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Category: natural substances and extractives
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Assay: | 95.00 to 100.00 %
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| Food Chemicals Codex Listed: | No |
| Melting Point: | 204.50 °C. @ 760.00 mm Hg
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| Boiling Point: | 336.60 °C. @ 760.00 mm Hg (est)
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| Flash Point: | 341.00 °F. TCC ( 171.50 °C. ) (est)
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| logP (o/w): | 0.540 (est) |
| Soluble in: |
| | water, 2.63E+04 mg/L @ 18C (exp) | | | water, 6.99e+004 mg/L @ 25 °C (est) |
Organoleptic Properties:
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| Odor and/or flavor descriptions from others (if found). |
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Cosmetic Information:
Suppliers:
Safety Information:
| Preferred SDS: View |
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| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
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| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
intraperitoneal-mouse LDLo 500 mg/kg "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 6, Pg. 147, 1954.
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| Dermal Toxicity: |
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Not determined
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| Inhalation Toxicity: |
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Not determined
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Safety in Use Information:
| Category: | natural substances and extractives |
| Recommendation for mesaconic acid usage levels up to: | | | not for fragrance use.
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| Recommendation for mesaconic acid flavor usage levels up to: |
| | not for flavor use.
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Safety References:
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| 2- | butenedioic acid, 2-methyl-, (2E)- | | 2- | butenedioic acid, 2-methyl-, (E)- (9CI) | | | butenedioic acid, methyl-, (E)- | | | fumaric acid, methyl- | | | kyselina mesakonova | | trans-2- | methyl-2-butenedioic acid | | (E)-2- | methylbut-2-enedioic acid | | | methylfumaric acid | | 2- | methylfumaric acid | | trans-1- | propene-1,2-dicarboxylic acid |
Articles:
| PubMed: | Terahertz time-domain spectroscopy and the quantitative monitoring of mechanochemical cocrystal formation. |
| PubMed: | Studies on the coupling product between oxidation products derived from pentachlorophenol and cyclodextrins. |
| PubMed: | Plausible molecular mechanism for activation by fumarate and electron transfer of the dopamine beta-mono-oxygenase reaction. |
| PubMed: | Insights into enzyme evolution revealed by the structure of methylaspartate ammonia lyase. |
| PubMed: | The structure of 3-methylaspartase from Clostridium tetanomorphum functions via the common enolase chemical step. |
| PubMed: | Crystallization and preliminary X-ray analysis of Citrobacter amalonaticus methylaspartate ammonia lyase. |
| PubMed: | Overexpression, purification, crystallization and data collection of 3-methylaspartase from Clostridium tetanomorphum. |
| PubMed: | Synthesis and polymerization of benzyl (3R,4R)-3-methylmalolactonate via enzymatic preparation of the chiral precursor. |
| PubMed: | 3-Methylaspartate ammonia-lyase from a facultative anaerobe, strain YG-1002. |
| PubMed: | Purification and properties of crystalline 3-methylaspartase from two facultative anaerobes, Citrobacter sp. strain YG-0504 and Morganella morganii strain YG-0601. |
| PubMed: | Purification and properties of a novel cytochrome: flavocytochrome c from Shewanella putrefaciens. |
| PubMed: | Crystalline 3-methylaspartase from a facultative anaerobe, Escherichia coli strain YG1002. |
| PubMed: | Cloning, sequencing, and expression in Escherichia coli of the Clostridium tetanomorphum gene encoding beta-methylaspartase and characterization of the recombinant protein. |
| PubMed: | Mechanism of C-3 hydrogen exchange and the elimination of ammonia in the 3-methylaspartate ammonia-lyase reaction. |
| PubMed: | Primary deuterium isotope effects for the 3-methylaspartase-catalyzed deamination of (2S)-aspartic acid, (2S,3S)-3-methylaspartic acid, and (2S,3S)-3-ethylaspartic acid. |
| PubMed: | Reaction of argininosuccinase with bromomesaconic acid: role of an essential lysine in the active site. |
| PubMed: | Changing plasma and urinary organic acid levels in a patient with isovaleric acidemia during an attack. |
| PubMed: | New metabolites in isovaleric acidemia. |
| PubMed: | Gas chromatography-mass spectrometry of saturated and unsaturated dicarboxylic acids in urine. |
| PubMed: | Deamination of glumatic and aspartic acids by Geotrichum candidum. |
| PubMed: | The reaction of 1-vinylnaphthalene and 6-methoxy-1-vinylnaphthalene with citraconic anhydride, fumaric acid and mesaconic acid. |
| PubMed: | The reaction of anthracene with maleic and fumaric acid and their derivatives and with citraconic anhydride and mesaconic acid. |
| PubMed: | Note on the isolation of mesaconic acid from cabbage leaves. |
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