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Category: herbicides / pesticides
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless odorless gas (est) |
| Assay: | 95.00 to 100.00 %
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| Food Chemicals Codex Listed: | No |
Organoleptic Properties:
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| Odor and/or flavor descriptions from others (if found). |
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Cosmetic Information:
Suppliers:
Safety Information:
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| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
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| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
oral-guinea pig LD50 100 mg/kg Dow Chemical Company Reports.
oral-rat LD50 100 mg/kg "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revisionVol. 3, Pg. 15, 1976/1977.
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| Dermal Toxicity: |
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Not determined
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| Inhalation Toxicity: |
inhalation-mouse LCLo 1200 ppm/1H LUNGS, THORAX, OR RESPIRATION: CYANOSIS
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 34, Pg. 581, 1973.
inhalation-rabbit LCLo 5000 ppm/1H LUNGS, THORAX, OR RESPIRATION: CYANOSIS
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 34, Pg. 581, 1973.
inhalation-rat LC50 991 ppm/4H LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
LUNGS, THORAX, OR RESPIRATION: CYANOSIS Fundamental and Applied Toxicology. Vol. 7, Pg. 664, 1986.
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Safety in Use Information:
| Category: | herbicides / pesticides |
| Recommendation for sulfuryl fluoride usage levels up to: | | | not for fragrance use.
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| Recommendation for sulfuryl fluoride flavor usage levels up to: |
| | not for flavor use.
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Safety References:
| European Food Safety Authority (EFSA) reference(s): |
Modification of the existing MRLs for sulfuryl fluoride and fluoride ion in chestnuts View page or View pdf |
Retrospective analysis of the immunotoxic effects of plant protection products as reported in the Draft Assessment Reports for their peer review at EU level View page or View pdf |
Outcome of the consultation on confirmatory data used in risk assessment for sulfuryl fluoride View page or View pdf |
Review of the existing maximum residue levels for sulfuryl fluoride according to Article 12 of Regulation (EC) No 396/2005 View page or View pdf |
| EPI System: | View |
| NIOSH International Chemical Safety Cards: | search |
| NIOSH Pocket Guide: | search |
| Cancer Citations: | Search |
| Toxicology Citations: | Search |
| EPA Substance Registry Services (TSCA): | 2699-79-8 |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| Laboratory Chemical Safety Summary : | 17607 |
| National Institute of Allergy and Infectious Diseases: | Data |
| | sulfuryl difluoride |
| Chemidplus: | 0002699798 |
| EPA/NOAA CAMEO: | hazardous materials |
| RTECS: | 2699-79-8 |
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | EPA pesticide chemical code 078003 | | | fluoro de sulfurilo | | | fluorure de sulfuryle | | | HSDB 828 | | | sulfonyl fluoride | | | sulfur difluoride dioxide | | | sulfuric oxyfluoride | | | sulfuryl difluoride | | | sulfuryl fluoride [UN2191] [Poison gas] | | | sulphuryl difluoride | | | sulphuryl fluoride | | | sulphuryl fluoride [ISO] | | | vikane |
Articles:
| PubMed: | Controlling pests in dry-cured ham: A review. |
| PubMed: | Evaluation of Structural Treatment Efficacy against Tribolium castaneum and Tribolium confusum (Coleoptera: Tenebrionidae) Using Meta-Analysis of Multiple Studies Conducted in Food Facilities. |
| PubMed: | Exposure of Brown Recluse and Brown Widow Spiders (Araneae: Sicariidae, Theridiidae) to a Commercial Sulfuryl Fluoride Fumigation. |
| PubMed: | Evaluation of methyl bromide alternatives efficacy against soil-borne pathogens, nematodes and soil microbial community. |
| PubMed: | Evaluation of sorbent materials for the sampling and analysis of phosphine, sulfuryl fluoride and methyl bromide in air. |
| PubMed: | Susceptibility to sulfuryl fluoride and lack of cross-resistance to phosphine in developmental stages of the red flour beetle, Tribolium castaneum (Coleoptera: Tenebrionidae). |
| PubMed: | Fumigation of bed bugs (Hemiptera: Cimicidae): effective application rates for sulfuryl fluoride. |
| PubMed: | Sulfur(VI) fluoride exchange (SuFEx): another good reaction for click chemistry. |
| PubMed: | A chemical "hub" for absolute quantification of a targeted protein: orthogonal integration of elemental and molecular mass spectrometry. |
| PubMed: | Sulfonyl fluorides as alternative to sulfonyl chlorides in parallel synthesis of aliphatic sulfonamides. |
| PubMed: | Ascertaining the suitability of aryl sulfonyl fluorides for [18F]radiochemistry applications: a systematic investigation using microfluidics. |
| PubMed: | Decomposition treatment of SO2F2 using packed bed DBD plasma followed by chemical absorption. |
| PubMed: | Production, partial purification and characterization of protease from a phytopathogenic fungi Alternaria solani (Ell. and Mart.) Sorauer. |
| PubMed: | Broad-spectrum antimalarial activity of peptido sulfonyl fluorides, a new class of proteasome inhibitors. |
