Articles:
Notes:
Blends well with woody notes. Gives good body.
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Azelis UK Life Sciences Chemical Distribution Azelis is a leading global distributor of speciality chemicals. Azelis is a leading global speciality chemicals distributor. We provide a diverse range of products and innovative services to more than 20,000 customers. Our in-depth local knowledge is supported by an international structure and value-added services including high levels of technical support and tailored solutions. Email: Graham Bott Voice: +32 3 613 01 20 Fax: +32 3 613 01 21 United Kingdom +44 (0) 1992 82 55 55 United Kingdom +44 (0) 1992 82 55 66 Product(s): METHYL IONONE GAMMA
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Berjé Inc. The solution is clear Where the world comes to its senses - Berjé is a global distributor of Essential Oils and Aromatic Chemicals. Berjé is a family-owned business that has been in operation for six decades. The company's origins and strength lie in a profound understanding of the supply and the quality of the diverse raw materials consumed by the flavor and fragrance industries. This base was expanded upon more than two decades ago to include fragrance production. The company's unparalleled raw material expertise is focused on the supply of essential oils and aromatic chemicals. This is supported by our long-standing relationships with a worldwide fabric of producers ensuring the greatest prospects for uninterrupted supply in markets that are often volatile and unpredictable. Email: For Information Email: For Sales Voice: 973-748-8980 Fax: 973-680-9618 Product(s): Methyl Ionone Gamma
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Fleurchem, Inc. Have A Flavorful Day A leading global manufacturer and supplier of ingredients for Flavors, Fragrances, AromaTherapy, Foods, Beverages, Personal Care Products, and other uses. Operating out of the 200,000 sq. ft., former Hercules/PFW facility in Middletown, NY; Fleurchem produces a full range of natural isolates, synthetic chemicals & specialities, essential oils and flavors. Additionally, the company performs toll manufacturing, as well as custom chemical synthesis for a wide range of clients. Email: Information US Voice: 845-341-2100 US Fax: 845-341-2121 Product(s): ionone, gamma methyl
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Lansdowne Chemicals With a focus on providing the highest level of service Lansdowne Chemicals has established itself at the forefront of the global chemical industry. Headquarters are in Carterton, Oxfordshire encompassing all of Lansdowne's Business Units. Our Regulatory Team and Quality Control Departments are based out of Carterton. Lansdowne Aromatic's state of the art warehouse facilities are located in Cricklade, covering 12,000 square ft. We are able to offer just-in-time deliveries for our full range of products, in a variety of pack sizes. Bonded facilities are available for goods going outside of the EU. Email: Contact Us: US Email: Dean Matienzo - Sales Manager Voice: +44 1993 843081 Fax: +44 1993 841261 US Voice: +1 973 886 3778 US Fax: +1 973 346 1106 Product(s): Methyl Ionone Pure
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Penta International Corporation Chemistry innovation At Penta, our products and services help businesses do business better. For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes. US Email: Technical Services US Email: Sales US Voice: (973) 740-2300 US Fax: (973) 740-1839 Product(s): 13-52700 METHYL IONONE GAMMA REGULAR, Kosher 13-52701 METHYL IONONE GAMMA EXTRA, Kosher
