acetone peroxide
1,2,4,5,7,8-hexoxonane, 3,3,6,6,9,9-hexamethyl-
 
Notes:
Used as a food additive [EAFUS]
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CAS Number: 1336-17-0Picture of molecule3D/inchi
Other(deleted CASRN): 8066-32-8
FDA UNII: 3O959710YK
XlogP: 2.90 (est)
Molecular Weight: 222.23766000
Formula: C9 H18 O6
NMR Predictor: Predict (works with chrome or firefox)
Category: flour maturing and bleaching, dough conditionings
 
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FDA Mainterm (SATF):1336-17-0 ; ACETONE PEROXIDES
FDA Regulation:
FDA PART 137 -- CEREAL FLOURS AND RELATED PRODUCTS
Subpart B--Requirements for Specific Standardized Cereal Flours and Related Products
Sec. 137.105 Flour.


FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION
Subpart I--Multipurpose Additives
Sec. 172.802 Acetone peroxides.
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Physical Properties:
Assay: 95.00 to 100.00 % 
Food Chemicals Codex Listed: No
Boiling Point: 183.00 to  186.00 °C. @ 760.00 mm Hg (est)
Vapor Pressure: 0.980000 mmHg @ 25.00 °C. (est)
Flash Point: 125.00 °F. TCC ( 51.50 °C. ) (est)
logP (o/w): 0.026 (est)
Soluble in:
 water, 3.725 mg/L @ 25 °C (est)
Similar Items: note
acetone alcohol
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Organoleptic Properties:
 
Odor and/or flavor descriptions from others (if found).
 
 
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Cosmetic Information:
None found
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Suppliers:
 None found
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Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: flour maturing and bleaching, dough conditionings
Recommendation for acetone peroxide usage levels up to:
 not for fragrance use.
 
Recommendation for acetone peroxide flavor usage levels up to:
 not for flavor use.
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Safety References:
EPI System: View
AIDS Citations: Search
Cancer Citations: Search
Toxicology Citations: Search
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
National Institute of Allergy and Infectious Diseases: Data
 3,3,6,6,9,9-hexamethyl-1,2,4,5,7,8-hexaoxonane
Chemidplus: 0001336170
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References:
 3,3,6,6,9,9-hexamethyl-1,2,4,5,7,8-hexaoxonane
NIST Chemistry WebBook: Search Inchi
Pubchem (sid): 135343023
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Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS): View
HMDB (The Human Metabolome Database): Search
FooDB: FDB008887
FDA Listing of Food Additive Status: View
ChemSpider: View
Wikipedia: View
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Potential Blenders and core components note
 
