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Category: information only not used for fragrances or flavors
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless to pale yellow clear liquid (est) |
| Assay: | 95.00 to 100.00 %
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| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.75100 to 0.75700 @ 20.00 °C.
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| Pounds per Gallon - (est).: | 6.256 to 6.306
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| Refractive Index: | 1.37500 to 1.37800 @ 20.00 °C.
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| Boiling Point: | 35.50 °C. @ 760.00 mm Hg
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| Vapor Pressure: | 581.400000 mmHg @ 25.00 °C. (est) |
| Flash Point: | -50.00 °F. TCC ( -45.56 °C. )
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| logP (o/w): | 1.040 |
| Soluble in: |
| | water, 1.00E+04 mg/L @ 25 °C (exp) | | | water, 1.741e+004 mg/L @ 25 °C (est) |
Organoleptic Properties:
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| Odor and/or flavor descriptions from others (if found). |
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Cosmetic Information:
Suppliers:
Safety Information:
| Preferred SDS: View |
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| Hazards identification |
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| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
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| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
oral-rat LD50 8160 uL/kg American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.
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| Dermal Toxicity: |
skin-rabbit LD50 > 20 mL/kg Union Carbide Data Sheet. Vol. 11/15/1971
skin-rat LD50 > 20000 mg/kg GAF Material Safety Data Sheet.
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| Inhalation Toxicity: |
inhalation-mouse LC50 324000 mg/m3/15M BEHAVIORAL: GENERAL ANESTHETIC Anesthesiology. Vol. 11, Pg. 455, 1950.
inhalation-rat LCLo 16000 ppm/4H Journal of Industrial Hygiene and Toxicology. Vol. 31, Pg. 343, 1949.
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Safety in Use Information:
| Category: | information only not used for fragrances or flavors |
| Recommendation for ethyl vinyl ether usage levels up to: | | | not for fragrance use.
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| Recommendation for ethyl vinyl ether flavor usage levels up to: |
| | not for flavor use.
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Safety References:
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | ethene, ethoxy | | | ethenoxyethane | | | ethenyl ethyl ether | | | ether, vinyl ethyl | | | ethoxyethene | | 1- | ethoxyethene | | | ethoxyethylene | | 1- | ethoxyethylene | | | ethoxythylene | | | ethyl ethenyl ether | | | ethylvinylether | | | vinamar | | | vinyl ethyl ether | | | vinyl ethyl ether, inhibited [UN1302] [Flammable liquid] | | (( | vinyl)oxy)ethane |
Articles:
| US Patents: | 3,963,783 - 4-Methyl-8-vinyl-4,7- and -4,8-nonadienals |
| PubMed: | Concise and high-yield synthesis of T808 and T808P for radiosynthesis of [(18)F]-T808, a PET tau tracer for Alzheimer's disease. |
| US Patents: | 3,979,425 - Process for the preparation of unsaturated aldehydes |
| PubMed: | Diastereoselective synthesis of nitroso acetals from (S,E)-γ-aminated nitroalkenes via multicomponent [4 + 2]/[3 + 2] cycloadditions promoted by LiCl or LiClO4. |
| PubMed: | Substituent effects on oxidation-induced formation of quinone methides from arylboronic ester precursors. |
| PubMed: | Continuous-flow synthesis of monoarylated acetaldehydes using aryldiazonium salts. |
| PubMed: | tBu or not tBu? |
| PubMed: | Identification of epoxide functionalities in protonated monofunctional analytes by using ion/molecule reactions and collision-activated dissociation in different ion trap tandem mass spectrometers. |
