iprovalicarb
carbamic acid, (1S)-2-methyl-1-1-(4-methylphenyl)ethylaminocarbonylpropyl-, 1-methylethyl ester
 
Notes:
a derivative of natural amino acid valine & carbamic acid; a fungicide.
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CAS Number: 140923-17-7Picture of molecule3D/inchi
Other: 1135443-12-7
FDA UNII: 94Q9V45M9B
MDL: MFCD04112614
XlogP3-AA: 3.70 (est)
Molecular Weight: 320.43276000
Formula: C18 H28 N2 O3
NMR Predictor: Predict (works with chrome or firefox)
Category: herbicides / pesticides
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
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Physical Properties:
Assay: 95.00 to 100.00 % 
Food Chemicals Codex Listed: No
Boiling Point: 497.80 °C. @ 760.00 mm Hg (est)
Flash Point: 491.00 °F. TCC ( 254.80 °C. ) (est)
logP (o/w): 3.560 (est)
Soluble in:
 water, 13.22 mg/L @ 25 °C (est)
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Organoleptic Properties:
 
Odor and/or flavor descriptions from others (if found).
 
 
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Cosmetic Information:
None found
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Suppliers:
Santa Cruz Biotechnology
For experimental / research use only.
Iprovalicarb ≥98%
Sigma-Aldrich
For experimental / research use only.
Iprovalicarb PESTANAL®, analytical standard
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Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: herbicides / pesticides
Recommendation for iprovalicarb usage levels up to:
 not for fragrance use.
 
Recommendation for iprovalicarb flavor usage levels up to:
 not for flavor use.
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Safety References:
European Food Safety Authority (EFSA) reference(s):
Conclusion on the peer review of the pesticide risk assessment of the active substance iprovalicarb
View page or View pdf
Outcome of the consultation with Member States, the applicant and EFSA on the pesticide risk assessment for iprovalicarb in light of confirmatory data
View page or View pdf
EPI System: View
Cancer Citations: Search
Toxicology Citations: Search
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 16212118
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 2
 propan-2-yl N-[(2R)-3-methyl-1-[1-(4-methylphenyl)ethylamino]-1-oxobutan-2-yl]carbamate
Chemidplus: 0140923177
RTECS: FC4755500 for cas# 140923-17-7
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References:
 propan-2-yl N-[(2R)-3-methyl-1-[1-(4-methylphenyl)ethylamino]-1-oxobutan-2-yl]carbamate
NIST Chemistry WebBook: Search Inchi
Pubchem (cid): 16212118
Pubchem (sid): 135211446
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Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
HMDB (The Human Metabolome Database): Search
ChemSpider: View
Wikipedia: View
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Potential Blenders and core components note
 
None Found
 
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Potential Uses:
None Found
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Occurrence (nature, food, other): note
 not found in nature
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Synonyms:
 carbamic acid, ((1S)-2-methyl-1-(((1-(4-methylphenyl)ethyl)amino)carbonyl)propyl)-, 1-methylethyl ester
 carbamic acid, (1S)-2-methyl-1-1-(4-methylphenyl)ethylaminocarbonylpropyl-, 1-methylethyl ester
 fencaramid
1-methylethyl ((1S)-2-methyl-1-(((1-(4-methylphenyl)ethyl)amino)carbonyl)propyl)carbamate
 nanogen code IPV, NIUS
 propan-2-yl N-[(2R)-3-methyl-1-[1-(4-methylphenyl)ethylamino]-1-oxobutan-2-yl]carbamate
isopropyl 2-methyl-1-{((RS)-1-p-tolylethyl)carbamoyl}-(S)-propylcarbamate
 SZX 0722
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Articles:
PubMed: Design, synthesis, and fungicidal activity of novel carboxylic acid amides represented by N-benzhydryl valinamode carbamates.
PubMed: Determination of fungicides in white grape bagasse by pressurized liquid extraction and gas chromatography tandem mass spectrometry.
PubMed: Finding of pesticides in fashionable fruit juices by LC-MS/MS and GC-MS/MS.
PubMed: Assessing the risk that Phytophthora melonis can develop a point mutation (V1109L) in CesA3 conferring resistance to carboxylic acid amide fungicides.
PubMed: Dissipation of fungicides in a vineyard soil amended with different spent mushroom substrates.
PubMed: Optimization of matrix solid-phase dispersion conditions for organic fungicides determination in soil samples.
PubMed: Residues behavior of some fungicides applied on two greenhouse tomato varieties different in shape and weight.
PubMed: Fate of iprovalicarb, indoxacarb, and boscalid residues in grapes and wine by GC-ITMS analysis.
PubMed: Solid-phase extraction followed by liquid chromatography quadrupole time-of-flight tandem mass spectrometry for the selective determination of fungicides in wine samples.
PubMed: Baseline sensitivity and resistance-risk assessment of Phytophthora capsici to iprovalicarb.
PubMed: Retention capacity of an organic bio-mixture against different mixtures of fungicides used in vineyards.
PubMed: Multi-residue analysis of 30 currently used pesticides in fine airborne particulate matter (PM 2.5) by microwave-assisted extraction and liquid chromatography-tandem mass spectrometry.
PubMed: Multiresidue determination of 11 new fungicides in grapes and wines by liquid-liquid extraction/clean-up and programmable temperature vaporization injection with analyte protectants/gas chromatography/ion trap mass spectrometry.
PubMed: Assessment of Iprovalicarb, a systemic fungicide in/on cabbage (Brassica oleracea var. capitata).
PubMed: Carbamates synergize the toxicity of acrinathrin in resistant western flower thrips (Thysanoptera: Thripidae).
PubMed: Chemical control of downy mildew on lettuce and basil under greenhouse.
PubMed: Differential Activity of Carboxylic Acid Amide Fungicides Against Various Developmental Stages of Phytophthora infestans.
PubMed: Accelerators increase permeability of cuticles for the lipophilic solutes metribuzin and iprovalicarb but not for hydrophilic methyl glucose.
PubMed: Development of an ELISA for the detection of the residues of the fungicide iprovalicarb.
PubMed: Liquid chromatographic determination of iprovalicarb in cabbage and soil.
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