tert-butyl methyl ether
2-methoxy-2-methylpropane
 
Notes:
used to dissolve gallstones; gasoline additive. superlist note chemical remains on mtl because of additional testing actions (see oecd/sids listing)
  • ECSA Chemicals
    • ECSA Chemicals
      Human Chemistry
      ECSA Chemicals has been active since 1913 in the trading and international commerce of raw materials. With an organisation divided into industrial segments managed by specialists, it has become one of the largest distributors worldwide.
      ECSA Chemicals is the largest Swiss-owned company in terms of warehouses for the distribution of chemical products. We have been distributing chemical products for over 100 years and we have a special interest in protecting the environment and in the safety of our facilities and collaborators.
      Established in 1913 as a small grocery store, in its over 100 years of activity ECSA Chemicals has become one of the most important Swiss-owned distributors of chemical products. The company, which is active in international distribution and trading, is organised into industrial segments that are managed by teams of specialists and experts. They guarantee professional and customised consultancy and services. With our experience, we can rapidly and safely connect you with the best suppliers on the market, providing you with a complete search, consulting and assistance service. The focus of our approach and operations is you, our customers. We strive every day to find the best products that satisfy your needs as quickly as possible. Your satisfaction is our greatest success. WHY CHOOSE ECSA? EXPERIENCE We have been working for 100 years. QUALITY We have obtained many certifications (ISO, SQAS, GDP, Responsible Care, Bio-Inspecta, RSPO, etc.). We guarantee full compliance with the current laws and continuous training for our staff. SAFETY We constantly carry out risk analyses for each infrastructure, defining safety levels and implementing corrective measures promptly wherever they are needed. WIDESPREAD DISTRIBUTION We have warehouses in strategic locations to supply goods to Switzerland and to the rest of the world. STORAGE CAPACITY The 3 ECSA-owned warehouses guarantee considerable storage area and capacity in each warehouse, with full availability of products (base chemicals and speciality chemicals). SPEED Presence all over the country, staff dedicated to sourcing raw materials and considerable storage capacity guarantee that goods are rapidly obtained and supplied. CONSULTANCY Our specialists - in-depth knowledge of the market and products allows us to provide full consulting services, from the purchase to the supply of raw materials.
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      Product(s):
      MP-018135 METHYLTERBUTHYLETHER
      RE-528974 TERT-BUTYLMETHYLETHER RE - PURE 1 L
      RE-528970 ter-BUTYLMETHYLETHER RE - PURE L 5
       
  • Glentham Life Sciences
  • Penta International
    • Penta International Corporation
      Chemistry innovation
      At Penta, our products and services help businesses do business better.
      For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes.
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      Product(s):
      02-65800 TERT-BUTYL METHYL ETHER
       
  • TCI AMERICA
    • TCI AMERICA
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      Product(s):
      B0991 tert-Butyl Methyl Ether >99.0%(GC)
       
Synonyms   Articles   Notes   Search
CAS Number: 1634-04-4Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg: 216-653-1
FDA UNII: 29I4YB3S89
Nikkaji Web: J27.142J
Beilstein Number: 1730942
MDL: MFCD00008812
XlogP3: 0.90 (est)
Molecular Weight: 88.14984000
Formula: C5 H12 O
BioActivity Summary: listing
NMR Predictor: Predict (works with chrome or firefox)
Category: solvents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar: Search
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Physical Properties:
Appearance: colorless clear liquid (est)
Assay: 98.00 to 100.00 % 
Water Content: <0.05%
Food Chemicals Codex Listed: No
Melting Point: -109.00 °C. @ 760.00 mm Hg
Boiling Point: 55.20 °C. @ 760.00 mm Hg
Vapor Pressure: 250.000000 mmHg @ 25.00 °C.
Vapor Density: 3.1 ( Air = 1 )
Flash Point: -27.00 °F. TCC ( -32.78 °C. )
logP (o/w): 0.940
Soluble in:
 alcohol
 water, 5.10E+04 mg/L @ 25 °C (exp)
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Organoleptic Properties:
Odor Description:
minty
 
Odor and/or flavor descriptions from others (if found).
 