| PubMed: | Quinone methide generation via photoinduced electron transfer. |
| PubMed: | Experimental and theoretical study of the 2-alkoxyethylidene rearrangement. |
| PubMed: | Absolute assignment of constitutional isomers via structurally diagnostic fragment ions: the challenging case of α- and β-acyl naphthalenes. |
| PubMed: | Dual reactivity of hydroxy- and methoxy- substituted o-quinone methides in aqueous solutions: hydration versus tautomerization. |
| PubMed: | α-Chloro-β,γ-ethylenic esters: enantiocontrolled synthesis and substitutions. |
| PubMed: | Photoarylation of alkenes and heteroaromatics by dibromo-BINOLs in aqueous solution. |
| PubMed: | Concise syntheses of (-)-galanthamine and (+/-)-codeine via intramolecular alkylation of a phenol derivative. |
| PubMed: | Quinone methides tethered to naphthalene diimides as selective G-quadruplex alkylating agents. |
| PubMed: | Reactions of an intramolecular frustrated Lewis pair with unsaturated substrates: evidence for a concerted olefin addition reaction. |
| PubMed: | Photochemical generation and the reactivity of o-naphthoquinone methides in aqueous solutions. |
| PubMed: | Selective arylation, alkenylation, and cyclization of dibromonaphthols, using visible light, via carbene intermediates. |
| PubMed: | Recognition and resolution of isomeric alkyl anilines by mass spectrometry. |
| PubMed: | Photolabile protection of alcohols, phenols, and carboxylic acids with 3-hydroxy-2-naphthalenemethanol. |
| PubMed: | Lewis acid-catalyzed intermolecular [4 + 2] cycloaddition of 3-alkoxycyclobutanones to aldehydes and ketones. |
| PubMed: | Au(I)-catalyzed efficient synthesis of functionalized bicyclo[3.2.0]heptanes. |
| PubMed: | Novel unsaturated sucrose ethers and their application as monomers. |
| PubMed: | Enantioselective 1,3-dipolar cycloaddition of nitrones with ethyl vinyl ether: the difference between Brønsted and Lewis acid catalysis. |
| PubMed: | Novel naphthalene diimides as activatable precursors of bisalkylating agents, by reduction and base catalysis. |
| PubMed: | A stereoselective synthesis of 6,6,6-trifluoro-L-daunosamine and 6,6,6-trifluoro-L-acosamine. |
| PubMed: | An efficient synthesis of novel pyrano[2,3-d]- and furopyrano[2,3-d]pyrimidines via indium-catalyzed multi-component domino reaction. |
| PubMed: | Kinetic study of the gas-phase reactions of OH and NO3 radicals and O3 with selected vinyl ethers. |
| PubMed: | Hydroxy-1-aminoindans and derivatives: preparation, stability, and reactivity. |
| PubMed: | Rate coefficients and equilibrium constant for the CH2CHO + O2 reaction system. |
| PubMed: | Catalytic enantioselective three-component hetero-[4+2] cycloaddition/allylboration approach to alpha-hydroxyalkyl pyrans: scope, limitations, and mechanistic proposal. |
| PubMed: | Building addressable libraries: spatially isolated, chip-based reductive amination reactions. |
| PubMed: | Reactions of the peroxo intermediate of soluble methane monooxygenase hydroxylase with ethers. |
| PubMed: | Inhibition of diethyl ether degradation in Rhodococcus sp. strain DEE5151 by glutaraldehyde and ethyl vinyl ether. |
| PubMed: | Generation of arylnitrenium ions by nitro-reduction and gas-phase synthesis of N-heterocycles. |
| PubMed: | CYP 17 and CYP 19 inhibitors. Evaluation of fluorine effects on the inhibiting activity of regioselectively fluorinated 1-(Naphthalen-2-ylmethyl)imidazoles. |
| PubMed: | Building addressable libraries: the use of electrochemistry for generating reactive Pd(II) reagents at preselected sites on a chip. |
| PubMed: | Mechanism and activity of ruthenium olefin metathesis catalysts: the role of ligands and substrates from a theoretical perspective. |
| PubMed: | Gas-phase reactions for selective detection of the explosives TNT and RDX. |
| PubMed: | A novel two-carbon homologation with N-vinylacetamides and ethyl vinyl ether as acetaldehyde anion equivalents in the synthesis of 9H-xanthene, 9H-thioxanthene, and 9,10-dihydro-9-acridine carboxaldehydes. |
