Articles:
(3R,4S,8S)-3,9-epoxy-1-p-menthene
Notes:
from dill weed oil of plant, anethum graveolens l.. Isol. from the leaf oil of Anethum graveolens (dill) [CCD] This is the natural occuring form of dill ether [FooDB]
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Chemical sources Association Inc Exchange of knowledge Need This Item for Flavor? You can contact the Chemical Sources Association. Events Links Product(s):
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| CAS Number: | 74410-10-9 |  3D/inchi
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| FDA UNII: | 2UX44R1B15 | |
| Nikkaji Web: | J487.723C | |
| XlogP3-AA: | 1.90 (est) | |
| Molecular Weight: | 152.23672000 | |
| Formula: | C10 H16 O | |
| NMR Predictor: | Predict (works with chrome or firefox) | |
Category: flavoring agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
| Google Scholar: | Search |
| Google Books: | Search |
| Google Scholar: with word "volatile" | Search |
| Google Scholar: with word "flavor" | Search |
| Google Scholar: with word "odor" | Search |
| Perfumer and Flavorist: | Search |
| Google Patents: | Search |
| US Patents: | Search |
| EU Patents: | Search |
| Pubchem Patents: | Search |
| PubMed: | Search |
| NCBI: | Search |
Physical Properties:
| Food Chemicals Codex Listed: | No |
| Boiling Point: | 207.00 to 208.00 °C. @ 760.00 mm Hg |
| Vapor Pressure: | 0.331000 mmHg @ 25.00 °C. (est) |
| Flash Point: | 164.00 °F. TCC ( 73.33 °C. ) |
| logP (o/w): | 2.815 (est) |
| Soluble in: | |
| alcohol | |
| water, 184.4 mg/L @ 25 °C (est) | |
| Insoluble in: | |
| water | |
Organoleptic Properties:
| Odor Strength: | medium , recommend smelling in a 10.00 % solution or less |
| Odor Description: at 10.00 % in dipropylene glycol. | dill |
| Odor and/or flavor descriptions from others (if found). | |
Cosmetic Information:
| None found |
Suppliers:
| Parchem |
| (3S,3aS,7aR)-Dill Ether |
| Chemical Sources Association |
| Need This Item for Flavor/Food?: You can contact the CSA |
Safety Information:
| Hazards identification | |
| Classification of the substance or mixture | |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |
| None found. | |
| GHS Label elements, including precautionary statements | |
| Pictogram | |
| Hazard statement(s) | |
| None found. | |
| Precautionary statement(s) | |
| None found. | |
| Oral/Parenteral Toxicity: | |
| Not determined | |
| Dermal Toxicity: | |
| Not determined | |
| Inhalation Toxicity: | |
| Not determined | |
Safety in Use Information:
| Category: | flavoring agents | ||
| Recommendation for (3S,3aS,7aR)-dill ether usage levels up to: | |||
| not for fragrance use. | |||
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). | |||
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library | |||
| publication number: 23 | |||
| average usual ppm | average maximum ppm | ||
| baked goods: | 100.00000 | 500.00000 | |
| beverages(nonalcoholic): | - | - | |
| beverages(alcoholic): | - | - | |
| breakfast cereal: | - | - | |
| cheese: | 25.00000 | 125.00000 | |
| chewing gum: | - | - | |
| condiments / relishes: | 25.00000 | 125.00000 | |
| confectionery froastings: | - | - | |
| egg products: | - | - | |
| fats / oils: | 50.00000 | 250.00000 | |
| fish products: | - | - | |
| frozen dairy: | - | - | |
| fruit ices: | - | - | |
| gelatins / puddings: | - | - | |
| granulated sugar: | - | - | |
