2-amino-4-picoline
ascensil
 
Notes:
None found
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      Product(s):
      695-34-1 2-Amino-4-methylpyridine
       
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CAS Number: 695-34-1Picture of molecule3D/inchi
Other(deleted CASRN): 135995-51-6
ECHA EINECS - REACH Pre-Reg: 211-780-9
FDA UNII: 394N1Z644H
Nikkaji Web: J31.382C
Beilstein Number: 0107066
XlogP3: 0.60 (est)
Molecular Weight: 108.14376000
Formula: C6 H8 N2
NMR Predictor: Predict (works with chrome or firefox)
Category: natural substances and extractives
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
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US Patents: Search
EU Patents: Search
Pubchem Patents: Search
PubMed: Search
NCBI: Search
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Physical Properties:
Assay: 95.00 to 100.00 % 
Food Chemicals Codex Listed: No
Soluble in:
 water, 3.668e+004 mg/L @ 25 °C (est)
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Organoleptic Properties:
 
Odor and/or flavor descriptions from others (if found).
 
 
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Cosmetic Information:
None found
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Suppliers:
BOC Sciences
For experimental / research use only.
2-Amino-4-methylpyridine
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Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: natural substances and extractives
Recommendation for 2-amino-4-picoline usage levels up to:
 not for fragrance use.
 
Recommendation for 2-amino-4-picoline flavor usage levels up to:
 not for flavor use.
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Safety References:
EPI System: View
Cancer Citations: Search
Toxicology Citations: Search
EPA Substance Registry Services (TSCA): 695-34-1
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 1533
National Institute of Allergy and Infectious Diseases: Data
 4-methylpyridin-2-amine
Chemidplus: 0000695341
RTECS: TJ5150000 for cas# 695-34-1
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References:
 4-methylpyridin-2-amine
NIST Chemistry WebBook: Search Inchi
Pubchem (cid): 1533
Pubchem (cas): 695-34-1
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Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
CHEMBL: View
HMDB (The Human Metabolome Database): Search
Export Tariff Code: 2933.39.4700
Typical G.C.
VCF-Online: VCF Volatile Compounds in Food
ChemSpider: View
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Potential Blenders and core components note
 
