metaldehyde
1,3,5,7-tetroxocane, 2,4,6,8-tetramethyl-
 
Notes:
polymer of acetaldehyde.
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CAS Number: 9002-91-9Picture of molecule3D/inchi
Nikkaji Web: J2.423F
MDL: MFCD00134115
XlogP3: 1.10 (est)
Formula: (C2 H4 O)x-
NMR Predictor: Predict (works with chrome or firefox)
Category: information only not used for fragrances or flavors
 
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Physical Properties:
Appearance: white crystalline solid (est)
Assay: 95.00 to 100.00 % 
Food Chemicals Codex Listed: No
Melting Point: 246.20 °C. @ 760.00 mm Hg (est)
Boiling Point: 194.30 °C. @ 760.00 mm Hg (est)
Vapor Pressure: 0.600000 mmHg @ 25.00 °C. (est)
Flash Point: 131.00 °F. TCC ( 55.00 °C. )
logP (o/w): 1.140 (est)
Soluble in:
 water, 4.536e+004 mg/L @ 25 °C (est)
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Organoleptic Properties:
 
Odor and/or flavor descriptions from others (if found).
 
 
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Cosmetic Information:
None found
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Suppliers:
Sigma-Aldrich: Sigma
For experimental / research use only.
Metaldehyde PESTANAL®, analytical standard
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Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-dog LD50  600 mg/kg
Pesticide Manual. Vol. 9, Pg. 556, 1991.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: information only not used for fragrances or flavors
Recommendation for metaldehyde usage levels up to:
 not for fragrance use.
 
Recommendation for metaldehyde flavor usage levels up to:
 not for flavor use.
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Safety References:
European Food Safety Authority (EFSA) reference(s):
Reasoned opinion on the review of the existing maximum residue levels (MRLs) for metaldehyde according to Article 12 of Regulation (EC) No 396/2005
View page or View pdf
Retrospective analysis of the immunotoxic effects of plant protection products as reported in the Draft Assessment Reports for their peer review at EU level
View page or View pdf
Modification of the existing maximum residue level for metaldehyde in leek
View page or View pdf
EPI System: View
Cancer Citations: Search
Toxicology Citations: Search
EPA Substance Registry Services (TSCA): 9002-91-9
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 61021
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 1
 2,4,6,8-tetramethyl-1,3,5,7-tetraoxocane
Chemidplus: 0009002919
EPA/NOAA CAMEO: hazardous materials
RTECS: AB3042000 for cas# 9002-91-9
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References:
 2,4,6,8-tetramethyl-1,3,5,7-tetraoxocane
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 9002-91-9
Pubchem (cid): 61021
Pubchem (sid): 135018300
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Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
CHEBI: View
CHEMBL: View
Metabolomics Database: Search
KEGG (GenomeNet): C18744
HMDB (The Human Metabolome Database): Search
Export Tariff Code: 2912.50.0000
ChemSpider: View
Wikipedia: View
Formulations/Preparations:
•corry's slug, snail & insect killer, get-a-bug snail, slug & insect killer : active ingredients 2.0%metaldehyde, 5.0% carbaryl •bug-geta snail & slug pellets: active ingredient 3.25% metaldehyde •durham metaldehyde granules 3.5: active ingredient 3.5% metaldehyde •corry's liquid slug & snail control, deadline bullets, deadline m-ps mini-pellets!, metaldehyde 4 bait, metarex 4% snail and slug bait: active ingredient 4.0% metaldehyde •durham metaldehyde granules 7.5: active ingredient 7.5% metaldehyde •slugit: active ingredient 20.0% metaldehyde •lonza meta metaldehyde technical molluscicide: active ingredient 99.0% metaldehyde •formulations: granules, pellets, minipellets, meal, paste, viscous liquid. •in the usa, metaldehyde formulations are limited to 4% concentrations and occasionally contain other toxic components (e.g., carbaryl, arsenates, and organophospates). european metaldehyde concentrations in molluscicides may reach 50% •antimilace •ariotox (sandoz) •cekumeta (cequisa) •deadline •halizan (tamogan) •helarion (fisons) •limax •limatox •limeol g •limovet •metason (jewnin-joffe) •mifaslug (farmers crop chemical) •namekil •slug baits (25-40 g aikg) in a protein-rich milling offal such as bran. •slug death •slugfest colloidel 25 •slugit •slug-tox •pelleted bait, granule, liquid, wettable powder; premixes: slug-n-snail plus (+ carbaryl)
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Potential Blenders and core components note
 