None Found
 
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Potential Uses:
None Found
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Occurrence (nature, food, other): note
 not found in nature
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Synonyms:
3,3,6,6,9,9-hexamethyl-1,2,4,5,7,8-hexaoxonane
3,3,6,6,9,9-hexamethyl-1,2,4,5,7,8-hexoxonane
1,2,4,5,7,8-hexoxonane, 3,3,6,6,9,9-hexamethyl-
 peroxyacetone
2-propanone peroxide
 TATP
 TCAP
 triacetone peroxide
 triacetonetriperoxide
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Articles:
PubMed: Titanium dioxide nanoparticles-based colorimetric sensors for determination of hydrogen peroxide and triacetone triperoxide (TATP)
PubMed: Reaction kinetics of acetone peroxide formation and structure investigations using Raman spectroscopy and X-ray diffraction
PubMed: Turn-on Fluorescent Detection of Hydrogen Peroxide and Triacetone Triperoxide via Enhancing Interfacial Interactions of a Blended System
PubMed: High-sensitivity detection of triacetone triperoxide (TATP) and its precursor acetone
PubMed: Solid-State Fluorescence-based Sensing of TATP via Hydrogen Peroxide Detection
PubMed: Sensitive determination of triacetone triperoxide explosives using electrogenerated chemiluminescence
PubMed: Towards the fluorogenic detection of peroxide explosives through host-guest chemistry
PubMed: A field-applicable colorimetric assay for notorious explosive triacetone triperoxide through nanozyme-catalyzed irreversible oxidation of 3, 3'-diaminobenzidine
PubMed: Redox-based colorimetric sensing of H(2)O(2) after removal of antioxidants with ABTS radical oxidation
PubMed: Cyclic pentanone peroxide: sensitiveness and suitability as a model for triacetone triperoxide
PubMed: Triacetone triperoxide (TATP): hapten design and development of antibodies
PubMed: Reductive Cleavage of Organic Peroxides by Iron Salts and Thiols
PubMed: Highly sensitive detection of explosive triacetone triperoxide by an In2O3 sensor
PubMed: A simple organic multi-analyte fluorescent prober: One molecule realizes the detection to DNT, TATP and Sarin substitute gas
PubMed: Visual detection of peroxide-based explosives using novel mimetic Ag nanoparticle/ZnMOF nanocomposite
PubMed: A Powdered Simulant of Triacetone Triperoxide (TATP) for Safe Testing of X-ray Transmission Screening Equipment
PubMed: Determination of Triacetone Triperoxide and Hexamethylene Triperoxide Diamine in Various Matrices Using Infrared Spectroscopy
PubMed: In situ trace detection of peroxide explosives by desorption electrospray ionization and desorption atmospheric pressure chemical ionization
PubMed: Mechanism for the uncatalyzed cyclic acetone-peroxide formation reaction: an experimental and computational study
PubMed: Electronic tongue for nitro and peroxide explosive sensing
PubMed: Detection of Triacetone Triperoxide (TATP) Precursors with an Array of Sensors Based on MoS?/RGO Composites
PubMed: Study of TATP: method for determination of residual acids in TATP
PubMed: Handy fluorescent paper device based on a curcumin derivative for ultrafast detection of peroxide-based explosives
PubMed: Chemiluminescence of black phosphorus quantum dots induced by hypochlorite and peroxide
PubMed: Factors affecting the intramolecular decomposition of hexamethylene triperoxide diamine and implications for detection
PubMed: Accumulation of explosives in hair--part II: factors affecting sorption
PubMed: A quantitative chemiluminescent assay for analysis of peroxide-based explosives
PubMed: Destruction of peroxide explosives
PubMed: Raman and infrared fingerprint spectroscopy of peroxide-based explosives
PubMed: Sensitivity to friction for primary explosives
PubMed: Characterization of the explosive triacetone triperoxide and detection by ion mobility spectrometry
PubMed: Flow injection analysis of organic peroxide explosives using acid degradation and chemiluminescent detection of released hydrogen peroxide
PubMed: Nanocrystalline tin oxide nanofibers deposited by a novel focused electrospinning method. Application to the detection of TATP precursors
PubMed: A field test for the detection of peroxide-based explosives
PubMed: Highly sensitive electrochemical detection of trace liquid peroxide explosives at a Prussian-blue 'artificial-peroxidase' modified electrode
PubMed: Reactions of Organic Peroxides with Alcohols in Atmospheric Pressure Chemical Ionization-the Pitfalls of Quantifying Triacetone Triperoxide (TATP)
PubMed: Paper spray ionization-high-resolution mass spectrometry (PSI-HRMS) of peroxide explosives in biological matrices
PubMed: Fluorescent signaling based on sulfoxide profluorophores: application to the visual detection of the explosive TATP
PubMed: The identification of chlorinated acetones in analyses of aged triacetone triperoxide (TATP)
PubMed: The Potential of Isotope Ratio Mass Spectrometry (IRMS) and Gas Chromatography-IRMS Analysis of Triacetone Triperoxide in Forensic Explosives Investigations
PubMed: Selective, sensitive, and rapid analysis with lateral-flow assays based on antibody-gated dye-delivery systems: the example of triacetone triperoxide
PubMed: Electrochemical detection of triacetone triperoxide employing the electrocatalytic reaction of iron(II/III)-ethylenediaminetetraacetate and hydrogen peroxide
PubMed: Dynamic headspace generation and quantitation of triacetone triperoxide vapor