None Found
 
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Potential Uses:
None Found
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Occurrence (nature, food, other): note
 carum petroselinum herb oil @ 0.40%
Data  GC  Search Trop  Picture
 found in nature
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Synonyms:
2-amino-4-methylpyridine
alpha-amino-gamma-picoline
 ascensil
4-methyl pyridine amine
4-methyl-2-aminopyridine
4-methyl-2-pyridinamine
4-methyl-2-pyridyl amine
 methyl-4-amino-2-pyridine
4-methylpyridin-2-amine
4-picolyl amine
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Articles:
PubMed: New carboxamide derivatives bearing benzenesulphonamide as a selective COX-II inhibitor: Design, synthesis and structure-activity relationship.
PubMed: Sonochemical synthesis, characterization, and effects of temperature, power ultrasound and reaction time on the morphological properties of two new nanostructured mercury(II) coordination supramolecule compounds.
PubMed: Influences of temperature, power ultrasound and reaction time on the morphological properties of two new mercury(II) coordination supramolecular compounds.
PubMed: Tautomerization, molecular structure, transition state structure, and vibrational spectra of 2-aminopyridines: a combined computational and experimental study.
PubMed: Spectrophotometric study on the proton transfer reaction between 2-amino-4-methylpyridine with 2,6-dichloro-4-nitrophenol in methanol, acetonitrile and the binary mixture 50% methanol+50% acetonitrile.
PubMed: Room-temperature transition-metal-free one-pot synthesis of 3-aryl imidazo[1,2-a]pyridines via iodo-hemiaminal intermediate.
PubMed: Oxidative regioselective amination of chromones exposes potent inhibitors of the hedgehog signaling pathway.
PubMed: An Accessible Chiral Linker to Enhance Potency and Selectivity of Neuronal Nitric Oxide Synthase Inhibitors.
PubMed: Synthesis, structural characterization and dielectric properties of (C6H9N2)2(Hg0.75Cd0.25)Cl4 compound.
PubMed: ¹H-MAS-NMR chemical shifts in hydrogen-bonded complexes of chlorophenols (pentachlorophenol, 2,4,6-trichlorophenol, 2,6-dichlorophenol, 3,5-dichlorophenol, and p-chlorophenol) and amine, and H/D isotope effects on ¹H-MAS-NMR spectra.
PubMed: An amino-imino resonance study of 2-amino-4-methylpyridinium nitrate and 2-amino-5-methylpyridinium nitrate.
PubMed: Molecular and crystal structures, vibrational studies and quantum chemical calculations of 3 and 5-nitroderivatives of 2-amino-4-methylpyridine.
PubMed: Feasibility and dosimetry studies for 18F-NOS as a potential PET radiopharmaceutical for inducible nitric oxide synthase in humans.
PubMed: Growth and characterization of 2-amino-4-picolinium toluene sulfonate single crystal.
PubMed: Quantitative morphometry of respiratory tract epithelial cells as a tool for testing chemopreventive agent efficacy.
PubMed: DNA binding ability and hydrogen peroxide induced nuclease activity of a novel Cu(II) complex with malonate as the primary ligand and protonated 2-amino-4-picoline as the counterion.
PubMed: Supramolecular assembly of Mg(II) complexes directed by associative lone pair-pi/pi-pi/pi-anion-pi/pi-lone pair interactions.
PubMed: Robust recognition of malonate and 2-amino-4-picolinium in conjunction with M(II) as a triad (M = Ni/Co/Mn): role of this highly stable hydrogen-bonded motif in driving supramolecular self-assembly.
PubMed: Design and synthesis of 2-amino-4-methylpyridine analogues as inhibitors for inducible nitric oxide synthase and in vivo evaluation of [18F]6-(2-fluoropropyl)-4-methyl-pyridin-2-amine as a potential PET tracer for inducible nitric oxide synthase.
PubMed: Rhodium(I)-catalyzed one-pot synthesis of dialkyl ketones from methanol and alkenes through directed sp3 C-H bond activation of N-methylamine.
PubMed: Decreased beta-adrenoceptor chronotropic response in selenium-deficient mice: negative crosstalk between iNOS activity and cAMP accumulation.
PubMed: Synthesis and evaluation of 3-aminopropionyl substituted fentanyl analogues for opioid activity.
PubMed: The fixation of bis(2-pyridylimino)isoindolato (BPI) ligands to dendritic carbosilanes.
PubMed: Inhibition of nitric oxide synthase aggravates cisplatin-induced nephrotoxicity: effect of 2-amino-4-methylpyridine.
PubMed: Differential activity of NO synthase inhibitors as chemopreventive agents in a primary rat tracheal epithelial cell transformation system.
PubMed: Synthesis of aliphatic ketones from allylic alcohols through consecutive isomerization and chelation-assisted hydroacylation by a rhodium catalyst.
PubMed: The inhibitory potency and selectivity of arginine substrate site nitric-oxide synthase inhibitors is solely determined by their affinity toward the different isoenzymes.
PubMed: Effects of intravenous nitric oxide inhibitors on endotoxin-induced fever in prepubertal pigs.
PubMed: Effects of 4-methyl-2-aminopyridine on [3H]-noradrenaline overflow and contractility of isolated rabbit arteries.
PubMed: Analgesic activity of 2-amino-4-methylpyridine, a novel NO synthase inhibitor.
PubMed: 2-Amino-4-methylpyridine as a potent inhibitor of inducible NO synthase activity in vitro and in vivo.
PubMed: [Study of the effect of analgeton on the release of beta-endorphin and its effect on chronic hyperalgesia].
PubMed: [Baroreflex effects on systolic arterial pressure and the intersystolic period in a comparative study of aminton and phenylephrine].
PubMed: Cholinergic effect of 4-aminopyridine and adrenergic effect of 4-methyl-2-aminopyridine in cardiac muscle.
PubMed: Actions of 4-methyl-2-aminopyridine on neuromuscular transmission and contractility of skeletal muscle.
PubMed: [Effect of aminton on noradrenaline and adrenaline depots in the rat heart].
PubMed: On the mechanism of action of 2-amino-4-methylpyridine, a morphine-like analgesic.
PubMed: [Effects of 4-methyl-2-aminopyridine on the heart and on circulation. Experimental research].
PubMed: [Clinical trials with 4-methyl-2-aminopyridine camphorsulfonate in the shock from recent infarct].
PubMed: [The action of 4-methyl-2-aminopyridine on the pressure of the greater and lesser circulations, on cerebral flow and on the coronary circulation].
PubMed: [Toxicological and pharmacological characteristics of a new cardiocirculatory analeptic with prolonged action: 4-methyl-2-aminopyridine camphorsulfonate].
PubMed: [Cardiocirculatory action of 4-methyl-2-aminopyridine camphorsulfonate].
PubMed: Cardiac effects of 4-methyl-2-aminopyridine and some of its isomers.
PubMed: [Circulatory effects of 2-amino-4-picoline].
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