2,4-ivy carbaldehyde / methyl anthranilate schiff's base
triplal/methyl anthranilate schiff base
 
Notes:
None found
  • BOC Sciences
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      Product(s):
      68845-02-3 Benzoic acid,2-[[(2,4-dimethyl-3-cyclohexen-1-yl)methylene]amino]-, methyl ester
       
  • Indukern F&F
  • Lluch Essence
    • Lluch Essence S.L.
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      SCHIFF BASE LIGUSTRAL/METHYL ANTHRANILATE
       
  • O'Laughlin Industries
    • O'Laughlin Industries Inc.
      Manufacturer of chemicals and ingredients used in flavors, fragrances, food, beverages and cosmetics
      Leading the Flavor and Fragrance Industry since 1980.
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      772-2062 VERTOLINE
       
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      Product(s):
      20-85450 TRIPLAL/METHYL ANTHRANILATE SCHIFF BASE
       
Synonyms   Articles   Notes   Search
Fragrance Demo Formulas
CAS Number: 68845-02-3Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 272-449-2
Nikkaji Web: J332.643H
XlogP3-AA: 3.10 (est)
Molecular Weight: 271.35977000
Formula: C17 H21 N O2
NMR Predictor: Predict (works with chrome or firefox)
Category: fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
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US Patents: Search
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Pubchem Patents: Search
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Physical Properties:
Appearance: yellow to orange yellow viscous liquid to solid (est)
Assay: 90.00 to 100.00 % sum of isomers
Food Chemicals Codex Listed: No
Specific Gravity: 1.04650 to 1.05450 @  25.00 °C.
Pounds per Gallon - (est).: 8.708 to  8.774
Refractive Index: 1.52400 to 1.53350 @  20.00 °C.
Boiling Point: 68.00 °C. @ 4.00 mm Hg
Vapor Density: >1 ( Air = 1 )
Flash Point: 230.00 °F. TCC ( 110.00 °C. )
logP (o/w): 6.321 (est)
Soluble in:
 alcohol
 water, 1.322 mg/L @ 25 °C (est)
Insoluble in:
 water
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Organoleptic Properties:
 
Odor Type: green
 
Odor Strength: medium
 
Substantivity: 268 hour(s) at 100.00 %
 
 fresh  aldehydic  green  natural  cortex  leafy  narcissus  
Odor Description:
at 100.00 %. 
fresh aldehydic green natural cortex leafy narcissus
Luebke, William tgsc, (1996)
 
Odor and/or flavor descriptions from others (if found).
 
Bedoukian Research
SCHIFF'S BASE TRIPLAL-METHYL ANTHRANILATE ≥90.0% (sum of isomers), Kosher
Odor Description: A very green, floral odor with a citrus note
Used in fine perfumes for its delicate floral citrus odor.
 
 
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Cosmetic Information:
None found
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Suppliers:
BOC Sciences
For experimental / research use only.
Benzoic acid,2-[[(2,4-dimethyl-3-cyclohexen-1-yl)methylene]amino]-, methyl ester
Ernesto Ventós
SCHIFF BASE, TRIPLAL/METHYL ANTHRANILATE
Odor: GREEN, FLORAL, ALDEHYDIC, CITRUS
Indukern F&F
SCHIFF BASE TRIPLAL
Lluch Essence
SCHIFF BASE LIGUSTRAL/METHYL ANTHRANILATE
O'Laughlin Industries
VERTOLINE
Penta International
TRIPLAL/METHYL ANTHRANILATE SCHIFF BASE
Perfumer Supply House
Triplal/Methyl Anthranilate Schiff’s Base
Odor: very sweet, green, grassy , leafy, narcissus
Perfumery Laboratory
TRIPLAL / methyl anthranilate Schiff's (Triplal / Methyl Anthranilate Schiff's Base)
Odor: Very sweet, green, herbal, leaf, flower narcissus and orange blossom
Vigon International
Methyl Anthranilate / Triplal Schiff Base
Odor: Fresh-green, narcotic with nuances reminiscent of orange-blossom
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Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: fragrance agents
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only)
2,4-ivy carbaldehyde Max. Found: 50.9 % and Reason: Sensitization
IFRA: View Standard
Recommendation for 2,4-ivy carbaldehyde / methyl anthranilate schiff's base usage levels up to:
  4.0000 % in the fragrance concentrate.
 
