Articles:
2-propenoic acid, methyl ester
Notes:
Methyl acrylate is a contact allergen present in nail lacquer.; Methyl acrylate is a volatile alpha beta unsubstituted methyl ester used in the preparation of polyamidoamine (PAMAM) dendrimers typically by Michael addition with a primary amine.
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| CAS Number: | 96-33-3 |  3D/inchi
|
| ECHA EINECS - REACH Pre-Reg: | 202-500-6 | |
| FDA UNII: | WC487PR91H | |
| Nikkaji Web: | J3.967E | |
| Beilstein Number: | 0605396 | |
| MDL: | MFCD00008627 | |
| CoE Number: | 10759 | |
| XlogP3: | 0.80 (est) | |
| Molecular Weight: | 86.09022000 | |
| Formula: | C4 H6 O2 | |
| BioActivity Summary: | listing | |
| NMR Predictor: | Predict (works with chrome or firefox) | |
Category: food contact substances for use only as components of articles intended for repeated use
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Assay: | 98.00 to 100.00 % |
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.95600 to 0.95800 @ 20.00 °C. |
| Pounds per Gallon - (est).: | 7.964 to 7.981 |
| Refractive Index: | 1.40100 to 1.40400 @ 20.00 °C. |
| Boiling Point: | 80.00 to 81.00 °C. @ 760.00 mm Hg |
| Vapor Pressure: | 86.280998 mmHg @ 25.00 °C. (est) |
| Flash Point: | 44.00 °F. TCC ( 6.67 °C. ) |
| logP (o/w): | 0.800 |
| Soluble in: | |
| water, 49400 mg/L @ 25 °C (exp) | |
Organoleptic Properties:
| Odor and/or flavor descriptions from others (if found). | |
Cosmetic Information:
| None found |
Suppliers:
| Arkema |
| Methylacrylate
Odor: characteristic Use: It can be polymerized with each other and copolymerized with other monomers to produce polymers having the optimal properties for your application. |
| BASF |
| Methyl Acrylate |
| Covalent Chemical |
| Methyl Acrylate |
| Penta International |
| METHYL ACRYLATE |
| Shiva Chemicals and Pharmaceuticals |
| Methyl Acrylate |
| Sigma-Aldrich: Aldrich |
| For experimental / research use only. |
| Methyl acrylate 99%, contains =100 ppm monomethyl ether hydroquinone as inhibitor |
| Silver Fern Chemical |
| Methyl Acrylate (MA)
Odor: characteristic Use: MA is commonly used to make acrylic polymers, amphoteric surfactants, vitamin B1, and as a chemical intermediate. |
| TCI AMERICA |
| For experimental / research use only. |
| Methyl Acrylate (stabilized with MEHQ) >99.0%(GC) |
Safety Information:
| Preferred SDS: View | |
| Hazards identification | |
| Classification of the substance or mixture | |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |
| None found. | |
| GHS Label elements, including precautionary statements | |
| Pictogram | |
| Hazard statement(s) | |
| None found. | |
| Precautionary statement(s) | |
| None found. | |
| Oral/Parenteral Toxicity: | |
|
oral-rat LD50 277 mg/kg Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 36, Pg. 58, 1975. intraperitoneal-mouse LD50 254 mg/kg Journal of Dental Research. Vol. 51, Pg. 526, 1972. oral-mouse LD50 827 mg/kg Toxicology Letters. Vol. 11, Pg. 125, 1982. oral-rabbit LDLo 280 mg/kg LUNGS, THORAX, OR RESPIRATION: DYSPNEA BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: TREMOR Journal of Industrial Hygiene and Toxicology. Vol. 31, Pg. 317, 1949. intraperitoneal-rat LD50 325 mg/kg Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 36, Pg. 58, 1975. | |
| Dermal Toxicity: | |
|
skin-rabbit LD50 1243 mg/kg Journal of Industrial Hygiene and Toxicology. Vol. 30, Pg. 63, 1948. | |
| Inhalation Toxicity: | |
|
inhalation-rat LC50 1350 ppm/4H SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE LUNGS, THORAX, OR RESPIRATION: DYSPNEA Journal of Toxicology and Environmental Health. Vol. 16, Pg. 811, 1985. inhalation-human TCLo 75 ppm SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 75, 1969. inhalation-mouse LC50 12800 mg/m3 Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 23(9), Pg. 55, 1979. inhalation-rabbit LCLo 2522 ppm/1H BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: DYSPNEA GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS Journal of Industrial Hygiene and Toxicology. Vol. 31, Pg. 317, 1949. | |
Safety in Use Information:
| Category: | food contact substances for use only as components of articles intended for repeated use | ||
| Recommendation for methyl acrylate usage levels up to: | |||
| not for fragrance use. | |||
| Recommendation for methyl acrylate flavor usage levels up to: | |||
| not for flavor use. | |||
Safety References:
| EPI System: | View |
| EPA-Iris: | IRIS |
| NIOSH International Chemical Safety Cards: | search |
| NIOSH Pocket Guide: | search |
| Chemical Carcinogenesis Research Information System: | Search |
| AIDS Citations: | Search |
| Cancer Citations: | Search |
| Toxicology Citations: | Search |
| EPA GENetic TOXicology: | Search |
| EPA Substance Registry Services (TSCA): | 96-33-3 |
| EPA ACToR: | Toxicology Data |
| EPA Substance Registry Services (SRS): | Registry |
| Laboratory Chemical Safety Summary : | 7294 |
| National Institute of Allergy and Infectious Diseases: | Data |
| WGK Germany: | 2 |
| methyl prop-2-enoate | |
| Chemidplus: | 0000096333 |
| EPA/NOAA CAMEO: | hazardous materials |
| RTECS: | 96-33-3 |
References:
| methyl prop-2-enoate | |
| NIST Chemistry WebBook: | Search Inchi |
| Canada Domestic Sub. List: | 96-33-3 |
| Pubchem (cid): | 7294 |
| Pubchem (sid): | 134972380 |
Other Information:
| (IUPAC): | Atomic Weights of the Elements 2011 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| FDA Substances Added to Food (formerly EAFUS): | View |
| FDA Indirect Additives used in Food Contact Substances: | View |
| CHEBI: | View |
| CHEMBL: | View |
| KEGG (GenomeNet): | C19443 |
| HMDB (The Human Metabolome Database): | HMDB33977 |
| FooDB: | FDB012209 |
| Export Tariff Code: | 2916.12.5020 |
| ChemSpider: | View |
| Wikipedia: | View |
| Formulations/Preparations: •grades: technical (inhibited) •methyl acrylate available commercially in us has the following typical properties: purity, 98.9%; acidity (as acrylic acid), 0.0008%; water, 0.06%; inhibitor (hydroquinine monomethyl ether), 15, 200 or 1000 mgkg (ppm) ... •grades or purity: 99.9% •stabilized against polymerization with hydroquinone monomethyl ether or a similar inhibitor | |
Potential Blenders and core components note
| None Found | ||
Potential Uses:
| None Found |
Occurrence (nature, food, other): note
| not found in nature |
Synonyms:
| acrylic acid methyl ester | |
| acrylic acid, methyl ester | |
| methoxycarbonyl ethylene | |
| methoxycarbonylethylene | |
| methyl 2-propenoate | |
| methyl ester of acrylic acid | |
| methyl prop-2-enoate | |
| methyl propenate | |
| methyl propenoate | |
| methyl-2-propenoate | |
| methylacrylate | |
| 2- | propenoic acid methyl ester |
| 2- | propenoic acid, methyl ester |