| gravies: | 50.00000 | 250.00000 | |
| hard candy: | - | - | |
| imitation dairy: | 50.00000 | 250.00000 | |
| instant coffee / tea: | - | - | |
| jams / jellies: | - | - | |
| meat products: | 25.00000 | 125.00000 | |
| milk products: | - | - | |
| nut products: | - | - | |
| other grains: | - | - | |
| poultry: | 25.00000 | 125.00000 | |
| processed fruits: | - | - | |
| processed vegetables: | 25.00000 | 125.00000 | |
| reconstituted vegetables: | 25.00000 | 125.00000 | |
| seasonings / flavors: | 500.00000 | 5000.00000 | |
| snack foods: | 50.00000 | 250.00000 | |
| soft candy: | - | - | |
| soups: | 25.00000 | 125.00000 | |
| sugar substitutes: | - | - | |
| sweet sauces: | - | - | |
Safety References:
| EPI System: | View |
| AIDS Citations: | Search |
| Cancer Citations: | Search |
| Toxicology Citations: | Search |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| Laboratory Chemical Safety Summary : | 126537 |
| National Institute of Allergy and Infectious Diseases: | Data |
| (3S,3aS,7aR)-3,6-dimethyl-2,3,3a,4,5,7a-hexahydro-1-benzofuran | |
| Chemidplus: | 0074410109 |
References:
| Leffingwell: | Chirality or Article |
| (3S,3aS,7aR)-3,6-dimethyl-2,3,3a,4,5,7a-hexahydro-1-benzofuran | |
| NIST Chemistry WebBook: | Search Inchi |
| Pubchem (cid): | 126537 |
| Pubchem (sid): | 135083528 |
| Flavornet: | 74410-10-9 |
| Pherobase: | View |
Other Information:
| (IUPAC): | Atomic Weights of the Elements 2011 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| HMDB (The Human Metabolome Database): | HMDB40766 |
| FooDB: | FDB030007 |
| Typical G.C. | |
| VCF-Online: | VCF Volatile Compounds in Food |
| ChemSpider: | View |
| Wikipedia: | View |
| EFSA Update of results on the monitoring of furan levels in food: | Read Report |
| EFSA Previous report: Results on the monitoring of furan levels in food: | Read Report |
| EFSA Report of the CONTAM Panel on provisional findings on furan in food: | Read Report |
Potential Blenders and core components note
| For Odor | ||
| coconut | ||
| wine lactone | FL/FR | |
| floral | ||
| geranium oil bourbon | FL/FR | |
| green | ||
| elemi absolute | FL/FR | |
| herbal | ||
| canarium luzonicum gum | FL/FR | |
| spicy | ||
| zvoulimba leaf oil | FR | |
| For Flavor | ||
| No flavor group found for these | ||
| wine lactone | FL/FR | |
| floral | ||
| geranium oil bourbon | FL/FR | |
| green | ||
| canarium luzonicum gum | FL/FR | |
| elemi absolute | FL/FR | |
Potential Uses:
| dill weed | FL/FR | |
| herbal | FL | |
| spice | FL |
Occurrence (nature, food, other): note
| dill leaf Search Trop Picture | |
| dill oil Search Trop Picture | |
| dill seed Search Trop Picture | |
| dill shoot oil Search Trop Picture | |
| dill weed oil cuba @ 14.85% Data GC Search Trop Picture | |
| dill weed oil reunion @ 20.80% Data GC Search Trop Picture |
Synonyms:
| anethofuran | |
| benzofuran, 2,3,3a,4,5,7a-hexahydro-3,6-dimethyl-, (3S-(3a,3aa,7aa))- | |
| (3S,3aS,7aR)-3,6- | dimethyl-2,3,3a,4,5,7a-hexahydro-1-benzofuran |
| (3S,3aS,7aR)-3,6- | dimethyl-2,3,3a,4,5,7a-hexahydro-1-benzofuran and (3R,4S,8S)-3,9-epoxy-1-para-menthene |
| (S)-3,6- | dimethyl-2,3,3a,4,5,7a-hexahydrobenzofuran |
| (3R,4S,8S)-3,9- | epoxy-1-p-menthene |
| (3R,4S,8S)-3,9- | epoxy-1-para-menthene |
| (3R,4S,8S)-3,9-1-para- | epoxymenthene |
| (3S- (3alpha,3aalpha, 7aalpha))- 2,3,3a,4,5,7a- | hexahydro-3,6-dimethyl benzofuran |