Recommendation for 2,4-ivy carbaldehyde / methyl anthranilate schiff's base flavor usage levels up to:
 not for flavor use.
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Safety References:
EPI System: View
EPA Substance Registry Services (TSCA): 68845-02-3
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 111378
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 2
 methyl 2-[(2,4-dimethyl-1-cyclohex-3-enyl)methylideneamino]benzoate
Chemidplus: 0068845023
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References:
 methyl 2-[(2,4-dimethyl-1-cyclohex-3-enyl)methylideneamino]benzoate
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 68845-02-3
Pubchem (cid): 111378
Pubchem (sid): 135067580
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Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
HMDB (The Human Metabolome Database): Search
Export Tariff Code: 2922.49.8050
ChemSpider: View
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Potential Blenders and core components note
 
For Odor
aldehydic
6,7,8-decen-1-olFR
 fresh carbaldehydeFR
 muguet undecadienalFR
 octane nitrileFR
amber
 amber caraneFR
animal
para-cresyl isobutyrateFL/FR
para-cresyl phenyl acetateFL/FR
balsamic
 cinnamyl formateFL/FR
 propyl cinnamateFL/FR
 tetrahydrofurfuryl cinnamateFL/FR
citrus
 citralFL/FR
 citral dimethyl acetalFL/FR
 citrus specialtyFR
(E)-4-decenalFL/FR
 grapefruit pentanolFR
 lime pyranFR
 limonene aldehydeFR
 neroli ketoneFR
 petitgrain combava oilFR
 tetrahydrocitralFL/FR
fatty
2-decenalFL/FR
(E,Z)-2,6-dodecadienalFL/FR
(E)-2-octenalFL/FR
floral
 allyl anthranilateFL/FR
 amyl benzoateFL/FR
alpha-amyl cinnamaldehyde diethyl acetalFR
 anisyl propanal / methyl anthranilate schiff's baseFR
 benzaldehyde propylene glycol acetalFL/FR
alpha-butyl cinnamaldehydeFL/FR
 citronellyl acetateFL/FR
 citronellyl propionateFL/FR
para-cresyl acetateFL/FR
 cumin carbinolFR
 cuminyl acetaldehydeFL/FR
 cyclamen propanalFR
 dimethyl benzyl carbinolFL/FR
 dimethyl benzyl carbinyl butyrateFL/FR
2,4-dimethyl cyclohexyl methyl acetateFR
6,8-dimethyl-2-nonanolFR
 ethyl 2-benzyl butyrateFL/FR
 farnesyl acetateFL/FR
 floral butanalFR
 geranium oil bourbonFL/FR
 geranyl acetoneFL/FR
 geranyl isobutyrateFL/FR
(Z)-3-hexen-1-yl salicylateFL/FR
alpha-hexyl cinnamaldehydeFL/FR
 hydroxycitronellal diethyl acetalFL/FR
 jasmin cyclopentanolFR
 lilac pentanolFL/FR
 magnolia indeneFR
 mimosa absolute franceFL/FR
 narcissus acetateFL/FR
 neroli oil bigardeFL/FR
 nerolidolFL/FR
 ocean propanalFL/FR
 ocean propanal / methyl anthranilate schiff's baseFR
 octahydro-4,7-methano-1H-indene-5-acetaldehyde + 6-methyl-octahydro-4,7-methano-indene-5-carbaldehydFR
