(Z)-3-hexen-1-yl cinnamate
cis-3-hexenyl cinnamate
 
Notes:
None found
  • Bedoukian Research
    • Bedoukian Research, Inc.
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      Working closely with our customers to meet their requirements.
      Paul Bedoukian founded the company to fill a niche as a supplier of high quality specialty aroma and flavor ingredients. In 1975 the company began manufacturing insect pheromones which are chemically similar to flavor and fragrance ingredients. Today, Bedoukian Research offers more than 450 Aroma Chemicals and 50 Insect Pheromones, while also providing custom manufacturing services to the pharmaceutical, agrochemical, and specialty chemical industries.
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      Product(s):
      109 cis-3-HEXENYL CINNAMATE ≥98.0% (cis), Kosher
      SDS
      Blends very well with galbanum and other herbaceous oils.
       
       
  • Penta International
    • Penta International Corporation
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      For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes.
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      Product(s):
      08-32700 CIS-3-HEXENYL CINNAMATE
       
  • Prodasynth
    • Prodasynth
      PRODUCTEUR PAR ESSENCE
      Chemical specialist in manufacturing, distributing and sourcing of tailor-made ingredients for the Flavour & Fragrance industry.
      Today we are also proud to say, we have created an important range of Natural Molecules which can be found in our Raw Material Compendium. The versatility of our small but efficient structure is one of our main strengths when trying to fulfill our clients' requirements.
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      Product(s):
      CIS-3-HEXENYL CINNAMATE (> 99%)
       
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CAS Number: 68133-75-5Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 268-702-1
Nikkaji Web: J184.133E
MDL: MFCD00036532
XlogP3: 4.40 (est)
Molecular Weight: 230.30686000
Formula: C15 H18 O2
NMR Predictor: Predict (works with chrome or firefox)
Category: fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
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Physical Properties:
Appearance: colorless clear liquid (est)
Assay: 98.00 to 100.00 % sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity: 1.00100 to 1.01100 @  25.00 °C.
Pounds per Gallon - (est).: 8.329 to  8.413
Refractive Index: 1.54400 to 1.55400 @  20.00 °C.
Boiling Point: 170.00 °C. @ 5.00 mm Hg
Vapor Pressure: 0.000060 mmHg @ 25.00 °C. (est)
Vapor Density: >1 ( Air = 1 )
Flash Point: 230.00 °F. TCC ( 110.00 °C. )
logP (o/w): 4.508 (est)
Soluble in:
 alcohol
 water, 3.592 mg/L @ 25 °C (est)
Insoluble in:
 water
Similar Items: note
allyl cinnamate
amyl cinnamate
isoamyl cinnamate
benzyl cinnamate
butyl cinnamate
isobutyl cinnamate
cinnamyl cinnamate
citronellyl cinnamate
cyclohexyl cinnamate
ethyl alpha-acetyl cinnamate
ethyl cinnamate
heptyl cinnamate
hexyl cinnamate
linalyl cinnamate
methyl cinnamate
octyl cinnamate
phenethyl cinnamate
3-phenyl propyl cinnamate
propyl cinnamate
isopropyl cinnamate
terpinyl cinnamate
tetrahydrofurfuryl cinnamate
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Organoleptic Properties:
 
Odor Type: balsamic
 
Odor Strength: medium
 
 fresh  balsamic  green  
Odor Description:
at 100.00 %. 
fresh balsam green
 
Odor and/or flavor descriptions from others (if found).
 
Bedoukian Research
cis-3-HEXENYL CINNAMATE ≥98.0% (cis), Kosher
Odor Description: Fresh, balsamic, green odor
Blends very well with galbanum and other herbaceous oils.
 
Prodasynth
CIS-3-HEXENYL CINNAMATE (> 99%)
Odor Description: FRESH, BALSAMIC, GREEN
 
 
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Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: perfuming agents
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Suppliers:
Apple Flavor & Fragrance
cis-3-Hexenyl cinnamate
Bedoukian Research
cis-3-HEXENYL CINNAMATE
≥98.0% (cis), Kosher
Odor: Fresh, balsamic, green odor
Use: Blends very well with galbanum and other herbaceous oils.
Penta International
CIS-3-HEXENYL CINNAMATE
Prodasynth
CIS-3-HEXENYL CINNAMATE
(> 99%)
Odor: FRESH, BALSAMIC, GREEN
Santa Cruz Biotechnology
For experimental / research use only.
cis-3-Hexen-1-yl Cinnamate
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Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
None - None found.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: fragrance agents
maximum skin levels for fine fragrances:
  0.0800 %  and are based on the assumption that the fragrance mixture is used at 20% in a consumer product (IFRA Use Level Survey). (IFRA, 2001)
Recommendation for (Z)-3-hexen-1-yl cinnamate usage levels up to:
  4.0000 % in the fragrance concentrate.
Dermal Systemic Exposure in Cosmetic Products:
 0.0178 mg/kg/day (IFRA, 2001)
 