 
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Cosmetic Information:
CosIng: cosmetic data
Cosmetic Uses: solvents
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Suppliers:
ECSA Chemicals
METHYLTERBUTHYLETHER
ECSA TRADE THE MOST UPDATED FINANCIAL PUBLICATION ON THE WORLD OF CHEMISTRY
ECSA Chemicals
ter-BUTYLMETHYLETHER RE - PURE L 5
ECSA Chemicals
TERT-BUTYLMETHYLETHER RE - PURE 1 L
EMD Millipore
For experimental / research use only.
tert-Butyl Methyl Ether
Glentham Life Sciences
tert-Butylmethylether
Indis NV
For experimental / research use only.
Methyl Tertbutyl Ether (MTBE)
LyondellBasell Industries
methyl tertiary butyl ether
Penta International
TERT-BUTYL METHYL ETHER
Santa Cruz Biotechnology
For experimental / research use only.
tert-Butyl Methyl Ether ≥99%
Sigma-Aldrich
For experimental / research use only.
tert-Butyl Methyl Ether anhydrous, 99.8%
TCI AMERICA
For experimental / research use only.
tert-Butyl Methyl Ether >99.0%(GC)
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Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
Xi - Irritant
R 11 - Highly flammable.
R 38 - Irritating to skin.
S 02 - Keep out of the reach of children.
S 03/07/09 - Keep container tightly closed in cool, well-ventilated place.
S 16 - Keep away from sources of ignition - No Smoking.
S 24 - Avoid contact with skin.
S 33 - Take precautionary measures against static discharge.
S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
intraperitoneal-mouse LD50  1700 ul/kg
Zhonghua Yixue Zazhi. Chinese Medical Journal. Vol. 70, Pg. 172, 1990.

oral-mouse LD50  5960 ul/kg
Zhonghua Yixue Zazhi. Chinese Medical Journal. Vol. 70, Pg. 172, 1990.

oral-rat LD50  4000 mg/kg
National Technical Information Service. Vol. PB87-174603

intraperitoneal-rat LD  > 148 mg/kg
Journal of Surgical Research. Vol. 53, Pg. 572, 1992.

intravenous-rat LDLo  148 mg/kg
Journal of Surgical Research. Vol. 53, Pg. 572, 1992.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
inhalation-rat LC50 23576 ppm/4H
National Technical Information Service. Vol. PB87-174603

inhalation-mouse LC50 141000 mg/m3/15M
Zhonghua Yixue Zazhi. Chinese Medical Journal. Vol. 70, Pg. 172, 1990.

inhalation-mouse LC50 141000 mg/m3/15M
BEHAVIORAL: GENERAL ANESTHETIC
Anesthesiology. Vol. 11, Pg. 455, 1950.

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Safety in Use Information:
Category: solvents
Recommendation for tert-butyl methyl ether usage levels up to:
 not for fragrance use.
 
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Safety References:
EPI System: View
EPA-Iris: IRIS
NIOSH International Chemical Safety Cards: search
Chemical Carcinogenesis Research Information System: Search
AIDS Citations: Search
Cancer Citations: Search
Toxicology Citations: Search
Carcinogenic Potency Database: Search
EPA Substance Registry Services (TSCA): 1634-04-4
EPA ACToR: Toxicology Data
EPA Substance Registry Services (SRS): Registry
Laboratory Chemical Safety Summary : 15413
National Institute of Allergy and Infectious Diseases: Data
WISER: UN 2398
WGK Germany: 1
 2-methoxy-2-methylpropane
Chemidplus: 0001634044
EPA/NOAA CAMEO: hazardous materials
RTECS: 1634-04-4
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References:
 2-methoxy-2-methylpropane
NIST Chemistry WebBook: Search Inchi
Canada Domestic Sub. List: 1634-04-4
Pubchem (cid): 15413
Pubchem (sid): 134980021
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Other Information:
(IUPAC): Atomic Weights of the Elements 2011 (pdf)
Videos: The Periodic Table of Videos
tgsc: Atomic Weights use for this web site
(IUPAC): Periodic Table of the Elements
CHEBI: View
CHEMBL: View
UM BBD: Search
KEGG (GenomeNet): C11344
HMDB (The Human Metabolome Database): Search
Export Tariff Code: 2909.19.1800
ChemSpider: View
Wikipedia: View
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Potential Blenders and core components note
 