None Found
 
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Potential Uses:
None Found
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Occurrence (nature, food, other): note
 not found in nature
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Synonyms:
 acetaldehyde homopolymer
 antimilace
 ariotox
 corry's slug death
 ethanal tetramer
 farmon mini slug pellets
 halizan
 limax
 limovet
 metacetaldehyde
 metaldehyde [ISO] [BSI]
 metaldehyde [UN1332] [Flammable solid]
 metaldeide
 namekil
 polyacetaldehyde
 schneckokorn
 slug-tox
 slugfest
 slugit
2,4,6,8-tetramethyl-1,3,5,7-tetraoxacyclooctane
2,4,6,8-tetramethyl-1,3,5,7-tetraoxocane
2,4,6,8-tetramethyl-1,3,5,7-tetroxocane
1,3,5,7-tetroxocane, 2,4,6,8-tetramethyl-
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Articles:
PubMed: [Field evaluation of a novel plant molluscicide "Luo-wei" against Oncomelania hupensis snails II molluscicidal effect in the field of lake areas in Hanchuan City, Hubei Province].
PubMed: Researches and applications of the ultrasonic emulsifications and dispersions.
PubMed: [Molluscicidal effect and cost-effectiveness of suspension concentrate of metaldehyde and niclosamide in the field in Honghu City].
PubMed: Metaldehyde exposures.
PubMed: Control measures for slug and snail hosts of Angiostrongylus cantonensis, with special reference to the semi-slug Parmarion martensi.
PubMed: Pacific oyster (Crassostrea gigas) hemocyte are not affected by a mixture of pesticides in short-term in vitro assays.
PubMed: [Molluscicidal effect of WPN and MNSC on Lymnaea].
PubMed: Evaluation of a UV-light emitting diodes unit for the removal of micropollutants in water for low energy advanced oxidation processes.
PubMed: Reports of metaldehyde and iron phosphate exposures in animals and characterization of suspected iron toxicosis in dogs.
PubMed: The impact of background organic matter and alkalinity on the degradation of the pesticide metaldehyde by two advanced oxidation processes: UV/H₂O₂ and UV/TiO₂.
PubMed: [Molluscicidal effect of suspension concentrate of metaldehyde and niclosamide in fields of mountainous areas in Yunnan Province].
PubMed: Metaldehyde removal from aqueous solution by adsorption and ion exchange mechanisms onto activated carbon and polymeric sorbents.
PubMed: Death by caffeine: presumptive malicious poisoning of a dog by incorporation in ground meat.
PubMed: Comparison of UV/H2O2 and UV/TiO2 for the degradation of metaldehyde: Kinetics and the impact of background organics.
PubMed: Suspected metaldehyde slug bait poisoning in dogs: a retrospective analysis of cases reported to the Veterinary Poisons Information Service.
PubMed: Effects of granulated baits on meso and macrofauna in soybean soil system.
PubMed: Pesticide pressure and fish farming in barrage pond in Northeastern France Part I: site characterization and water quality.
PubMed: Surveillance. SAC C vs disease surveillance report. Cases of poisoning in Scottish cattle and sheep.
PubMed: Snails and slugs damaging the cut foliage, Cordyline fruticosa and use of biorationals towards their management.
PubMed: [Evaluation on molluscicidal effect of suspension concentrate of metaldehyde and niclosamide].
PubMed: Epileptic brain damage in dogs and cats: myth or reality?
PubMed: Effect of prolonged status epilepticus as a result of intoxication on epileptogenesis in a UK canine population.
PubMed: Molluscicidal activity of cardiac glycosides from Nerium indicum against Pomacea canaliculata and its implications for the mechanisms of toxicity.
