Group Evaluation 8, Revision 1 (FGE.08Rev1): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30
View page or View pdf
Scientific Opinion on Flavouring Group Evaluation 8, Revision 3 (FGE.08Rev3): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30
View page or View pdf
Scientific Opinion on Flavouring Group Evaluation 91, Revision 1 (FGE.91Rev1): Consideration of simple aliphatic and aromatic sulphides and thiols evaluated by JECFA (53rd and 68th meetings) structurally related to aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups evaluated by EFSA in FGE.08Rev3 (2011)
View page or View pdf
Scientific Opinion on Flavouring Group Evaluation 08, Revision 4 (FGE.08Rev4): Aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups from chemical groups 20 and 30
View page or View pdf
Scientific Opinion on Flavouring Group Evaluation 91, Revision 2 (FGE.91Rev2): Consideration of simple aliphatic and aromatic sulphides and thiols evaluated by the JECFA (53rd and 68th meetings) structurally related to aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups evaluated by EFSA in FGE.08Rev5 (2012)
View page or View pdf
Scientific Opinion on Flavouring Group Evaluation 91, Revision 3 (FGE.91Rev3): consideration of aliphatic, aromatic and a,-unsaturated sulfides and thiols evaluated by JECFA (53rd, 61st, 68th and 76th meetings), structurally related to substances in FGE.08Rev5
View page or View pdf
EPI System: View
AIDS Citations: Search
Cancer Citations: Search
Toxicology Citations: Search
EPA Substance Registry Services (TSCA): 100-68-5
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 7520
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 3
 methylsulfanylbenzene
Chemidplus: 0000100685
RTECS: DA6200000 for cas# 100-68-5
Synonyms   Articles   Notes   Search   Top
References:
 methylsulfanylbenzene
NIST Chemistry WebBook: Search Inchi
Pubchem (cid): 7520
Pubchem (sid): 134972860
Synonyms   Articles   Notes   Search   Top
Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS): View
CHEMBL: View
HMDB (The Human Metabolome Database): HMDB34448
FooDB: FDB012855
Export Tariff Code: 2930.90.2900
VCF-Online: VCF Volatile Compounds in Food
ChemSpider: View
FAO: Methyl phenyl sulfide
Synonyms   Articles   Notes   Search   Top
Potential Blenders and core components note
 
For Odor
anise
star anise oil CO2 extractFL/FR
balsamic
 benzoin absolute replacerFL/FR
 croton glabellus bark extractFL/FR
 frankincense absoluteFL/FR
 guaiyl acetateFL/FR
 myrrh oil CO2 extractFL/FR
 opoponax absolute (balsamodendron kafal)FL/FR
earthy
3-octanolFL/FR
floral
 lavender oilFL/FR
 mimosa absoluteFL/FR
 mimosa absolute franceFL/FR
 mimosa absolute indiaFL/FR
green
alpha-elemolFL/FR
 octanal diethyl acetalFL/FR
 perilla alcoholFL/FR
herbal
 anthemis nobilis flower oil romanFL/FR
 apium graveolens seed oilFL/FR
sweet basil absoluteFL/FR
 canarium luzonicum oilFL/FR
 clary sage oil franceFL/FR
 dill seed oilFL/FR
 dill seed oil CO2 extractFL/FR
 laurus nobilis leaf oilFL/FR