None Found
 
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Potential Uses:
None Found
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Occurrence (nature, food, other): note
 not found in nature
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Synonyms:
tert-butoxymethane
tert-butyl-methyl-ether
tert-butylmethyl ether
tert-butylmethylether
1,1-dimethylethyl methyl ether
 ether, t-butyl methyl
 ether, tert-butyl methyl
2-methoxy-2-methyl propane
2-methoxy-2-methylpropane
 methyl 1,1-dimethyl ethyl ether
 methyl 1,1-dimethylethyl ether
 methyl t-butyl ether
 methyl tert-butyl ether
 methyl tertiary butyl ether
 methyl tertiary-butyl ether
2-methyl-2-methoxypropane
 methyl-t-butyl ether
 methyl-tert-butyl ether
 methyltert-butylether
 MTBE
 propane, 2-methoxy-2-methyl-
 TBME
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Articles:
US Patents: 7,943,560 - Cyclopropanated macrocyclic ketones and lactones
PubMed: Methyl tert butyl ether is anti-angiogenic in both in vitro and in vivo mammalian model systems.
PubMed: [Determination of migration of 25 primary aromatic amines from food contact plastic materials by gas chromatography-mass spectrometry].
PubMed: High throughput identification and quantification of 16 antipsychotics and 8 major metabolites in serum using ultra-high performance liquid chromatography-tandem mass spectrometry.
PubMed: A fast isocratic liquid chromatography method for the quantification of xanthophylls and their stereoisomers.
PubMed: Health assessment of gasoline and fuel oxygenate vapors: micronucleus and sister chromatid exchange evaluations.
PubMed: Health assessment of gasoline and fuel oxygenate vapors: reproductive toxicity assessment.
PubMed: The effects of methyl tert-butyl ether (MTBE) on the male rat reproductive system.
PubMed: Determination and quantification of the emetic toxin cereulide from Bacillus cereus in pasta, rice and cream with liquid chromatography-tandem mass spectrometry.
PubMed: [Determination of the migration of bisphenol diglycidyl ethers from food contact materials by high performance chromatography-tandem mass spectrometry coupled with multi-walled carbon nanotubes solid phase extraction].
PubMed: On-line liquid chromatography-gas chromatography: A novel approach for the analysis of phytosterol oxidation products in enriched foods.
PubMed: A new, direct analytical method using LC-MS/MS for fatty acid esters of 3-chloro-1,2-propanediol (3-MCPD esters) in edible oils.
PubMed: Liquid chromatography-tandem mass spectrometric assay for aliskiren, a novel renin inhibitor in micro-volumes of human plasma: a pharmacokinetic application in healthy South Indian male subjects.
PubMed: Determination of ochratoxin A in baby food by immunoaffinity column cleanup with liquid chromatography: interlaboratory study.
PubMed: Rapid purification method for fumonisin B1 using centrifugal partition chromatography.
PubMed: Quantification of clenbuterol at trace level in human urine by ultra-high pressure liquid chromatography-tandem mass spectrometry.
PubMed: Tentative identification of torulene cis/trans geometrical isomers isolated from Sporidiobolus pararoseus by high-performance liquid chromatography-diode array detection-mass spectrometry and preparation by column chromatography.
PubMed: Evaluating the use of fatty acid profiles to differentiate human pathogenic and nonpathogenic Listeria species.
PubMed: High-resolution Orbitrap mass spectrometry for the analysis of carotenoids in tomato fruit: validation and comparative evaluation towards UV-VIS and tandem mass spectrometry.
PubMed: Urinary biomarkers of exposure and of oxidative damage in children exposed to low airborne concentrations of benzene.
PubMed: Fatty acid composition analysis in polysorbate 80 with high performance liquid chromatography coupled to charged aerosol detection.
PubMed: [Determination of lutein in infant formula milk powder using ultra-high performance liquid chromatography].
PubMed: Isolation of cyanidin 3-glucoside from blue honeysuckle fruits by high-speed counter-current chromatography.