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Phoenix Aromas & Essential Oils, Inc. EXCEPTIONAL Flavor and Fragrance Ingredients Phoenix sources the finest flavor and fragrance ingredients for its customers. Phoenix Aromas & Essential Oils LLC was founded in 1994, grounded in a simple set of core values: provide top-quality products, cost-effective pricing and personalized attention to all our customers. After two decades, we remain committed to those values. With extensive market knowledge of our products, we anticipate, as opposed to merely react, to industry challenges. You can rely on us for all your flavor and fragrance ingredient needs. Customers benefit from Phoenix's long-standing relationships with experienced and reputable growers, processors and manufacturers in key global locations, who are committed to sustainability and green programs. With a strategically located 80,000 sq-ft facility, customers can rely on Phoenix to deliver quality products on time, and cost-effectively. Email: EU Info US Email: Info US Email: Kristina Streva Voice: +44(0) 208 532 1022 Fax: +44(0) 208 532 1023 US Voice: 201-784-6100 US Fax: 201-784-8566 Product(s): Gamma-Methyl Ionone
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SRS Aromatics Ltd For over 25 years Bringing flavour and fragrance into your world. As suppliers / distributors of ingredients to the fragrance and flavour industries, our goal is to provide high quality materials at competitive prices with an exceptional level of service. Established in 1984, SRS Aromatics Ltd is an independent family owned business which has become very well-respected within the fragrance and flavour industry as a reliable and trustworthy partner. Over the years this has allowed the company to develop strong relationships with many global manufacturers; several of whom we represent in the UK. A core aim of our business is to work extremely closely with both our suppliers and customers to maximise service levels with minimum disruption to supply. Email: Info Email: Sales Voice: +44 (0) 1284 704076 Fax: +44 (0) 1284 760819 Product(s): METHYL IONONE GAMMA METHYL IONONE GAMMA 90 D METHYL IONONE GAMMA D
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The John D. Walsh Company, Inc Suppliers Since 1942 Supplying the fragrance and flavor industry with high quality products. The John D. Walsh Company, Inc. has evolved from its beginnings as an agent/broker into a distributor of essential oils, aroma chemicals, concretes and absolutes. We currently represent the following companies, as their North American distributor: Destilerias Munoz Galvez, S.A. International Flavors & Fragrances PFW Aroma Chemicals B.V. Innospec Widnes Limited Hydrodiffusion de Guatemala, S. A. DSM Nutritional Products The John D. Walsh Company, Inc. is proud to be a founding member of IFEAT, an active member of IFRA, North America, and a corporate sponsor of the WFFC. Email: Information Email: Sales Email: Firmenich Flavor inquiries Voice: 973-962-1400 Fax: 973-962-1557 Firmenich Flavor Phone: 973-962-1888 Firmenich Flavor Fax: 973-962-1898 Product(s): Methyl Ionone Gamma Methyl Ionone Gamma Coeur Methyl Ionone Gamma Extra Methyl Ionone Gamma Pure Methyl Ionone Gamma 70 MSDS
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Treatt PLC Full Range of Naturals World-leading, independent ingredients supplier to the flavour and fragrance industries. We are proud of our heritage in trading essential oils. Our founder Richard Court Treatt's charismatic and personable approach still embodies the spirit of Treatt today. Email: Enquiries US Email: Enquiries Voice: +44 (0) 1284 702500 Fax: +44 (0) 1284 703809 US Voice: +1 863 668 9500 US Fax: +1 863 668 3388 Product(s): Alpha-isoMethyl Ionone
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| Fragrance Demo Formulas Flavor Demo Formulas | |
| (E)-3-methyl-4-(2,6,6-trimethyl-1-cyclohex-2-enyl)but-3-en-2-one (50% min.) (Click)
IUPAC Name: (E)-3-methyl-4-(2,6,6-trimethyl-1-cyclohex-2-enyl)but-3-en-2-one (50% min.)