PubMed: Residues and dissipation dynamics of molluscicide metaldehyde in cabbage and soil.
PubMed: Analysis of molluscicide metaldehyde in vegetables by dispersive solid-phase extraction and liquid chromatography-tandem mass spectrometry.
PubMed: Canine status epilepticus due to acute intoxication.
PubMed: Metaldehyde poisoning in a dairy herd.
PubMed: Five common toxins and activated charcoal: part 2.
PubMed: Determination of metaldehyde in human serum by headspace solid-phase microextraction and gas chromatography-mass spectrometry.
PubMed: Metaldehyde poisoning of dogs.
PubMed: Metaldehyde poisoning of dogs.
PubMed: Backbone cyclised peptides from plants show molluscicidal activity against the rice pest Pomacea canaliculata (golden apple snail).
PubMed: Self-poisoning with metaldehyde.
PubMed: Clinical, neurological and clinicopathological signs, treatment and outcome of metaldehyde intoxication in 18 dogs.
PubMed: Arsenic and metaldehyde toxicosis in a beef herd.
PubMed: Identification of environmental factors limiting plant uptake of metaldehyde seed treatments under field conditions.
PubMed: A laboratory-based comparison of a molluscicide and an alternative food source (red clover) as means of reducing slug damage to winter wheat.
PubMed: Acute metaldehyde poisoning in Taiwan.
PubMed: [Case report-fatal snail bait (metaldehyde) overdose presenting aspiration pneumonia].
PubMed: The effects of repeated applications of the molluscicide metaldehyde and the biocontrol nematode Phasmarhabditis hermaphrodita on molluscs, earthworms, nematodes, acarids and collembolans: a two-year study in north-west Spain.
PubMed: Thin layer chromatography convulsant screen extended by gas chromatography-mass spectrometry.
PubMed: Seed dressings to control slug damage in oilseed rape.
PubMed: Pesticide toxicosis in the horse.
PubMed: [Pesticide poisoning].
PubMed: Determination of metaldehyde in suspected cases of animal poisoning using gas chromatography-ion trap mass spectrometry.
PubMed: Adsorption effects of activated charcoal on metaldehyde toxicity in rats.
PubMed: Phenobarbital-type P-450 inducers protect rats against metaldehyde toxicity.
PubMed: Environmental impact of two molluscicides: niclosamide and metaldehyde in a rice paddy ecosystem.
PubMed: Inhibition of feeding responses by the molluscicide, metaldehyde.
PubMed: Metaldehyde toxicosis in ducklings.
PubMed: Ultrastructure and pyruvate formate-lyase radical quenching property of the multienzymic AdhE protein of Escherichia coli.
PubMed: Persistence of metaldehyde during acute molluscicide poisoning.
PubMed: Metaldehyde.
PubMed: Zoonoses and other findings in hedgehogs (Erinaceus europaeus): a survey of mortality and review of the literature.
PubMed: Biochemical studies on the terrestrial snail, Eubania vermiculata (Müller) treated with some pesticides.
PubMed: 4-week oral toxicity study of a combination of eight chemicals in rats: comparison with the toxicity of the individual compounds.
PubMed: Metaldehyde poisoning.
PubMed: Toxic pneumonitis in an adolescent following exposure to Snow Storm tablets.
PubMed: Toxicant adsorption on activated charcoal: is the fraction adsorbed a unique function of the charcoal:adsorbate ratio?
PubMed: The determination of volatile carbonyl compounds in diagnostic samples.
PubMed: Metaldehyde poisoning.
PubMed: Anaesthetic control for metaldehyde poisoning.
PubMed: Anaesthetic control for metaldehyde poisoning.
