methyl cyclopropane
cyclopropane, methyl-
 
Notes:
do not confuse with mcp cpd (1-methylcyclopropene).
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CAS Number: 594-11-6Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 209-825-2
Nikkaji Web: J467G
XlogP3-AA: 1.90 (est)
Molecular Weight: 56.10776000
Formula: C4 H8
NMR Predictor: Predict (works with chrome or firefox)
Category: information only not used for fragrances or flavors
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
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Physical Properties:
Assay: 95.00 to 100.00 % 
Food Chemicals Codex Listed: No
Boiling Point: 0.70 °C. @ 760.00 mm Hg
Vapor Pressure: 1779.200000 mmHg @ 25.00 °C. (est)
Flash Point: -111.00 °F. TCC ( -79.30 °C. ) (est)
logP (o/w): 2.180 (est)
Soluble in:
 water, 615.4 mg/L @ 25 °C (exp)
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Organoleptic Properties:
 
Odor and/or flavor descriptions from others (if found).
 
 
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Cosmetic Information:
None found
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Suppliers:
 None found
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Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: information only not used for fragrances or flavors
Recommendation for methyl cyclopropane usage levels up to:
 not for fragrance use.
 
Recommendation for methyl cyclopropane flavor usage levels up to:
 not for flavor use.
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Safety References:
EPI System: View
Cancer Citations: Search
Toxicology Citations: Search
EPA Substance Registry Services (TSCA): 594-11-6
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 11657
National Institute of Allergy and Infectious Diseases: Data
 methylcyclopropane
Chemidplus: 0000594116
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References:
 methylcyclopropane
NIST Chemistry WebBook: Search Inchi
Pubchem (cid): 11657
Pubchem (sid): 134978247
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Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
HMDB (The Human Metabolome Database): Search
ChemSpider: View
Wikipedia: View
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Potential Blenders and core components note
 
