sodium methoxide
methanol, sodium salt
 
Notes:
a colorless, flammable liquid used in the manufacture of formaldehyde and acetic acid, in chemical synthesis, antifreeze, and as a solvent. ingestion of methanol is toxic and may cause blindness.
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      SODIUM METHOXIDE
       
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      Product(s):
      S0486 Sodium Methoxide (ca. 5mol/L in Methanol)
       
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CAS Number: 124-41-4Picture of molecule3D/inchi
Other(deleted CASRN): 27419-20-1
ECHA EINECS - REACH Pre-Reg: 204-699-5
FDA UNII: IG663U5EMC
Nikkaji Web: J2.934C
Beilstein Number: 3592982
MDL: MFCD00012179
Molecular Weight: 54.02387928
Formula: C H3 Na O
NMR Predictor: Predict (works with chrome or firefox)
Category: pharmaceuticals / chemical synthisis
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
Google Books: Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Google Patents: Search
US Patents: Search
EU Patents: Search
Pubchem Patents: Search
PubMed: Search
NCBI: Search
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Physical Properties:
Appearance: white amorphous powder (est)
Assay: 95.00 to 100.00 % 
Food Chemicals Codex Listed: No
Boiling Point: 48.10 °C. @ 760.00 mm Hg (est)
Vapor Pressure: 265.000000 mmHg @ 25.00 °C. (est)
Flash Point: 52.00 °F. TCC ( 11.10 °C. ) (est)
logP (o/w): -0.719 (est)
Soluble in:
 water, 1e+006 mg/L @ 25 °C (est)
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Organoleptic Properties:
 
Odor and/or flavor descriptions from others (if found).
 
 
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Cosmetic Information:
None found
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Suppliers:
American Elements
Sodium Methoxide 99%
Odor: characteristic
Use: Sodium Methoxide is generally immediately available in most volumes. High purity, submicron and nanopowder forms may be considered. American Elements produces to many standard grades when applicable, including Mil Spec (military grade); ACS, Reagent and Technical Grade; Food, Agricultural and Pharmaceutical Grade; Optical Grade, USP and EP/BP (European Pharmacopoeia/British Pharmacopoeia) and follows applicable ASTM testing standards.
Charkit Chemical
SODIUM METHOXIDE
Covalent Chemical
Sodium Methoxide
ECSA Chemicals
SODIUM METHYLATE 30% SOLUTION IN METHANOL
ECSA TRADE THE MOST UPDATED FINANCIAL PUBLICATION ON THE WORLD OF CHEMISTRY
Glentham Life Sciences
Sodium methoxide
Penta International
SODIUM METHYLATE 25% ON METHANOL
Sigma-Aldrich
For experimental / research use only.
Sodium methoxide solution 25 wt. % in methanol
TCI AMERICA
For experimental / research use only.
Sodium Methoxide (ca. 5mol/L in Methanol)
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Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50  2037 mg/kg
SENSE ORGANS AND SPECIAL SENSES: CHROMODACYRORREA: EYE LUNGS, THORAX, OR RESPIRATION: DYSPNEA BEHAVIORAL: ATAXIA
National Technical Information Service. Vol. OTS0555267

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: pharmaceuticals / chemical synthisis
Recommendation for sodium methoxide usage levels up to:
 not for fragrance use.
 
Recommendation for sodium methoxide flavor usage levels up to:
 not for flavor use.
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Safety References:
EPI System: View
NIOSH International Chemical Safety Cards: search
AIDS Citations: Search
Cancer Citations: Search
Toxicology Citations: Search
EPA Substance Registry Services (TSCA): 124-41-4
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 10942334
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 1
 sodium;methanolate
Chemidplus: 0000124414
EPA/NOAA CAMEO: hazardous materials
RTECS: 124-41-4
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References:
 sodium;methanolate
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 124-41-4
Pubchem (cid): 10942334
Pubchem (sid): 134975215
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Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
HMDB (The Human Metabolome Database): Search
Export Tariff Code: 2931.90.9050
ChemSpider: View
Wikipedia: View
Formulations/Preparations:
•97.5% sodium methylate; 30% solution in methanol. •technical; and 98% purity grade.
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Potential Blenders and core components note
 
None Found
 
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Potential Uses:
None Found
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Occurrence (nature, food, other): note
 not found in nature
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Synonyms:
 feldalat NM
 methanol, sodium salt
 methoxysodium
 sodium methanolate
 sodium methylate
 sodium;methanolate
 sodiummethanolate
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Articles:
PubMed: Synthesis of linoleoyl ethanolamide.
PubMed: Effect of thermal heating on some lignans in flax seeds, sesame seeds and rye.
PubMed: A heteroleptic cyclometalated iridium(III) fluorophenylpyridine complex from partial defluorohydrogenation reaction: synthesis, photophysical properties and mechanistic insights.
PubMed: Effects of chemical interesterification on the physicochemical, microstructural and thermal properties of palm stearin, palm kernel oil and soybean oil blends.
PubMed: Optimization of sunflower oil transesterification process using sodium methoxide.
PubMed: Chemical interesterification of blends of palm stearin, coconut oil, and canola oil: physicochemical properties.
PubMed: Effect of chemical randomization on positional distribution and stability of omega-3 oil triacylglycerols.
PubMed: Modification of palm oil by chemical and enzyme catalyzed interesterification.
PubMed: Rapid and simple micromethod for the simultaneous determination of 3-MCPD and 3-MCPD esters in different foodstuffs.
PubMed: High yield and conversion of biodiesel from a nonedible feedstock (Pongamia pinnata).
PubMed: Hydrogenation and interesterification effects on the oxidative stability and melting point of soybean oil.
PubMed: Recommended methods of fatty acid methylester preparation for conjugated dienes and trienes in food and biological samples.
PubMed: Determination of c9,t11-CLA in major human plasma lipid classes using a combination of methylating methodologies.
PubMed: Genotypic variation in fatty acid content of blackcurrant seeds.
PubMed: Direct methylation procedure for converting fatty amides to fatty acid methyl esters in feed and digesta samples.
PubMed: Determination of lipids in infant formula powder by direct extraction methylation of lipids and fatty acid methyl esters (FAME) analysis by gas chromatography.
PubMed: Influence of the derivatization procedure on the results of the gaschromatographic fatty acid analysis of human milk and infant formulae.
PubMed: A qualitative colorimetric test for brominated vegetable oil in soft drinks.
PubMed: Evaluation and confirmation of an alkylation-gas-liquid chromatographic method for the determination of carbamate and urea herbicides in foods.
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