PubMed: Anaesthetic control for metaldehyde poisoning.
PubMed: An investigation of metaldehyde and acetaldehyde toxicities in dogs.
PubMed: Toxicity episodes involving agricultural chemicals and other substances in birds in Victoria, Australia.
PubMed: Epidemiological features of snail and slug bait poisoning in dogs and cats.
PubMed: Gas chromatographic analysis of metaldehyde in urine and plasma.
PubMed: Metaldehyde toxicity: a review.
PubMed: Practical toxicologic diagnosis.
PubMed: The determination of metaldehyde in biological material by head-space gas chromatography.
PubMed: The incidence and seasonal characteristics of veterinary toxicoses in Saskatchewan.
PubMed: Determination of metaldehyde in workroom air.
PubMed: Metaldehyde poisoning in horses.
PubMed: Anti-convulsant activity of diazepam and clonidine on metaldehyde-induced seizures in mice: effects on brain gamma-amino butyric acid concentrations and monoamine oxidase activity.
PubMed: Metaldehyde and paraquat poisoning.
PubMed: Metaldehyde poisoning from slug bait ingestion.
PubMed: Pesticide poisoning of livestock: a review of cases investigated.
PubMed: Metaldehyde residues on and in citrus fruits after a soil broadcast of a granular formulation and after a spray application to citrus trees.
PubMed: Pharmacological aspects of metaldehyde poisoning in mice.
PubMed: Metaldehyde poisoning.
PubMed: Metaldehyde: pet poisonings.
PubMed: Poisoning of animals in the Los Angeles area with pesticides during 1977.
PubMed: Metaldehyde poisoning in a dairy herd.
PubMed: Treatment of metaldehyde poisoning in dogs with megadoses of acepromazine maleate.
PubMed: [Poisoning with meta (metaldehyde) in a horse].
PubMed: Analysis of metaldehyde in cow blood samples.
PubMed: [Metaldehyde against terrestrial molluscs].
PubMed: Metaldehyde poisoning in cattle.
PubMed: Three cases of metaldehyde poisoning in cattle.
PubMed: Letter: Blindness associated with metaldehyde poisoning.
PubMed: Metaldehyde poisoning in three horses.
PubMed: Attempted suicide with a pesticide mixture.
PubMed: Long-tern toxicity and reproduction studies with metaldehyde in rats.
PubMed: [Reaction of metaldehyde with indoles].
PubMed: An outbreak of metaldehyde poisoning in sheep.
PubMed: [Materials for hygienic standardization of metaldehyde in the air of the working area].
PubMed: Letter: Toxicity of metaldehyde to dogs.
PubMed: The toxicity of the molluscicides metaldehyde and methiocarb to dogs.
PubMed: Gas chromatographic method for the analysis of metaldehyde in crop tissue.
PubMed: Metaldehyde poisoning in horses (two case reports).
PubMed: Technique of recording slug movement and some results of tests with metaldehyde and bran, and bran baits only.
PubMed: Thin layer chromatography of metaldehyde.
PubMed: [Acute poisonings and convulsive crises. Electroencephalographic study of 3 very different products: Rimifon, chloralose, metaldehyde].
PubMed: Metaldehyde poisoning in the dog.
PubMed: Danger to dogs of metaldehyde pellets.
PubMed: Metaldehyde poisoning in farm animals.
PubMed: [Toxicity of metaldehyde for the dog. Determination of DL50].
PubMed: [Metaldehyde poisoning on a bivouac].
PubMed: [Renal repercussions of metaldehyde poisoning; attempted pathogenetic interpretation].
PubMed: [Murder by metaldehyde poisoning].
PubMed: [Identification and determination of metaldehyde].
PubMed: The identification of metaldehyde by Koflers' micro method.
PubMed: [Toxicology of metaldehyde].
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