Recommendation for (Z)-3-hexen-1-yl cinnamate flavor usage levels up to:
 not for flavor use.
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Safety References:
EPI System: View
EPA Substance Registry Services (TSCA): 68133-75-5
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 5744267
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 3
 [(E)-hex-3-enyl] (E)-3-phenylprop-2-enoate
Chemidplus: 0068133755
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References:
 [(E)-hex-3-enyl] (E)-3-phenylprop-2-enoate
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 68133-75-5
Pubchem (cid): 5744267
Pubchem (sid): 135256850
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Other Information:
(IUPAC): Atomic Weights of the Elements 2009
(IUPAC): Atomic Weights of the Elements 2009 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
HMDB (The Human Metabolome Database): Search
Export Tariff Code: 2916.39.0002
ChemSpider: View
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Potential Blenders and core components note
 
For Odor
No odor group found for these
 cinnamyl salicylate 
 cinnamyl valerateFL/FR
balsamic
 betula pubescens bud oilFL/FR
isobutyl cinnamateFL/FR
 cinnamyl alcoholFL/FR
 cinnamyl benzoateFL/FR
 cinnamyl butyrateFL/FR
 cinnamyl cinnamateFL/FR
 cotinus coggygria branch/leaf oilFL/FR
 ethyl cinnamateFL/FR
 linalyl cinnamateFL/FR
 octyl cinnamateFR
 peru balsam oilFL/FR
 peru balsam resinoidFL/FR
2-phenoxyethyl formateFR
black poplar bud oleoresinFL/FR
 tetrahydrofurfuryl cinnamateFL/FR
 valerian rhizome absoluteFL/FR
caramellic
 mesitene lactoneFR
floral
 cinnamyl phenyl acetateFL/FR
 cyclohexyl salicylateFR
(Z,E)-phytolFL/FR
fruity
 cinnamyl hexanoateFL/FR
 cinnamyl isobutyrateFL/FR
green
 galbanum absoluteFL/FR
herbal
 canarium luzonicum oilFL/FR
spicy
alpha-amyl cinnamyl alcoholFL/FR
 cinnamyl acetateFL/FR
 cinnamyl isovalerateFL/FR
 cinnamyl propionateFL/FR
woody
 cinnamyl tiglateFL/FR
 woody acetateFR
 
For Flavor
 
No flavor group found for these
 betula pubescens bud oilFL/FR
 cinnamyl benzoateFL/FR
 cinnamyl hexanoateFL/FR
 cinnamyl phenyl acetateFL/FR
 cinnamyl salicylate 
 cinnamyl tiglateFL/FR
 cinnamyl valerateFL/FR
 cotinus coggygria branch/leaf oilFL/FR
 methyl furfuracrylateFL
black poplar bud oleoresinFL/FR
 tetrahydrofurfuryl cinnamateFL/FR
balsamic
isobutyl cinnamateFL/FR
 ethyl cinnamateFL/FR
 peru balsam oilFL/FR
 peru balsam resinoidFL/FR
(Z,E)-phytolFL/FR
floral
 cinnamyl propionateFL/FR
fruity
 cinnamyl isobutyrateFL/FR
 cinnamyl isovalerateFL/FR
 linalyl cinnamateFL/FR
 valerian rhizome absoluteFL/FR
green
 canarium luzonicum oilFL/FR
 cinnamyl alcoholFL/FR
 galbanum absoluteFL/FR
spicy
alpha-amyl cinnamyl alcoholFL/FR
 cinnamyl acetateFL/FR
 cinnamyl cinnamateFL/FR
winey
 cinnamyl butyrateFL/FR
 
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Potential Uses:
 balsamFR
 fresh and cleanFR
 fruitFR
 greenFR
 herbalFR
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Occurrence (nature, food, other): note
 not found in nature
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Synonyms:
 hex-3-enyl (Z)-cinnamate
[(E)-hex-3-enyl] (E)-3-phenylprop-2-enoate
(Z)-3-hexen-1-yl cinnamate
cis-3-hexen-1-yl cinnamate
(Z)-3-hexenyl 3-phenyl-2-propenoate
(Z)-3-hexenyl cinnamate
cis-3-hexenyl cinnamate
3-phenyl-2-propenoic acid (3Z)-3-hexen-1-yl ester
2-propenoic acid, 3-phenyl-, (3Z)-3-hexen-1-yl ester
2-propenoic acid, 3-phenyl-, (3Z)-3-hexenyl ester
2-propenoic acid, 3-phenyl-, 3-hexenyl ester, (?,Z)-
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