 orange leaf absoluteFL/FR
bitter orangeflower absolute moroccoFL/FR
bitter orangeflower absolute tunisiaFL/FR
 papaya isobutyrateFL/FR
clementine petitgrain oilFL/FR
 phenyl acetaldehyde diisobutyl acetalFL/FR
2-phenyl propionaldehyde ethylene glycol acetalFR
isopropyl phenyl acetateFL/FR
 reseda acetalFR
 rose absolute (rosa damascena) bulgariaFL/FR
 rose butanoateFL/FR
laevo-rose oxideFL/FR
 styralyl formateFL/FR
 tea acetateFR
 terpinyl isobutyrateFL/FR
 verdyl acetateFR
fresh
3-(3-propen-2-yl phenyl) butanalFR
fruity
 benzyl methyl etherFL/FR
 dimethyl succinateFL/FR
 ethyl methyl-para-tolyl glycidateFL/FR
 heptanal cyclic ethylene acetalFR
2-hexen-1-olFL/FR
(E)-2-hexen-1-olFL/FR
 peach pivalateFR
green
 acetaldehyde butyl phenethyl acetalFL/FR
 acetaldehyde di-(Z)-3-hexen-1-yl acetalFL/FR
 acetaldehyde ethyl phenethyl acetalFL/FR
 acetaldehyde methyl hexyl acetalFR
isoamyl 3-(2-furan) propionateFL/FR
isobutyl benzyl carbinolFL/FR
2-isobutyl thiazoleFL/FR
 chrysanthemum oxideFL/FR
 cilantro leaf oilFL/FR
 cumin acetaldehydeFL/FR
homocuminic aldehydeFR
3,5,6-neocyclocitralFR
isocyclocitral (IFF)FL/FR
 decanal propylene glycol acetalFL/FR
 diphenyl oxideFL/FR
 earthy acetalFL/FR
 fern specialtyFR
 flower hexeneFR
 galbanum oilFL/FR
 galbanum oil terpenelessFL/FR
 geranium absoluteFL/FR
 green carbaldehydeFR
 green specialtyFR
 heptyl cinnamateFL/FR
3-hexen-1-olFL/FR
(Z)-2-hexen-1-olFL/FR
(E)-2-hexen-1-yl acetateFL/FR
(Z)-3-hexen-1-yl benzoateFL/FR
(Z)-3-hexen-1-yl lactateFL/FR
(Z)-3-hexen-1-yl methyl carbonateFL/FR
3-hexenalFL/FR
 hexoxyacetaldehyde dimethyl acetalFR
 hexyl heptanoateFL/FR
2,4-ivy carbaldehydeFL/FR
 ivy carbaldehydeFL/FR
3,5-ivy carbaldehydeFL/FR
 ivy dioxolaneFR
(Z)-leaf acetalFL/FR
 leafy acetalFL/FR
 leafy oximeFR
 lilac acetaldehydeFL/FR
 marine specialtyFR
 methyl cyclocitrone (IFF)FR
 methyl heptine carbonateFL/FR
para-methyl hydratropaldehydeFL/FR
 methyl octine carbonateFL/FR
4-methyl-4-phenyl pentanoneFR
 narcissus flower absoluteFR
(E,Z)-2,6-nonadien-1-yl acetateFL/FR
 octanal dimethyl acetalFL/FR
(E)-2-octen-1-yl acetateFL/FR
(Z)-5-octen-1-yl propionateFL/FR
 octyl oxyacetaldehydeFR
 olive oil absoluteFL/FR
 phenethyl acetalFR
 phenoxyacetaldehyde 50% in benzyl alcoholFR
 phenyl acetaldehydeFL/FR
3-phenyl propionaldehydeFL/FR
isopropyl phenyl propionaldehydeFR
isopropyl quinolineFR
 rose leaf absolute (rosa centifolia)FL/FR
 styralyl acetateFL/FR
 triplal / ethyl anthranilate schiff's baseFR
herbal
sweet basil absoluteFL/FR
 clary sage absoluteFL/FR
 herbal heptaneFR
1-(2-methyl allyl oxy) heptaneFR
marine
 marine hexaneFR
minty
isopulegyl formateFL/FR
waxy
 allyl nonanoateFL/FR
 decanal diethyl acetalFL/FR
3-decanoneFL/FR
 