Std.InChI: InChI=1S/C14H22O/c1-10-7-6-8-14(4,5)13(10)9-11(2)12(3)15/h7,9,13H,6,8H2,1-5H3/b11-9+
InChI: InChI=1/C14H22O/c1-10-7-6-8-14(4,5)13(10)9-11(2)12(3)15/h7,9,13H,6,8H2,1-5H3/b11-9+
Std.InChIKey: JRJBVWJSTHECJK-PKNBQFBNSA-N
InChIKey: JRJBVWJSTHECJK-PKNBQFBNBZ
SMILES: CC1=CCCC(C1/C=C(\C)/C(=O)C)(C)C
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| CAS Number: | 127-51-5 |
| % from: | 50.00% to 59.00% |
| ECHA EC Number: | 204-846-3 |
| FDA UNII: | 9XP4LC555B |
| FEMA Number: | 2714 |
| CoE Number: | 169 |
| XlogP3-AA: | 3.30 (est) |
| Molecular Weight: | 206.32854000 |
| Formula: | C14 H22 O |
| NMR Predictor: | Predict |
| Also(can) Contains: | (E)-alpha-methyl ionone (74-80%) 14.00% to 31.00% |
| beta-isomethyl ionone 3.00% to 7.00% | |
| (E)-beta-methyl ionone 1.00% to 4.00% | |
| pseudomethyl ionone 0.10% to 2.00% | |
| Category: | flavor and fragrance agents |
| US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: | |
| Google Scholar: | Search |
| Google Books: | Search |
| Google Scholar: with word "volatile" | Search |
| Google Scholar: with word "flavor" | Search |
| Google Scholar: with word "odor" | Search |
| Perfumer and Flavorist: | Search |
| Google Patents: | Search |
| US Patents: | Search |
| EU Patents: | Search |
| Pubchem Patents: | Search |
| JECFA Food Flavoring: | 404 alpha-isomethylionone (50% min.) |
| Flavis Number: | 07.036 (Old) |
| EU SANCO Food Flavourings: | 07.036 alpha-isomethyl ionone |
| FEMA Number: | 2714 alpha-isomethylionone (50% min.) |
| FDA Mainterm: | ALPHA-ISOMETHYLIONONE |
| FDA Regulation: | |
| FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION Subpart F--Flavoring Agents and Related Substances Sec. 172.515 Synthetic flavoring substances and adjuvants. | |
Physical Properties:
| Appearance: | colorless to yellow clear oily liquid (est) |
| Assay: | 98.00 to 100.00 % sum of isomers |
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.92500 to 0.93500 @ 25.00 °C. |
| Pounds per Gallon - (est).: | 7.697 to 7.780 |
| Refractive Index: | 1.49650 to 1.50400 @ 20.00 °C. |
| Boiling Point: | 76.00 °C. @ 0.30 mm Hg |
| Boiling Point: | 231.00 to 232.00 °C. @ 760.00 mm Hg |
| Acid Value: | 1.00 max. KOH/g |
| Vapor Pressure: | 0.006000 mm/Hg @ 20.00 °C. |
| Vapor Density: | 7.0 ( Air = 1 ) |
| Flash Point: | > 212.00 °F. TCC ( > 100.00 °C. ) |
| logP (o/w): | 4.315 |
| Shelf Life: | 36.00 month(s) or longer if stored properly. |
| Storage: | store in cool, dry place in tightly sealed containers, protected from heat and light. |
Organoleptic Properties:
| Odor Type: | floral |
| Odor Strength: | medium , recommend smelling in a 10.00 % solution or less |
| Odor Description: at 10.00 % in dipropylene glycol. | violet sweet orris powdery floral woody Luebke, William tgsc, (1985) |
| Odor sample from: | Union Camp Corporation |
| Substantivity: | 124 Hour(s) |
Cosmetic Information:
| CosIng: | cosmetic data |
| Cosmetic Uses: |
perfuming agents skin conditioning |
Suppliers:
| Augustus Oils |
| Methyl Ionone |
| Azelis |
| METHYL IONONE GAMMA |
| Berjé |
| Methyl Ionone Gamma |
| CG Herbals |
| Methyl Ionone
Odor: Woody, floral, violet, orris Use: Used in many floral fragrances, particularly violet. Blends with and support woody, leathery, and oriental accords. |
| Fleurchem |
| ionone, gamma methyl |
| Global Essence |
| Methyl Ionone Gamma |
| IFF |
| METHYL IONONE GAMMA A