 linalyl acetateFL/FR
curled parsley seed oilFL/FR
 petroselinum crispum seed oil CO2 extractFL/FR
 salvia sclarea distillatesFL/FR
 theaspiraneFL/FR
orris
 eugenyl formateFL/FR
para-isopropyl acetophenoneFL/FR
phenolic
4-methyl-2,6-dimethoxyphenolFL/FR
2-isopropyl phenolFL/FR
spicy
 allspice berry absoluteFL/FR
 artemisia dracunculus herb oilFL/FR
 cardamom seed oil CO2 extractFL/FR
 carvacrolFL/FR
 caryophylleneFL/FR
beta-caryophylleneFL/FR
alpha-caryophyllene alcoholFL/FR
 cascarilla oil replacerFL/FR
 cassia bark oil chinaFL/FR
 cassia leaf oilFL/FR
 cinnamon bark absoluteFL/FR
 cinnamon bark oilFL/FR
 cinnamon bark oil (cinnamomum zeylanicum) indiaFL/FR
 cinnamon bark oil ceylonFL/FR
 cinnamon leaf oil ceylonFL/FR
 cinnamon oleoresin ceylonFL/FR
 clove bud absoluteFL/FR
 clove bud oilFL/FR
 clove bud oil CO2 extractFL/FR
 clove leaf oilFL/FR
 clove stem oilFL/FR
 croton eluteria bark oilFL/FR
 eugenyl acetateFL/FR
 galangal root oilFL/FR
 ginger oleoresin africaFL/FR
 ginger root oil brazilFL/FR
 ginger root oil chinaFL/FR
 grains of paradise oilFL/FR
 mace absoluteFL/FR
 mace oilFL/FR
 myristica fragrans fruit extractFL/FR
 myristica fragrans seed tinctureFL/FR
 nutmeg oilFL/FR
 nutmeg oleoresinFL/FR
black pepper absoluteFL/FR
black pepper oil CO2 extractFL/FR
 pepper tree berry absoluteFL/FR
 pepper tree berry oilFL/FR
 piper longum fruit oilFL/FR
 piper longum fruit oil CO2 extractFL/FR
(E)-tiglic acidFL/FR
 turmeric root absoluteFL/FR
 zingiber officinale root extractFL/FR
 zingiber officinale root tinctureFL/FR
terpenic
para-cymeneFL/FR
 pine needle oil dwarfFL/FR
vanilla
 vanillin propylene glycol acetalFL/FR
woody
 bornyl valerateFL/FR
 caryophyllene formateFL/FR
beta-caryophyllene oxideFL/FR
 curcuma zedoaria bark extractFL/FR
 frankincense resinoidFL/FR
(E)-germacrene DFL/FR
 guaiacwood oilFL/FR
 guaiacyl acetateFL/FR
 juniper berry oleoresinFL/FR
4-isopropyl phenolFL/FR
 sabineneFL/FR
 spicy pentanoneFL/FR
 spikenard oilFL/FR
 spikenard oil CO2 extractFL/FR
 thuja occidentalis leaf oilFL/FR
 zedoary bark oilFL/FR
 zedoary root oilFL/FR
 zedoary root oil CO2 extractFL/FR
 
For Flavor
 
No flavor group found for these
alpha-caryophyllene alcoholFL/FR
 caryophyllene formateFL/FR
 croton glabellus bark extractFL/FR
alpha-elemolFL/FR
 eugenyl formateFL/FR
(E)-germacrene DFL/FR
 grains of paradise oilFL/FR
 guaiyl acetateFL/FR
 spikenard oilFL/FR
 spikenard oil CO2 extractFL/FR
anise
star anise oil CO2 extractFL/FR
balsamic
 benzoin absolute replacerFL/FR
 myrrh oil CO2 extractFL/FR
 opoponax absolute (balsamodendron kafal)FL/FR
brown
(E)-tiglic acidFL/FR
burnt
4-isopropyl phenolFL/FR
cooling
 theaspiraneFL/FR
floral
 linalyl acetateFL/FR
fruity
 piper longum fruit oil CO2 extractFL/FR
 spicy pentanoneFL/FR
green
 canarium luzonicum oilFL/FR
 octanal diethyl acetalFL/FR
herbal
 anthemis nobilis flower oil romanFL/FR
 apium graveolens seed oilFL/FR
sweet basil absoluteFL/FR
 clary sage oil franceFL/FR
 dill seed oilFL/FR