| PubMed: | Chemical proteomics with sulfonyl fluoride probes reveals selective labeling of functional tyrosines in glutathione transferases. |
| PubMed: | Efficacy of sulfuryl fluoride against the pinewood nematode, Bursaphelenchus xylophilus (Nematoda: Aphelenchidae), in Pinus pinaster boards. |
| PubMed: | Evaluation of sulfuryl fluoride as a soil fumigant in China. |
| PubMed: | Tribolium castaneum (Coleoptera: Tenebrionidae) associated with rice mills: fumigation efficacy and population rebound. |
| PubMed: | Sulfonyl fluoride analogues as activity-based probes for serine proteases. |
| PubMed: | Sulfonyl fluoride-based prosthetic compounds as potential 18F labelling agents. |
| PubMed: | Effectiveness of sulfuryl fluoride for control of different life stages of stored-product psocids (Psocoptera). |
| PubMed: | Europium-labeled activity-based probe through click chemistry: absolute serine protease quantification using (153)Eu isotope dilution ICP/MS. |
| PubMed: | Polyisoprenylation potentiates the inhibition of polyisoprenylated methylated protein methyl esterase and the cell degenerative effects of sulfonyl fluorides. |
| PubMed: | Synthesis and biological evaluation of novel irreversible serine protease inhibitors using amino acid based sulfonyl fluorides as an electrophilic trap. |
| PubMed: | Anomeric effects in sulfonyl compounds: an experimental and computational study of fluorosulfonyl azide, FSO(2)N(3), and trifluoromethylsulfonyl azide, CF(3)SO(2)N(3). |
| PubMed: | Sulfuryl fluoride as a quarantine treatment for emerald ash borer (Coleoptera: Buprestidae) in ash logs. |
| PubMed: | Environmental and health risks of sulfuryl fluoride, a fumigant replacement for methyl bromide. |
| PubMed: | Sulfuryl fluoride as a quarantine treatment for Chlorophorus annularis (Coleoptera: Cerambycidae) in Chinese bamboo poles. |
| PubMed: | Sulfuryl fluoride fumigation effects on the safety, volatile composition, and sensory quality of dry cured ham. |
| PubMed: | Reactive and nonreactive quenching of O(1D) by the potent greenhouse gases SO2F2, NF3, and SF5CF3. |
| PubMed: | Atmospheric chemistry of sulfuryl fluoride: reaction with OH radicals, Cl atoms and O3, atmospheric lifetime, IR spectrum, and global warming potential. |
| PubMed: | Experimental and theoretical study of the atmospheric chemistry and global warming potential of SO2F2. |
| PubMed: | Systemic fluoride poisoning and death from inhalational exposure to sulfuryl fluoride. |
| PubMed: | Sorption of sulfuryl fluoride by food commodities. |
| PubMed: | [Determination of sulfuryl fluoride and ethylene oxide in aerosol pesticide by GC]. |
| PubMed: | Evaluation of microwave irradiation for analysis of carbonyl sulfide, carbon disulfide, cyanogen, ethyl formate, methyl bromide, sulfuryl fluoride, propylene oxide, and phosphine in hay. |
| PubMed: | Lipid chain selectivity by outer membrane phospholipase A. |
| PubMed: | Sulfuryl fluoride as a quarantine treatment for Anoplophora glabripennis (Coleoptera: Cerambycidae) in regulated wood packing material. |
| PubMed: | A convenient preparation of heteroaryl sulfonamides and sulfonyl fluorides from heteroaryl thiols. |
| PubMed: | A scaled quantum mechanical force field for the sulfuryl halides II. The SO(2)XF (X=Cl, Br) halides. |
| PubMed: | Rapid uptake, metabolism, and elimination of inhaled sulfuryl fluoride fumigant by rats. |
| PubMed: | Convenient synthesis of fluorinated nucleosides with perfluoroalkanesulfonyl fluorides. |
| PubMed: | Alternatives to methyl bromide treatments for stored-product and quarantine insects. |
| PubMed: | Inhibition of lipoprotein lipase by alkanesulfonyl fluorides. |
| PubMed: | Centrifugal Distortion Analysis of a Near-Spherical Top, SO(2)F(2): The First Determination of All Six Quartic Centrifugal Distortion Constants for an Asymmetric Top. |
| PubMed: | Health effects associated with sulfuryl fluoride and methyl bromide exposure among structural fumigation workers. |
| PubMed: | Agreement between company-recorded and self-reported estimates of duration and frequency of occupational fumigant exposure. |
| PubMed: | Sulfonyl fluorides and the promotion of diisopropyl fluorophosphate neuropathy. |
| PubMed: | Residues of methyl bromide and sulfuryl fluoride in manufacturer-packaged household foods following fumigation. |
| PubMed: | Fluoride residues in frozen foods fumigated with sulfuryl fluoride. |
| PubMed: | The effects of inhalation exposure to sulfuryl fluoride on fetal development in rats and rabbits. |
| PubMed: | Inhalation toxicity of sulfuryl fluoride in rats and rabbits. |
| PubMed: | Subchronic neurotoxicity in rats of the structural fumigant, sulfuryl fluoride. |
| PubMed: | Desorption of residual sulfuryl fluoride from structural and household commodities by headspace analysis using gas chromatography. |
| PubMed: | Leads from the MMWR. Fatalities resulting from sulfuryl fluoride exposure after home fumigation--Virginia. |
| PubMed: | Fatalities resulting from sulfuryl fluoride exposure after home fumigation--Virginia. |
| PubMed: | Incapacitation and treatment of rats exposed to a lethal dose of sulfuryl fluoride. |
| PubMed: | Suicide by exposure to sulfuryl fluoride. |
| PubMed: | Neurobehavioral evaluation of soil and structural fumigators using methyl bromide and sulfuryl fluoride. |
| PubMed: | Carpet beetle dermatitis. |
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