Odor: Woody, Floral, Violet Use: Woody, tobacco, floral (orris and violet). Powdery tone. Great strength as both top and body notes. Excellent performance to cost ratio. |
| IFF |
| METHYLYL IONONE GAMMA PURE
Odor: Woody, Floral, Violet Use: Woody, tobacco, floral (orris and violet). Powdery tone. Great strength as both top note and body notes. Excellent performance to cost ratio. |
| Kun Shan P&A |
| Methyl Ionone Gamma A |
| Kun Shan P&A |
| Methyl Ionone Gamma Coeur |
| Lansdowne Chemicals |
| Methyl Ionone Pure |
| Miltitz Aromatics |
| METHYLIONONE GAMMA 90D
min. 85 % Odor: Fine violet character Use: Extremely versatile, may be used as modifier, supporter and blender for floral, woody and leather notes. |
| Miltitz Aromatics |
| METHYLIONONE GAMMA D
min. 60 – 70 % Odor: Mild flowery, woody violet note, somewhat orris-like and dry Use: METHYLIONONE GAMMA D is widely used in floral, woody and oriental compositions for imparting volume and substantivity. Main uses are in household and cosmetic products as well as in fine fragrances. |
| Penta International |
| METHYL IONONE GAMMA EXTRA, Kosher |
| Penta International |
| METHYL IONONE GAMMA REGULAR, Kosher |
| Phoenix Aromas & Essential Oils |
| Gamma-Methyl Ionone |
| Privi Organics |
| Violetone Coeur |
| SRS Aromatics |
| METHYL IONONE GAMMA 90 D |
| SRS Aromatics |
| METHYL IONONE GAMMA D |
| SRS Aromatics |
| METHYL IONONE GAMMA |
| Taytonn |
| Methyl Ionone Gamma A
Odor: Floral, Powder/ Powdery, Tobacco, Woody |
| The John D. Walsh Company |
| Methyl Ionone Gamma 70 |
| The John D. Walsh Company |
| Methyl Ionone Gamma Coeur |
| The John D. Walsh Company |
| Methyl Ionone Gamma Extra |
| The John D. Walsh Company |
| Methyl Ionone Gamma Pure |
| The John D. Walsh Company |
| Methyl Ionone Gamma |
| Treatt |
| Alpha-isoMethyl Ionone |
Safety Information:
| European information : | |||
| Most important hazard(s): | |||
| Xi N - Irritant, Dangerous for the environment. | |||
|
R 38 - Irritating to skin. R 43 - May cause sensitisation by skin contact. R 51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S 02 - Keep out of the reach of children. S 37 - Wear suitable gloves. | |||
| Hazards identification | |||
| Classification of the substance or mixture | |||
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |||
| Skin sensitisation (Category 1), H317 | |||
| GHS Label elements, including precautionary statements | |||
| Pictogram |  | ||
| Signal word | Warning | ||
| Hazard statement(s) | |||
| H317 - May cause an allergic skin reaction | |||
| Precautionary statement(s) | |||
| P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P272 - Contaminated work clothing should not be allowed out of the workplace. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P302 + P352 - IF ON SKIN: wash with plenty of soap and water. P333 + P313 - IF SKIN irritation or rash occurs: Get medical advice/attention. P363 - Wash contaminated clothing before reuse. P501 - Dispose of contents/ container to an approved waste disposal plant. | |||
| Oral/Parenteral Toxicity: | |||
|
oral-rat LD50 > 5000 mg/kg Dispose of contents/ container to an approved waste disposal plant. | |||
| Dermal Toxicity: | |||
|
skin-rabbit LD50 > 5000 mg/kg Dispose of contents/ container to an approved waste disposal plant. | |||
| Inhalation Toxicity: | |||
| Not determined | |||
Safety in Use Information:
| Category: | flavor and fragrance agents | ||
| IFRA Critical Effect: | Sensitization | ||