PubMed: In vitro metabolism of HMTD and blood stability and toxicity of peroxide explosives (TATP and HMTD) in canines and humans
PubMed: Forensic analysis of explosives using isotope ratio mass spectrometry (IRMS)--preliminary study on TATP and PETN
PubMed: Dopant-Assisted Positive Photoionization Ion Mobility Spectrometry Coupled with Time-Resolved Thermal Desorption for On-Site Detection of Triacetone Triperoxide and Hexamethylene Trioxide Diamine
PubMed: Sulfuric, hydrochloric, and nitric acid-catalyzed triacetone triperoxide (TATP) reaction mixtures: an aging study
PubMed: Determination of Peroxide Explosive TATP and Related Compounds by Dielectric Barrier Discharge Ionization-Mass Spectrometry (DBDI-MS)
PubMed: Non-invasive monitoring of immunization progress in mice via IgG from feces
PubMed: Use of Mass Spectrometric Vapor Analysis To Improve Canine Explosive Detection Efficiency
PubMed: Determination of peroxide-based explosives with copper(II)-neocuproine assay combined with a molecular spectroscopic sensor
PubMed: Fluorescence ratiometric sensor for trace vapor detection of hydrogen peroxide
PubMed: A colorimetric sensor array for detection of triacetone triperoxide vapor
PubMed: Analysis of triacetone triperoxide by gas chromatography/mass spectrometry and gas chromatography/tandem mass spectrometry by electron and chemical ionization
PubMed: Gas chromatography/mass spectrometry analysis of triacetone triperoxide (TATP) degradation products
PubMed: Characterization of TATP gas phase product ion chemistry via isotope labeling experiments using ion mobility spectrometry interfaced with a triple quadrupole mass spectrometer
PubMed: Detection of explosives in hair using ion mobility spectrometry
PubMed: Turn-on fluorescence detection of H2O2 and TATP
PubMed: Self-immolative dendritic probe for direct detection of triacetone triperoxide
PubMed: Flow injection analysis of picric acid explosive using a copper electrode as electrochemical detector
PubMed: Theoretical and experimental study of sensing triacetone triperoxide (TATP) explosive through nanostructured TiO? substrate
PubMed: Trace analysis of peroxide-based explosives
PubMed: Detecting a peroxide-based explosive via molecular gelation
PubMed: Fast detection of triacetone triperoxide (TATP) from headspace using planar solid-phase microextraction (PSPME) coupled to an IMS detector
PubMed: Current trends in the detection of peroxide-based explosives
PubMed: The detection of improvised nonmilitary peroxide based explosives using a titania nanotube array sensor
PubMed: A novel array of chemiluminescence sensors for sensitive, rapid and high-throughput detection of explosive triacetone triperoxide at the scene
PubMed: Power of TATP based explosives
PubMed: Application of selected-ion flow tube mass spectrometry to the real-time detection of triacetone triperoxide
PubMed: Some properties of explosive mixtures containing peroxides Part I. Relative performance and detonation of mixtures with triacetone triperoxide
PubMed: "One-step" simplified electrochemical sensing of TATP based on its acid treatment
PubMed: Molecular simulations of adsorption of RDX and TATP on IRMOF-1(Be)
PubMed: Accumulation of explosives in hair--Part 3: Binding site study
PubMed: Resonant and nonresonant multiphoton ionization processes in the mass spectrometry of explosives
PubMed: A simple but highly efficient multi-formyl phenol-amine system for fluorescence detection of peroxide explosive vapour
PubMed: An initial evaluation of stable isotopic characterisation of post-blast plastic debris from improvised explosive devices
PubMed: Vibrational spectroscopy of triacetone triperoxide (TATP): anharmonic fundamentals, overtones and combination bands
PubMed: Technical note: Headspace analysis of explosive compounds using a novel sampling chamber
PubMed: Geometry-independent neutral desorption device for the sensitive EESI-MS detection of explosives on various surfaces
PubMed: Highly Energetic, Low Sensitivity Aromatic Peroxy Acids
PubMed: Time-resolved, laser initiated detonation of TATP supports the previously predicted non-redox mechanism
PubMed: Selective gas-phase capture of explosives on metal beta-diketonate polymers
PubMed: Role of metal ions in the destruction of TATP: theoretical considerations
PubMed: A novel microarray chemiluminescence method based on chromium oxide nanoparticles catalysis for indirect determination of the explosive triacetone triperoxide at the scene
PubMed: Reproducible vapor-time profiles using solid-phase microextraction with an externally sampled internal standard
PubMed: Characterizing the gas phase ion chemistry of an ion trap mobility spectrometry based explosive trace detector using a tandem mass spectrometer
PubMed: Accumulation of explosives in hair
PubMed: Analysis of oligomeric peroxides in synthetic triacetone triperoxide samples by tandem mass spectrometry
PubMed: Some properties of explosive mixtures containing peroxides Part II. Relationships between detonation parameters and thermal reactivity of the mixtures with triacetone triperoxide
PubMed: Detection of explosives and explosives-related compounds by single photon laser ionization time-of-flight mass spectrometry
PubMed: Improved method for the detection of TATP after explosion
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