| PubMed: | Exclusive formation of alpha-methyleneoxetanes in ketene-alkene cycloadditions. Evidence for intervention of both an alpha-methyleneoxetane and the subsequent 1,4-zwitterion. |
| PubMed: | Gas-phase polar [4+ + 2] cycloaddition with ethyl vinyl ether: a structurally diagnostic ion-molecule reaction for 2-azabutadienyl cations. |
| PubMed: | Catalyst-controlled inverse-electron-demand hetero-Diels-Alder reactions in the enantio- and diastereoselective synthesis of iridoid natural products. |
| PubMed: | Photochemistry of cyclic vicinal tricarbonyl compounds. Laser flash photolysis study of the reaction of indane-1,2,3-trione and its 5-methoxy derivative with olefins. |
| PubMed: | Regioselective photocycloaddition of pyridine derivatives to electron-rich alkenes. |
| PubMed: | A synthesis of the phenolic lipid, 3-[(Z)-pentadec-8-enyl] catechol, (15:1)-urushiol. |
| PubMed: | Uncatalyzed [4 + 2] cycloadditions of 3-nitrocoumarins with vinyl ethers in solventless conditions. A new entry to chromene derivatives. |
| PubMed: | Hetero-Diels-Alder reactions of alpha-aryl-beta-monohalo-alpha-nitrosoethylenes: diastereoselective synthesis of 6-substituted 3-aryl-4-halo-5,6-dihydro-4H-1,2-oxazines. |
| PubMed: | A Facile Access to Polycyclic Homo- and Heteroaromatic Hydrocarbons Based on the Ceric Ammonium Nitrate-Promoted Oxidative Addition of 3-Aryl-1-[(trimethylsilyl)oxy]cyclohexenes to Ethyl Vinyl Ether. |
| PubMed: | A New Cycloaddition Process Involving Nitro Group Participation in Polynitroaromatic Chemistry. |
| PubMed: | Regio- and endo-selective |
| PubMed: | New blocking method for the hydroxyl group on carbohydrate. Determination of the O-acylated position of the modified glycolipid. |
| PubMed: | Biocatalytic plastics as active and stable materials for biotransformations. |
| PubMed: | Ultrasound effects on photochemical reactions, part 1: photochemical reactions of ketones with alkenes. |
| PubMed: | Acid-Catalyzed Hydration of anti-Sesquinorbornene. |
| PubMed: | Reactivity of N-Phenyl-1-Aza-2-Cyano-1,3-Butadienes in the Diels-Alder Reaction. |
| PubMed: | Convenient Synthesis of Julolidines Using Benzotriazole Methodology. |
| PubMed: | Quality improvement of spray-dried, protein-loaded D,L-PLA microspheres by appropriate polymer solvent selection. |
| PubMed: | Fast atom bombardment tandem mass spectrometry employing ion-molecule reactions for the differentiation of phospholipid classes. |
| PubMed: | Comparative studies on the metabolism and mutagenicity of vinyl ethers. |
| PubMed: | The effect of anaesthetic agents on cerebral cortical responses in the rat. |
| PubMed: | The release of monovalent counterions by addition of divalent countemons to aqueous solutions of maleic acid copolymer. |
| PubMed: | Glycosides for testing glycosidases: vinyl, 1-ethoxyethyl, and 1-ethoxybut-3-enyl D-glucopyranosides. |
| PubMed: | Dielectric dispersion of alternating copolymers of maleic acid. |
| PubMed: | Sister chromatid exchanges induced by inhaled anesthetics. |
| PubMed: | Glucuronic acid conjugates of bilirubin-IXalpha in normal bile compared with post-obstructive bile. Transformation of the 1-O-acylglucuronide into 2-, 3-, and 4-O-acylglucuronides. |
| PubMed: | An investigation into the hepatic cytochrome P-450 catalysed metabolism of the anaesthetic fluroxene (2,2,2-trifluoroethyl vinyl ether). |
| PubMed: | Obstetrical anesthesia with ethyl vinyl ether and oxygen. |
| PubMed: | The anesthetic effects of ethyl vinyl ether, divinyl ether, and diethyl ether on mice. |
| PubMed: | Ethyl vinyl ether in dental anesthesia: preliminary study. |
| PubMed: | Ethyl vinyl ether: pharmacological and clinical evaluation. |
| PubMed: | Clinical and laboratory experience with ethyl vinyl ether. |
| PubMed: | Anesthesia; the anesthetic action of ethyl vinyl ether. |
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