| IFRA Other Specification: | <= 2% Pseudomethylionone | ||
| IFRA: | View Standard | ||
| Fragrance usage is IFRA RESTRICTED. View Standard for complete information. | |||
| Please review all IFRA documents for complete information. | |||
| IFRA categories: limits in the finished product: (For a description of the categories, refer to the IFRA QRA Information Booklet.) | |||
| Category 1: See Note (1) | 2.00 % (1) | ||
| Category 2: | 2.60 % | ||
| Category 3: | 10.60 % | ||
| Category 4: | 31.70 % | ||
| Category 5: | 16.70 % | ||
| Category 6: | 50.70 % (1) | ||
| Category 7: | 5.30 % | ||
| Category 8: | 2.00 % | ||
| Category 9: | 5.00 % | ||
| Category 10: | 2.50 % | ||
| Category 11: | See Note (2) | ||
| Notes: | |||
For this material, for pragmatic reasons, restrictive levels allowed by the QRA for certain categories but actually being higher than those already in place before applying the QRA, will temporarily not be implemented until the end of a 5 year monitoring phase. At the end of the 5 years the position will be reevaluated again. | |||
(1) IFRA would recommend that any material used to impart perfume or flavour in products intended for human ingestion should consist of ingredients that are in compliance with appropriate regulations for foods and food flavourings in the countries of planned distribution and, where these are lacking, with the recommendations laid down in the Code of Practice of IOFI (International Organisation of the Flavor Industry). Further information about IOFI can be found on its website (www.iofi.org). | |||
(2) Category 11 includes all non-skin contact or incidental skin contact products. Due to the negligible skin contact from these types of products there is no justification for a restriction of the concentration of this fragrance ingredient in the finished product. | |||
| Recommendation for alpha-isomethyl ionone (50% min.) flavor usage levels up to: | |||
| 25.0000 ppm in the finished product. | |||
Safety References:
| European Food Safety Authority (EFSA) reference(s): | |
| Flavouring Group Evaluation 213: alpha,beta-Unsaturated alicyclic ketones and precursors from chemical subgroup 2.7 of FGE.19 page or pdf | |
| Flavouring Group Evaluation 210: alpha,beta-Unsaturated alicyclic ketones and precursors from chemical subgroup 2.4 of FGE.19[1] page or pdf | |
| EPI System: | View |
| Chemicalize.org: | Calculate predicted properties |
| EPA Substance Registry Services (TSCA): | 127-51-5 |
| EPA ACToR: | Toxicology Data |
| National Institute of Allergy and Infectious Diseases: | Data |
| SCCNFP: | opinion |
| WGK Germany: | 2 |
| (E)-3-methyl-4-(2,6,6-trimethyl-1-cyclohex-2-enyl)but-3-en-2-one (50% min.) | |
| Chemidplus: | 0000127515 |
References:
| Leffingwell: | chirality |
| (E)-3-methyl-4-(2,6,6-trimethyl-1-cyclohex-2-enyl)but-3-en-2-one (50% min.) | |
| NIST Chemistry WebBook: | Search Inchi |
| Canada Domestic Sub. List: | 127-51-5 |
| Pubchem (cid): | 5372174 |
| Pubchem (sid): | 135016869 |
Other Information:
| (IUPAC): | Atomic Weights of the Elements 2009 |
| (IUPAC): | Atomic Weights of the Elements 2009 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| FDA Everything Added to Food in the United States (EAFUS): | View |
| Export Tariff Code: | 2914.23.0000 |
| ChemSpider: | View |
Potential Blenders and core components note
| animal carbolactone | FR | |
| calamus root oil | FR | |
| cardamom seed oil | FL/FR | |
| wild | carrot seed oil | FL/FR |