PubMed: Development of a rapid method for the analysis of trenbolone, nortestosterone, and zeranol in bovine liver using liquid chromatography tandem mass spectrometry.
PubMed: [Determination of three estrogens in animal liver and kidney tissues by liquid chromatography-tandem mass spectrometry].
PubMed: Simple and fast HPLC method for simultaneous determination of retinol, tocopherols, coenzyme Q(10) and carotenoids in complex samples.
PubMed: Analysis of metronidazole in equine plasma using liquid chromatography/tandem mass spectrometry and high-resolution accurate mass spectrometry.
PubMed: Selective enrichment of phosphatidylcholines from food and biological matrices using metal oxides as solid-phase extraction materials prior to analysis by HPLC-ESI-MS/MS.
PubMed: Involvement of the cytochrome P450 system EthBAD in the N-deethoxymethylation of acetochlor by Rhodococcus sp. strain T3-1.
PubMed: A matrix effect-free method for reliable quantification of perfluoroalkyl carboxylic acids and perfluoroalkane sulfonic acids at low parts per trillion levels in dietary samples.
PubMed: Simultaneous analysis of antiretroviral drugs abacavir and tenofovir in human hair by liquid chromatography-tandem mass spectrometry.
PubMed: Analysis of (all-E)-lutein and its (Z)-isomers during illumination in a model system.
PubMed: Modified dispersive liquid-liquid microextraction followed by high-performance liquid chromatography for the determination of clenbuterol in swine urine.
PubMed: Separation and identification of anthocyanin extracted from mulberry fruit and the pigment binding properties toward human serum albumin.
PubMed: [Preparation of crocin from gardenia yellow pigment by slow rotary countercurrent chromatography].
PubMed: [Simultaneous determination of residues of six zeranols in eggs by high performance liquid chromatography with immunoaffinity cleanup column].
PubMed: An on-line normal-phase high performance liquid chromatography method for the rapid detection of radical scavengers in non-polar food matrixes.
PubMed: High-performance liquid chromatography/tandem mass spectrometry method for the determination of arbidol in human plasma.
PubMed: Application of pH-zone-refining countercurrent chromatography for the separation of indole alkaloids from Aspidosperma rigidum Rusby.
PubMed: Analytical separation of tea catechins and food-related polyphenols by high-speed counter-current chromatography.
PubMed: Migration of lubricants from food packagings. Screening for lipid classes and quantitative estimation using normal-phase liquid chromatographic separation with evaporative light scattering detection.
PubMed: New phenolic grape skin products from Vitis vinifera cv. Pinot Noir.
PubMed: Quantification of triamcinolone acetonide in ocular tissues after intravitreal injection to rabbit using liquid chromatography-tandem mass spectrometry.
PubMed: A validated bioanalytical method in mouse, rat, rabbit and human plasma for the quantification of one of the steroid glycosides found in Hoodia gordonii extract.
PubMed: [Simultaneous determination of stimulant, narcotics and antiestrogen in urine by gas chromatography-nitrogen phosphorous detection].
PubMed: Isolation of cytotoxic glucoerebrosides and long-chain bases from sea cucumber Cucumaria frondosa using high speed counter-current chromatography.
PubMed: Identification of six species in the new genus Cronobacter (Enterobacter sakazakii) from culture using gas chromatographic analysis of fatty acid methyl esters.
PubMed: [Determination of ten sedative residues in pork and kidney by ultra performance liquid chromatography-tandem mass spectrometry].
PubMed: Antimutagenic; differentiation-inducing; and antioxidative effects of fragrant ingredients in Katsura-uri (Japanese pickling melon; Cucumis melo var. conomon).
PubMed: [Determination of anabolic steroid hormones in animal muscle tissues by gas chromatography/mass spectrometry].
PubMed: Development of a faster determination of 10 anabolic steroids residues in animal muscle tissues by liquid chromatography tandem mass spectrometry.