None Found
 
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Potential Uses:
None Found
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Occurrence (nature, food, other): note
 not found in nature
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Synonyms:
 cyclopropane, methyl-
 methylcyclopropane
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Articles:
PubMed: Transient regulation of three clustered tomato class-I small heat-shock chaperone genes by ethylene is mediated by SlMADS-RIN transcription factor.
PubMed: The Enigmatic P450 Decarboxylase OleT Is Capable of, but Evolved To Frustrate, Oxygen Rebound Chemistry.
PubMed: Internal Rotation of Methylcyclopropane and Related Molecules: Comparison of Experiment and Theory.
PubMed: Ruta montana L. leaf essential oil and extracts: characterization of bioactive compounds and suppression of crown gall disease.
PubMed: Palladium(0)-Catalyzed Methylcyclopropanation of Norbornenes with Vinyl Bromides and Mechanism Study.
PubMed: An antibacterial ortho-quinone diterpenoid and its derivatives from Caryopteris mongolica.
PubMed: Two abscission zones proximal to Lansium domesticum fruit: one more sensitive to exogenous ethylene than the other.
PubMed: Transcriptome changes in apple peel tissues during CO2 injury symptom development under controlled atmosphere storage regimens.
PubMed: Environmental exposure to pyrethroids and sperm sex chromosome disomy: a cross-sectional study.
PubMed: S-adenosyl-L-methionine usage during climacteric ripening of tomato in relation to ethylene and polyamine biosynthesis and transmethylation capacity.
PubMed: Targeted systems biology profiling of tomato fruit reveals coordination of the Yang cycle and a distinct regulation of ethylene biosynthesis during postclimacteric ripening.
PubMed: Ethylene supports colonization of plant roots by the mutualistic fungus Piriformospora indica.
PubMed: Thermal rearrangements of 1-ethynyl-2-methylcyclopropane: a computational study.
PubMed: Recombinant monoclonal antibody yield in transgenic tobacco plants is affected by the wounding response via an ethylene dependent mechanism.
PubMed: Suppression of 9-cis-epoxycarotenoid dioxygenase, which encodes a key enzyme in abscisic acid biosynthesis, alters fruit texture in transgenic tomato.
PubMed: Effects of abscisic acid on ethylene biosynthesis and perception in Hibiscus rosa-sinensis L. flower development.
PubMed: Use of homologous and heterologous gene expression profiling tools to characterize transcription dynamics during apple fruit maturation and ripening.
PubMed: Jasmonic acid and ethylene modulate local responses to wounding and simulated herbivory in Nicotiana attenuata leaves.
PubMed: Metabolism of procymidone derivatives in female rats.
PubMed: Transition state-finding strategies for use with the growing string method.
PubMed: Different lepidopteran elicitors account for cross-talk in herbivory-induced phytohormone signaling.
PubMed: Kinetic study of thermally stimulated dissociation of inclusion complex of 1-methylcyclopropene with alpha-cyclodextrin by thermal analysis.
PubMed: In vitro inhibition of food spoilage and foodborne pathogenic bacteria by essential oil and leaf extracts of Magnolia liliflora Desr.
PubMed: Chemical composition and antifungal activity of essential oil and various extract of Silene armeria L.
PubMed: Differential feedback regulation of ethylene biosynthesis in pulp and peel tissues of banana fruit.
PubMed: Analysis of the ambruticin and jerangolid gene clusters of Sorangium cellulosum reveals unusual mechanisms of polyketide biosynthesis.
PubMed: Postharvest variation in apple (Malus x domestica Borkh.) Flavonoids following harvest, storage, and 1-MCP treatment.
PubMed: Contrasting interactions between ethylene and abscisic acid in Rumex species differing in submergence tolerance.
PubMed: Searching for intermediates in the carbon skeleton rearrangement of 2-methyleneglutarate to (R)-3-methylitaconate catalyzed by coenzyme B12-dependent 2-methyleneglutarate mutase from Eubacterium barkeri.
PubMed: The Arabidopsis mutant eer2 has enhanced ethylene responses in the light.
PubMed: A GH3-like gene, CcGH3, isolated from Capsicum chinense L. fruit is regulated by auxin and ethylene.
PubMed: Six- and eightfold palladium-catalyzed cross-coupling reactions of hexa- and octabromoarenes.
PubMed: Strain energy of small ring hydrocarbons. Influence of C-h bond dissociation energies.
PubMed: 1-methylcyclopropene increases storability and shelf life in climacteric and nonclimacteric plums.
PubMed: Hepatic biotransformation of the new calcium-mimetic agent, RWJ-68025, in the rat and in man--API-MS/MS identification of metabolites.
PubMed: Ethylene rapidly up-regulates the activities of both monomeric GTP-binding proteins and protein kinase(s) in epicotyls of pea.
PubMed: Quantitative relationships between induced jasmonic acid levels and volatile emission in Zea mays during Spodoptera exigua herbivory.
PubMed: Ethylene biosynthesis in detached young persimmon fruit is initiated in calyx and modulated by water loss from the fruit.
PubMed: Regulation of root hair initiation and expansin gene expression in Arabidopsis.
PubMed: A convenient preparation of 2-fluoro-3-alkoxy-1,3-butadienes.
PubMed: Mechanistic insights into C-H activation from radical clock chemistry: oxidation of substituted methylcyclopropanes catalyzed by soluble methane monooxygenase from Methylosinus trichosporium OB3b.
PubMed: Regulation of programmed cell death in maize endosperm by abscisic acid.
PubMed: Herbivore-induced ethylene suppresses a direct defense but not a putative indirect defense against an adapted herbivore.
PubMed: Relationships between respiration, ethylene, and aroma production in ripening banana.
PubMed: Analysis of programmed cell death in wheat endosperm reveals differences in endosperm development between cereals.
PubMed: Differential expression and internal feedback regulation of 1-aminocyclopropane-1-carboxylate synthase, 1-aminocyclopropane-1-carboxylate oxidase, and ethylene receptor genes in tomato fruit during development and ripening.
PubMed: Expression and internal feedback regulation of ACC synthase and ACC oxidase genes in ripening tomato fruit.
PubMed: Effects of chilling on the expression of ethylene biosynthetic genes in Passe-Crassane pear (Pyrus communis L.) fruits.
PubMed: Pharmacokinetic analysis and antiepileptic activity of tetra-methylcyclopropane analogues of valpromide.
PubMed: Cytochrome P450-catalyzed hydroxylation of hydrocarbons: kinetic deuterium isotope effects for the hydroxylation of an ultrafast radical clock.
PubMed: Cytochrome P450 hydroxylation of hydrocarbons: variation in the rate of oxygen rebound using cyclopropyl radical clocks including two new ultrafast probes.
PubMed: Total synthesis of the racemic form of the second juvenile hormone (methyl 12-homojuvenate) from the cecropia silk moth.
PubMed: Methylcyclopropane; infrared absorption spectrum and synthesis from i-butyl chloride.
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