 dill seed oil CO2 extractFL/FR
 laurus nobilis leaf oilFL/FR
 lavender oilFL/FR
curled parsley seed oilFL/FR
 petroselinum crispum seed oil CO2 extractFL/FR
 salvia sclarea distillatesFL/FR
medicinal
 frankincense absoluteFL/FR
musty
3-octanolFL/FR
nutty
 nutty thiazoleFL
phenolic
4-methyl-2,6-dimethoxyphenolFL/FR
pine
 pine needle oil dwarfFL/FR
smoky
 prosopis juliflora wood extractFL
solvent
2-isopropyl phenolFL/FR
spicy
 allspice berry absoluteFL/FR
 artemisia dracunculus herb oilFL/FR
 cardamom seed oil CO2 extractFL/FR
 carvacrolFL/FR
 caryophylleneFL/FR
beta-caryophylleneFL/FR
 cascarilla oil replacerFL/FR
 cassia bark oil chinaFL/FR
 cassia leaf oilFL/FR
 cinnamon bark absoluteFL/FR
 cinnamon bark oilFL/FR
 cinnamon bark oil (cinnamomum zeylanicum) indiaFL/FR
 cinnamon bark oil ceylonFL/FR
 cinnamon leaf oil ceylonFL/FR
 cinnamon oleoresin ceylonFL/FR
 clove bud absoluteFL/FR
 clove bud oilFL/FR
 clove bud oil CO2 extractFL/FR
 clove leaf oilFL/FR
 clove stem oilFL/FR
 croton eluteria bark oilFL/FR
 eugenyl acetateFL/FR
 galangal root oilFL/FR
 ginger oleoresin africaFL/FR
 ginger root oil brazilFL/FR
 ginger root oil chinaFL/FR
 mace absoluteFL/FR
 mace oilFL/FR
 myristica fragrans fruit extractFL/FR
 myristica fragrans seed tinctureFL/FR
 nutmeg oilFL/FR
 nutmeg oleoresinFL/FR
black pepper absoluteFL/FR
black pepper oil CO2 extractFL/FR
white pepper oleoresinFL
 pepper tree berry absoluteFL/FR
 pepper tree berry oilFL/FR
 piper longum fruit oilFL/FR
para-isopropyl acetophenoneFL/FR
 turmeric oleoresinFL
 turmeric root absoluteFL/FR
 zingiber officinale root extractFL/FR
 zingiber officinale root tinctureFL/FR
terpenic
para-cymeneFL/FR
vanilla
 vanillin propylene glycol acetalFL/FR
waxy
 mimosa absoluteFL/FR
 mimosa absolute franceFL/FR
 mimosa absolute indiaFL/FR
woody
 bornyl valerateFL/FR
beta-caryophyllene oxideFL/FR
 curcuma zedoaria bark extractFL/FR
 frankincense resinoidFL/FR
 guaiacwood oilFL/FR
 guaiacyl acetateFL/FR
 juniper berry oleoresinFL/FR
 perilla alcoholFL/FR
 sabineneFL/FR
 thuja occidentalis leaf oilFL/FR
 zedoary bark oilFL/FR
 zedoary root oilFL/FR
 zedoary root oil CO2 extractFL/FR
 
Synonyms   Articles   Notes   Search   Top
Potential Uses:
 cherryFL
 mintFL
 timber 
 whiskeyFL
 woodyFR
Synonyms   Articles   Notes   Search   Top
Occurrence (nature, food, other): note
 coffee
Search  PMC Picture
Synonyms   Articles   Notes   Search   Top
Synonyms:
 benzene, (methylthio)-
 methyl phenyl sulphide
 methyl phenyl thioether
 methyl phenylsulfide
(methyl thio) benzene
 methyl-phenyl sulfide
 methylphenylsulfide
(methylsulfanyl)benzene
 methylsulfanylbenzene
(methylthio)benzene
 phenyl methyl sulfide
 phenyl thiomethane
1-phenyl-1-thiaethane
1-phenyl-1-thioethane
 phenylthiomethane
 sulfide, methyl phenyl
(1-thiaethyl) benzene
(1-thiaethyl)benzene
 thioanisol
 thioanisole
Synonyms   Articles   Notes   Search   Top
Articles:
US Patents: 3,952,024 - Furfurylthioacetone
PubMed: Synthesis of isotopically labeled 1,3-dithiane.