PubMed: [Simultaneous determination of nine beta-agonist residues in animal derived foods by ultra performance liquid chromatography-tandem mass spectrometry].
PubMed: [Determination of eleven steroid hormones in animal muscle tissues and eggs using ultra-performance liquid chromatography-tandem mass spectrometry].
PubMed: Determination of phthalates in milk and milk products by liquid chromatography/tandem mass spectrometry.
PubMed: Separation of lac dye components by high-speed counter-current chromatography.
PubMed: Determination of 2-isopropyl thioxanthone and 2-ethylhexyl-4-dimethylaminobenzoate in milk: comparison of gas and liquid chromatography with mass spectrometry.
PubMed: Semi-industrial isolation of salicin and amygdalin from plant extracts using slow rotary counter-current chromatography.
PubMed: Developmental toxicity evaluation of methyl tertiary-butyl ether (MTBE) by inhalation in mice and rabbits.
PubMed: Rapid and cost-effective determination of acrylamide in coffee by planar chromatography and fluorescence detection after derivatization with dansulfinic acid.
PubMed: Exposure assessment of environmental organic chemicals at contaminated sites: a multicompartment modelling approach.
PubMed: Risk characterization of methyl tertiary butyl ether (MTBE) in tap water.
PubMed: Differentiation of Enterobacter sakazakii from closely related Enterobacter and Citrobacter species using fatty acid profiles.
PubMed: Current management of symptomatic gallstones.
PubMed: Teratology evaluation of methyl tertiary butyl ether in rats and mice.
PubMed: Evaluation of evidence for infection as a mode of action for induction of rat lymphoma.
PubMed: Rapid response of Arctic ringed seals to changes in perfluoroalkyl production.
PubMed: Compound-specific carbon isotope analysis of volatile organic compounds in the low-microgram per liter range.
PubMed: Biofuels bandwagon hits a rut.
PubMed: Determination of anabolic steroids in muscle tissue by liquid chromatography-tandem mass spectrometry.
PubMed: Normal-phase high-performance liquid chromatography of tocopherols and tocotrienols. Comparison of different chromatographic columns.
PubMed: Separation and purification of anthocyanins by high-speed countercurrent chromatography and screening for antioxidant activity.
PubMed: Isolation of hydroxycinnamoyltartaric acids from grape pomace by high-speed counter-current chromatography.
PubMed: Characterization of pigments from different high speed countercurrent chromatography wine fractions.
PubMed: Identification and quantification of carotenoids including geometrical isomers in fruit and vegetable juices by liquid chromatography with ultraviolet-diode array detection.
PubMed: Fractionation of grape anthocyanin classes using multilayer coil countercurrent chromatography with step gradient elution.
PubMed: Comparative fatty acid selectivity of lipases in esterification reactions with glycerol and diol analogues in organic media.
PubMed: Preparative separation of di- and trisulfonated components of Quinoline Yellow using affinity-ligand pH-zone-refining counter-current chromatography.
PubMed: Centrifugal precipitation chromatography -- a novel chromatographic system for fractionation of polymeric pigments from black tea and red wine.
PubMed: Analysis of xanthophylls in corn by HPLC.
PubMed: Preparative separation of isomeric 2-(2-quinolinyl)-1H-indene-1,3(2H)-dione monosulfonic acids of the color additive D&C Yellow No. 10 (quinoline yellow) by pH-zone-refining counter-current chromatography.
PubMed: Alternative methodology for the analysis of progesterone, testosterone, and epi-testosterone in bovine liver and veal muscle.
PubMed: Isolation of two anthocyanin sambubiosides from bilberry (Vaccinium myrtillus) by high-speed counter-current chromatography.
PubMed: Analysis of lycopene geometrical isomers in biological microsamples by liquid chromatography with coulometric array detection.
PubMed: Characterization of carotenoids in juice of red navel orange (Cara Cara).
PubMed: Thin-layer chromatographic detection of ivermectin in cattle serum.
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