For Flavor
 
No flavor group found for these
 acetaldehyde di-(Z)-3-hexen-1-yl acetalFL/FR
 allyl anthranilateFL/FR
 amyl benzoateFL/FR
 decanal propylene glycol acetalFL/FR
3-decanoneFL/FR
 earthy acetalFL/FR
 ethyl 2-benzyl butyrateFL/FR
 heptyl cinnamateFL/FR
3-hexen-1-olFL/FR
 hexyl heptanoateFL/FR
3,5-ivy carbaldehydeFL/FR
 ivy carbaldehydeFL/FR
isopulegyl formateFL/FR
 styralyl formateFL/FR
 terpinyl isobutyrateFL/FR
 tetrahydrocitralFL/FR
 tetrahydrofurfuryl cinnamateFL/FR
isoamyl 3-(2-furan) propionateFL/FR
alpha-butyl cinnamaldehydeFL/FR
amber
isobutyl benzyl carbinolFL/FR
aromatic
para-cresyl acetateFL/FR
para-cresyl isobutyrateFL/FR
 leafy acetalFL/FR
citrus
 cilantro leaf oilFL/FR
 citralFL/FR
 citral dimethyl acetalFL/FR
clementine petitgrain oilFL/FR
fatty
2-decenalFL/FR
(Z)-3-hexen-1-yl benzoateFL/FR
(E)-2-octenalFL/FR
floral
 citronellyl acetateFL/FR
 citronellyl propionateFL/FR
 dimethyl benzyl carbinyl butyrateFL/FR
 farnesyl acetateFL/FR
 geranium oil bourbonFL/FR
 geranyl acetoneFL/FR
 geranyl isobutyrateFL/FR
 neroli oil bigardeFL/FR
 ocean propanalFL/FR
 orange leaf absoluteFL/FR
bitter orangeflower absolute moroccoFL/FR
bitter orangeflower absolute tunisiaFL/FR
 rose absolute (rosa damascena) bulgariaFL/FR
laevo-rose oxideFL/FR
fruity
 benzaldehyde propylene glycol acetalFL/FR
 benzyl methyl etherFL/FR
 dimethyl succinateFL/FR
 ethyl methyl-para-tolyl glycidateFL/FR
2-hexen-1-olFL/FR
 lilac acetaldehydeFL/FR
 lilac pentanolFL/FR
 propyl cinnamateFL/FR
 rose butanoateFL/FR
 styralyl acetateFL/FR
green
 acetaldehyde butyl phenethyl acetalFL/FR
 acetaldehyde ethyl phenethyl acetalFL/FR
2-isobutyl thiazoleFL/FR
 chrysanthemum oxideFL/FR
 clary sage absoluteFL/FR
 cumin acetaldehydeFL/FR
 cuminyl acetaldehydeFL/FR
isocyclocitral (IFF)FL/FR
 diphenyl oxideFL/FR
(E,Z)-2,6-dodecadienalFL/FR
 galbanum oilFL/FR
 galbanum oil terpenelessFL/FR
 geranium absoluteFL/FR
(Z)-2-hexen-1-olFL/FR
(E)-2-hexen-1-olFL/FR
(E)-2-hexen-1-yl acetateFL/FR
(Z)-3-hexen-1-yl lactateFL/FR
(Z)-3-hexen-1-yl methyl carbonateFL/FR
(Z)-3-hexen-1-yl salicylateFL/FR
3-hexenalFL/FR
2,4-ivy carbaldehydeFL/FR
(Z)-leaf acetalFL/FR
 methyl heptine carbonateFL/FR
para-methyl hydratropaldehydeFL/FR
 methyl octine carbonateFL/FR
 narcissus acetateFL/FR
 nerolidolFL/FR
(E,Z)-2,6-nonadien-1-yl acetateFL/FR
 octanal dimethyl acetalFL/FR
(E)-2-octen-1-yl acetateFL/FR
(Z)-5-octen-1-yl propionateFL/FR
 papaya isobutyrateFL/FR
 phenyl acetaldehyde diisobutyl acetalFL/FR
3-phenyl propionaldehydeFL/FR
 rose leaf absolute (rosa centifolia)FL/FR
herbal
sweet basil absoluteFL/FR
honey
 phenyl acetaldehydeFL/FR
isopropyl phenyl acetateFL/FR
medicinal
 dimethyl benzyl carbinolFL/FR
melon
 hydroxycitronellal diethyl acetalFL/FR
oily
 olive oil absoluteFL/FR
phenolic
para-cresyl phenyl acetateFL/FR
ripe
(E)-4-decenalFL/FR
spicy
 cinnamyl formateFL/FR
waxy
 allyl nonanoateFL/FR
 decanal diethyl acetalFL/FR
alpha-hexyl cinnamaldehydeFL/FR
 mimosa absolute franceFL/FR
 
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Potential Uses:
 floralFR
 greenFR
 hyacinthFR
 hydrangeaFR
 lilacFR
 lily of the valleyFR
 magnoliaFR
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Occurrence (nature, food, other): note
 not found in nature
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Synonyms:
 benzoic acid, 2-(((2,4-dimethyl-3-cyclohexen-1-yl)methylene)amino)-, methyl ester
N-(2,4-dimethyl-3-cyclohexenyl) methylidene anthranilic acid methyl ester
N-(2,4-dimethyl-3-cyclohexenyl)methylideneanthranilic acid, methyl ester
 methyl 2-(((2,4-dimethyl-3-cyclohexen-1-yl)methylene)amino) benzoate
 methyl 2-(((2,4-dimethyl-3-cyclohexen-1-yl)methylene)amino)benzoate
 methyl 2-[(2,4-dimethyl-1-cyclohex-3-enyl)methylideneamino]benzoate
 methyl 2-[(2,4-dimethylcyclohex-3-en-1-yl)methylideneamino]benzoate
 methyl anthranilate / 2,4-ivy carbaldehyde schiff's base
 methyl anthranilate / triplal schiff base
 schiff's base triplal-methyl anthranilate
 schiff's base tripleame
 triplal/methyl anthranilate schiff base
 vertoline
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