cycloxydim
(+-)-2-(1-(ethoxyimino)butyl)-3-hydroxy-5-thian-3-cyclohex-2-enone
 
Notes:
None found
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CAS Number: 101205-02-1Picture of molecule3D/inchi
Other(deleted CASRN): 101062-69-5
FDA UNII: 9NJ0YM991I
Nikkaji Web: J94.769E
Beilstein Number: 8436332
MDL: MFCD01741622
XlogP3-AA: 3.70 (est)
Molecular Weight: 325.47179000
Formula: C17 H27 N O3 S
NMR Predictor: Predict (works with chrome or firefox)
Category: herbicides / pesticides
 
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Physical Properties:
Assay: 95.00 to 100.00 % 
Food Chemicals Codex Listed: No
Melting Point: 41.00 °C. @ 760.00 mm Hg
Soluble in:
 water, 40 mg/L @ 20 °C (exp)
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Organoleptic Properties:
 
Odor and/or flavor descriptions from others (if found).
 
 
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Cosmetic Information:
None found
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Suppliers:
Sigma-Aldrich
For experimental / research use only.
Cycloxydim PESTANAL®, analytical standard
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Safety Information:
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50  3940 mg/kg
Pesticide Manual. Vol. 9, Pg. 197, 1991.

Dermal Toxicity:
skin-rat LD50 > 4000 mg/kg
Pesticide Manual. Vol. 9, Pg. 197, 1991.

Inhalation Toxicity:
Not determined
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Safety in Use Information:
Category: herbicides / pesticides
Recommendation for cycloxydim usage levels up to:
 not for fragrance use.
 
Recommendation for cycloxydim flavor usage levels up to:
 not for flavor use.
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Safety References:
European Food Safety Authority (EFSA) reference(s):
Reasoned opinion on the modification of the existing MRLs for cycloxydim in various crops
View page or View pdf
Modification of the existing maximum residue level for cycloxydim in strawberries
View page or View pdf
Review of the existing maximum residue levels for cycloxydim according to Article 12 of Regulation (EC) No 396/2005
View page or View pdf
EPI System: View
AIDS Citations: Search
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EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 91765
National Institute of Allergy and Infectious Diseases: Data
WGK Germany: 3
 2-[1-(ethoxyamino)butylidene]-5-(thian-3-yl)cyclohexane-1,3-dione
Chemidplus: 0101205021
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References:
 2-[1-(ethoxyamino)butylidene]-5-(thian-3-yl)cyclohexane-1,3-dione
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 101205-02-1
Pubchem (cid): 91765
Pubchem (sid): 135049455
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Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
CHEBI: View
CHEMBL: View
KEGG (GenomeNet): C10913
HMDB (The Human Metabolome Database): Search
ChemSpider: View
Wikipedia: View
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Potential Blenders and core components note
 
None Found
 
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Potential Uses:
None Found
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Occurrence (nature, food, other): note
 not found in nature
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Synonyms:
 BAS 517
 BAS 517-02H
 BAS 51701H
 BAS 51704H
 BAS 517H
2-cyclohexen-1-one, 2-(1-(ethoxyimino)butyl)-3-hydroxy-5-(tetrahydro-2H-thiopyran-3-yl)-
2-[1-(ethoxyamino)butylidene]-5-(thian-3-yl)cyclohexane-1,3-dione
2-(1-(ethoxyimino)butyl)-3-hydroxy-5-(tetrahydro-2H-thiopyran-3-yl)-2-cyclohexen-1-one
(+-)-2-(1-(ethoxyimino)butyl)-3-hydroxy-5-thian-3-cyclohex-2-enone
 focus ultra
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Articles:
PubMed: Acute Toxic Effects of the Herbicide Formulation Focus(®) Ultra on Embryos and Larvae of the Moroccan Painted Frog, Discoglossus scovazzi.
PubMed: Effects of an environmentally relevant temporal application scheme of low herbicide concentrations on larvae of two anuran species.
PubMed: Acute toxic effects of the herbicide formulation and the active ingredient used in cycloxydim-tolerant maize cultivation on embryos and larvae of the African clawed frog, Xenopus laevis.
PubMed: Accelerated dissipation of the herbicide cycloxydim on wax films in the presence of the fungicide chlorothalonil and under the action of solar light.
PubMed: Part II: temporal and spatial distribution of multiclass pesticide residues in lake sediments of northern Greece: application of an optimized MAE-LC-MS/MS pretreatment and analytical method.
PubMed: HERBICIDE SENSITIVITY OF ECHINOCHLOA CRUS-GALLI POPULATIONS: A COMPARISON BETWEEN CROPPING SYSTEMS.
PubMed: A test of the potentialities of the APEX software (Aqueous Photochemistry of Environmentally occurring Xenobiotics). Modelling the photochemical persistence of the herbicide cycloxydim in surface waters, based on literature kinetic data.
PubMed: Photolysis of cycloxydim, a cyclohexanedione oxime herbicide. Detection, characterization and reactivity of the iminyl radical.
PubMed: Role of a novel I1781T mutation and other mechanisms in conferring resistance to acetyl-CoA carboxylase inhibiting herbicides in a black-grass population.
PubMed: A novel W1999S mutation and non-target site resistance impact on acetyl-CoA carboxylase inhibiting herbicides to varying degrees in a UK Lolium multiflorum population.
PubMed: Silky bent grass resistance to herbicides: one year of monitoring in Belgium.
PubMed: The presence of two different target-site resistance mechanisms in individual plants of Alopecurus myosuroides Huds., identified using a quick molecular test for the characterisation of six ALS and seven ACCase SNPs.
PubMed: Reactivity of cycloxydim toward singlet oxygen in solution and on wax film.
PubMed: Resistance to ACCase-inhibiting herbicides in the weed Lolium multiflorum.
PubMed: Detection of ACCase target-site resistant Alopecurus myosuroides Huds. (black-grass) in Belgian populations.
PubMed: Cross-resistance patterns to ACCase-inhibiting herbicides conferred by mutant ACCase isoforms in Alopecurus myosuroides Huds. (black-grass), re-examined at the recommended herbicide field rate.
PubMed: In vitro studies on the integrated control of rapeseed white stem rot disease through the application of herbicides and Trichoderma species.
PubMed: Uptake and modeling of pesticides by roots and shoots of parrotfeather (Myriophyllum aquaticum).
PubMed: Effects of water management and herbicide treatments on red rice control.
PubMed: PCR-based detection of resistance to acetyl-CoA carboxylase-inhibiting herbicides in black-grass (Alopecurus myosuroides Huds) and ryegrass (Lolium rigidum gaud).
PubMed: Resistance to ACCase-inhibiting herbicides and isoproturon in UK populations of Lolium multiflorum: mechanisms of resistance and implications for control.
PubMed: ["More is not better"--evaluation of toxicologic risks of the heavy metals, lead and cadmium, and the herbicides, linuron, fluazifop-P-butyl and cycloxydim in dried Chamomile flowers (Chamomilla recutita L. Rauschert)].
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