US Patents: Certain 2,5-dimethyl-3-thiopyrazines
PubMed: Hypochlorous acid turn-on boron dipyrromethene probe based on oxidation of methyl phenyl sulfide.
US Patents: Flavoring agent
PubMed: Highly enantioselective oxidation of phenyl methyl sulfide and its derivatives into optically pure (S)-sulfoxides with Rhodococcus sp. CCZU10-1 in an n-octane-water biphasic system.
PubMed: Heterometallic cerium(IV) perrhenate, permanganate, and molybdate complexes supported by the imidodiphosphinate ligand [N(i-Pr2PO)2]-.
PubMed: High cell density cultivation of Pseudomonas putida strain HKT554 and its application for optically active sulfoxide production.
PubMed: The oxidative properties of a manganese(IV) hydroperoxide moiety and its relationships with the corresponding manganese(IV) oxo and hydroxo moieties.
PubMed: The use of stable isotope labelling for the analytical chemistry of drugs.
PubMed: Diruthenium(II,III) tetramidates as a new class of oxygenation catalysts.
PubMed: The effect of solvent on the catalytic properties of microperoxidase-11.
PubMed: Resolution of racemic sulfoxides with high productivity and enantioselectivity by a Rhodococcus sp. strain as an alternative to biooxidation of prochiral sulfides for efficient production of enantiopure sulfoxides.
PubMed: Synthesis and properties of chiral pyrazolidines derived from (+)-pulegone.
PubMed: Synthesis, characterization, and application of vanadium-salan complexes in oxygen transfer reactions.
PubMed: Polystyrene bound oxidovanadium(IV) and dioxidovanadium(V) complexes of histamine derived ligand for the oxidation of methyl phenyl sulfide, diphenyl sulfide and benzoin.
PubMed: Cyclodextrin inclusion compounds of vanadium complexes: structural characterization and catalytic sulfoxidation.
PubMed: Protein engineering of toluene monooxygenases for synthesis of chiral sulfoxides.
PubMed: catena-Poly[[chlorido(methyl phenyl sulfide-κS)mercury(II)]-μ-chlorido].
PubMed: Removal of malodorous organic sulfides with molecular oxygen and visible light over metal phthalocyanine.
PubMed: Synthesis, characterization, and structures of oxovanadium(V) complexes of Schiff bases of beta-amino alcohols as tunable catalysts for the asymmetric oxidation of organic sulfides and asymmetric alkynylation of aldehydes.
PubMed: Synthesis, characterization, reactivity, and catalytic potential of model vanadium(IV, V) complexes with benzimidazole-derived ONN donor ligands.
PubMed: Selective synthesis of sulfoxides from sulfides using ultrasound.
PubMed: Selective catalytic oxidation of organosulfur compounds with tert-butyl hydroperoxide.
PubMed: Effects of the environment on microperoxidase-11 and on its catalytic activity in oxidation of organic sulfides to sulfoxides.
PubMed: Fe2+-catalyzed heterolytic RO-OH bond cleavage and substrate oxidation: a functional synthetic non-heme iron monooxygenase system.
PubMed: Oxidation of organic sulfides by vanadium haloperoxidase model complexes.
PubMed: Enantioselective Sulfoxidation Catalyzed by Vanadium Haloperoxidases.
PubMed: Sulfoxidation mechanism of vanadium bromoperoxidase from Ascophyllum nodosum. Evidence for direct oxygen transfer catalysis.
PubMed: Reactions of sulfides with S-330, a potential decontaminant of sulfur mustard in formulations.
PubMed: Chloroperoxidase-catalyzed enantioselective oxidation of methyl phenyl sulfide with dihydroxyfumaric acid/oxygen or ascorbic acid/oxygen as oxidants.
PubMed: Oxidation reactions by prostaglandin cyclooxygenase-hydroperoxidase.
PubMed: Deuterium isotope effects during formation of phenols by hepatic monoxygenases. Evidence for an alternative to arene oxide pathway.
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