| cassie absolute | FL/FR | |
| cedarwood oil virginia | FR | |
| cedrela wood oil | FR | |
| clary sage oil france | FL/FR | |
| copaiba balsam oil | FL/FR | |
| costus root oil | FL | |
| costus valerolactone | FR | |
| dihydrojasmone | FL/FR | |
| elecampane root absolute | FL | |
| iso | eugenyl acetate | FL/FR |
| frankincense oil | FL/FR | |
| heliotropyl acetone | FL/FR | |
| hexyl 2-methyl butyrate | FL/FR | |
| hydroxycitronellal | FL/FR | |
| juniper berry oil | FL/FR | |
| labdanum resinoid | FR | |
| iso | longifolene epoxide | FR |
| methyl cedryl ketone | FL/FR | |
| mimosa absolute france | FL/FR | |
| nerolidol | FL/FR | |
| opoponax oil (balsamodendron kafal) | FL/FR | |
| orris rhizome absolute (iris pallida) | FL/FR | |
| phenethyl anthranilate | FL/FR | |
| allspice berry oil | FL/FR | |
| rosemary oil spain | FL/FR | |
| sandalwood oil | FL/FR | |
| amchoor powder | ||
| turmeric root oil china | FL/FR | |
| watermelon ketone | FR |
Potential Uses:
| anais anais | ||
| beeswax cire d'abeille | FL/FR | |
| berry | FR | |
| blueberry | FR | |
| cassia | FR | |
| charlie | ||
| chloe | ||
| chypre | FR | |
| cranberry | FR | |
| cyclamen | FR | |
| diffusion | ||
| estee | ||
| fidji | ||
| fir needle pine needle | FL/FR | |
| floral | FR | |
| fruit | FR | |
| genet genista broom | FR | |
| l'air du temps | ||
| l'heure bleue | ||
| l'origan | ||
| leather | FR | |
| leather russian | FR | |
| mimosa | FR | |
| norell | ||
| oakmoss mousse de chene moss | FR | |
| oriental | FR | |
| paris | ||
| patchouli | FR | |
| prune | FR | |
| raspberry | FR | |
| rose | FR | |
| strawberry | FR | |
| vika cologne | ||
| violet | FR |
Natural Occurrence in: note
| not found in nature |
Synonyms:
| 3- | buten-2-one, 3-methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-, (3E)- | ||
| gammanolene | |||
| iraldeine gamma | |||
| iso | iraldeine pure | ||
| irisantheme | |||
| alpha-iso | methyl ionone | ||
| iso-alpha- | methyl ionone | ||
| gamma- | methyl ionone (so called) | ||
| methyl ionone gamma | |||
| methyl ionone gamma A | |||
| methyl ionone gamma coeur | |||
| methyl ionone gamma extra | |||
| methyl ionone gamma pure | |||
| methyl ionone gamma regular | |||
| methyl ionone gamma supreme | |||
| methyl ionone gamma suprime | |||
| (E)-3- | methyl-4-(2,6,6-trimethyl-1-cyclohex-2-enyl)but-3-en-2-one (50% min.) | ||
| (3E)-3- | methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one | ||
| 3- | methyl-4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-3-buten-2-one | ||
| (E)-3- | methyl-4-(2,6,6-trimethyl-cyclohex-2-enyl)-but-3-en-2-one | ||
| (3E)-3- | methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-one | ||
| (3E)-3- | methyl-4-(2,6,6-trimethylcyclohex-2-enyl)but-3-en-2-one | ||
| alpha-iso | methylionone (50% min.) | ||
| methylionone gamma D | |||
| methylyl ionone gamma pure | |||
| raldeine gamma | |||
| 4,2,6,6- | trimethyl-2-cyclohexen-1-yl-3-methyl-3-buten-2-one |
click on the picture(s) below to interact with the 3D model | |
| |
| Soluble in: | |
| alcohol | |
| dipropylene glycol | |
| paraffin oil | |
| water, 2.98 mg/L @ 25 °C (est) | |
| Insoluble in: | |
| water | |
| Stability: | |
| acid cleaner | |
| alcoholic lotion | |
| deo stick | |
| detergent perborate | |
| fabric softener | |
| hair spray | |
| hard surface cleaner | |
| liquid detergent | |
| non-discoloring in most media | |
| shampoo | |
| soap | |